CN107641376A - A kind of printing-ink - Google Patents

A kind of printing-ink Download PDF

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Publication number
CN107641376A
CN107641376A CN201711121727.5A CN201711121727A CN107641376A CN 107641376 A CN107641376 A CN 107641376A CN 201711121727 A CN201711121727 A CN 201711121727A CN 107641376 A CN107641376 A CN 107641376A
Authority
CN
China
Prior art keywords
parts
printing
ink
agent
defoamer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711121727.5A
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Chinese (zh)
Inventor
李琳
朱宏文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Tongli Plastic Color Printing Co Ltd
Original Assignee
Anhui Tongli Plastic Color Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Tongli Plastic Color Printing Co Ltd filed Critical Anhui Tongli Plastic Color Printing Co Ltd
Priority to CN201711121727.5A priority Critical patent/CN107641376A/en
Publication of CN107641376A publication Critical patent/CN107641376A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of printing-ink, is made up of the raw material of following weight parts:20 40 parts of polyurethane resin, 40 60 parts of solvent, 5 10 parts of polyamides ester resin, 15 parts of organobentonite, 07 parts of conductive component, 36 parts of curing agent, 13 parts of polymerization inhibitor, 13 parts of vegetable oil, 15 parts of defoamer, 13 parts of waterproofing agent, 13 parts of colouring matter, 13 parts of wetting agent, 5 10 parts of pH stabilizers, the addition of the printing-ink vegetable oil of the present invention, on the one hand the lubricity and dispersiveness of ink can be improved, on the other hand suitable viscosity can be allocated, so that more particularly suitable yield behavior in the presence of grease, is presented in ink;Organobentonite is nano level particulate matter, higher with the conjugation of ink, can more fully play bentonite characteristic;The raw material that present invention addition triethanolamine buffer or dimethylacetamide amine buffering agent use is reduced in ink printing process because the change of ink viscosity and rate of drying caused by pH value changes, the printing effect stablized as pH stabilizers.

