CN107652596A - A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof - Google Patents

A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof Download PDF

Info

Publication number
CN107652596A
CN107652596A CN201711026930.4A CN201711026930A CN107652596A CN 107652596 A CN107652596 A CN 107652596A CN 201711026930 A CN201711026930 A CN 201711026930A CN 107652596 A CN107652596 A CN 107652596A
Authority
CN
China
Prior art keywords
parts
fire
plasticizer
cable material
resistant cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711026930.4A
Other languages
Chinese (zh)
Inventor
张如才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Jiaxing Metal Materials Co Ltd
Original Assignee
Anhui Jiaxing Metal Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Jiaxing Metal Materials Co Ltd filed Critical Anhui Jiaxing Metal Materials Co Ltd
Priority to CN201711026930.4A priority Critical patent/CN107652596A/en
Publication of CN107652596A publication Critical patent/CN107652596A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

It is prepared the invention discloses a kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof, including by the raw material of following parts by weight:4 third 30 40 parts of fluorubber, 20 35 parts of trioctyl trimellitate (TOTM), 20 35 parts of polyphenylene oxide resin, 10 15 parts of zinc molybdate, 10 20 parts of saponite, 15 30 parts of talcum powder, 15 35 parts of melamine cyanurate, 12 parts of stearic acid.The present invention is added in combination antioxidant, lubricant, compatilizer, plasticizer, fire retardant, stabilizer and plasticizer using the proportioning of the above-mentioned raw materials such as 4 third fluorubber, trioctyl trimellitate (TOTM), polyphenylene oxide resin, zinc molybdate, saponite, talcum powder, melamine cyanurate, stearic acid, polybutylene terephthalate (PBT) progress science and carries out reaction fusion, process of preparing is simple, prepared product has preferable fire protection flame retarding, insulating properties, is adapted to use in multiple fields.

