CN107703565A - A kind of anti-high-energy gold-tinted resin lens and its production method - Google Patents
A kind of anti-high-energy gold-tinted resin lens and its production method Download PDFInfo
- Publication number
- CN107703565A CN107703565A CN201710661012.2A CN201710661012A CN107703565A CN 107703565 A CN107703565 A CN 107703565A CN 201710661012 A CN201710661012 A CN 201710661012A CN 107703565 A CN107703565 A CN 107703565A
- Authority
- CN
- China
- Prior art keywords
- tinted
- resin
- grams
- hours
- gold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
- G02C7/104—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses having spectral characteristics for purposes other than sun-protection
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F122/10—Esters
- C08F122/12—Esters of phenols or saturated alcohols
- C08F122/18—Esters containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2335/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Derivatives of such polymers
- C08J2335/02—Characterised by the use of homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Ophthalmology & Optometry (AREA)
- General Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
A kind of anti-high-energy gold-tinted blue light resin lens and its production method, it is by weight, composed of the following components：Resin monomer brominated bisphenol-A diacrylate or 985 991 grams of thio polyurethanes, 0.4 2.0 grams of resin catalyst, 13 grams of resin releasing agent, 7 12 grams of ultraviolet absorber, anti-4 15 milligrams of high energy gold-tinted absorbent.The present invention, detected using ultraviolet specrophotometer UV 2550, high energy gold-tinted 585nm transmitances are down to 30% 70%, it is seen that transmittance reaches 75% 95%, has stronger absorption to 585nm or so high-energy gold-tinted.
Description
Technical field
The invention belongs to eyeglass manufacturing technology field, and in particular to a kind of producer of anti-high-energy gold-tinted resin lens
Method.
Background technology
Correlative study shows, 585nm or so high-energy gold-tinted can cause eyeball ARM, mesh under directly acting on for a long time
The preceding field functional lens are still in space state, therefore it is very to develop a kind of functional health eyeglass for possessing anti-high energy gold-tinted
It is necessary.
The content of the invention
The defects of being existed according to prior art, the present invention propose a kind of anti-high-energy gold-tinted blue light resin lens and its production
Method, the resin lens have absorption to 585nm or so high-energy gold-tinted.
The technical scheme is that be accomplished by the following way：A kind of anti-high-energy gold-tinted blue light resin lens, with
Weight meter, it is composed of the following components：Resin monomer brominated bisphenol-A diacrylate or 985-991 grams of thio polyurethanes, resin
0.4-2.0 grams of catalyst, 1-3 grams of resin releasing agent, 7-12 grams of ultraviolet absorber, anti-high energy gold-tinted absorbent 4-15 milligrams.
Described resin monomer is brominated bisphenol-A diacrylate or thio polyurethane.
Described resin catalyst is dibutyltin dichloride, 1,1- di-t-butyl peroxies -3,3,5- front three basic rings
Hexane or ABVN.
Described resin releasing agent is that organic silicone oil or acidity are even for acid esters.
Described ultraviolet absorber is 2-（2- hydroxyl -5- t-octyl phenyl）BTA or 2-（The tert-butyl group of 2- hydroxyls-3-
5 aminomethyl phenyls）- 5- chlorinated benzotriazoles.
Described anti-high-energy gold-tinted absorbent is copper phthalocyanine blue.
The production method of the present invention comprises the following steps：
1）, by resin monomer brominated bisphenol-A diacrylate or 985-991 grams of thio polyurethanes, resin catalyst 0.4-2.0
Gram, 1-3 grams of resin releasing agent, 7-12 grams of ultraviolet absorber, anti-high energy gold-tinted absorbent 4-15 milligrams be proportionally added into sealing
In reactor, fall air using dry nitrogen displacement, form composition；
2）, mixed 1 ~ 3 hour at 10-25 DEG C of technological temperature after, degassing is vacuumized to -0.01MPa, after 30-45 minutes
Above-mentioned composition is forced into 0.10---0.25Mpa, is filled to what is fixed with adhesive tape after being filtered with 0.5-5 micron filters
In glass mold, the mould filled is put into progress polymerisation in baking oven；
The reaction temperature of described polymerisation, reaction time is：1）- 35 DEG C of room temperature, 0.5 hour； 2）35 DEG C, 1 hour；3）
35 DEG C -40 DEG C, 2 hours；4）40 DEG C -60 DEG C, 3 hours；5）60 DEG C, 4 hours；6）60 DEG C -120 DEG C, 7 hours；7）120℃、2
Hour；8）120 DEG C -70 DEG C, 1 hour；
3）, glass mold is removed when being down to 70 DEG C of temperature, resulting eyeglass carries out annealing stress-removal at a temperature of 120 DEG C
Processing；
4）, combine to be heating and curing using dip-coating, spin coating or spraying method the thick stiffened coating of 0.5-5 microns formed on eyeglass；
5）, using vacuum coating technology lens surface plates antireflective, waterproof membrane forms anti-high-energy gold-tinted resin lens；
6）, detection storage.
