CN107674533A - A kind of anti-flaming dope for refrigerator - Google Patents
A kind of anti-flaming dope for refrigerator Download PDFInfo
- Publication number
- CN107674533A CN107674533A CN201711058478.XA CN201711058478A CN107674533A CN 107674533 A CN107674533 A CN 107674533A CN 201711058478 A CN201711058478 A CN 201711058478A CN 107674533 A CN107674533 A CN 107674533A
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- China
- Prior art keywords
- parts
- refrigerator
- flaming dope
- raw material
- minutes
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:10 15 parts of acrylic resin, 10 15 parts of kaolin, 5 10 parts of Tissuemat E, 5 10 parts of APP, 15 parts of sepiolite powder, 15 parts of ammonium dihydrogen phosphate, 0.5 1 parts of silica, 0.5 1 parts of makrolon, 0.5 1 parts of zinc stearate, 0.1 1 parts of ceramic, 0.01 0.05 parts of N methyl morpholine N oxides, 25 parts of additive.The made anti-flaming dope of the present invention is applied to the processing of outcase of refrigerator, the anti-flaming dope and outcase of refrigerator, which mainly process raw material, has good comixing compatibility between ABS and PC, and the blending for effectively facilitating raw material is compatible, can play made outcase of refrigerator of sening as an envoy to has the impact of performance of excellent flame retardancy.
Description
Technical field:
The present invention relates to outcase of refrigerator processing technique field, and in particular to a kind of anti-flaming dope for refrigerator.
Background technology:
With the fast development of refrigerator industry, outcase of refrigerator is also therewith towards intensity is high, rigidity is big, light-weighted direction hair
Exhibition.At present, in the market majority outcase of refrigerator is all to do raw material using PC/ABS engineering plastic alloys, and this material both has PC
Excellent heat-resisting weatherability, dimensional stability and the impact resistance of resin, there is the excellent processing fluidity of ABS resin again.
But with the development of refrigerator, for the fragile electronic component of protection, strengthen the factors such as integral frame intensity
Consider, the comprehensive mechanical performance of PC/ABS alloys seems not ideal enough, therefore also needs to be used for performance to be further improved
And raising.
The content of the invention:
The technical problems to be solved by the invention are to provide that a kind of flame retardant rating reaches V-0 levels and oxygen index (OI) reaches
44.5% anti-flaming dope for refrigerator.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
Acrylic resin 10-15 parts, kaolin 10-15 parts, Tissuemat E 5-10 parts, APP 5-10 parts, sepiolite
Powder 1-5 parts, ammonium dihydrogen phosphate 1-5 parts, silica 0.5-1 parts, makrolon 0.5-1 parts, zinc stearate 0.5-1 parts, ceramics
Micro mist 0.1-1 parts, N-methylmorpholine-N- oxide 0.01-0.05 parts, additive 2-5 parts.
The above-mentioned anti-flaming dope for refrigerator, the raw material for being preferably as follows parts by weight are made:
13 parts of acrylic resin, 13 parts of kaolin, 8 parts of APP, 3 parts of sepiolite powder, 3 parts of ammonium dihydrogen phosphate, dioxy
0.8 part of SiClx, 0.8 part of makrolon, 0.8 part of zinc stearate, 0.5 part of ceramic, N-methylmorpholine-N- oxides 0.03
Part, 4 parts of additive.
Further, the additive is made up of the raw material of following parts by weight:Graphite 3-6 parts, mica powder 2-4 parts, pottery
Porcelain fiber 2-4's, cornstarch 1-3 parts, bamboo-carbon fibre 1-2 parts, chitin 0.8-1.2 parts, pitch 0.3-0.8 parts, aromatic naphtha
0.5-1 parts.
Further, the additive is preferably as follows the raw materials of parts by weight and is made:5 parts of graphite, 3 parts of mica powder, ceramics
Fiber 3,2 parts of cornstarch, 1.5 parts of bamboo-carbon fibre, 1 part of chitin, 0.5 part of pitch, 0.8 part of aromatic naphtha.
Its preparation method comprises the following steps:
A, acrylic resin, kaolin, APP, silica, zinc stearate are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20-30 minutes;
B, sepiolite powder, ammonium dihydrogen phosphate, makrolon, ceramic, N-methylmorpholine-N- oxides are added to instead
Answer in kettle, temperature setting is reacted, the reaction time is 30-40 minutes in 120-150 degree;
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800-1000r/
Min, temperature setting 80-90, mixing time are 20-30 minutes;
D, additive is added in step c mixer, continues to stir, mixing speed 1200-1400r/min, temperature
Degree is arranged to 40-60, and mixing time is 30-40 minutes;
E, the mixture for handling step d well, it is ground, that is, obtains finished product.