Description

A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof
Technical field
The present invention relates to technical field of cable production, and in particular to a kind of fire-resistant cable material of high temperature resistant cracking resistance and its preparation Method.
Background technology
At present, it is also continuous to the quality requirement of cable with the development of the social economy, electric wire dosage increases rapidly Improve, such as the cable used in the industries such as steel, metallurgy, electric power, chemical industry, oil, service life, anti-electromagnetism to cable Requirement in terms of interference, pull resistance, shielding properties and high temperature resistant is all especially high, only meets the requirements, and could improve these Security when being manufactured in field.
Electric power is the energy using electric energy as power, and the invention and application of electric power have started second of industrialization climax, from This science and technology changes the life of people.In order to ensure the Electrical Safety of people, it is necessary on the electric equipment products surface for having insulating requirements Coat insulating materials.Insulating materials is for making device in the material electrically to insulate, that is, can prevent what electric current passed through Material.Its resistivity is very high, has good electrical insulation capability and high-temperature physical property, also with long shelf-life, moisture resistivity The features such as good and fire-retardant.
The content of the invention
To solve the above problems, the invention provides a kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof.
To achieve the above object, the technical scheme taken of the present invention is:
A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof, including be prepared by the raw material of following parts by weight:Four Third fluorubber 30-40 parts, trioctyl trimellitate (TOTM) 20-35 parts, polyphenylene oxide resin 20-35 parts, zinc molybdate 10-15 parts, saponite 10- 20 parts, talcum powder 15-30 parts, melamine cyanurate 15-35 parts, stearic acid 1-2 parts, polybutylene terephthalate (PBT) 5- 10 parts, fume colloidal silica 1-10 parts, modified carbide slag powder 1-5 parts, maleic anhydride grafted ethene-vinyl acetate copolymerization 2-5 Part, nanocrystal cellulose 5-10 parts, antioxidant 10-30 parts, lubricant 10-20 parts, compatilizer 10-30 parts, plasticizer 10-20 Part, fire retardant 15-35 parts, stabilizer 1-10 parts and plasticizer 2-7 parts.
Further, the antioxidant is the double octadecyl esters of thio-2 acid, the lubricant be stearic acid, stearate, One or more in polyvinyl chloride wax, the compatilizer are the H of POE-g-M I, and the plasticizer is phthalate chemical combination Thing, the flame-retardants melamine, the stabilizer are barium cadmium zinc.
Further, a kind of fire-resistant cable material of high temperature resistant cracking resistance, including be prepared by the raw material of following parts by weight:Four Third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 parts, zinc molybdate 12-14 parts, saponite 11- 18 parts, talcum powder 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 parts, polybutylene terephthalate (PBT) 6- 9 parts, fume colloidal silica 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafted ethene-vinyl acetate copolymerization 3-5 parts, Nanocrystal cellulose 6-9 parts, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13-24 parts, plasticizer 14-19 parts, Fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts.
Further, a kind of preparation method of the fire-resistant cable material of high temperature resistant cracking resistance, comprises the following steps:
S1,4 third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 are weighed according to parts by weight Part, zinc molybdate 12-14 parts, saponite 11-18 parts, talcum powder 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 Part, polybutylene terephthalate (PBT) 6-9 parts, fume colloidal silica 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafting Ethylene-vinyl acetate c 3-5 parts, nanocrystal cellulose 6-9 parts are added in ultrasonic agitation dispersion machine, are carried out ultrasound and are stirred Mix scattered, obtain mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, extruded at 160-250 DEG C of temperature It is granulated;Obtain fire-resistant cable material;
S3, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13-24 will be added in the fire-resistant cable material obtained by step S2 Part, plasticizer 14-19 parts, fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts, reacted at being 55-88 DEG C in temperature 15-35min;Then 10-30min is quickly stirred with 400-900r/min speed, produces this product.
