CN107690460A - A kind of decentralized waterborne general color chips - Google Patents
A kind of decentralized waterborne general color chips Download PDFInfo
- Publication number
- CN107690460A CN107690460A CN201680027502.0A CN201680027502A CN107690460A CN 107690460 A CN107690460 A CN 107690460A CN 201680027502 A CN201680027502 A CN 201680027502A CN 107690460 A CN107690460 A CN 107690460A
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- CN
- China
- Prior art keywords
- decentralized
- color chips
- general color
- dispersing resin
- parts
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Developing Agents For Electrophotography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
A kind of decentralized waterborne general color chips, is made up of each component in mass ratio：Acrylic dispersing resin 20~40%, toner 60~80%, while also disclose the preparation method of the decentralized waterborne general color chips.Long shelf-life of the present invention, applied widely, strong coloring force, technological process is simple, is carrier without the use of deionized water, and production cost is low, and will not cause environmental pollution.
Description
Technical field
The present invention relates to water-based coloring field, more particularly to a kind of decentralized waterborne general color chips.
Background technology
Coating on textile printing and dyestuff, synthetic leather material and building inside and outside wall uses oil pastes mostly, so
And oil pastes also have because the toxic gases such as its own volatile formaldehyde, azo cause certain destruction to environment to human body
Toxic.Therefore, it has been proposed that carrying out pigment coloration to weaving, synthetic leather using aqueous color paste.But water currently on the market
Property mill base, because its it is water base be difficult with various textiles, synthesis leather goods resinae blend, cause a kind of mill base can only be to one
The colouring of kind of product, aqueous color paste are difficult to general in various textiles, synthetic leather material and building inside and outside wall, and interchangeability is poor.And
The waterborne general color paste manufactured using deionized water as matrix, solves above mentioned problem to a certain extent.But because of toner not
Easily disperse in deionized water solvent, therefore the toner content of existing deionized water solvent waterborne general color paste is not high, thus
Concentration property is not high, and tinting strength, tinting power is also poor compared to oil pastes.
Therefore, a kind of long shelf-life how is realized, textile, synthetic leather material or Discussion on architecture wall can be common to,
Strong coloring force, it is technology urgently to be resolved hurrily in the industry that will not cause decentralized waterborne general color chips of environmental pollution and preparation method thereof
Problem.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of decentralized waterborne general color chips, the color chips long shelf-life, energy
Textile, synthetic leather material or Discussion on architecture wall are enough common to, strong coloring force, the decentralized of environmental pollution will not be caused water-based
General color chips and its manufacture method.
In order to solve the above-mentioned technical problem, the technical scheme is that, a kind of decentralized waterborne general color chips, by following
The each component composition of mass ratio：Acrylic dispersing resin 20~40%, toner 60~80%, wherein, acrylic dispersing resin bag
Include each component of following mass fraction：
The polymer that the acrylic dispersing resin each group lease making saponification forms, as acrylic dispersing resin.
A kind of method for making decentralized waterborne general color chips, is comprised the steps of：
(1) acrylic dispersing resin, toner described in saponification are added in kneading pot successively, and tentatively mediated
Into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading in kneader；
(3) by the colloid after high-speed kneading after the hot-press solidifying of tilted back type three roll machine for being heated to 125 DEG C, place normal
Temperature cooling, forms color lump, decentralized waterborne general color chips is can obtain after color lump is crushed.
Using above-mentioned technical proposal, due to being combined using propylene dispersion resin with colorant, decentralized waterborne general is extended
The storage life of color chips, and the scope of application of the color chips has been widened, textile, synthetic leather material or building can be common to
External and internal wall, strong coloring force, propylene dispersion resin and color need to be only passed through when being produced additionally, due to the decentralized waterborne general color chips
Kneading, the solidification of material, are carrier without the use of deionized water, technological process is simple, and production cost is low, and will not cause environment
Pollution.
Embodiment
It is described further with reference to embodiment.Herein it should be noted that for these embodiments
Illustrate to be used to help understand the present invention, but do not form limitation of the invention.In addition, each reality of invention described below
It is mutually combined as long as applying technical characteristic involved in mode and not forming conflict can each other.
During due to being prepared in the acrylic dispersing resin in the present invention, though the adding proportion of each component is different, but instead
The acrylic dispersing resin that should be generated afterwards, its property approach, therefore are only generated with each component saponification of following mass fraction
The acrylic dispersing resin made in lower embodiment of acrylic dispersing resin illustrate.