Description

A kind of printing-ink
Technical field
The present invention relates to printing technology, specifically a kind of printing-ink.
Background technology
After ink is imprinted on printed matter, because wearability is bad, printed matter can produce ink during transport, use and take off Fall, phenomena such as falling the effect of ink, in transportation, excessively transmission speed is very fast, and the layer of ink of printed matter surface can be because rub and part Come off, influence the outward appearance and quality of printed matter, if reducing the degree of scratching by reducing transmission speed, production effect can be reduced Rate.
Rate of drying, thixotropy, the skeleton property of ink have tremendous influence to production efficiency, product quality, and The composition of ink has an impact to human body, how to study harm to the human body is as far as possible small, wearability is good, production efficiency is high, it is environment-friendly, The low ink of cost turns into the developing direction of later printing industry.
The content of the invention
It is an object of the invention to provide a kind of printing-ink, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of printing-ink, it is made up of the raw material of following weight parts:
Polyurethane resin 20-40 parts, solvent 40-60 parts, polyamides ester resin 5-10 parts, organobentonite 1-5 parts, conductive group Divide 0-7 parts, curing agent 3-6 parts, polymerization inhibitor 1-3 parts, vegetable oil 1-3 parts, defoamer 1-5 parts, waterproofing agent 1-3 parts, colouring matter 1-3 Part, wetting agent 1-3 parts, pH stabilizer 5-10 parts.
A kind of printing-ink, it is made up of the raw material of following weight parts:
It is 20 parts of polyurethane resin, 40 parts of solvent, 5 parts of polyamides ester resin, 1 part of organobentonite, 0.5 part of conductive component, solid 3 parts of agent, 1 part of polymerization inhibitor, 1 part of vegetable oil, 1 part of defoamer, 1 part of waterproofing agent, 1 part of colouring matter, 1 part of wetting agent, pH stabilizers 5 Part.
A kind of printing-ink, it is made up of the raw material of following weight parts:
40 parts of polyurethane resin, 60 parts of solvent, 10 parts of polyamides ester resin, 5 parts of organobentonite, 7 parts of conductive component, solidification 6 parts of agent, 3 parts of polymerization inhibitor, 3 parts of vegetable oil, 5 parts of defoamer, 3 parts of waterproofing agent, 3 parts of colouring matter, 3 parts of wetting agent, pH stabilizers 10 Part.
A kind of printing-ink, it is made up of the raw material of following weight parts:
It is 30 parts of polyurethane resin, 50 parts of solvent, 8 parts of polyamides ester resin, 3 parts of organobentonite, 3.5 parts of conductive component, solid 4 parts of agent, 2 parts of polymerization inhibitor, 2 parts of vegetable oil, 3 parts of defoamer, 2 parts of waterproofing agent, 2 parts of colouring matter, 2 parts of wetting agent, pH stabilizers 8 Part.
The conductive component is nano-graphene, ZnOw, CNT, conductive fiber by 1:2:2:1 mass ratio The mixture of mixing.
The curing agent is one kind in ethylenediamine, polyamide, methyl tetrahydrophthalic anhydride.
The polymerization inhibitor is three (N- nitrosos-N-Phenylhydroxylamine) aluminium salts.
The vegetable oil is olive oil and almond oil according to 2:The mixture of 1 mixing.
Preferably, the solvent is ethanol, n-butanol, isobutanol, terpinol, isopropanol, glycerine, the positive fourth of acetic acid At least one of ester, propylene glycol n-butyl ether.
Preferably, the defoamer is non-organic silicon class defoamer.
The pH stabilizers are the triethanolamine buffer or dimethylacetamide amine buffering agent that pH value is 8.5.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention printing-ink there is good electric conductivity, can effectively extend the holding time of printed article, reduce because The problem of printed article natural environment causes;The addition of vegetable oil, the lubricity and dispersiveness of ink on the one hand can be improved, it is another Aspect can allocate suitable viscosity so that more particularly suitable yield behavior is presented in the presence of grease in ink;Organic swelling Soil is nano level particulate matter, and nano particle specific surface area is big, higher with the conjugation of ink, can more fully play The bentonitic characteristic of machine;It is steady as pH that the present invention adds the raw material that triethanolamine buffer or dimethylacetamide amine buffering agent use Determine agent, reduce in ink printing process because the change of ink viscosity and rate of drying caused by pH value changes, is stablized Printing effect;Wetting agent is added, obtained ink surface tension is small, and its wetting effect is good, strong with printed matter surface adhesion;Peace Completely without evil, harmful substance pollution environment will not be discharged, it is more environmentally-friendly.Add defoamer so that the ink layer after printing has very Small coefficient of friction, so as to substantially improve the wearability of ink.
Embodiment
Embodiment 1
A kind of printing-ink, it is made up of the raw material of following weight parts:
It is 20 parts of polyurethane resin, 40 parts of solvent, 5 parts of polyamides ester resin, 1 part of organobentonite, 0.5 part of conductive component, solid 3 parts of agent, 1 part of polymerization inhibitor, 1 part of vegetable oil, 1 part of defoamer, 1 part of waterproofing agent, 1 part of colouring matter, 1 part of wetting agent, pH stabilizers 5 Part, 0.1 part of dehydration Apples acid esters, 1 part of dextrin.
The conductive component is nano-graphene, ZnOw, CNT, conductive fiber by 1:2:2:1 mass ratio The mixture of mixing.
The curing agent is one kind in ethylenediamine, polyamide, methyl tetrahydrophthalic anhydride.
The polymerization inhibitor is three (N- nitrosos-N-Phenylhydroxylamine) aluminium salts.
The vegetable oil is olive oil and almond oil according to 2:The mixture of 1 mixing.
Preferably, the solvent is ethanol, n-butanol, isobutanol, terpinol, isopropanol, glycerine, the positive fourth of acetic acid At least one of ester, propylene glycol n-butyl ether.
Preferably, the defoamer is non-organic silicon class defoamer.
The pH stabilizers are the triethanolamine buffer or dimethylacetamide amine buffering agent that pH value is 8.5.
Embodiment 2
A kind of printing-ink, it is made up of the raw material of following weight parts:
40 parts of polyurethane resin, 60 parts of solvent, 10 parts of polyamides ester resin, 5 parts of organobentonite, 7 parts of conductive component, solidification 6 parts of agent, 3 parts of polymerization inhibitor, 3 parts of vegetable oil, 5 parts of defoamer, 3 parts of waterproofing agent, 3 parts of colouring matter, 3 parts of wetting agent, pH stabilizers 10 Part, 1 part of dehydration Apples acid esters, 3 parts of dextrin.
The conductive component is nano-graphene, ZnOw, CNT, conductive fiber by 1:2:2:1 mass ratio The mixture of mixing.
The curing agent is one kind in ethylenediamine, polyamide, methyl tetrahydrophthalic anhydride.
The polymerization inhibitor is three (N- nitrosos-N-Phenylhydroxylamine) aluminium salts.
The vegetable oil is olive oil and almond oil according to 2:The mixture of 1 mixing.
Preferably, the solvent is ethanol, n-butanol, isobutanol, terpinol, isopropanol, glycerine, the positive fourth of acetic acid At least one of ester, propylene glycol n-butyl ether.
Preferably, the defoamer is non-organic silicon class defoamer.
The pH stabilizers are the triethanolamine buffer or dimethylacetamide amine buffering agent that pH value is 8.5.
Embodiment 3
A kind of printing-ink, it is made up of the raw material of following weight parts:
It is 30 parts of polyurethane resin, 50 parts of solvent, 8 parts of polyamides ester resin, 3 parts of organobentonite, 3.5 parts of conductive component, solid 4 parts of agent, 2 parts of polymerization inhibitor, 2 parts of vegetable oil, 3 parts of defoamer, 2 parts of waterproofing agent, 2 parts of colouring matter, 2 parts of wetting agent, pH stabilizers 8 Part, 0.5 part of dehydration Apples acid esters, 2 parts of dextrin.
The conductive component is nano-graphene, ZnOw, CNT, conductive fiber by 1:2:2:1 mass ratio The mixture of mixing.
The curing agent is one kind in ethylenediamine, polyamide, methyl tetrahydrophthalic anhydride.
The polymerization inhibitor is three (N- nitrosos-N-Phenylhydroxylamine) aluminium salts.
The vegetable oil is olive oil and almond oil according to 2:The mixture of 1 mixing.
Preferably, the solvent is ethanol, n-butanol, isobutanol, terpinol, isopropanol, glycerine, the positive fourth of acetic acid At least one of ester, propylene glycol n-butyl ether.
Preferably, the defoamer is non-organic silicon class defoamer.
The pH stabilizers are the triethanolamine buffer or dimethylacetamide amine buffering agent that pH value is 8.5.

