CN107735112B - 将皮肤有益剂施加于吸收性物品的方法 - Google Patents
将皮肤有益剂施加于吸收性物品的方法 Download PDFInfo
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- CN107735112B CN107735112B CN201680039463.6A CN201680039463A CN107735112B CN 107735112 B CN107735112 B CN 107735112B CN 201680039463 A CN201680039463 A CN 201680039463A CN 107735112 B CN107735112 B CN 107735112B
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Abstract
将皮肤有益剂施加于吸收性物品的方法,所述吸收性物品包括具有面向身体表面和面向衣服表面的顶片层,所述物品具有纵向前部、纵向后部和位于前部和后部之间的裆部。所述方法至少包括通过在线同步印刷技术在物品上印刷包括粘合剂和微胶囊化皮肤有益剂的水基油墨组合物的步骤,所述皮肤有益剂至少是部分疏水性的或亲脂性物质或添加剂,微胶囊材料在20℃时不溶于水。
Description
技术领域
本公开涉及将皮肤有益剂施加于吸收性物品的方法。
背景技术
诸如卫生巾和卫生护垫的吸收性物品有时包括着色区域以突出物品的各个部分,例如在物品的裆部中的吸收芯位置。在组装物品之前或期间,可将油墨印刷在物品的顶片材料或任何其它材料或层上。可以向物品中加入局部添加剂,如乳液,以便为物品的使用者提供皮肤状况益处。可以通过连续喷雾或挤出方法或通过印刷来施加乳液的添加(US2011/0264065)。
需要一种改进的将添加剂施加到吸收性物品的方法,特别是高成本的皮肤有益剂。
发明内容
本发明涉及根据权利要求1的方法和根据权利要求15的吸收性物品,提供了一种新的改进的施加方法和包括皮肤有益剂的物品。
因此,所述方法涉及一种将皮肤有益剂施加于吸收性物品的方法,所述吸收性物品包括具有面向身体表面和面向衣服表面的顶片层,所述物品具有纵向前部、纵向后部和位于前部和后部之间的裆部。所述方法至少需要借助于在线同步印刷技术,在所述物品上印刷包含粘合剂和微胶囊化皮肤有益剂的水基油墨组合物的步骤,所述皮肤有益剂是至少部分疏水性或亲脂性物质或添加剂,且微胶囊材料在20℃时不溶于水。
吸收性物品因此包括具有面向身体表面和面向衣服表面的顶片层,所述物品具有纵向前部、纵向后部和位于前部和后部之间的裆部,并且其中所述物品具有水基油墨组合物,所述油墨组合物包括通过在线同步印刷技术在物品上印刷的粘合剂和微囊化皮肤有益剂,所述皮肤有益剂为至少部分疏水性或亲脂性物质或添加剂,并且所述微胶囊材料在20℃不溶于水。
以时间和成本高效、多功能和方便的方式将皮肤有益剂加入到物品中。由于在相同的组合物和一个工艺步骤中将油墨和皮肤有益剂一起添加的较少的机器操作,所需的机械加工消耗的空间更少且投资成本更低。
由于皮肤有益剂恰好应用在物品上的正确位置,皮肤有益制剂的成本降低。在施加阶段,皮肤有益剂被保护免受油墨组合物的影响。由于在物品的使用期间皮肤有益剂从微胶囊缓慢释放,对使用者的益处也增加。传统的施加方法导致制剂从施加时暴露出来,并且制剂散布在物品的大表面积上。
附图说明
图1是具有油墨组合物的卫生巾的俯视图,所述油墨组合物包括施加于其顶片材料的微胶囊化皮肤有益剂;
图2是具有油墨组合物的尿布的俯视图,所述油墨组合物包括施加于其顶片材料的微胶囊化皮肤有益剂。
具体实施方式