In embodiments of the invention, toner can be tested using different colours, and can only be made using different toners
Into the difference of color, phthalocyanine blue toner, dark green toner, carbon black toner can be such as used, different colors can't be to it
Other characteristics in addition to color have an impact, and in order that have comparativity between different embodiment and comparative example, implement below
Example, the toner of comparative example use carbon black toner, and preservative and defoamer are conventional type, if defoamer can be organic disappears
The common types such as infusion, organic silicon defoamer and polyether-type defoamer, and preservative is conventional technical grade preservative, is prevented
Rotten agent and the reaction for being not involved in system, therefore specific limitation is had no to the species of preservative, only entered herein with CTAC preservatives
Row explanation.
Embodiment 1
Carbon black toner 75%, acrylic dispersing resin 25% are taken in mass ratio, and it is added in kneading pot successively
Row is preliminary to be mediated, and colloid is formed after the completion of kneading, then will be mediated 2 hours in colloid and high-speed kneading machine, again will after high-speed kneading
Colloid carries out hot-press solidifying by being heated on 125 DEG C of tilted back type three roll machines, and its normal temperature is cooled down, and forms color lump, and by color
Block can form decentralized waterborne general color chips after crushing.
Embodiment 2
Carbon black toner 70%, acrylic dispersing resin 30% are taken in mass ratio, and it is added in kneading pot successively
Row is preliminary to be mediated, and colloid is formed after the completion of kneading, then will be mediated 2 hours in colloid and high-speed kneading machine, again will after high-speed kneading
Colloid carries out hot-press solidifying by being heated on 125 DEG C of tilted back type three roll machines, and its normal temperature is cooled down, and forms color lump, and by color
Block can form decentralized waterborne general color chips after crushing.
Embodiment 3
Carbon black toner 80%, acrylic dispersing resin 20% are taken in mass ratio, and it is added in kneading pot successively
Row is preliminary to be mediated, and colloid is formed after the completion of kneading, then will be mediated 2 hours in colloid and high-speed kneading machine, again will after high-speed kneading
Colloid carries out hot-press solidifying by being heated on 125 DEG C of tilted back type three roll machines, and its normal temperature is cooled down, and forms color lump, and by color
Block can form decentralized waterborne general color chips after crushing.
Embodiment 4
Using carbon black toner as colorant, take phthalocyanine blue toner 60%, acrylic dispersing resin 40% in mass ratio, and by its according to
Secondary be added in kneading pot is tentatively mediated, and colloid is formed after the completion of kneading, then colloid is small with mediating 2 in high-speed kneading machine
When, again colloid is subjected to hot-press solidifying by being heated on 125 DEG C of tilted back type three roll machines after high-speed kneading, and its normal temperature is cold
But, color lump is formed, and decentralized waterborne general color chips can be formed after color lump is crushed.
Comparative example
At present, traditional color chips is made up of the raw material of following mass fraction：1250~5600 parts of carbon black toner；Styrene-the third
2100~3700 parts of olefin(e) acid resin；300 parts of monoethanolamine；5000 parts of water.During preparation, each original is weighed by above-mentioned mass fraction first
Material；Then styrene-acrylic resins, monoethanolamine and water are poured into the material cylinder of ball mill, grinds 5~20 minutes, fill it
The mixed dissolution divided, emulsion is made；Then primary colors powder is poured into material cylinder, is disperseed within 2~2.5 hours using ball mill grinding, made
Emulsion is sufficiently mixed with primary colors powder, and slurry is made；Finally, slurry is dried using drying machine, obtains the water of solid
Property color chips.
When above example and comparative example are tested, test formulations that tinting strength, tinting power, dispersiveness and viscosity use for：
60g deionized waters add 40g color chips, while use commercially available laboratory high speed dispersor (model：KFS-400W) with speed
4000RPM disperse 2 hours, and last test result is as follows：
Tinting strength, tinting power is also known as tinctorial strength, refers to that a certain pigment forms the strong and weak ability of color after being mixed with benchmark pigment,
Color power assay method is usually taken compared with standard sample, is determined, is expressed as a percentage with its difference ratio.
Dispersiveness is mainly filtered with 1000 mesh filter screens, and its dispersed height is contrasted by determining whether there is residue.
After tested, decentralized waterborne general color chips of the invention compare comparative example product viscosity it is at least high by 10%, simultaneously
Toner content is higher than comparative example color chips, so as to which tinting strength, tinting power is more preferable than comparative example, in addition, the grain fineness of the present invention is less than 5 μm, has
Sharp toner disperses in system, and toner retention time in system is grown.
It is explained in detail above in association with embodiments of the present invention, but the invention is not restricted to described embodiment.
For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out
A variety of change, modification, replacement and modification, still fall within protection scope of the present invention.