The present invention, detected using ultraviolet specrophotometer UV-2550, high energy gold-tinted 585nm transmitances are down to 30%-
70%, it is seen that transmittance reaches 75%-95%, has stronger absorption to 585nm or so high-energy gold-tinted.
Embodiment
Embodiment 1：
1st, anti-high-energy gold-tinted blue light resin lens, 1KG formulas：Thio 990 grams of polyurethane, catalyst dibutyltin dichloride 2
Gram, releasing agent it is acid even for 1 gram of acid esters, ultraviolet absorber 2-（The aminomethyl phenyl of -3 tert-butyl group of 2- hydroxyls -5）- 5- chloro benzos three
7 grams of azoles, anti-4.5 milligrams of high energy gold-tinted absorbent copper phthalocyanine blue.
2nd, production method：Add in the reactor of sealing after above-mentioned monomer is weighed by formula, put using dry nitrogen
Air is changed, after then being mixed 2 hours at 15 DEG C, degassing is vacuumized afterwards to -0.01MPa 30 minutes, is finally filled with
Air pressurized is filled to the glass molds fixed with adhesive tape after combinations of the above thing is filtered with 1 micron filter to 0.15Mpa
In tool, the mould filled is put into baking oven by following heating schedule progress polymerisation：
Reactions steps：Reaction temperature, reaction time is：1）- 35 DEG C of room temperature, 0.5 hour； 2）35 DEG C, 1 hour；3）35℃-40
DEG C, 2 hours；4）40 DEG C -60 DEG C, 3 hours；5）60 DEG C, 4 hours；6）60 DEG C -120 DEG C, 7 hours；7）120 DEG C, 2 hours；8）
120 DEG C -70 DEG C, 1 hour；
Then glass mold is removed at 70 DEG C, resulting eyeglass carries out stress-removal processing of annealing at a temperature of 120 DEG C.
Prepared eyeglass, through silane coupler containing hydrolysis on over cleaning and surface dip-coating, Ludox dispersion liquid
Coating simultaneously solidifies the stiffened film layer for obtaining 2.0 microns of thickness, lens surface is obtained containing silica using vacuum vapour deposition
With the anti-reflective film layer of zirconia film.
Performance test
3rd, performance measurement：Refractive index 1.558, abbe number 43, it is seen that transmittance 89.0%,
High energy gold-tinted 585nm transmitances 68%.
Embodiment 2：
1st, 1KG is formulated：985 grams of brominated bisphenol-A diacrylate gram, 0.5 gram of catalyst ABVN, releasing agent are acid
Occasionally for 3 grams of acid esters, ultraviolet absorber 2-（The aminomethyl phenyl of -3 tert-butyl group of 2- hydroxyls -5）12 grams of -5- chlorinated benzotriazoles, 585 anti-height
Can 10 milligrams of gold-tinted absorbent.
2nd, production method：Added after monomer is weighed by formula in the reactor of sealing, then mix 2 at room temperature
After hour, vacuum outgas afterwards 30 minutes, be finally filled with air pressurized to 0.2Mpa by combinations of the above thing with 1 micron filter
It is filled to after filtering in the glass mold fixed with adhesive tape, the mould filled is put into baking oven and carried out by following heating schedule
Polymerisation：
Reactions steps：Reaction temperature, reaction time is：1）- 35 DEG C of room temperature, 0.5 hour； 2）35 DEG C, 1 hour；3）35℃-40
DEG C, 2 hours；4）40 DEG C -60 DEG C, 3 hours；5）60 DEG C, 4 hours；6）60 DEG C -120 DEG C, 7 hours；7）120 DEG C, 2 hours；8）
120 DEG C -70 DEG C, 1 hour；
Then glass mold is removed at 70 DEG C, resulting eyeglass carries out stress-removal processing of annealing at a temperature of 120 DEG C.Institute
The eyeglass of preparation, through the silane coupler containing hydrolysis, the coating of Ludox dispersion liquid and solidification in over cleaning and surface dip-coating
The stiffened film layer of 2.0 microns of thickness is obtained, obtains lens surface using vacuum vapour deposition thin containing silica and zirconium oxide
The anti-reflective film layer of film.
