CN107740273A - A kind of anti-ultraviolet finishing agent and preparation method thereof - Google Patents
A kind of anti-ultraviolet finishing agent and preparation method thereof Download PDFInfo
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- CN107740273A CN107740273A CN201710913832.6A CN201710913832A CN107740273A CN 107740273 A CN107740273 A CN 107740273A CN 201710913832 A CN201710913832 A CN 201710913832A CN 107740273 A CN107740273 A CN 107740273A
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- parts
- finishing agent
- ultraviolet finishing
- ultraviolet
- ethanol
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 70
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 63
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 53
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 101710130081 Aspergillopepsin-1 Proteins 0.000 claims abstract description 21
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 claims abstract description 21
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 21
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 21
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001540 sodium lactate Substances 0.000 claims abstract description 20
- 229940005581 sodium lactate Drugs 0.000 claims abstract description 20
- 235000011088 sodium lactate Nutrition 0.000 claims abstract description 20
- 239000000344 soap Substances 0.000 claims abstract description 16
- YKXCWZVUWWQSAV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O YKXCWZVUWWQSAV-BTVCFUMJSA-N 0.000 claims abstract description 15
- BSYNRYMUTXBXSQ-FOQJRBATSA-N 59096-14-9 Chemical compound CC(=O)OC1=CC=CC=C1[14C](O)=O BSYNRYMUTXBXSQ-FOQJRBATSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 235000019441 ethanol Nutrition 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 14
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 claims description 9
- 229960001138 acetylsalicylic acid Drugs 0.000 claims description 9
- 238000007664 blowing Methods 0.000 claims description 7
- 238000005538 encapsulation Methods 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000008103 glucose Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 2
- ZZUUMCMLIPRDPI-UHFFFAOYSA-N 2-hydroxypropanoic acid;sodium Chemical compound [Na].CC(O)C(O)=O ZZUUMCMLIPRDPI-UHFFFAOYSA-N 0.000 claims 1
- -1 glucose lipid Chemical class 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000011787 zinc oxide Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 206010015150 Erythema Diseases 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000321 erythema Toxicity 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 201000009030 Carcinoma Diseases 0.000 description 1
- 206010056474 Erythrosis Diseases 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 208000007442 rickets Diseases 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of anti-ultraviolet finishing agent and preparation method thereof, the anti-ultraviolet finishing agent is made up of the raw material of following parts by weight：5 10 parts of PEPA, 10 20 parts of acetylsalicylic acid, 35 parts of acetic acid, 10 20 parts of ethylene glycol, 5 10 parts of Tea Polyphenols, 35 parts of sodium lactate, 35 parts of glucose sodium soap, 57 parts of nano zine oxide, 10 15 parts of ethanol, 12 parts of triethanolamine.After the anti-ultraviolet finishing agent application fabric of the present invention, the ultraviolet ray transmissivity of fabric is no more than 2%.The anti-ultraviolet finishing agent manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and human body is not stimulated, and volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of anti-ultraviolet finishing agent and its preparation side
Method.
Background technology
It is ultraviolet that ultraviolet (ultraviolet rays abbreviation UV) is divided into long wave ultraviolet (UV-A, 320-400nm), medium wave
Line (UV-B, 280-320nm) and short wave ultraviolet (UV-C, 200-280nm).UV-B effect is 1000 times of UV-A, summer
Mildew mainly due to UV-B effect, veins beneath the skin absorb UV-B after can cause expansion make erythrosis produce erythema, sternly
It can be inflamed during weight.It can also equally have influence on subcutaneous elastomer, skin is followed the string, and form coarse wrinkle,
UB-C has certain bactericidal action as a kind of stronger ultraviolet, but also harmful.Generally speaking, ultraviolet C can not
Ground is reached, but due to the raising of fluorinated volume in air in recent years, the UV-B and C for reaching ground are consequently increased.According to the study
Show, appropriate ultraviolet is beneficial to human body：It can promote the synthesis of vitamin D, have inhibitory action to rickets, and have
There is sterilization.But excessive ultraviolet is extremely harmful to human body, and it can not only increase human body melanin, make skin
Skin aging, it is serious skin is got blister, erythema, or even can also cause cutaneum carcinoma.
Anti-uv finishing is by strengthening fabric to the reflection of the absorbability of ultraviolet or enhancing fabric to ultraviolet
Ability reduces the transit dose of ultraviolet.After anti-uv finishing, ultraviolet is absorbed fabric by fabric, therefore passes through fabric
Ultraviolet quantity be greatly reduced, have good protective action to human body.Arranged by ultra-violet absorber, the light of fiber is old
Change, the fastness to light of dyed fabric also can all substantially improve, so protective action is many, purposes is also many-sided.