Further, a kind of fire-resistant cable material of high temperature resistant cracking resistance, including be prepared by the raw material of following parts by weight:Four Third 35 parts of fluorubber, 25 parts of trioctyl trimellitate (TOTM), 27 parts of polyphenylene oxide resin, 13 parts of zinc molybdate, 16 parts of saponite, talcum powder 18 Part, 25 parts of melamine cyanurate, 1 part of stearic acid, 7 parts of polybutylene terephthalate (PBT), 5 parts of fume colloidal silica, change 3 parts of property calcium carbide ground-slag, 4 parts of maleic anhydride grafted ethene-vinyl acetate copolymerization, 7 parts of nanocrystal cellulose, antioxidant 19 Part, 17 parts of lubricant, 16 parts of compatilizer, 17 parts of plasticizer, 26 parts of fire retardant, 5 parts of stabilizer and 4 parts of plasticizer.
The present invention is using 4 third fluorubber, trioctyl trimellitate (TOTM), polyphenylene oxide resin, zinc molybdate, saponite, talcum powder, three Poly cyanamid cyanurate, stearic acid, polybutylene terephthalate (PBT), fume colloidal silica, modified carbide slag powder, maleic anhydride The above-mentioned raw materials such as grafted ethene-vinyl acetate copolymerization, nanocrystal cellulose carry out science proportioning be added in combination antioxidant, Lubricant, compatilizer, plasticizer, fire retardant, stabilizer and plasticizer carry out reaction fusion, and process of preparing is simple, made Standby product has preferable fire protection flame retarding, insulating properties, is adapted to use in multiple fields.
Embodiment
In order that objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight:4 third fluorubber 30-40 parts, tri trimellitate Monooctyl ester 20-35 parts, polyphenylene oxide resin 20-35 parts, zinc molybdate 10-15 parts, saponite 10-20 parts, talcum powder 15-30 parts, melamine Amine cyanurate 15-35 parts, stearic acid 1-2 parts, polybutylene terephthalate (PBT) 5-10 parts, fume colloidal silica 1-10 parts, Modified carbide slag powder 1-5 parts, maleic anhydride grafted ethene-vinyl acetate copolymerization 2-5 parts, nanocrystal cellulose 5-10 parts, Antioxidant 10-30 parts, lubricant 10-20 parts, compatilizer 10-30 parts, plasticizer 10-20 parts, fire retardant 15-35 parts, stabilizer 1-10 parts and plasticizer 2-7 parts.
The antioxidant is the double octadecyl esters of thio-2 acid, and the lubricant is stearic acid, stearate, polyvinyl chloride wax In one or more, the compatilizer is the H of POE-g-M I, and the plasticizer is phthalate compound, the resistance Agent melamine is fired, the stabilizer is barium cadmium zinc.
A kind of fire-resistant cable material of high temperature resistant cracking resistance, including be prepared by the raw material of following parts by weight:4 third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 parts, zinc molybdate 12-14 parts, saponite 11-18 parts, cunning Stone flour 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 parts, polybutylene terephthalate (PBT) 6-9 parts, gas Phase method white carbon 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafted ethene-vinyl acetate copolymerization 3-5 parts, nano junction Crystalline cellulose 6-9 parts, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13-24 parts, plasticizer 14-19 parts, fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts.
A kind of preparation method of the fire-resistant cable material of high temperature resistant cracking resistance, comprises the following steps:
S1,4 third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 are weighed according to parts by weight Part, zinc molybdate 12-14 parts, saponite 11-18 parts, talcum powder 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 Part, polybutylene terephthalate (PBT) 6-9 parts, fume colloidal silica 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafting Ethylene-vinyl acetate c 3-5 parts, nanocrystal cellulose 6-9 parts are added in ultrasonic agitation dispersion machine, are carried out ultrasound and are stirred Mix scattered, obtain mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, extruded at 160-250 DEG C of temperature It is granulated;Obtain fire-resistant cable material;
S3, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13-24 will be added in the fire-resistant cable material obtained by step S2 Part, plasticizer 14-19 parts, fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts, reacted at being 55-88 DEG C in temperature 15-35min;Then 10-30min is quickly stirred with 400-900r/min speed, produces this product.