Claims (3)
1. a kind of decentralized waterborne general color chips, it is characterised in that be made up of each component of following mass ratio：The scattered tree of acrylic acid
Fat 20~40%, toner 60~80%, the acrylic dispersing resin include each component of following mass fraction：
30~32 parts of ethyl acrylate
10~12 parts of butyl acrylate
4~5 parts of methyl methacrylate
1 part of methacrylic acid
1 part of hydroxyethyl methacrylate
0.4~1 part of DAAM
0.1~0.3 part of oxalyl dihydrazide
1 part of triethanolamine
0.2 part of potassium peroxydisulfate
1.5 parts of palmitin acid butyl ester
2~3 parts of surfactant
0.05 part of defoamer
40~45 parts of water
The saponification polymer formed of acrylic dispersing resin each group lease making, as acrylic dispersing resin.
2. decentralized waterborne general color chips according to claim 1, it is characterised in that described acrylic dispersing resin bag
Include the preservative of 0.01 mass fraction.
A kind of 3. method of the decentralized waterborne general color chips made described in claim 1, it is characterised in that include following step
Suddenly：
(1) acrylic dispersing resin of saponification synthesis, toner are added in kneading pot, and tentatively pinched successively
Synthesize colloid；
(2) above-mentioned colloid is subjected to high-speed kneading in kneader；
(3) by the colloid after high-speed kneading after the hot-press solidifying of tilted back type three roll machine for being heated to 125 DEG C, it is cold to place normal temperature
But, color lump is formed, decentralized waterborne general color chips is can obtain after color lump is crushed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/091682 WO2018018399A1 (en) | 2016-07-26 | 2016-07-26 | Dispersion type water-based universal color chips |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107690460A true CN107690460A (en) | 2018-02-13 |
Family
ID=61015569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680027502.0A Pending CN107690460A (en) | 2016-07-26 | 2016-07-26 | A kind of decentralized waterborne general color chips |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN107690460A (en) |
| WO (1) | WO2018018399A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841251A (en) * | 2018-07-04 | 2018-11-20 | 浙江大利实业有限公司 | Opaque adhesive tape mill base of a kind of aqueous, environmental protective for joint sealing and preparation method thereof |
| CN109385138A (en) * | 2018-11-06 | 2019-02-26 | 厦门易统水墨有限公司 | A kind of aqueous solid soluble ink and processing technology again |
| CN115073869A (en) * | 2021-08-12 | 2022-09-20 | 东莞市集丰塑化材料有限公司 | Preparation method of acrylic solid pigment and acrylic solid pigment |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206360A (en) * | 2011-03-31 | 2011-10-05 | 佛山市顺德区天隆颜料有限公司 | Water-based color chip for artificial leather and preparation method thereof |
| CN102212278A (en) * | 2011-03-31 | 2011-10-12 | 佛山市顺德区天隆颜料有限公司 | Aqueous black sheet used for artificial leather and preparation method thereof |
| CN102212277A (en) * | 2011-03-31 | 2011-10-12 | 佛山市顺德区天隆颜料有限公司 | Aqueous white color chip for artificial leather and preparation method thereof |
| CN103965393A (en) * | 2014-05-06 | 2014-08-06 | 江门骅弘颜料有限公司 | Water-based acrylic resin |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003087248A1 (en) * | 2002-04-15 | 2003-10-23 | Kuboko Paint Co., Ltd. | Water-dispersed powder coating, process for the production thereof, and color matching method |
| CN103965698A (en) * | 2014-05-06 | 2014-08-06 | 江门骅弘颜料有限公司 | Water-oil dual-use color paste |
-
2016
- 2016-07-26 WO PCT/CN2016/091682 patent/WO2018018399A1/en active Application Filing
- 2016-07-26 CN CN201680027502.0A patent/CN107690460A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206360A (en) * | 2011-03-31 | 2011-10-05 | 佛山市顺德区天隆颜料有限公司 | Water-based color chip for artificial leather and preparation method thereof |
| CN102212278A (en) * | 2011-03-31 | 2011-10-12 | 佛山市顺德区天隆颜料有限公司 | Aqueous black sheet used for artificial leather and preparation method thereof |
| CN102212277A (en) * | 2011-03-31 | 2011-10-12 | 佛山市顺德区天隆颜料有限公司 | Aqueous white color chip for artificial leather and preparation method thereof |
| CN103965393A (en) * | 2014-05-06 | 2014-08-06 | 江门骅弘颜料有限公司 | Water-based acrylic resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841251A (en) * | 2018-07-04 | 2018-11-20 | 浙江大利实业有限公司 | Opaque adhesive tape mill base of a kind of aqueous, environmental protective for joint sealing and preparation method thereof |
| CN109385138A (en) * | 2018-11-06 | 2019-02-26 | 厦门易统水墨有限公司 | A kind of aqueous solid soluble ink and processing technology again |
| CN115073869A (en) * | 2021-08-12 | 2022-09-20 | 东莞市集丰塑化材料有限公司 | Preparation method of acrylic solid pigment and acrylic solid pigment |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018018399A1 (en) | 2018-02-01 |
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Application publication date: 20180213 |
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