Further, described to be ground to three sections of grindings, grinding rate is respectively:90-100/rpm, 100-120/rpm,
120-150/rpm。
The beneficial effects of the invention are as follows:The made anti-flaming dope of the present invention is applied to the processing of outcase of refrigerator, the anti-flaming dope
Mainly being processed raw material with outcase of refrigerator has good comixing compatibility between ABS and PC, and effectively facilitates the blending phase of raw material
Hold;And the anti-flaming dope is remarkably improved the anti-flammability of made outcase of refrigerator when its quality addition is 2.5%, fire-retardant
Grade reaches V-0 levels, and oxygen index (OI) reaches 44.5%, therefore made outcase of refrigerator tool of sening as an envoy to can be played on the basis of its low dosage
There is the impact of performance of excellent flame retardancy.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
10 parts of acrylic resin, 10 parts of kaolin, 5 parts of APP, 1 part of sepiolite powder, 1 part of ammonium dihydrogen phosphate, dioxy
0.5 part of SiClx, 0.5 part of makrolon, 0.5 part of zinc stearate, 0.1 part of ceramic, N-methylmorpholine-N- oxides 0.01
Part, 2 parts of additive.
The additive is made up of the raw material of following parts by weight:3 parts of graphite, 2 parts of mica powder, ceramic fibre 2, corn
1 part of starch, 1 part of bamboo-carbon fibre, 0.8 part of chitin, 0.3 part of pitch, 0.5 part of aromatic naphtha.
Its preparation method comprises the following steps:
A, acrylic resin, kaolin, APP, silica, zinc stearate are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20 minutes;
B, sepiolite powder, ammonium dihydrogen phosphate, makrolon, ceramic, N-methylmorpholine-N- oxides are added to instead
Answer in kettle, temperature setting is reacted at 120 degree, and the reaction time is 30 minutes;
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800r/min, temperature
Degree is arranged to 80, and mixing time is 20 minutes;
D, additive is added in step c mixer, continues to stir, mixing speed 1200r/min, temperature setting
For 40, mixing time is 30 minutes;
E, the mixture for handling step d well, segmentation grinding is carried out, that is, obtains finished product.
Further, the segmentation grinding is divided into three sections, and grinding rate is respectively:90/rpm, 100/rpm, 120/rpm.
Embodiment 2
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
15 parts of acrylic resin, 15 parts of kaolin, 10 parts of APP, 5 parts of sepiolite powder, 5 parts of ammonium dihydrogen phosphate, dioxy
1 part of SiClx, 1 part of makrolon, 1 part of zinc stearate, 1 part of ceramic, 0.05 part of N-methylmorpholine-N- oxides, additive 5
Part.
Further, the additive is made up of the raw material of following parts by weight:6 parts of graphite, 4 parts of mica powder, ceramics are fine
Dimension 4,3 parts of cornstarch, 2 parts of bamboo-carbon fibre, 1.2 parts of chitin, 0.8 part of pitch, 1 part of aromatic naphtha.
Its preparation method comprises the following steps:
A, acrylic resin, kaolin, APP, silica, zinc stearate are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 30 minutes;
B, sepiolite powder, ammonium dihydrogen phosphate, makrolon, ceramic, N-methylmorpholine-N- oxides are added to instead
Answer in kettle, temperature setting is reacted at 150 degree, 40 minutes reaction time;
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 1000r/min, temperature
Degree is arranged to 90, and mixing time is 30 minutes;
D, additive is added in step c mixer, continues to stir, mixing speed 1400r/min, temperature setting
For 60, mixing time is 40 minutes;
E, the mixture for handling step d well, segmentation grinding is carried out, that is, obtains finished product.
Further, the segmentation grinding is divided into three sections, and grinding rate is respectively:100/rpm, 120/rpm, 150/rpm.
Embodiment 1
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
10 parts of acrylic resin, 10 parts of kaolin, 5 parts of APP, 1 part of sepiolite powder, 1 part of ammonium dihydrogen phosphate, dioxy
0.5 part of SiClx, 0.5 part of makrolon, 0.5 part of zinc stearate, 0.1 part of ceramic, N-methylmorpholine-N- oxides 0.01
Part.
Its preparation method comprises the following steps:
A, acrylic resin, kaolin, APP, silica, zinc stearate are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20 minutes;
B, sepiolite powder, ammonium dihydrogen phosphate, makrolon, ceramic, N-methylmorpholine-N- oxides are added to instead
Answer in kettle, temperature setting is reacted at 120 degree, and the reaction time is 30 minutes;
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800r/min, temperature
Degree is arranged to 80, and mixing time is 20 minutes;
D, additive is added in step c mixer, continues to stir, mixing speed 1200r/min, temperature setting
For 40, mixing time is 30 minutes;
E, the mixture for handling step d well, it is ground, that is, obtains finished product.
Embodiment 2
A kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
15 parts of acrylic resin, 15 parts of kaolin, 10 parts of APP, 5 parts of sepiolite powder, 5 parts of ammonium dihydrogen phosphate, dioxy
1 part of SiClx, 1 part of makrolon, 1 part of zinc stearate, 1 part of ceramic, 0.05 part of N-methylmorpholine-N- oxides.