如本文所用,“皮肤有益剂”是本领域技术人员已知的具有可能影响、改善或维持皮肤或粘膜健康状态的性质的物质或制剂。特别地,皮肤有益剂将带来除香味或气味之外的功能。该功能可以是皮肤的物理刺激,例如增加血液循环、保持细胞在皮肤中的自然平衡或者通过增加保湿作用,摄取维生素或通过皮肤或粘膜分配药物。该功能可以是在基底上的物理变化,使得吸收性物品上将具有更亲肤的微环境和/或提供基底材料的改善的功能,例如阻挡物以将体液保持在吸收性物品上。该功能可以是导致物理感觉的化学反应,例如感觉到的冷却或加热效应。
该制剂的皮肤有益功能可以因该物品的穿着者使皮肤或粘液与皮肤有益剂接触而被激活。
皮肤有益剂至少是部分疏水性或亲脂性物质或添加剂。皮肤有益剂因此可以至少部分与疏水性物质混溶。皮肤有益剂在20℃时可能不溶于水。
皮肤有益剂可以选自油、脂肪或蜡或者是这些中的任何的混合物或衍生物。皮肤有益剂可以来自天然来源。
皮肤有益剂可以选自植物、草本、水果、种子、香料和油的提取物。
所述皮肤有益剂可以选自以下任何物质或是以下任何物质的提取物:杏仁油、摩洛哥坚果油、芝麻籽油、霍霍巴油、葡萄籽油、乳木果油、橄榄油、椰子油、鳄梨油、柠檬烯、芳樟醇、香叶醇、柠檬醛、香豆素、木槿、薰衣草、金盏花、洋甘菊、薄荷、檀香、桃、芒果、杏、沙棘、咖啡、巧克力、薄荷醇、木糖醇。
皮肤有益剂还可以选自氨甲酰脲、甘油、聚二甲基硅氧烷、生育酚(维生素E)、抗坏血酸(维生素C)、尿囊素、百里酚、水杨酸盐。
皮肤有益剂也可以是天然皮肤有益剂的合成等价物。
如本文所用,“吸收性物品”是指选自卫生巾、卫生护垫、失禁垫、失禁尿布、带式尿布、婴儿尿布或卫生棉条的物品。
该油墨组合物至少包括粘合剂和微胶囊化皮肤有益剂。除了具有皮肤有益剂的微胶囊之外,油墨组合物可以是本领域技术人员已知的标准配方。油墨组合物是水基的。油墨组合物可以包括有色颜料或染料或是无色的。油墨还可以包括本领域技术人员熟知的典型印刷添加剂,例如溶剂、助溶剂和加工助剂。溶剂可以包括醇、酯、醛和水以及其他。粘合剂可以是,但不限于,基于苯乙烯、丙烯酸酯、乙酸酯、烷基化物、聚氨酯、硝化纤维素或其它纤维素衍生物、聚乙二醇、聚乙烯醇缩丁醛、聚乙烯醇、聚乙烯吡咯烷酮及其衍生物或混合物的聚合物、树脂、乳液和混合物。成分,例如,分散剂、表面活性剂、润湿助剂、消泡剂、抗泡剂、蜡、硅氧烷、粘度调节剂、pH调节剂、防滑剂和防腐剂也可以与一种或多种胶囊化的有益添加剂一起存在于油墨配方中。油墨组合物中的粘合剂确保油墨硬化,并保持包含微胶囊在内的油墨定位在材料上。
微胶囊的尺寸可以是至少1μm、或者至少3μm、或者至少10μm,并且可以小于100μm、或者小于70μm、或者小于30μm。微胶囊的尺寸可以是1-100μm、或者1-70μm、或者3-30μm。
皮肤有益剂以微胶囊的形式加入,使得包封的添加剂从周围介质中被封闭,即当施加到吸收性物品的材料上时的印刷油墨。可以通过完全包封不相容的流体(例如水基油墨中的油),通过非渗透性或半渗透性不溶于水的壁或通过将添加剂结合不溶于水的基质来实现封闭。
添加剂的微胶囊化技术已知用于其它用途,例如化妆品。生产这种微胶囊的公司的实例是Devan Chemicals,比利时;Encapsys,美国;Micro Capsule Technologies,法国;和Robert Blondel,法国。
微胶囊化可以通过在水包油乳液中的乳液聚合来进行以形成乳液、分散体或干粉。典型的壳材料包括聚合物、三聚氰胺和硅基组合物。微胶囊材料可以是硅酮和三聚氰胺聚合物的复合物。微胶囊材料在20℃时不溶于水。
皮肤有益剂是微胶囊化的并且可以作为乳液、分散体或作为粉加入到油墨组合物中。所得油墨组合物中微胶囊的浓度和施加到吸收性物品上的油墨组合物的量可由本领域技术人员通过常规实验来确定,并针对每种特定用途进行配制。微胶囊的浓度取决于使用的有益剂和物品的期望效果。施加到吸收性物品上的油墨的量将取决于油墨的组成和物品上所需的图案。所需的油墨量也可以根据表面吸收性而变化。
物品上的微胶囊浓度可以为至少0.001g/m2、或者至少0.01g/m2、或者至少0.1g/m2、或者至少0.05g/m2并且低于5g/m2、或低于1.0g/m2或低于0.6g/m2。物品上的微胶囊浓度可以是0.001-5g/m2、或者0.01-1g/m2或0.05-0.6g/m2。