Claims (10)

1. a kind of printing-ink, it is characterised in that be made up of the raw material of following weight parts:
Polyurethane resin 20-40 parts, solvent 40-60 parts, polyamides ester resin 5-10 parts, organobentonite 1-5 parts, conductive component 0- 7 parts, curing agent 3-6 parts, polymerization inhibitor 1-3 parts, vegetable oil 1-3 parts, defoamer 1-5 parts, waterproofing agent 1-3 parts, colouring matter 1-3 parts, Wetting agent 1-3 parts, pH stabilizer 5-10 parts.
2. printing-ink according to claim 1, it is characterised in that be made up of the raw material of following weight parts:
20 parts of polyurethane resin, 40 parts of solvent, 5 parts of polyamides ester resin, 1 part of organobentonite, 0.5 part of conductive component, curing agent 3 Part, 1 part of polymerization inhibitor, 1 part of vegetable oil, 1 part of defoamer, 1 part of waterproofing agent, 1 part of colouring matter, 1 part of wetting agent, 5 parts of pH stabilizers.
3. printing-ink according to claim 1, it is characterised in that be made up of the raw material of following weight parts:
40 parts of polyurethane resin, 60 parts of solvent, 10 parts of polyamides ester resin, 5 parts of organobentonite, 7 parts of conductive component, curing agent 6 Part, 3 parts of polymerization inhibitor, 3 parts of vegetable oil, 5 parts of defoamer, 3 parts of waterproofing agent, 3 parts of colouring matter, 3 parts of wetting agent, 10 parts of pH stabilizers.
4. printing-ink according to claim 1, it is characterised in that be made up of the raw material of following weight parts:
30 parts of polyurethane resin, 50 parts of solvent, 8 parts of polyamides ester resin, 3 parts of organobentonite, 3.5 parts of conductive component, curing agent 4 Part, 2 parts of polymerization inhibitor, 2 parts of vegetable oil, 3 parts of defoamer, 2 parts of waterproofing agent, 2 parts of colouring matter, 2 parts of wetting agent, 8 parts of pH stabilizers.
5. printing-ink according to claim 1, it is characterised in that the conductive component is nano-graphene, zinc oxide Whisker, CNT, conductive fiber press 1:2:2:The mixture of 1 mass ratio mixing.
6. printing-ink according to claim 1, it is characterised in that the curing agent is ethylenediamine, polyamide, methyl four One kind in hydrogen phthalic anhydride.
7. printing-ink according to claim 1, it is characterised in that the polymerization inhibitor is three (N- nitroso-N- phenyl hydroxyls Amine) aluminium salt.
8. printing-ink according to claim 1, it is characterised in that the vegetable oil be olive oil and almond oil according to 2:The mixture of 1 mixing.
9. printing-ink according to claim 1, it is characterised in that the defoamer is non-organic silicon class defoamer.
10. printing-ink according to claim 1, it is characterised in that the pH stabilizers are three ethanol that pH value is 8.5 Amine buffering agent or dimethylacetamide amine buffering agent.
CN201711121727.5A 2017-11-14 2017-11-14 A kind of printing-ink Pending CN107641376A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711121727.5A CN107641376A (en) 2017-11-14 2017-11-14 A kind of printing-ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711121727.5A CN107641376A (en) 2017-11-14 2017-11-14 A kind of printing-ink

