CN107652794A - A kind of graphene is modified radiating anti-corrosion fluorine carbon functional paint and preparation method thereof - Google Patents
A kind of graphene is modified radiating anti-corrosion fluorine carbon functional paint and preparation method thereof Download PDFInfo
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- CN107652794A CN107652794A CN201711014851.1A CN201711014851A CN107652794A CN 107652794 A CN107652794 A CN 107652794A CN 201711014851 A CN201711014851 A CN 201711014851A CN 107652794 A CN107652794 A CN 107652794A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to functional paint technical field, especially a kind of graphene is modified radiating anti-corrosion fluorine carbon functional paint and preparation method thereof.It includes following components by weight：Water-based 20 45 parts of FEVE fluorocarbon resins emulsion, 5 25 parts of polymethyl methacrylate emulsion, 5 20 parts of functionalization graphene dispersion liquid, 5 10 parts of radial pattern inorganic matter, 10 35 parts of color stuffing, 5 10 parts of auxiliary agent, 10 35 parts of deionized water.The present invention improves its compatibility with resin matrix, so as to play radiating and antisepsis of the graphene in coating system using water-based FEVE fluorocarbon resins emulsion and polymethyl methacrylate emulsion as main film forming matter by the modification to graphene；Meanwhile the heat dispersion of film is can further improve by adding radial pattern inorganic matter；Obtained coating has the characteristics of perfect heat-dissipating, antiseptic property are excellent, combination property is good, environment-friendly, has good social and economic benefit.
Description
Technical field
The present invention relates to functional paint technical field, especially a kind of graphene is modified radiating-anti-corrosion fluorine carbon functional paint
And preparation method thereof.
Background technology
Known, graphene makes it all present huge potentiality in every field because of special performance possessed by its structure
With application prospect, at present turn into domestic and international scientific research focus.However, relevant graphene and its composite are in paint field
Application it is also relatively fewer, the compatibility of especially graphene and polymer is that the current graphene that restricts is applied in paint field
One of key issue.
The content of the invention
For above-mentioned the shortcomings of the prior art, one of purpose of the invention is that providing a kind of graphene is modified
Radiating-anti-corrosion fluorine carbon functional paint；It is another object of the present invention to provide a kind of graphene to be modified radiating-anti-corrosion fluorine carbon work(
The preparation method of energy coating.
To achieve these goals, the present invention use first technical scheme for：
A kind of graphene is modified radiating-anti-corrosion fluorine carbon functional paint, by weight, including following components：Water-based FEVE
Fluorocarbon resin emulsion 20-45 parts, polymethyl methacrylate emulsion 5-25 parts, functionalization graphene dispersion liquid 5-20 parts, radiation
Type inorganic matter 5-10 parts, color stuffing 10-35 parts, auxiliary agent 5-10 parts, deionized water 10-35 parts.
Wherein, preferred scheme is：The quality of the water-based FEVE fluorocarbon resins emulsion and polymethyl methacrylate emulsion
Than for 1:5-15.
Wherein, preferred scheme is：The quality of the functionalization graphene dispersion liquid and water-based FEVE fluorocarbon resins emulsion and
Ratio between the gross mass of polymethyl methacrylate emulsion is 1:10-25.
Wherein, preferred scheme is：The functionalization graphene dispersion liquid includes following component by weight：Aoxidize stone
Black alkene 1-10 parts, chloroacetic acid 1-5 parts, cetyl trimethylammonium bromide 1-5 parts, sodium hydroxide 0.5-2 parts, emulsifying agent 0-5
Part, water 1-50 parts, ethanol 1-15 parts.
Wherein, preferred scheme is：The radial pattern inorganic matter is the tin-antiomony oxide and indium oxide that particle diameter is equal 20-200nm
At least one of tin.
Wherein, preferred scheme is：The mass ratio of tin oxide and antimony oxide in the tin-antiomony oxide is 9:1, the oxidation
The mass ratio of indium oxide and antimony oxide in indium tin is 9:1.
Wherein, preferred scheme is：The color stuffing is one kind or several in montmorillonite, rutile type titanium white and sericite
Kind combination.
Wherein, preferred scheme is：The auxiliary agent includes following component by weight：Defoamer 0.05-5 parts, disperse
Agent 0.05-5 parts, wetting agent 0.05-5 parts, thickener 0.05-5 parts, film forming agent 0.05-5 parts, antifreezing agent 1.01-5 parts, PH regulations
Agent 0.05-5 parts；
Wherein, the defoamer is mineral oil defoaming agent or polyethers defoamer, and the dispersant is polycarboxylate sodium
Type dispersant, the wetting agent are sulfonic acid anion surfactant, the thickener be polyacrylate-type thickeners or
Polyvinyl alcohol thickener, the film forming agent are lauryl alcohol ester, and the antifreezing agent is propane diols, and the PH conditioning agents are Organic Alcohol
Aminated compounds.