The transmitance of the fabric ultraviolet by anti-uv finishing in the market is 3% or so, washing fastness
Difference, therefore a kind of high-performance of searching, water-fastness anti-ultraviolet finishing agent are current urgent problems.
The content of the invention
It is an object of the invention to provide a kind of anti-ultraviolet finishing agent and preparation method, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical scheme：
A kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 5-10 parts, acetyl water
Poplar acid 10-20 parts, acetic acid 3-5 parts, ethylene glycol 10-20 parts, Tea Polyphenols 5-10 parts, sodium lactate 3-5 parts, glucose sodium soap 3-
5 parts, nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts.
Preferably, the ethanol in described anti-ultraviolet finishing agent is absolute ethyl alcohol, and purity is pure to analyze.
Preferably, described anti-ultraviolet finishing agent, according to parts by weight, including following components：5 parts of PEPA,
10 parts of acetylsalicylic acid, 3 parts of acetic acid, 10 parts of ethylene glycol, 5 parts of Tea Polyphenols, 3 parts of sodium lactate, glucose sodium soap 3 part, nanometer
5 parts of zinc oxide, 10 parts of ethanol, 1 part of triethanolamine.
Preferably, described anti-ultraviolet finishing agent, according to parts by weight, including following components：8 parts of PEPA,
15 parts of acetylsalicylic acid, 4 parts of acetic acid, 15 parts of ethylene glycol, 8 parts of Tea Polyphenols, 4 parts of sodium lactate, glucose sodium soap 4 part, nanometer
6 parts of zinc oxide, 13 parts of ethanol, 1.5 parts of triethanolamine.
Preferably, described anti-ultraviolet finishing agent, according to parts by weight, including following components：10 parts of PEPA,
20 parts of acetylsalicylic acid, 5 parts of acetic acid, 20 parts of ethylene glycol, 10 parts of Tea Polyphenols, 5 parts of sodium lactate, glucose sodium soap 5 part, nanometer
7 parts of zinc oxide, 15 parts of ethanol, 2 parts of triethanolamine.
A kind of preparation method of anti-ultraviolet finishing agent, is comprised the following steps that：
(1) ethylene glycol 10-20 parts are added in a kettle, and rise temperature is to 60-70 DEG C；
(2) PEPA 5-10 parts, acetylsalicylic acid 10-20 parts are added, 500-1000 revs/min, stirring 20-30 divides
Clock；
(3) first by nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts, with ultrasonic disperse, ultrasonic power
For 500-1000W, ultrasonic time is 20-30 minutes；
(4) solution of step (3) is added in the solution of step (2), 500-1000 revs/min, 10-20 points of stirring
Clock；
(5) 20-35 DEG C is cooled to, adds acetic acid 3-5 parts, Tea Polyphenols 5-10 parts, sodium lactate 3-5 parts, glucose aliphatic acid
Sodium 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, after anti-ultraviolet finishing agent application fabric of the invention, the ultraviolet ray transmissivity of fabric is no more than 2%.
2nd, anti-ultraviolet finishing agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic
It is harmless, human body is not stimulated, volatility is low, the fabric after arrangement its toughness, color and luster, feel, intensity and color fastness substantially not by
Influence.
3rd, mutual compatibility, synergy, collectively constituting property between various raw materials used in anti-ultraviolet finishing agent of the invention
The excellent product of energy.
4th, anti-ultraviolet finishing agent of the invention absorbs the wave-length coverage broadness of ultraviolet, works well.
5th, anti-ultraviolet finishing agent of the invention is water-fastness and dry-cleans, and to light, thermally and chemically product are stable.
6th, anti-ultraviolet finishing agent of the invention is in application process, absorb not yellowing after ultraviolet, do not produce it is poisonous
Gas or solid matter.
7th, technique is simplified, safe operation is simple, is easy to industrialized production.
8th, anti-ultraviolet finishing agent construction is simple of the invention, can by impregnating, spraying, roller coat etc. applied, it is raw
Efficiency is produced to improve.
9th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 5-
10 parts, acetylsalicylic acid 10-20 parts, acetic acid 3-5 parts, ethylene glycol 10-20 parts, Tea Polyphenols 5-10 parts, sodium lactate 3-5 parts, grape
Sugar fatty acid sodium 3-5 parts, nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts.
