CN107699776A - A kind of lockmaking Alloy Materials and preparation method thereof - Google Patents

A kind of lockmaking Alloy Materials and preparation method thereof Download PDF

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Publication number
CN107699776A
CN107699776A CN201710976868.9A CN201710976868A CN107699776A CN 107699776 A CN107699776 A CN 107699776A CN 201710976868 A CN201710976868 A CN 201710976868A CN 107699776 A CN107699776 A CN 107699776A
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parts
steel
lockmaking
alloy materials
alloy
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胡方尧
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NINGBO DATER LOCK PRODUCTS CO Ltd
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NINGBO DATER LOCK PRODUCTS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/006Making ferrous alloys compositions used for making ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The invention discloses a kind of lockmaking Alloy Materials and preparation method thereof, a kind of lockmaking Alloy Materials, include the raw materials of following parts by weight:300~400 parts of Fe,12~15 parts of C,5~12 parts of Zn,5~12 parts of Al,2~8 parts of aluminium nitride,Discarded 200~300 parts of steel,3~6 parts of B,10~15 parts of Cr,3~8 parts of Ni,3~8 parts of Mn,9~12 parts of Mo,4~10 parts of Cu,10~14 parts of Si,6~10 parts of Ti,5~8 parts of Nb,5~12 parts of Ta,4~9 parts of Zr,3~8 parts of V,3~8 parts of Ce,5~8 parts of rare earth,Discarded steel are put into derusting bucket,Add rust remover,Stand 2~4h,Bleed off rust remover,Add rust remover,Carry out secondary rust removal,Stand 2~4h,Bleed off rust remover,And put it into anaerobic room,It is dried processing with Hot-air fan,Steel A after being derusted.Anti-corrosive properties of the present invention are strong, and quality is good, and intensity is high, are adapted to lockmaking, and cost is low, are adapted to promote.

Description

A kind of lockmaking Alloy Materials and preparation method thereof
Technical field
The present invention relates to Alloy Materials technical field, more particularly to a kind of lockmaking Alloy Materials and its making side Method.
Background technology
Lockset has referred to the utensil of sealing process, and it includes lock, key and its annex, and general explanation is that " must use key What can be absolved seals device ", now, lockset can also be used up, the instruction such as electricity, magnetic, sound and fingerprint is opened in addition to being opened with key Open.Lockset is not singly protective articles, also has the function that " to manage " and " decoration ".Also there is a kind of ceremony in international association, use Give the expression of symbolistic " key " as friendship.Chinese lockset is born to be continuous thousands of years, and Yangshao culture ruins are found that Wood lock, there is bronze lock in the Western Zhou Dynasty, arrived the Eastern Han Dynasty generally production, using metal latch, until middle 1950s, Chinese ancient lock steps down from the stage of history.The material of lock, substantially there are two major classes, one is wood lock, and one is metal latch.The production palpus of wood lock Cut out and expect through sawing, axe is split into shape, and chisel eye burrows, the technological processes such as drilling of scraping.Metal latch will then smelt, gold and silver copper and iron, base Material is cut out in casting, cutting, is welded riveting mosaic, is punched a hole, the hardware technological process such as filing polishing.One lockset from raw material to being made, The how many works meticulously of locksmiths to be expended are not known.
Modern lock needs to use high strength steel material, avoids lockset from being also needed to by pinch off etc, lockset with anti-corrosion Corrosion, avoid getting rusty in keyhole and cause key can not be matched with lockset, existing lockmaking material generally use steel alloy, close Golden steel is typically made with the pig iron, but the quantity of scrap iron is more and more, how using scrap iron to produce steel alloy, and How the steel alloy of production ensures anticorrosive property, therefore, the present invention proposes a kind of lockmaking Alloy Materials and its making side Method.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of lockmaking alloy green wood proposed Material and preparation method thereof.