Second technical scheme that the present invention uses for：
A kind of graphene is modified the preparation method of radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：Including following step
Suddenly：
S1, by weight ratio by the defoamer in deionized water, radial pattern inorganic matter, color stuffing and auxiliary agent, scattered
Agent, wetting agent, thickener, film forming agent and antifreezing agent are added in container, and 10-25min is stirred with 1000-1500rpm speed, then
20-30min is stirred with 2000-2500rpm speed, slurry is made；
S2, in the case where slurry is in stirring, added by weight ratio into slurry water-based FEVE fluorocarbon resins emulsion,
Polymethyl methacrylate emulsion and functionalization graphene dispersion liquid, after 1500-2000rpm speed stirring 20min, it is made
Coating semi-finished product；
S3, the PH conditioning agents in auxiliary agent are added in coating semi-finished product and by the pH value of coating semi-finished product by weight ratio
After being adjusted to 7-8, discharged after continuing the speed stirring 20-30min with 2000-2500rpm, you can obtained graphene modification radiating-
Anti-corrosion fluorine carbon functional paint finished product.
Wherein, preferred scheme is：The step of it also prepares functionalization graphene dispersion liquid including one；Prepare function graphite
The step of alkene dispersion liquid is：
(1) the chloride step of graphene oxide：
First, parts by weights proportioning is added graphene oxide into suitable quantity of water, is made ultrasonic wave after vibration shakes up and is disperseed 40-
60min, then it is again heated to 40-60 DEG C；
Secondly, after adding chloroacetic acid, sodium hydroxide and ethanol by weight ratio, stirring reaction 10-30min, so as to
Carboxyl on graphene oxide is converted into acid chloride group by esterification, to form primary first-order equation thing；
(2) amidation step of graphene oxide：Cetyl trimethylammonium bromide is added once by weight ratio
In reactant, the acid chloride group generated on graphene oxide is converted into acid amides, there is the function of stablizing covalent bond so as to generate
Graphite alkene dispersion liquid；
(3) emulsifying step of graphene oxide：Parts by weights proportioning, which adds emulsifying agent in secondary response thing, stirs 10-
30min, so as to the hydrophilicity of enhanced feature graphite alkene dispersion liquid.
As a result of such scheme, it has the advantages that：1st, by innovatively carrying out work(to graphene oxide
Energyization is modified, and improves the compatibility of graphene and resin matrix, more effectively plays radiating of the graphene in coating system
And antisepsis；2nd, the good thermal conductivity of graphene assigns coating system excellent heat sinking function, and the big table of the sheet of graphene
Face structure and electric conductivity then assign coating system excellent antiseptic property；3rd, there is the radial pattern of high IR emitting performance in system
The addition of inorganic matter, it can further improve the radiating effect of film；4th, with water-based FEVE fluorocarbon resins emulsion and poly- methyl-prop
E pioic acid methyl ester emulsion is Primary resins film forming matrix, assigns the outstanding advantage of the excellent combination property of the coating and normal temperature cure,
There is environment-friendly characteristic simultaneously.
Embodiment
Embodiments of the invention are described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Embodiment one：
1st, functionalization graphene dispersion liquid is prepared：
(1) chloride of graphene oxide：
First, by graphene oxide and add in suitable quantity of water using configuration in concentration as 10g/L solution, vibrated by solution liquid
Make ultrasonic wave after shaking up and disperse 40-60min, be 10g/L graphene oxide aqueous dispersions so as to which concentration be made；
Secondly, take 50mL graphene oxide aqueous dispersions to be heated to 45 DEG C, then add 0.5g chloroacetic acids, 0.5g hydrogen
After sodium oxide molybdena and 15g ethanol, stirring reaction 30min, so as to which the carboxyl on graphene oxide is converted into acyl by esterification
Chloro, to form primary first-order equation thing；
(1) amidatioon of graphene oxide：3g cetyl trimethylammonium bromides are added in primary first-order equation thing, by oxygen
The acid chloride group generated on graphite alkene is converted into acid amides, has the functionalization graphene dispersion liquid for stablizing covalent bond so as to generate；
(2) emulsification of graphene oxide：1g emulsifying agents are added in secondary response thing and stir 10-30min, so as to lift work(
The hydrophilicity of energy graphite alkene dispersion liquid.