Embodiment 1:
A kind of preparation method of the fire-resistant cable material of high temperature resistant cracking resistance, comprises the following steps:
S1,38 parts of 4 third fluorubber, 30 parts of trioctyl trimellitate (TOTM), 30 parts of polyphenylene oxide resin, zinc molybdate are weighed according to parts by weight 14 parts, 18 parts of saponite, 20 parts of talcum powder, 28 parts of melamine cyanurate, 2 parts of stearic acid, polybutylene terephthalate (PBT) 9 Part, 7 parts of fume colloidal silica, 4 parts of modified carbide slag powder, 5 parts of maleic anhydride grafted ethene-vinyl acetate copolymerization, nano junction 9 parts of crystalline cellulose is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is disperseed, obtains mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, carrying out extrusion at 160 DEG C of temperature makes Grain;Obtain fire-resistant cable material;
S3,26 parts of antioxidant, 18 parts of lubricant, 24 parts of compatilizer, plasticizer will be added in the fire-resistant cable material obtained by step S2 6 parts of 19 parts, 29 parts of fire retardant, 9 parts of stabilizer and plasticizer, react 30min at being 90 DEG C in temperature;Then with 800r/min's Speed quickly stirs 25min, produces this product.
Embodiment 2:
A kind of preparation method of the fire-resistant cable material of high temperature resistant cracking resistance, comprises the following steps:
S1,35 parts of 4 third fluorubber, 25 parts of trioctyl trimellitate (TOTM), 27 parts of polyphenylene oxide resin, zinc molybdate are weighed according to parts by weight 13 parts, 16 parts of saponite, 18 parts of talcum powder, 25 parts of melamine cyanurate, 1 part of stearic acid, polybutylene terephthalate (PBT) 7 Part, 5 parts of fume colloidal silica, 3 parts of modified carbide slag powder, 4 parts of maleic anhydride grafted ethene-vinyl acetate copolymerization, nano junction 7 parts of crystalline cellulose is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is disperseed, obtains mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, carrying out extrusion at 250 DEG C of temperature makes Grain;Obtain fire-resistant cable material;
S3,19 parts of antioxidant, 17 parts of lubricant, 16 parts of compatilizer, plasticizer will be added in the fire-resistant cable material obtained by step S2 4 parts of 17 parts, 26 parts of fire retardant, 5 parts of stabilizer and plasticizer, react 27min at being 88 DEG C in temperature;Then with 700r/min's Speed quickly stirs 18min, produces this product.
Embodiment 3:
A kind of preparation method of the fire-resistant cable material of high temperature resistant cracking resistance, comprises the following steps:
S1,32 parts of 4 third fluorubber, 22 parts of trioctyl trimellitate (TOTM), 23 parts of polyphenylene oxide resin, zinc molybdate are weighed according to parts by weight 12 parts, 11 parts of saponite, 16 parts of talcum powder, 23 parts of melamine cyanurate, 1 part of stearic acid, polybutylene terephthalate (PBT) 6 Part, 3 parts of fume colloidal silica, 2 parts of modified carbide slag powder, 3 parts of maleic anhydride grafted ethene-vinyl acetate copolymerization, nano junction 6 parts of crystalline cellulose is added in ultrasonic agitation dispersion machine, is carried out ultrasonic agitation and is disperseed, obtains mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, carrying out extrusion at 190 DEG C of temperature makes Grain;Obtain fire-resistant cable material;
S3,15 parts of antioxidant, 14 parts of lubricant, 13 parts of compatilizer, plasticizer will be added in the fire-resistant cable material obtained by step S2 3 parts of 14 parts, 22 parts of fire retardant, 3 parts of stabilizer and plasticizer, react 20min at being 65 DEG C in temperature;Then with 500r/min's Speed quickly stirs 15min, produces this product.
The present invention is using 4 third fluorubber, trioctyl trimellitate (TOTM), polyphenylene oxide resin, zinc molybdate, saponite, talcum powder, three Poly cyanamid cyanurate, stearic acid, polybutylene terephthalate (PBT), fume colloidal silica, modified carbide slag powder, maleic anhydride The above-mentioned raw materials such as grafted ethene-vinyl acetate copolymerization, nanocrystal cellulose carry out science proportioning be added in combination antioxidant, Lubricant, compatilizer, plasticizer, fire retardant, stabilizer and plasticizer carry out reaction fusion, and process of preparing is simple, made Standby product has preferable fire protection flame retarding, insulating properties, is adapted to use in multiple fields.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (5)