To achieve these goals, present invention employs following technical scheme:
A kind of lockmaking Alloy Materials, include the raw material of following parts by weight:300~400 parts of Fe, 12~15 parts of C, Zn 5~12 parts, 5~12 parts of Al, 2~8 parts of aluminium nitride, discarded 200~300 parts of steel, 3~6 parts of B, 10~15 parts of Cr, Ni 3 ~8 parts, 3~8 parts of Mn, 9~12 parts of Mo, 4~10 parts of Cu, 10~14 parts of Si, 6~10 parts of Ti, 5~8 parts of Nb, Ta 5~ 12 parts, 4~9 parts of Zr, 3~8 parts of V, 3~8 parts of Ce, 5~8 parts of rare earth.
Preferably, the raw material of following parts by weight is included:310~390 parts of Fe, 12~15 parts of C, 5~12 parts of Zn, Al 5 ~12 parts, 2~8 parts of aluminium nitride, discarded 220~280 parts of steel, 3~6 parts of B, 10~14 parts of Cr, 3~8 parts of Ni, Mn 3~7 Part, 9~11 parts of Mo, 4~10 parts of Cu, 10~14 parts of Si, 6~9.5 parts of Ti, 5~7.8 parts of Nb, 5~11 parts of Ta, Zr 4 ~8.6 parts, 3~7.6 parts of V, 3~7.6 parts of Ce, 5~7.6 parts of rare earth.
Preferably, the raw material of following parts by weight is included:350 parts of Fe, 13.5 parts of C, 8.5 parts of Zn, 8.5 parts of Al, nitridation 5 parts of aluminium, discarded 250 parts of steel, 4.5 parts of B, 12.5 parts of Cr, 5.5 parts of Ni, 5.5 parts of Mn, 10.5 parts of Mo, 7 parts of Cu, Si 12 parts, 8 parts of Ti, 6.5 parts of Nb, 8.5 parts of Ta, 6.5 parts of Zr, 5.5 parts of V, 5.5 parts of Ce, 6.5 parts of rare earth.
Preferably, the Fe, Zn, Al, aluminium nitride and Ti weight ratio are 80~100:2~3.2:2~3:1.2~1.5: 1。
Preferably, the weight ratio of the Fe, Zn, Al, aluminium nitride and discarded steel is 80~100:2~3.2:2~3:1.2 ~1.5:60~70.
Preferably, the rare earth element is selected from least one of lanthanum, cerium, neodymium, terbium, yttrium and scandium, preferably in yttrium and scandium At least one.
A kind of preparation method of lockmaking Alloy Materials, comprises the following steps,
S1, discarded steel are put into derusting bucket, add rust remover, 2~4h is stood, bleeds off rust remover, add derusting Agent, secondary rust removal is carried out, stand 2~4h, bleed off rust remover, and put it into anaerobic room, it is done with Hot-air fan Dry processing, the steel A after being derusted;
S2, C, Zn, Al, aluminium nitride, B, Cr, Ni, Mn, Mo, Cu, Si, Ti, Nb, Ta, Zr, V, Ce particle are put into ball milling Ground in machine, grind 400~500min, be then taken out drying and pulverize standby, obtain mixed powder B;
S3, steel A and the pig iron are put into smelting furnace simultaneously, after high-temperature heating fusing, keep fusion temperature constant, continue 2.0~4.0h of melting, mixed with 200~300r/min rotating speed in fusion process, obtain mixing liquid C;
S4, mixed powder is added in mixing liquid C, after heating fusing, the whole fusion process that heats is with 300~400r/ Min rotating speed is stirred, and rare earth element is added after stirring 2~4h, is improved rotating speed to 500~700r/min, is obtained mixing and close Golden material D;
S5, steel alloy D is heated to 500~660 DEG C, and is incubated 80~160 minutes, be heated to 830~880 DEG C afterwards, And it is incubated 150~380 minutes steel alloy E for obtaining austenitizing;
S6, the steel alloy E of austenitizing is quenched to obtain the steel alloy F of formation of martensite, the conjunction of the formation of martensite after quenching Jin Gang temperature is not higher than 70 DEG C;And the steel alloy of formation of martensite is heated to 480~650 DEG C, and 200~320 minutes are incubated, Alloy Materials G is obtained after cooling.