2nd, prepare graphene and be modified radiating-anti-corrosion fluorine carbon functional paint, i.e.,：
First, each component is weighed according to the following formulation：Water-based FEVE fluorocarbon resins emulsion 40g, polymethyl methacrylate
Emulsion is (i.e.：PMMA) 8g, functionalization graphene dispersion liquid 15mL, radial pattern inorganic matter 5g, color stuffing 13g, auxiliary agent 14.5g, go
Ionized water 15g；Wherein,
Radial pattern inorganic matter selects tin-antiomony oxide (i.e.：ATO, wherein, the mass ratio of tin oxide and antimony oxide is SnO2:
Sb2O3=9:1)；
Color stuffing selects 8g montmorillonites and 5g rutile type titanium whites；
Selection of auxiliary 0.5g mineral oil defoaming agents (such as NXZ), 1g polycarboxylate sodium's type dispersants (such as SN-5040), 1g
Wetting agent is (i.e.：Sulfonic acid anion surfactant, such as SN WET991), 3g polyvinyl alcohols thickener (such as PEG800 or
PEG600), 1g film forming agents are (i.e.：Lauryl alcohol ester), 3g antifreezing agents (i.e.:Propane diols) and 5g PH conditioning agents (such as organic alcohol amine CP-
802)。
Secondly, prepare according to the following steps：
S1, the defoamer by deionized water, radial pattern inorganic matter, color stuffing and auxiliary agent, dispersant, wetting agent, increasing
Thick dose, film forming agent and antifreezing agent are added in container, first stir 10-25min with 1000-1500rpm speed, then with 2000-
2500rpm speed stirring 30min, is made slurry；
S2, in the case where slurry is in stirring, water-based FEVE fluorocarbon resins emulsion, polymethyl methacrylate into slurry
Emulsion and functionalization graphene dispersion liquid, after 1500-2000rpm speed stirring 20min, coating semi-finished product are made；
S3, will after PH conditioning agents in auxiliary agent add in coating semi-finished product and the pH value of coating semi-finished product are adjusted into 7-8, after
Discharged after the continuous speed stirring 30min with 2000-2500rpm, you can graphene is made and is modified radiating-anti-corrosion fluorine carbon functional paint
Finished product.
Embodiment two：It is with the differential point of embodiment one：It is configuration solubility when preparing functionalization graphene dispersion liquid
For 20g/L graphene oxide aqueous dispersions.
Embodiment three：First, each component is weighed according to the following formulation：Water-based FEVE fluorocarbon resins emulsion 45g, poly- methyl-prop
Functionalization graphene dispersion liquid 15mL, radial pattern inorganic matter 5g, color stuffing 16g in e pioic acid methyl ester emulsion 5g, embodiment one, help
Agent 14.5g, deionized water 15g；Wherein,
Radial pattern inorganic matter selects tin indium oxide (i.e.：ITO, wherein, the mass ratio of indium oxide and tin oxide is In2O3:
SnO2=9:1)；
Color stuffing selects 8g montmorillonites and 8g rutile type titanium whites；
Selection of auxiliary 0.5g polyethers defoamer (such as GPE), 1g polycarboxylate sodium's type dispersants (such as SN-5040), 1g profits
Humectant is (i.e.：Sulfonic acid anion surfactant, such as SN WET991), 3g polyvinyl alcohols thickener (such as PEG800 or
PEG600), 1g film forming agents are (i.e.：Lauryl alcohol ester), 3g antifreezing agents (i.e.:Propane diols) and 5g PH conditioning agents (such as organic alcohol amine CP-
802)。
Secondly, graphene modification radiating-anti-corrosion fluorine carbon functional paint is prepared using with the identical method and step of embodiment one.
Radiating-anti-corrosion fluorine carbon functional paint progressive is modified to the graphene of embodiment one, embodiment two and embodiment three
It can detect, the data result of detection see the table below.
From testing result, graphene provided by the invention, which is modified radiating-anti-corrosion fluorine carbon functional paint, to be had waterproof, dissipates
Many advantages, such as good in thermal property, its combination property are good.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the scope of the invention, every utilization
The equivalent structure or equivalent flow conversion that present specification is made, or directly or indirectly it is used in other related technologies
Field, it is included within the scope of the present invention.
Claims (10)
1. a kind of graphene is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：By weight, including following components：
Water-based FEVE fluorocarbon resins emulsion 20-45 parts, polymethyl methacrylate emulsion 5-25 parts, functionalization graphene dispersion liquid 5-20
Part, radial pattern inorganic matter 5-10 parts, color stuffing 10-35 parts, auxiliary agent 5-10 parts, deionized water 10-35 parts.
2. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The water
Property FEVE fluorocarbon resins emulsion and polymethyl methacrylate emulsion mass ratio be 1:5-15.
3. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The work(
Can graphite alkene dispersion liquid quality and water-based FEVE fluorocarbon resins emulsion and polymethyl methacrylate emulsion gross mass it
Between ratio be 1:10-25.
4. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The work(
Energy graphite alkene dispersion liquid includes following component by weight：Graphene oxide 1-10 parts, chloroacetic acid 1-5 parts, 16
Alkyl trimethyl ammonium bromide 1-5 parts, sodium hydroxide 0.5-2 parts, emulsifying agent 0-5 parts, water 1-50 parts, ethanol 1-15 parts.
5. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The spoke
Emitting inorganic matter is at least one of the tin-antiomony oxide that particle diameter is equal 20-200nm and tin indium oxide.
6. a kind of graphene as claimed in claim 5 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The oxygen
The mass ratio for changing the tin oxide in tin antimony and antimony oxide is 9:1, the mass ratio of indium oxide and antimony oxide in the tin indium oxide
For 9:1.
7. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：The face
Filler is the one or more combination in montmorillonite, rutile type titanium white and sericite.
8. a kind of graphene as claimed in claim 1 is modified radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：It is described to help
Agent includes following component by weight：Defoamer 0.05-5 parts, dispersant 0.05-5 parts, wetting agent 0.05-5 parts, thickening
Agent 0.05-5 parts, film forming agent 0.05-5 parts, antifreezing agent 1.01-5 parts, PH conditioning agent 0.05-5 parts；
Wherein, the defoamer is mineral oil defoaming agent or polyethers defoamer, and the dispersant is polycarboxylate sodium's type point
Powder, the wetting agent are sulfonic acid anion surfactant, and the thickener is polyacrylate-type thickeners or poly- second
Enol class thickener, the film forming agent are lauryl alcohol ester, and the antifreezing agent is propane diols, and the PH conditioning agents are Organic Alcohol amine
Compound.
9. a kind of graphene is modified the preparation method of radiating-anti-corrosion fluorine carbon functional paint, it is characterised in that：Comprise the following steps：
S1, by weight ratio by the defoamer in deionized water, radial pattern inorganic matter, color stuffing and auxiliary agent, dispersant, profit
Humectant, thickener, film forming agent and antifreezing agent are added in container, with 1000-1500rpm speed stirring 10-25min, then with
2000-2500rpm speed stirring 20-30min, is made slurry；
S2, in the case where slurry is in stirring, add water-based FEVE fluorocarbon resins emulsion, poly- first by weight ratio into slurry
Base methyl acrylate emulsion and functionalization graphene dispersion liquid, after 1500-2000rpm speed stirring 20min, coating is made
Semi-finished product；
S3, the PH conditioning agents in auxiliary agent are added in coating semi-finished product by weight ratio and are adjusted to the pH value of coating semi-finished product
After 7-8, discharged after continuing the speed stirring 20-30min with 2000-2500rpm, you can graphene is made and is modified radiating-anti-corrosion
Fluorine carbon functional paint finished product.
10. a kind of graphene as claimed in claim 9 is modified the preparation method of radiating-anti-corrosion fluorine carbon functional paint, its feature
It is：The step of it also prepares functionalization graphene dispersion liquid including one；The step of preparing functionalization graphene dispersion liquid be：
(1) the chloride step of graphene oxide：
First, parts by weights proportioning is added graphene oxide into suitable quantity of water, is made ultrasonic wave after vibration shakes up and is disperseed 40-
60min, then it is again heated to 40-60 DEG C；
Secondly, after adding chloroacetic acid, sodium hydroxide and ethanol by weight ratio, stirring reaction 10-30min, so as to by oxygen
Carboxyl on graphite alkene is converted into acid chloride group by esterification, to form primary first-order equation thing；
(2) amidation step of graphene oxide：Cetyl trimethylammonium bromide is added into primary first-order equation by weight ratio
In thing, the acid chloride group generated on graphene oxide is converted into acid amides, there is the function fossil for stablizing covalent bond so as to generate
Black alkene dispersion liquid；
(3) emulsifying step of graphene oxide：Parts by weights proportioning, which adds emulsifying agent in secondary response thing, stirs 10-30min,
So as to the hydrophilicity of enhanced feature graphite alkene dispersion liquid.
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| CN111117408A (en) * | 2019-12-13 | 2020-05-08 | 陈婧晗 | Fingerprint-resistant water-based paint and preparation process thereof |
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| CN111349372A (en) * | 2020-04-24 | 2020-06-30 | 容七英 | Novel water-based fluororesin coating and preparation method thereof |
| CN116496652A (en) * | 2023-06-29 | 2023-07-28 | 优美特（北京）环境材料科技股份公司 | Acrylic acid powder coating and application thereof |
| CN116496652B (en) * | 2023-06-29 | 2023-09-22 | 优美特（北京）环境材料科技股份公司 | Acrylic acid powder coating and application thereof |
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Application publication date: 20180202 |