该皮肤有益剂可以施加在物品的0.1-40%的面积上,例如0.1-25%、如大于物品的0.1%并小于10%、或者大于物品的0.1%并小于5%。
皮肤有益剂的微胶囊包封的优点在于,否则与油墨不相容的制剂可作为微胶囊加入并适当地分散。另一个优点是,在物品的使用过程中,制剂的释放是逐渐的,并且固有气味,如果有的话,在制造操作中以及在架子上将减少。
通过在吸收性物品上印刷来施加油墨组合物。对于印刷,我们在此意指任何种类的精确施加流体以在基底上形成涂层或其他干燥层。对于精确,我们的意思是,介质将被定位在基板上的指定区域,而不是以控制不良的方式,例如当使用喷涂或挤出技术时。该印刷可以是接触式的,例如选自柔版印刷、丝网印刷、胶版印刷、轮转凹版印刷或非接触式的、例如选自数字喷墨,其可以是连续的或按需滴落的、由压电形成的间歇滴落的、热活化的或其他类型的技术。
指定区域可以是通过在线同步印刷精确定位皮肤有益添加剂在产品上的功能区域,以使产品上的特定添加剂达到最佳性能,即在其中物质将是最有效的,例如,在产品的最有利的部分。
通过在线同步印刷技术施加油墨组合物,允许油墨组合物的精确定位。
在线同步印刷的步骤可以作为制造吸收性物品的过程中的步骤而被结合,或者可以在组装产品之前将这些层在线同步印刷。
在吸收性物品上施加油墨之后,任何溶剂将蒸发,使得油墨几乎瞬间干燥。然而,可以添加干燥步骤,例如在印刷表面上吹热空气。
油墨组合物可以根据需要并以任何期望的图案应用于选定区域。本方法允许非常准确的图案和细线和点形成。
当布置在吸收性物品中时,顶片具有面向身体的表面和面向衣服的表面。油墨组合物可以施加于所述表面中的一个或两个。通过在面向身体的表面上施加油墨组合物,使用者获得对皮肤有益剂的直接接近。通过在面向衣服表面上提供油墨,获得对于某些应用可能需要的较慢的微胶囊的活化和释放。皮肤有益剂也可以施加于物品的中间层。
取决于油墨的位置,可以获得各种有利的功能效果。以下给出具有不同功能的油墨图案的实例。这些图案可以单独使用,但是当然可以有利地组合以实现吸收性物品的期望特性。
油墨组合物可以作为沿着纵向侧边的至少一部分的一个或多个液体屏障来施加,该液体屏障可以由连续线或虚线形成。此外,油墨组合物的点群可以被施加在物品的中央部分。
微胶囊化有益剂可以印刷在选自以下区域的物品的区域或地带上:
-沿裆部的纵向侧边;
-裆部的中央区域;
-前部的中央区域;
-后部的中央区域。
吸收性物品可以进一步包括从物品的每个纵向侧边延伸的翼部,并且可以将微胶囊化的皮肤有益剂印刷在所述翼部的区域上。
印刷区域或地带可以是具有椭圆形、圆形、月亮形、心形、箭头形状等的区域或地带,并定位在产品的特定区域中以提供独特的功能。
吸收性物品包括至少一个顶片层,并且如果需要,还包括一个底片层和一个设置在顶片和底片层之间的吸收层。
吸收性物品的每一层具有面向衣服表面和面向身体表面,并且该油墨可以被施加到任何所述表面上。油墨组合物可以被添加到位于顶片下方的中间层(例如采集层)中。
本发明还涉及具有印刷在其上的包括微胶囊化皮肤有益剂的油墨组合物的吸收性物品。
吸收性物品可以包括非织造物、薄膜或其层压体或泡沫体的面向身体的顶片、以及液体不可渗透的聚合物膜材料或膜和无纺材料的层压体的底片、以及包括纸浆和/或超吸收性材料和/或纤维幅的吸收层。
底片材料可以是透气的或不透气的。在使用期间,底片与使用者背离,并且与吸收性物品的面向身体的顶片层相反。紧固装置可以被施加在底片的面向衣服侧上,其可以被防粘纸或单个包装物覆盖。
微胶囊的活化可以通过机械活化来进行,其中胶囊通过剪切力或接触时的压力破碎。由于使用者的动作,各微球将破裂。并非所有的微胶囊会同时破裂,因为一些微胶囊可能会被进一步埋在材料中,因此在使用该物品的过程中将会缓慢、持续和有益地释放该制剂。因此可以达到长期的效果。