A kind of lockmaking Alloy Materials proposed by the present invention, by the addition of Al powder, the anticorrosion of metal can be improved Property, Zn powder further improve the anticorrosive property of metal, and the addition of Ti powder effectively improves the intensity of metal, the addition of rare earth, can be with The intensity of metal is improved, Mo addition can improve the wearability of Alloy Materials, that is, improve the wearability of lockset, this Invention also proposed a kind of preparation method of lockmaking Alloy Materials, and the steel alloy E of austenitizing is quenched to obtain martensite The steel alloy F of change, the temperature of the steel alloy of the formation of martensite after quenching are not higher than 70 DEG C;And the steel alloy of formation of martensite is heated To 550 DEG C, and 260 minutes being incubated, Alloy Materials G is obtained after cooling so that metal strength is higher, is more applicable for lockset, The addition of discarded steel, can not drop low-alloyed performance while reduce cost, anti-corrosive properties of the present invention are strong, and quality is good, intensity Height, it is adapted to lockmaking, cost is low, is adapted to promote.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example only part of the embodiment of the present invention, rather than whole embodiments.
Embodiment one
A kind of lockmaking Alloy Materials proposed by the present invention, include the raw material of following parts by weight:350 parts of Fe, C 13.5 Part, 8.5 parts of Zn, 8.5 parts of Al, 5 parts of aluminium nitride, discarded 250 parts of steel, 4.5 parts of B, 12.5 parts of Cr, 5.5 parts of Ni, Mn 5.5 parts, 10.5 parts of Mo, 7 parts of Cu, 12 parts of Si, 8 parts of Ti, 6.5 parts of Nb, 8.5 parts of Ta, 6.5 parts of Zr, 5.5 parts of V, Ce 5.5 parts, 6.5 parts of rare earth.
A kind of preparation method of lockmaking Alloy Materials proposed by the present invention, comprises the following steps,
S1, discarded steel are put into derusting bucket, add rust remover, 2h is stood, bleeds off rust remover, add rust remover, Secondary rust removal is carried out, 2h is stood, bleeds off rust remover, and is put it into anaerobic room, it is dried processing with Hot-air fan, Steel A after being derusted;
S2, C, Zn, Al, aluminium nitride, B, Cr, Ni, Mn, Mo, Cu, Si, Ti, Nb, Ta, Zr, V, Ce particle are put into ball milling Ground in machine, grind 400min, be then taken out drying and pulverize standby, obtain mixed powder B;
S3, steel A and the pig iron are put into smelting furnace simultaneously, after high-temperature heating fusing, keep fusion temperature constant, continue Melting 2.0h, mixed with 200r/min rotating speed in fusion process, obtain mixing liquid C;
S4, mixed powder is added in mixing liquid C, after heating fusing, the whole fusion process that heats is with 300r/min's Rotating speed is stirred, and rare earth element is added after stirring 2h, is improved rotating speed to 500r/min, is obtained hybrid alloys material D;
S5, steel alloy D is heated to 500 DEG C, and is incubated 80 minutes, be heated to 830 DEG C afterwards, and be incubated 150 minutes To the steel alloy E of austenitizing;
S6, the steel alloy E of austenitizing is quenched to obtain the steel alloy F of formation of martensite, the conjunction of the formation of martensite after quenching Jin Gang temperature is not higher than 70 DEG C;And the steel alloy of formation of martensite is heated to 480 DEG C, and 200 minutes are incubated, obtained after cooling Alloy Materials G.