Present invention also offers a kind of preparation method of anti-ultraviolet finishing agent, comprise the following steps that：
(1) ethylene glycol 10-20 parts are added in a kettle, and rise temperature is to 60-70 DEG C；
(2) PEPA 5-10 parts, acetylsalicylic acid 10-20 parts are added, 500-1000 revs/min, stirring 20-30 divides
Clock；
(3) first by nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts, with ultrasonic disperse, ultrasonic power
For 500-1000W, ultrasonic time is 20-30 minutes；
(4) solution of step (3) is added in the solution of step (2), 500-1000 revs/min, 10-20 points of stirring
Clock；
(5) 20-35 DEG C is cooled to, adds acetic acid 3-5 parts, Tea Polyphenols 5-10 parts, sodium lactate 3-5 parts, glucose aliphatic acid
Sodium 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 5
Part, 10 parts of acetylsalicylic acid, 3 parts of acetic acid, 10 parts of ethylene glycol, 5 parts of Tea Polyphenols, 3 parts of sodium lactate, 3 parts of glucose sodium soap, receive
5 parts of zinc oxide of rice, 10 parts of ethanol, 1 part of triethanolamine.
Present invention also offers a kind of preparation method of anti-ultraviolet finishing agent, comprise the following steps that：
(1) 10 parts of ethylene glycol is added in a kettle, and rise temperature is to 60 DEG C；
(2) 5 parts of PEPA, 10 parts of acetylsalicylic acid are added, 800 revs/min, is stirred 20 minutes；
(3) first by 5 parts of nano zine oxide, 10 parts of ethanol, 1 part of triethanolamine, with ultrasonic disperse, ultrasonic power 500W,
Ultrasonic time is 20 minutes；
(4) solution of step (3) is added in the solution of step (2), 500 revs/min, stirred 10 minutes；
(5) it is cooled to 20 DEG C, adds 3 parts of acetic acid, 5 parts of Tea Polyphenols, 3 parts of sodium lactate, 3 parts of glucose sodium soap, 800
Rev/min, stir 20 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 8
Part, 15 parts of acetylsalicylic acid, 4 parts of acetic acid, 15 parts of ethylene glycol, 8 parts of Tea Polyphenols, 4 parts of sodium lactate, 4 parts of glucose sodium soap, receive
6 parts of zinc oxide of rice, 13 parts of ethanol, 1.5 parts of triethanolamine.
Present invention also offers a kind of preparation method of anti-ultraviolet finishing agent, comprise the following steps that：
(1) 15 parts of ethylene glycol is added in a kettle, and rise temperature is to 65 DEG C；
(2) 8 parts of PEPA, 15 parts of acetylsalicylic acid are added, 800 revs/min, is stirred 25 minutes；
(3) first by 6 parts of nano zine oxide, 13 parts of ethanol, 1.5 parts of triethanolamine, with ultrasonic disperse, ultrasonic power is
800W, ultrasonic time are 25 minutes；
(4) solution of step (3) is added in the solution of step (2), 800 revs/min, stirred 15 minutes；
(5) it is cooled to 28 DEG C, adds 4 parts of acetic acid, 8 parts of Tea Polyphenols, 4 parts of sodium lactate, 4 parts of glucose sodium soap, 800
Rev/min, stir 25 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 10
Part, 20 parts of acetylsalicylic acid, 5 parts of acetic acid, 20 parts of ethylene glycol, 10 parts of Tea Polyphenols, 5 parts of sodium lactate, 5 parts of glucose sodium soap,
7 parts of nano zine oxide, 15 parts of ethanol, 2 parts of triethanolamine.
Present invention also offers a kind of preparation method of anti-ultraviolet finishing agent, comprise the following steps that：
(1) 20 parts of ethylene glycol is added in a kettle, and rise temperature is to 70 DEG C；
(2) 10 parts of PEPA, 20 parts of acetylsalicylic acid are added, 1000 revs/min, is stirred 30 minutes；
(3) first by 7 parts of nano zine oxide, 15 parts of ethanol, 2 parts of triethanolamine, with ultrasonic disperse, ultrasonic power 1000W,
Ultrasonic time is 30 minutes；
(4) solution of step (3) is added in the solution of step (2), 1000 revs/min, stirred 20 minutes；
(5) it is cooled to 35 DEG C, adds 5 parts of acetic acid, 10 parts of Tea Polyphenols, 5 parts of sodium lactate, 5 parts of glucose sodium soap, 1000
Rev/min, stir 30 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of anti-ultraviolet finishing agent, according to parts by weight, including following components：PEPA 5
Part, 20 parts of acetylsalicylic acid, 5 parts of acetic acid, 20 parts of ethylene glycol, 10 parts of Tea Polyphenols, 3 parts of sodium lactate, 3 parts of glucose sodium soap,
6 parts of nano zine oxide, 10 parts of ethanol, 2 parts of triethanolamine.