相比于当添加剂例如作为顶片上的纺丝油剂的成分,以所谓的鸡尾酒(cocktail)的方式施加时(该方式通常由非织造物供应商使用),通过印刷的施加允许精确地将精致的印刷图案定位在物品上的选定的区域中。为了进一步提高益处,印刷与在任何产品上的印刷的精确的在线定位(同步)相结合。这使印刷品能够定位在区域或地带中,即产品的特定功能区域中。通过这种方式,皮肤有益成分将仅施加在印刷区域,从而使定制区域的数量和可能性更小。印刷的在线同步和微胶囊化皮肤有益剂还允许通过在油墨组合物中包括颜料或染料来掩蔽皮肤有益剂的污渍(如果有的话)。包封的皮肤有益剂在施加到物品上的过程中和之后被良好地保护免受油墨组合物中的另外的成分的影响。
现在将参照附图通过实施例的方式来描述本公开。
图1显示了一种卫生巾且图2显示了一种尿布,分别具有油墨组合物,该油墨组合物包括通过印刷施加到该物品的顶片上的微胶囊化皮肤有益剂。该物品具有细长的形状,其具有纵向前部、纵向后部以及位于前部和后部之间的中央部或裆部。图1中的物品具有从物品的每个纵向侧边延伸的翼。通过在线同步印刷技术将油墨组合物印刷在物品的区域或地带中。这些区域是以下印刷区域:物品的翼和侧部上(a)、在物品的裆部的中央(b)、物品的后部(c)以及物品的前部(d)。将油墨组合物印刷在润湿区域(1)中、在后部(5、6)的前部(2、3、4)中以及沿着物品的纵向侧部(7、8)以及在翼部(9)。
包括一种或多种皮肤有益添加剂的印刷品可以施加在产品的不同层中。在上面的实例中印刷顶片,但是也可以印刷中间层、芯或采集层、或底片、胶粘部分、包装或防粘纸。在产品的同一层上并且也在产品的不同层上可能有多于一个印刷区域,其具有相同或不同的印刷有益添加剂。印刷的有益区域可以定位在物品的吸收区域内或吸收区域外部。
实施例
除非以下另有说明,量以重量计。
实施例1
在400g Pantone 298U蓝色油墨(Kappaflex P1/11588,Kapp Chemie,德国)中加入57g平均胶囊尺寸为13μm的含有35%的牛油树脂(No.6573,Micro CapsuleTechnologies,法国)的活性物质的微胶囊乳液,在环境温度下通过搅拌器连续混合30分钟。通过在线同步柔版印刷以300m/min将所得混合物施加到表面重量为20g/m2的纺粘非织造物幅上,随后在热空气中干燥,随后在线层压至芯和底片材料形成用于卫生用途的个人护理产品,其中包括微胶囊化皮肤有益剂的印刷图案位于最终产品的顶片的面向衣服侧的前部和后部中。在干燥材料表面上的牛油树脂的所得表面浓度对应于0.2g/m2,并且覆盖顶片表面积的2%。
实施例2
在400g Pantone 250U粉色油墨(Kappaflex P1/11473,Kapp Chemie,德国)加入24g平均胶囊尺寸为12μm的含有42%杏仁油(Captex Amande Douces no.20005,RobertBlondel,法国)的活性物质的微胶囊乳液,在环境温度下通过搅拌器连续混合30分钟。将得到的混合物通过在线同步柔版印刷以400m/min的速度施加到表面重量为15g/m2的SMS非织造物幅上,随后在热空气中干燥,随后在线转化成用于卫生用途的个人护理产品,其中包括微胶囊包封的有益添加剂的印刷图案沿着最终产品的顶片的面向身体侧的纵向侧定位。在干燥材料表面上得到的杏仁油表面浓度相当于0.1g/m2,并且覆盖顶片表面积的3%。
实施例3
在通过搅拌器在环境温度下连续混合30分钟的过程中,在300g Pantone P305U蓝色油墨(WNWP-05-22006,Sun Chemical,法国)中加入130.5g平均胶囊尺寸为22.5μm的包括35%薄荷醇(No.2154,Micro Capsule Technologies,法国)的活性物质的微胶囊乳液。通过在线同步柔版印刷以360m/min的速度将所得混合物施加到表面重量为80g/m2的气流成网(LDA)材料幅上,随后在热空气中干燥,随后与顶片、芯和底片层压并在线转换成用于卫生用途的个人护理产品,其中包括微胶囊化的有益添加剂的印刷图案位于最终产品的芯材料的面向身体侧的中央。在干燥材料表面上得到的薄荷醇表面浓度对应于0.15g/m2,并且覆盖了顶片表面积的0.5%。