Its preparation method comprises the following steps:
A, all material is heated to molten condition, is stirred reaction, mixing time is 30 minutes;
B, the material of step a molten conditions is stirred, mixing speed 1000r/min, temperature setting 90, stirred
Time is 30 minutes.
C, the mixture for handling step b well, segmentation grinding is carried out, that is, obtains finished product.
Table 1 is added in the production process of back boards for the present invention with control group, performance test
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (6)
1. a kind of anti-flaming dope for refrigerator, it is made up of the raw material of following parts by weight:
Acrylic resin 10-15 parts, kaolin 10-15 parts, Tissuemat E 5-10 parts, APP 5-10 parts, sepiolite powder 1-5
Part, ammonium dihydrogen phosphate 1-5 parts, silica 0.5-1 parts, makrolon 0.5-1 parts, zinc stearate 0.5-1 parts, ceramic
0.1-1 parts, N-methylmorpholine-N- oxide 0.01-0.05 parts, additive 2-5 parts.
2. the anti-flaming dope according to claim 1 for refrigerator, it is characterised in that:It is preferably as follows the raw material of parts by weight
It is made:13 parts of acrylic resin, 13 parts of kaolin, 8 parts of APP, 3 parts of sepiolite powder, 3 parts of ammonium dihydrogen phosphate, silica
0.8 part, 0.8 part of makrolon, 0.8 part of zinc stearate, 0.5 part of ceramic, 0.03 part of N-methylmorpholine-N- oxides, add
Add 4 parts of agent.
3. the anti-flaming dope according to claim 1 for refrigerator, it is characterised in that:The additive is by following parts by weight
Several raw materials are made:Graphite 3-6 parts, mica powder 2-4 parts, ceramic fibre 2-4's, cornstarch 1-3 parts, bamboo-carbon fibre 1-2 parts,
Chitin 0.8-1.2 parts, pitch 0.3-0.8 parts, aromatic naphtha 0.5-1 parts.
4. the anti-flaming dope according to claim 1 for refrigerator, it is characterised in that:The additive is preferably as follows weight
The raw material of number is made:5 parts of graphite, 3 parts of mica powder, ceramic fibre 3,2 parts of cornstarch, 1.5 parts of bamboo-carbon fibre, chitin
1 part, 0.5 part of pitch, 0.8 part of aromatic naphtha.
5. the anti-flaming dope according to claim 1 or 2 for refrigerator, it is characterised in that:Its preparation method includes as follows
Step:
A, acrylic resin, kaolin, APP, silica, zinc stearate are mixed, is heated to molten condition, carried out
Stirring reaction, mixing time are 20-30 minutes;
B, sepiolite powder, ammonium dihydrogen phosphate, makrolon, ceramic, N-methylmorpholine-N- oxides are added to reactor
In, temperature setting is reacted, the reaction time is 30-40 minutes in 120-150 degree;
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800-1000r/min, temperature
Degree is arranged to 80-90, and mixing time is 20-30 minutes;
D, additive is added in step c mixer, continues to stir, mixing speed 1200-1400r/min, temperature is set
40-60 is set to, mixing time is 30-40 minutes;
E, the mixture for handling step d well, it is ground, that is, obtains finished product.
6. the anti-flaming dope according to claim 5 for refrigerator, it is characterised in that:It is described to be ground to three sections of grindings, grind
Grinding speed is respectively:90-100/rpm, 100-120/rpm, 120-150/rpm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711058478.XA CN107674533A (en) | 2017-11-01 | 2017-11-01 | A kind of anti-flaming dope for refrigerator |
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CN201711058478.XA CN107674533A (en) | 2017-11-01 | 2017-11-01 | A kind of anti-flaming dope for refrigerator |
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CN107674533A true CN107674533A (en) | 2018-02-09 |
Family
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CN201711058478.XA Pending CN107674533A (en) | 2017-11-01 | 2017-11-01 | A kind of anti-flaming dope for refrigerator |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108329798A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | Anti-flaming dope for new-energy automobile |
CN114716716A (en) * | 2022-04-28 | 2022-07-08 | 昆山吉山会津塑料工业股份有限公司 | Flame-retardant left outer guard plate of right rear seat |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107151500A (en) * | 2017-06-29 | 2017-09-12 | 太仓红潮新材料科技有限公司 | Anti-flaming dope and its application |
-
2017
- 2017-11-01 CN CN201711058478.XA patent/CN107674533A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107151500A (en) * | 2017-06-29 | 2017-09-12 | 太仓红潮新材料科技有限公司 | Anti-flaming dope and its application |
Non-Patent Citations (1)
Title |
---|
涂料工艺编委会: "《涂料工艺 第三版 下册》", 31 December 1997, 化学工业出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108329798A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | Anti-flaming dope for new-energy automobile |
CN114716716A (en) * | 2022-04-28 | 2022-07-08 | 昆山吉山会津塑料工业股份有限公司 | Flame-retardant left outer guard plate of right rear seat |
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Application publication date: 20180209 |