Present invention also offers a kind of preparation method of anti-ultraviolet finishing agent, comprise the following steps that：
(1) 20 parts of ethylene glycol is added in a kettle, and rise temperature is to 70 DEG C；
(2) 5 parts of PEPA, 20 parts of acetylsalicylic acid are added, 1000 revs/min, is stirred 20 minutes；
(3) first by 6 parts of nano zine oxide, 10 parts of ethanol, 2 parts of triethanolamine, with ultrasonic disperse, ultrasonic power 1000W,
Ultrasonic time is 20 minutes；
(4) solution of step (3) is added in the solution of step (2), 800 revs/min, stirred 20 minutes；
(5) it is cooled to 30 DEG C, adds 5 parts of acetic acid, 10 parts of Tea Polyphenols, 3 parts of sodium lactate, 3 parts of glucose sodium soap, 800
Rev/min, stir 20 minutes；
(6) stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；
(7) stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Test case
4 pieces of identical fabrics are put into the anti-ultraviolet finishing agent solution of embodiment 1,2,3,4 and padded, by two leachings two
Roll, then heat to 100-110 DEG C of prebake, then dried at 130-150 DEG C, then cleaned with 50 DEG C of hot water, finally use cold water
Rinse, dried after cleaning, 4 pieces of cloth with ultraviolet resistance can be obtained.Test result is as follows：
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
- A kind of 1. anti-ultraviolet finishing agent, it is characterised in that：The anti-ultraviolet finishing agent includes the raw material of following parts by weight： PEPA 5-10 parts, acetylsalicylic acid 10-20 parts, acetic acid 3-5 parts, ethylene glycol 10-20 parts, Tea Polyphenols 5-10 parts, lactic acid Sodium 3-5 parts, glucose sodium soap 3-5 parts, nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts.
- 2. anti-ultraviolet finishing agent according to claim 1, it is characterised in that：The ethanol is absolute ethyl alcohol, and purity is Analyze pure.
- 3. anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including following components： 5 parts of PEPA, 10 parts of acetylsalicylic acid, 3 parts of acetic acid, 10 parts of ethylene glycol, 5 parts of Tea Polyphenols, 3 parts of sodium lactate, glucose lipid 3 parts of fat acid sodium, 5 parts of nano zine oxide, 10 parts of ethanol, 1 part of triethanolamine.
- 4. anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including following components： 8 parts of PEPA, 5 parts of acetylsalicylic acid, 4 parts of acetic acid, 15 parts of ethylene glycol, 8 parts of Tea Polyphenols, 4 parts of sodium lactate, glucose fat Sour 4 parts of sodium, 6 parts of nano zine oxide, 13 parts of ethanol, 1.5 parts of triethanolamine.
- 5. anti-ultraviolet finishing agent according to claim 1, it is characterised in that：According to parts by weight, including following components： 10 parts of PEPA, 20 parts of acetylsalicylic acid, 5 parts of acetic acid, 20 parts of ethylene glycol, 10 parts of Tea Polyphenols, 5 parts of sodium lactate, glucose 5 parts of sodium soap, 7 parts of nano zine oxide, 15 parts of ethanol, 2 parts of triethanolamine.
- A kind of 6. preparation method of any described anti-ultraviolet finishing agent in 1-5 using the claims, it is characterised in that： Comprise the following steps that：Step 1, ethylene glycol 10-20 parts are added in a kettle, and rise temperature is to 60-70 DEG C；Step 2, PEPA 5-10 parts, acetylsalicylic acid 10-20 parts are added, 500-1000 revs/min, stirring 20-30 divides Clock；Step 3, first by nano zine oxide 5-7 parts, ethanol 10-15 parts, triethanolamine 1-2 parts, with ultrasonic disperse, ultrasonic power is 500-1000W, ultrasonic time are 20-30 minutes；Step 4, the solution of step 3 is added in the solution of step 2,500-1000 revs/min, stirs 10-20 minutes；Step 5,20-35 DEG C is cooled to, adds acetic acid 3-5 parts, Tea Polyphenols 5-10 parts, sodium lactate 3-5 parts, glucose sodium soap 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；Step 6, stirring is closed down, the liquid anti-ultraviolet finishing agent prepared；Step 7, stand and be cooled in stirred tank liquid anti-ultraviolet finishing agent and be less than 20 DEG C, blowing encapsulation, finished product.
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Cited By (1)
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