实施例4
在环境温度下剧烈搅拌20分钟的过程中,在420g的Pantone 376U绿色油墨(Kappaflex P1/11550,Kapp Chemie,德国)中加入200g平均胶囊尺寸为5μm的胶囊化的芦荟凝胶(R-eSCENTial 250,Devan Chemicals,比利时)。将所得混合物通过在线柔版印刷以250m/min的速度施加在具有31g/m2的总表面重量的穿孔膜和非织造层压物的幅上,随后在热空气中干燥,随后在线接合至其他幅材料,切割、粘合并转化为用于卫生用途的个人护理产品,其中包括微胶囊化的有益添加剂的印刷图案位于最终产品上的非织造材料的中央。干燥材料表面上所产生的芦荟表面浓度对应于1.0g/m2,并且覆盖了顶片表面积的9%。
实施例5
在用搅拌器在环境温度下连续混合30分钟的过程中,在400g Pantone 266U紫色油墨(WNWP-06-21935Sun Chemical,法国)中加入85g平均胶囊尺寸为7.5μm含有35%葡萄籽油(No.6564,Micro Capsule Technologies,法国)活性物质的微胶囊乳液。通过在线同步柔版印刷以300m/min的速度将所得混合物施加到具有21g/m2的表面重量的粗梳非织造物的幅上,随后在热空气中干燥,随后与顶片、芯和底片层压,并在线转化成用于卫生用途的个人护理产品,其中包括微胶囊化皮肤有益添加剂的印刷图案位于最终产品的顶片的面向衣服侧的前部和后部中。干燥材料表面上的葡萄籽油的表面浓度对应于0.5g/m2,并且覆盖了顶片表面积的2%。
实施例6
在此产品中,通过在线同步柔版印刷将具有如实施例3(薄荷醇)和实施例5(葡萄籽油)的有益添加剂的两种油墨以320m/min的速度施加到相同的材料幅上,使得包括各自微胶囊化皮肤有益添加剂的印刷图案定位于产品顶片的面向衣服侧的前部和纵向侧部。薄荷醇和葡萄籽油在干燥材料表面上的表面浓度分别对应于0.15g/m2和0.5g/m2,并且覆盖了顶片表面积的8%。
Claims (15)
1.一种将皮肤有益剂施加于吸收性物品的方法,所述吸收性物品包括具有面向身体表面和面向衣服表面的顶片层,所述物品具有纵向前部、纵向后部和位于所述前部和所述后部之间的裆部,所述方法包括:
-通过在线同步印刷技术在所述物品上印刷包括粘合剂和微胶囊化皮肤有益剂的水基油墨组合物,所述皮肤有益剂至少是部分疏水性或亲脂性物质或添加剂,并且微胶囊材料在20℃时不溶于水,
其中所述粘合剂确保油墨硬化并保持包括微胶囊在内的油墨定位在物品上,
所述皮肤有益剂用于影响、改善或维持皮肤或粘膜的健康状态,并且
在物品的使用期间所述皮肤有益剂从微胶囊缓慢释放。
2.根据权利要求1所述的方法,其中所述皮肤有益剂施加于所述物品的大于0.1%且小于10%的表面积上。
3.根据权利要求1或2所述的方法,其中在所述物品的表面上具有皮肤有益剂的微胶囊的浓度可以是0.01-1.0g/m2。
4.根据权利要求1或2所述的方法,其中所述微胶囊化皮肤有益剂印刷在选自以下的地带或区域上:
-沿裆部的纵向侧边;
-裆部的中央区域;
-前部的中央区域;
-后部的中央区域。
5.根据权利要求1或2所述的方法,其中所述油墨组合物印刷在选自所述顶片的面向身体表面和面向衣服表面的表面上。
6.根据权利要求1或2所述的方法,其中所述物品还包括底片和中间层,并且所述油墨组合物被印刷在所述中间层上。
7.根据权利要求1或2所述的方法,其中所述吸收性物品还包括从所述物品的每个纵向侧边延伸的翼部,并且在所述翼部的区域上印刷微胶囊化皮肤有益剂。
8.根据权利要求1或2所述的方法,其中所述油墨组合物包括颜料或染料。
9.根据权利要求1或2所述的方法,其中所述微胶囊的尺寸为3-30μm。