Publications (1)

Publication Number Publication Date
CN107641376A true CN107641376A (en) 2018-01-30

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108081777A (en) * 2018-02-02 2018-05-29 浙江迈高工艺礼品有限公司 A kind of gold and silver printing process
CN108248236A (en) * 2018-02-02 2018-07-06 浙江迈高工艺礼品有限公司 A kind of embossment reflex printing method
CN108312729A (en) * 2018-02-02 2018-07-24 浙江迈高工艺礼品有限公司 A kind of frosted printing process
CN108641466A (en) * 2018-05-02 2018-10-12 安徽华新印务有限公司 A kind of waterproof printing oil base and preparation method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1687259A (en) * 2005-04-12 2005-10-26 王崇高 Dedicated printing ink for electroplating products and preparation method thereof
CN103113786A (en) * 2013-03-07 2013-05-22 苏州牛剑新材料有限公司 Graphene conductive ink and preparation method thereof
CN103834235A (en) * 2014-02-20 2014-06-04 江苏格美高科技发展有限公司 Conductive graphene carbon slurry printing ink and preparation method thereof
CN104212241A (en) * 2014-09-01 2014-12-17 江苏格美高科技发展有限公司 High-thermal-conductivity polymer conductive ink and production process thereof
CN107298901A (en) * 2017-08-28 2017-10-27 厦门大学 A kind of carbon series conductive ink
CN107312377A (en) * 2017-08-01 2017-11-03 安徽原动力生产力促进中心有限公司 A kind of preparation technology of 3D printing ink

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1687259A (en) * 2005-04-12 2005-10-26 王崇高 Dedicated printing ink for electroplating products and preparation method thereof
CN103113786A (en) * 2013-03-07 2013-05-22 苏州牛剑新材料有限公司 Graphene conductive ink and preparation method thereof
CN103834235A (en) * 2014-02-20 2014-06-04 江苏格美高科技发展有限公司 Conductive graphene carbon slurry printing ink and preparation method thereof
CN104212241A (en) * 2014-09-01 2014-12-17 江苏格美高科技发展有限公司 High-thermal-conductivity polymer conductive ink and production process thereof
CN107312377A (en) * 2017-08-01 2017-11-03 安徽原动力生产力促进中心有限公司 A kind of preparation technology of 3D printing ink
CN107298901A (en) * 2017-08-28 2017-10-27 厦门大学 A kind of carbon series conductive ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108081777A (en) * 2018-02-02 2018-05-29 浙江迈高工艺礼品有限公司 A kind of gold and silver printing process
CN108248236A (en) * 2018-02-02 2018-07-06 浙江迈高工艺礼品有限公司 A kind of embossment reflex printing method
CN108312729A (en) * 2018-02-02 2018-07-24 浙江迈高工艺礼品有限公司 A kind of frosted printing process
CN108641466A (en) * 2018-05-02 2018-10-12 安徽华新印务有限公司 A kind of waterproof printing oil base and preparation method

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Application publication date: 20180130