Embodiment two
A kind of lockmaking Alloy Materials proposed by the present invention, include the raw material of following parts by weight:350 parts of Fe, C 13.5 Part, 8.5 parts of Zn, 8.5 parts of Al, 5 parts of aluminium nitride, discarded 250 parts of steel, 4.5 parts of B, 12.5 parts of Cr, 5.5 parts of Ni, Mn 5.5 parts, 10.5 parts of Mo, 7 parts of Cu, 12 parts of Si, 8 parts of Ti, 6.5 parts of Nb, 8.5 parts of Ta, 6.5 parts of Zr, 5.5 parts of V, Ce 5.5 parts, 6.5 parts of rare earth.
A kind of preparation method of lockmaking Alloy Materials proposed by the present invention, comprises the following steps,
S1, discarded steel are put into derusting bucket, add rust remover, 3h is stood, bleeds off rust remover, add rust remover, Secondary rust removal is carried out, 3h is stood, bleeds off rust remover, and is put it into anaerobic room, it is dried processing with Hot-air fan, Steel A after being derusted;
S2, C, Zn, Al, aluminium nitride, B, Cr, Ni, Mn, Mo, Cu, Si, Ti, Nb, Ta, Zr, V, Ce particle are put into ball milling Ground in machine, grind 450min, be then taken out drying and pulverize standby, obtain mixed powder B;
S3, steel A and the pig iron are put into smelting furnace simultaneously, after high-temperature heating fusing, keep fusion temperature constant, continue Melting 3h, mixed with 250r/min rotating speed in fusion process, obtain mixing liquid C;
S4, mixed powder is added in mixing liquid C, after heating fusing, the whole fusion process that heats is with 350r/min's Rotating speed is stirred, and rare earth element is added after stirring 3h, is improved rotating speed to 600r/min, is obtained hybrid alloys material D;
S5, steel alloy D is heated to 580 DEG C, and is incubated 120 minutes, be heated to 855 DEG C afterwards, and be incubated 220 minutes To the steel alloy E of austenitizing;
S6, the steel alloy E of austenitizing is quenched to obtain the steel alloy F of formation of martensite, the conjunction of the formation of martensite after quenching Jin Gang temperature is not higher than 70 DEG C;And the steel alloy of formation of martensite is heated to 550 DEG C, and 260 minutes are incubated, obtained after cooling Alloy Materials G.
Embodiment three
A kind of lockmaking Alloy Materials proposed by the present invention, include the raw material of following parts by weight:350 parts of Fe, C 13.5 Part, 8.5 parts of Zn, 8.5 parts of Al, 5 parts of aluminium nitride, discarded 250 parts of steel, 4.5 parts of B, 12.5 parts of Cr, 5.5 parts of Ni, Mn 5.5 parts, 10.5 parts of Mo, 7 parts of Cu, 12 parts of Si, 8 parts of Ti, 6.5 parts of Nb, 8.5 parts of Ta, 6.5 parts of Zr, 5.5 parts of V, Ce 5.5 parts, 6.5 parts of rare earth.
A kind of preparation method of lockmaking Alloy Materials proposed by the present invention, comprises the following steps,
S1, discarded steel are put into derusting bucket, add rust remover, 4h is stood, bleeds off rust remover, add rust remover, Secondary rust removal is carried out, 4h is stood, bleeds off rust remover, and is put it into anaerobic room, it is dried processing with Hot-air fan, Steel A after being derusted;
S2, C, Zn, Al, aluminium nitride, B, Cr, Ni, Mn, Mo, Cu, Si, Ti, Nb, Ta, Zr, V, Ce particle are put into ball milling Ground in machine, grind 500min, be then taken out drying and pulverize standby, obtain mixed powder B;
S3, steel A and the pig iron are put into smelting furnace simultaneously, after high-temperature heating fusing, keep fusion temperature constant, continue Melting 4.0h, mixed with 300r/min rotating speed in fusion process, obtain mixing liquid C;
S4, mixed powder is added in mixing liquid C, after heating fusing, the whole fusion process that heats is with 400r/min's Rotating speed is stirred, and rare earth element is added after stirring 4h, is improved rotating speed to 700r/min, is obtained hybrid alloys material D;
S5, steel alloy D is heated to 660 DEG C, and is incubated 160 minutes, be heated to 880 DEG C afterwards, and be incubated 380 minutes To the steel alloy E of austenitizing;
S6, the steel alloy E of austenitizing is quenched to obtain the steel alloy F of formation of martensite, the conjunction of the formation of martensite after quenching Jin Gang temperature is not higher than 70 DEG C;And the steel alloy of formation of martensite is heated to 650 DEG C, and 320 minutes are incubated, obtained after cooling Alloy Materials G.