1. a kind of fire-resistant cable material of high temperature resistant cracking resistance, it is characterised in that including being prepared by the raw material of following parts by weight:Four Third fluorubber 30-40 parts, trioctyl trimellitate (TOTM) 20-35 parts, polyphenylene oxide resin 20-35 parts, zinc molybdate 10-15 parts, saponite 10- 20 parts, talcum powder 15-30 parts, melamine cyanurate 15-35 parts, stearic acid 1-2 parts, polybutylene terephthalate (PBT) 5- 10 parts, fume colloidal silica 1-10 parts, modified carbide slag powder 1-5 parts, maleic anhydride grafted ethene-vinyl acetate copolymerization 2-5 Part, nanocrystal cellulose 5-10 parts, antioxidant 10-30 parts, lubricant 10-20 parts, compatilizer 10-30 parts, plasticizer 10-20 Part, fire retardant 15-35 parts, stabilizer 1-10 parts and plasticizer 2-7 parts.
2. the fire-resistant cable material of a kind of high temperature resistant cracking resistance according to claim 1, it is characterised in that the antioxidant is sulphur For the double octadecyl esters of dipropionic acid, the lubricant is stearic acid, the one or more in stearate, polyvinyl chloride wax, the phase Appearance agent is the H of POE-g-M I, and the plasticizer is phthalate compound, the flame-retardants melamine, the stabilization Agent is barium cadmium zinc.
3. the fire-resistant cable material of a kind of high temperature resistant cracking resistance according to claim 1, it is characterised in that including by following weight The raw material of part is prepared:4 third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 parts, molybdenum It is sour zinc 12-14 parts, saponite 11-18 parts, talcum powder 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 parts, poly- Mutual-phenenyl two acid bromide two alcohol ester 6-9 parts, fume colloidal silica 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafted ethene- Vinyl acetate copolymerization 3-5 parts, nanocrystal cellulose 6-9 parts, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13- 24 parts, plasticizer 14-19 parts, fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts.
A kind of 4. preparation method of the fire-resistant cable material of high temperature resistant cracking resistance according to claim 1, it is characterised in that including Following steps:
S1,4 third fluorubber 32-38 parts, trioctyl trimellitate (TOTM) 22-30 parts, polyphenylene oxide resin 23-30 are weighed according to parts by weight Part, zinc molybdate 12-14 parts, saponite 11-18 parts, talcum powder 16-20 parts, melamine cyanurate 23-28 parts, stearic acid 1-2 Part, polybutylene terephthalate (PBT) 6-9 parts, fume colloidal silica 3-7 parts, modified carbide slag powder 2-4 parts, maleic anhydride grafting Ethylene-vinyl acetate c 3-5 parts, nanocrystal cellulose 6-9 parts are added in ultrasonic agitation dispersion machine, are carried out ultrasound and are stirred Mix scattered, obtain mixed material;
S2, the mixed material obtained by step S1 poured into double-screw extruding pelletizing machine, extruded at 160-250 DEG C of temperature It is granulated;Obtain fire-resistant cable material;
S3, antioxidant 15-26 parts, lubricant 14-18 parts, compatilizer 13-24 will be added in the fire-resistant cable material obtained by step S2 Part, plasticizer 14-19 parts, fire retardant 22-29 parts, stabilizer 3-9 parts and plasticizer 3-6 parts, reacted at being 55-95 DEG C in temperature 15-35min;Then 10-30min is quickly stirred with 400-900r/min speed, produces this product.
5. the fire-resistant cable material of a kind of high temperature resistant cracking resistance according to claim 1, it is characterised in that including by following weight The raw material of part is prepared:4 third 35 parts of fluorubber, 25 parts of trioctyl trimellitate (TOTM), 27 parts of polyphenylene oxide resin, 13 parts of zinc molybdate, 16 parts of saponite, 18 parts of talcum powder, 25 parts of melamine cyanurate, 1 part of stearic acid, 7 parts of polybutylene terephthalate (PBT), gas 5 parts of phase method white carbon, 3 parts of modified carbide slag powder, 4 parts of maleic anhydride grafted ethene-vinyl acetate copolymerization, nanocrystal fiber 7 parts of element, 19 parts of antioxidant, 17 parts of lubricant, 16 parts of compatilizer, 17 parts of plasticizer, 26 parts of fire retardant, 5 parts of stabilizer and plasticising 4 parts of agent.
CN201711026930.4A 2017-10-27 2017-10-27 A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof Pending CN107652596A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711026930.4A CN107652596A (en) 2017-10-27 2017-10-27 A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711026930.4A CN107652596A (en) 2017-10-27 2017-10-27 A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107652596A true CN107652596A (en) 2018-02-02