3rd, performance measurement：Refractive index 1.597, abbe number 33, it is seen that transmittance 80%, high energy gold-tinted 585nm are saturating
Cross rate 35%.
Claims (7)
1. a kind of anti-high-energy gold-tinted blue light resin lens, by weight, composed of the following components：Resin monomer brominated bisphenol-A
Diacrylate or 985-991 grams of thio polyurethanes, 0.4-2.0 grams of resin catalyst, 1-3 grams of resin releasing agent, ultraviolet suction
Receive 7-12 grams of agent, anti-high energy gold-tinted absorbent 4-15 milligrams.
A kind of 2. anti-high-energy gold-tinted blue light resin lens according to claim 1, it is characterised in that：Described resin list
Body is brominated bisphenol-A diacrylate or thio polyurethane.
A kind of 3. anti-high-energy gold-tinted blue light resin lens according to claim 1, it is characterised in that：Described resin is urged
Agent is dibutyltin dichloride, 1,1- di-t-butyl peroxies -3,3,5- trimethyls thiacyclohexane or ABVN.
A kind of 4. anti-high-energy gold-tinted blue light resin lens according to claim 1, it is characterised in that：Described resin takes off
Mould agent is that organic silicone oil or acidity are even for acid esters.
Described ultraviolet absorber is 2-（2- hydroxyl -5- t-octyl phenyl）BTA or 2-（The first of -3 tert-butyl group of 2- hydroxyls -5
Base phenyl）- 5- chlorinated benzotriazoles.
A kind of 5. anti-high-energy gold-tinted blue light resin lens according to claim 1, it is characterised in that：Described anti-high energy
It is copper phthalocyanine blue to measure gold-tinted absorbent.
A kind of 6. method for producing the anti-high-energy gold-tinted blue light resin lens described in claim 1, it is characterised in that including such as
Lower step：
1）, by resin monomer brominated bisphenol-A diacrylate or 985-991 grams of thio polyurethanes, resin catalyst 0.4-2.0
Gram, 1-3 grams of resin releasing agent, 7-12 grams of ultraviolet absorber, anti-high energy gold-tinted absorbent 4-15 milligrams be proportionally added into sealing
In reactor, fall air using dry nitrogen displacement, form composition；
2）, mixed 1 ~ 3 hour at 10-25 DEG C of technological temperature after, degassing is vacuumized to -0.01MPa, after 30-45 minutes
Above-mentioned composition is forced into 0.10---0.25Mpa, is filled to what is fixed with adhesive tape after being filtered with 0.5-5 micron filters
In glass mold, the mould filled is put into progress polymerisation in baking oven；
The reaction temperature of described polymerisation, reaction time is：1）- 35 DEG C of room temperature, 0.5 hour； 2）35 DEG C, 1 hour；3）
35 DEG C -40 DEG C, 2 hours；4）40 DEG C -60 DEG C, 3 hours；5）60 DEG C, 4 hours；6）60 DEG C -120 DEG C, 7 hours；7）120℃、2
Hour；8）120 DEG C -70 DEG C, 1 hour；
3）, glass mold is removed when being down to 70 DEG C of temperature, resulting eyeglass carries out annealing stress-removal at a temperature of 120 DEG C
Processing；
4）, combine to be heating and curing using dip-coating, spin coating or spraying method the thick stiffened coating of 0.5-5 microns formed on eyeglass；
5）, using vacuum coating technology lens surface plates antireflective, waterproof membrane forms anti-high-energy gold-tinted resin lens；
6）, detection storage.