The resistance to corrosion of the high strength steel material prepared is tested in the embodiment of the present invention one~tetra- respectively, and tests market The high strength steel material sold compares, and high strength steel material is put into the saline solution that concentration is 20g/L, placed 30 days Rate of corrosion is obtained, draws following parameter:
Rate of corrosion
Embodiment one 0.050%
Embodiment two 0.046%
Embodiment three 0.047%
Control group 0.115%
A kind of lockmaking Alloy Materials proposed by the present invention, by the addition of Al powder, the anticorrosion of metal can be improved Property, Zn powder further improve the anticorrosive property of metal, and the addition of Ti powder effectively improves the intensity of metal, the addition of rare earth, can be with The intensity of metal is improved, Mo addition can improve the wearability of Alloy Materials, that is, improve the wearability of lockset, this Invention also proposed a kind of preparation method of lockmaking Alloy Materials, and the steel alloy E of austenitizing is quenched to obtain martensite The steel alloy F of change, the temperature of the steel alloy of the formation of martensite after quenching are not higher than 70 DEG C;And the steel alloy of formation of martensite is heated To 550 DEG C, and 260 minutes being incubated, Alloy Materials G is obtained after cooling so that metal strength is higher, is more applicable for lockset, The addition of discarded steel, can not drop low-alloyed performance while reduce cost, anti-corrosive properties of the present invention are strong, and quality is good, intensity Height, it is adapted to lockmaking, cost is low, is adapted to promote.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of lockmaking Alloy Materials, it is characterised in that include the raw material of following parts by weight:300~400 parts of Fe, C 12 ~15 parts, 5~12 parts of Zn, 5~12 parts of Al, 2~8 parts of aluminium nitride, discarded 200~300 parts of steel, 3~6 parts of B, Cr 10~ 15 parts, 3~8 parts of Ni, 3~8 parts of Mn, 9~12 parts of Mo, 4~10 parts of Cu, 10~14 parts of Si, 6~10 parts of Ti, Nb 5~8 Part, 5~12 parts of Ta, 4~9 parts of Zr, 3~8 parts of V, 3~8 parts of Ce, 5~8 parts of rare earth.
2. a kind of lockmaking Alloy Materials according to claim 1, it is characterised in that include the original of following parts by weight Material:310~390 parts of Fe, 12~15 parts of C, 5~12 parts of Zn, 5~12 parts of Al, 2~8 parts of aluminium nitride, discarded steel 220~ 280 parts, 3~6 parts of B, 10~14 parts of Cr, 3~8 parts of Ni, 3~7 parts of Mn, 9~11 parts of Mo, 4~10 parts of Cu, Si 10~ 14 parts, it is 6~9.5 parts of Ti, 5~7.8 parts of Nb, 5~11 parts of Ta, 4~8.6 parts of Zr, 3~7.6 parts of V, 3~7.6 parts of Ce, dilute 5~7.6 parts of soil.