Family

ID=61095821

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711026930.4A Pending CN107652596A (en) 2017-10-27 2017-10-27 A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107652596A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113416349A (en) * 2021-06-18 2021-09-21 佛山金戈新材料股份有限公司 Molybdate composition flame-retardant smoke suppressant and preparation method thereof
US11401416B2 (en) 2017-10-17 2022-08-02 Celanese Sales Germany Gmbh Flame retardant polyamide composition

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103554796A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 Tear-resistant and high-temperature-aging-resistant modified terafluoroethylene-propylene rubber cable material
CN105111672A (en) * 2015-08-27 2015-12-02 无为县茂林电缆材料有限公司 High-temperature-resistant crack-resistant flame-retardant cable material and preparation method thereof
CN105153529A (en) * 2015-08-27 2015-12-16 无为县茂林电缆材料有限公司 Anti-tearing flame-retardant cable material and method for manufacturing same
CN106009543A (en) * 2016-06-29 2016-10-12 郑旭 Power insulation flame-retardant cable and preparation method thereof
CN106519412A (en) * 2016-11-09 2017-03-22 重庆联邦中北电缆股份有限公司 Anti-tearing cable material, and preparation method thereof
CN107057244A (en) * 2017-06-13 2017-08-18 江西吉恩重工有限公司 Ageing-resistant and fire-retardant a kind of CABLE MATERIALS and preparation method thereof
CN107151409A (en) * 2017-04-27 2017-09-12 东莞市骏豪电线科技有限公司 Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103554796A (en) * 2013-10-25 2014-02-05 安徽文峰电子科技集团有限公司 Tear-resistant and high-temperature-aging-resistant modified terafluoroethylene-propylene rubber cable material
CN105111672A (en) * 2015-08-27 2015-12-02 无为县茂林电缆材料有限公司 High-temperature-resistant crack-resistant flame-retardant cable material and preparation method thereof
CN105153529A (en) * 2015-08-27 2015-12-16 无为县茂林电缆材料有限公司 Anti-tearing flame-retardant cable material and method for manufacturing same
CN106009543A (en) * 2016-06-29 2016-10-12 郑旭 Power insulation flame-retardant cable and preparation method thereof
CN106519412A (en) * 2016-11-09 2017-03-22 重庆联邦中北电缆股份有限公司 Anti-tearing cable material, and preparation method thereof
CN107151409A (en) * 2017-04-27 2017-09-12 东莞市骏豪电线科技有限公司 Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof
CN107057244A (en) * 2017-06-13 2017-08-18 江西吉恩重工有限公司 Ageing-resistant and fire-retardant a kind of CABLE MATERIALS and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11401416B2 (en) 2017-10-17 2022-08-02 Celanese Sales Germany Gmbh Flame retardant polyamide composition
US11981812B2 (en) 2017-10-17 2024-05-14 Celanese Sales Germany Gmbh Flame retardant polyamide composition
CN113416349A (en) * 2021-06-18 2021-09-21 佛山金戈新材料股份有限公司 Molybdate composition flame-retardant smoke suppressant and preparation method thereof
CN113416349B (en) * 2021-06-18 2022-08-26 佛山金戈新材料股份有限公司 Molybdate composition flame-retardant smoke suppressant and preparation method thereof

Similar Documents

Publication Publication Date Title
CN105295241B (en) Ceramic polyvinyl chloride wire and cable material and preparation method thereof
CN103923411B (en) Hollow glass micropearl/polrvinyl chloride component-type wire cable material and preparation method thereof
CN105367965B (en) Fire-resisting cable halogen-free flameproof ceramic cable material of polyolefin and preparation method thereof
CN105733107A (en) Efficient flame-retardant cable material for railway locomotive
CN105906982A (en) Cable material for electric thermal insulation, insulation and flame retardance and preparation method thereof
CN105153642A (en) Insulation material for cables and preparation method thereof
CN107652596A (en) A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof
CN105153528A (en) Irradiation-crosslinked and environmental-friendly polyolefin cable material with flexibility and wear resistance and preparation method of polyolefin cable material
CN107189324A (en) A kind of electronic engineering cable elastomer sheathing material and preparation method thereof
CN110845783A (en) Low-smoke halogen-free flame-retardant polyolefin wire material for B1-grade wire distribution and preparation method thereof
CN102295794B (en) 150 DGE C irradiation crosslinking low-smoke halogen-free antiflaming polyolefin sheathing compound for locomotive thin-walled line as well as preparation and application thereof
CN104893196A (en) CPVC wire and cable material resistant to temperature of 125 DEG C, and manufacturing method thereof
CN107652622A (en) A kind of high-strength anti-flaming cable for building and preparation method thereof
CN107868436A (en) A kind of building CABLE MATERIALS of high-performance refractory fire resisting and preparation method thereof
CN109265861A (en) Network system cable sheath material and preparation method thereof
CN107915886A (en) A kind of cold-resistant fire-resistant cable material and preparation method thereof
CN105111660A (en) Waterproof type thermoplastic elastomer sheath material for data lines and preparation method thereof
CN112961424A (en) Halogen-free flame-retardant fireproof cable and preparation method thereof
CN108148259A (en) A kind of novel flame-retardant cable material and preparation method thereof
CN106566039A (en) A semiconductive shield cable material including surface-grafted modified carbon black
CN105111666A (en) Flame-resistant synergy data line sheath material having good processing fluidity and preparation method thereof
CN108864614A (en) A kind of low-smoke non-halogen flame-retardant polyvinyl chloride cable material and preparation method thereof
CN107722441A (en) A kind of cold-resistant tear-proof insulated cable material and preparation method thereof
CN105778239A (en) Ceramic polyolefin flame-retardant fire-resistant cable material
CN105885430A (en) High-wear-resistance tensile environmental-friendly high-speed rail cable material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180202