A kind of 7. production method of anti-high-energy gold-tinted blue light resin lens according to claim 6, it is characterised in that：Institute
The step 2 stated）In the reaction temperature of polymerisation, the reaction time be：1）- 35 DEG C of room temperature, 0.5 hour； 2）35 DEG C, it is 1 small
When；3）35 DEG C -40 DEG C, 2 hours；4）40 DEG C -60 DEG C, 3 hours；5）60 DEG C, 4 hours；6）60 DEG C -120 DEG C, 7 hours；7）
120 DEG C, 2 hours；8）120 DEG C -70 DEG C, 1 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710661012.2A CN107703565A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-high-energy gold-tinted resin lens and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710661012.2A CN107703565A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-high-energy gold-tinted resin lens and its production method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107703565A true CN107703565A (en) | 2018-02-16 |
Family
ID=61170632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710661012.2A Pending CN107703565A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-high-energy gold-tinted resin lens and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107703565A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046741A (en) * | 1988-04-30 | 1990-11-07 | 三井东圧化学株式会社 | Based on the resin of polysulfide, the method that contains the plastic lens of this resin and make this kind lens |
| US5015523A (en) * | 1983-07-29 | 1991-05-14 | Seiko Epson Corporation | Coated synthetic resin lens |
| CN103080162A (en) * | 2011-06-13 | 2013-05-01 | Dic株式会社 | Radically polymerizable composition, cured product, and plastic lens |
| CN104945284A (en) * | 2015-04-30 | 2015-09-30 | 江苏俊视光学有限公司 | High-Abbe-number ultra-light wear-resistant resin material, lens and preparation methods thereof |
| CN106977902A (en) * | 2013-09-30 | 2017-07-25 | 豪雅镜片泰国有限公司 | Transparent plastic substrate and plastic lens |
-
2017
- 2017-08-04 CN CN201710661012.2A patent/CN107703565A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015523A (en) * | 1983-07-29 | 1991-05-14 | Seiko Epson Corporation | Coated synthetic resin lens |
| CN1046741A (en) * | 1988-04-30 | 1990-11-07 | 三井东圧化学株式会社 | Based on the resin of polysulfide, the method that contains the plastic lens of this resin and make this kind lens |
| CN103080162A (en) * | 2011-06-13 | 2013-05-01 | Dic株式会社 | Radically polymerizable composition, cured product, and plastic lens |
| CN106977902A (en) * | 2013-09-30 | 2017-07-25 | 豪雅镜片泰国有限公司 | Transparent plastic substrate and plastic lens |
| CN104945284A (en) * | 2015-04-30 | 2015-09-30 | 江苏俊视光学有限公司 | High-Abbe-number ultra-light wear-resistant resin material, lens and preparation methods thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102675538B (en) | Combination for preparing high-light-transmittance and high-weather-resistance optical lens materials | |
| CN102143984B (en) | Polymerizable compound for optical material, optical material, and optical material manufacturing method | |
| EP2168757B1 (en) | Method of manufacturing a plastic lens | |
| CN107479123A (en) | A kind of anti-high energy blue light resin lens and its manufacturing process | |
| KR102105717B1 (en) | Polymerizable composition for high refractive optical material and method of preparing the optical material | |
| CN104231945B (en) | A kind of liquid optical cement | |
| CN107092043B (en) | 1.67 polyurethane lens with blue-violet protection performance and manufacturing method thereof | |
| WO2016204080A1 (en) | Composition for optical material and optical material using the same | |
| CN103145944B (en) | PMC (Polymer-matrix composite) radiation-proof resin lens and manufacturing process thereof | |
| CN108503740A (en) | A kind of anti-blue light resin monomer, resin material, eyeglass and preparation method thereof | |
| CN108164627B (en) | High-transmittance blue-light-proof spectacle lens and preparation method thereof | |
| CN107238945A (en) | A kind of polycarbonate ophthalmic lenses preparation method of anti-harmful light wave | |
| CN105176042A (en) | Resin lens with good fog resistance and preparation method thereof | |
| CN102660115A (en) | Combination for preparing lens with good safety and preparation method of lens | |
| CN107949584A (en) | Polymerizable composition for optical material, the optical material and plastic lens obtained by said composition | |
| CN106699996B (en) | Resin lens and production method by ultraviolet photo-curing refractive index for 1.56 | |
| CN107703565A (en) | A kind of anti-high-energy gold-tinted resin lens and its production method | |
| CN113845619A (en) | High-refractive-index color-changing monomer and preparation method and application thereof | |
| CN109669279A (en) | A kind of production method of anti-blue light eyeglass | |
| CN101472976A (en) | Polymerizable composition, resin using the same, optical component and compound | |
| CN107216420B (en) | Polymer polyatomic alcohol and combinations thereof and purposes | |
| CN106842612B (en) | A kind of double photopolymer resin eyeglasses and preparation method thereof | |
| CN107501499A (en) | The shock proof resin lens composition of high-bond and polarized lenses preparation method | |
| JP7046801B2 (en) | Eyeglass lens | |
| CN101833175A (en) | Preparation method of 580 nanometer anti-glare resin lens |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180216 |
|
| WD01 | Invention patent application deemed withdrawn after publication |