3. a kind of lockmaking Alloy Materials according to claim 1, it is characterised in that include the original of following parts by weight Material:350 parts of Fe, 13.5 parts of C, 8.5 parts of Zn, 8.5 parts of Al, 5 parts of aluminium nitride, discarded 250 parts of steel, 4.5 parts of B, Cr 12.5 parts, 5.5 parts of Ni, 5.5 parts of Mn, 10.5 parts of Mo, 7 parts of Cu, 12 parts of Si, 8 parts of Ti, 6.5 parts of Nb, 8.5 parts of Ta, Zr 6.5 parts, 5.5 parts of V, 5.5 parts of Ce, 6.5 parts of rare earth.
4. a kind of lockmaking Alloy Materials according to claim 1, it is characterised in that the Fe, Zn, Al, aluminium nitride Weight ratio with Ti is 80~100:2~3.2:2~3:1.2~1.5:1.
5. a kind of lockmaking Alloy Materials according to claim 1, it is characterised in that the Fe, Zn, Al, aluminium nitride Weight ratio with discarded steel is 80~100:2~3.2:2~3:1.2~1.5:60~70.
A kind of 6. lockmaking Alloy Materials according to claim 1, it is characterised in that the rare earth element be selected from At least one of lanthanum, cerium, neodymium, terbium, yttrium and scandium, preferably at least one of yttrium and scandium.
A kind of 7. preparation method of lockmaking Alloy Materials, it is characterised in that comprise the following steps,
S1, discarded steel are put into derusting bucket, add rust remover, 2~4h is stood, bleeds off rust remover, add rust remover, enter Row secondary rust removal, 2~4h is stood, bleeds off rust remover, and put it into anaerobic room, it is dried place with Hot-air fan Reason, the steel A after being derusted;
S2, C, Zn, Al, aluminium nitride, B, Cr, Ni, Mn, Mo, Cu, Si, Ti, Nb, Ta, Zr, V, Ce particle are put into ball mill Grinding, 400~500min is ground, be then taken out drying and pulverize standby, obtain mixed powder B;
S3, steel A and the pig iron are put into smelting furnace simultaneously, after high-temperature heating fusing, keep fusion temperature constant, continue melting 2.0~4.0h, mixed with 200~300r/min rotating speed in fusion process, obtain mixing liquid C;
S4, mixed powder is added in mixing liquid C, after heating fusing, the whole fusion process that heats is with 300~400r/min's Rotating speed is stirred, and rare earth element is added after stirring 2~4h, is improved rotating speed to 500~700r/min, is obtained hybrid alloys material D;
S5, steel alloy D is heated to 500~660 DEG C, and is incubated 80~160 minutes, be heated to 830~880 DEG C afterwards, and protect The steel alloy E that temperature obtains austenitizing in 150~380 minutes;
S6, the steel alloy E of austenitizing is quenched to obtain the steel alloy F of formation of martensite, the steel alloy of the formation of martensite after quenching Temperature be not higher than 70 DEG C;And the steel alloy of formation of martensite is heated to 480~650 DEG C, and 200~320 minutes are incubated, cooling After obtain Alloy Materials G.
CN201710976868.9A 2017-10-19 2017-10-19 A kind of lockmaking Alloy Materials and preparation method thereof Pending CN107699776A (en)

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CN104195469A (en) * 2014-07-29 2014-12-10 锐展(铜陵)科技有限公司 Alloy steel for automobile brake disc and manufacturing method for alloy steel
CN106591727A (en) * 2016-12-12 2017-04-26 苏州陈恒织造有限公司 Corrosion-resistant and high-temperature-resistant shell for oil-immersed transformer

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN104195469A (en) * 2014-07-29 2014-12-10 锐展(铜陵)科技有限公司 Alloy steel for automobile brake disc and manufacturing method for alloy steel
CN106591727A (en) * 2016-12-12 2017-04-26 苏州陈恒织造有限公司 Corrosion-resistant and high-temperature-resistant shell for oil-immersed transformer

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Title
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