10.根据权利要求1或2所述的方法,其中所述皮肤有益剂在20℃是不溶于水的。
11.根据权利要求1或2所述的方法,其中所述皮肤有益剂选自油、脂肪或蜡或者是这些中任何的混合物或衍生物。
12.根据权利要求1或2所述的方法,其中所述皮肤有益剂来自天然来源。
13.根据权利要求1或2所述的方法,其中所述皮肤有益剂选自植物、草本、水果、种子、香料和油的提取物。
14.根据权利要求1或2所述的方法,其中所述物品选自卫生巾、卫生护垫、失禁垫、失禁尿布、带式尿布、婴儿尿布或卫生棉条。
15.一种吸收性物品,包括具有面向身体表面和面向衣服表面的顶片层,所述物品具有纵向前部、纵向后部和位于所述前部和所述后部之间的裆部,并且其中所述物品具有通过在线同步印刷技术在其上印刷的包括粘合剂和微胶囊化皮肤有益剂的水基油墨组合物,所述皮肤有益剂为至少部分疏水性或亲脂性物质或添加剂,并且微胶囊材料在20℃时不溶于水,其中所述粘合剂确保油墨硬化并保持包括微胶囊在内的油墨定位在物品上,所述皮肤有益剂用于影响、改善或维持皮肤粘膜的健康状态,并且在物品的使用期间所述皮肤有益剂从微胶囊缓慢释放。
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2016
- 2016-06-22 US US15/741,368 patent/US20190001017A1/en active Pending
- 2016-06-22 PL PL16821732T patent/PL3316920T3/pl unknown
- 2016-06-22 BR BR112017028383-2A patent/BR112017028383B1/pt active IP Right Grant
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AU2016291108B2 (en) | 2018-11-08 |
EP3316920B1 (en) | 2020-09-23 |
RU2693488C1 (ru) | 2019-07-03 |
WO2017007398A1 (en) | 2017-01-12 |
BR112017028383A2 (pt) | 2018-08-28 |
ECSP18007606A (es) | 2018-06-30 |
MY171344A (en) | 2019-10-09 |
AU2016291108B9 (en) | 2018-11-29 |
EP3316920A4 (en) | 2019-03-06 |
KR102057164B1 (ko) | 2019-12-18 |
CA2991182A1 (en) | 2017-01-12 |
MX2017016822A (es) | 2018-09-06 |
CA2991182C (en) | 2019-09-24 |
KR20180020208A (ko) | 2018-02-27 |
ES2828035T3 (es) | 2021-05-25 |
JP2018519094A (ja) | 2018-07-19 |
ZA201800457B (en) | 2019-06-26 |
US20190001017A1 (en) | 2019-01-03 |
AU2016291108A1 (en) | 2018-01-25 |
BR112017028383B1 (pt) | 2021-07-06 |
CN107735112A (zh) | 2018-02-23 |
CO2018000404A2 (es) | 2018-04-10 |
EP3316920A1 (en) | 2018-05-09 |
JP6581222B2 (ja) | 2019-09-25 |
PL3316920T3 (pl) | 2021-02-08 |
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