CN107638038A - A kind of drop resistant heat-preservation liner formula cup - Google Patents
A kind of drop resistant heat-preservation liner formula cup Download PDFInfo
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- CN107638038A CN107638038A CN201710924745.0A CN201710924745A CN107638038A CN 107638038 A CN107638038 A CN 107638038A CN 201710924745 A CN201710924745 A CN 201710924745A CN 107638038 A CN107638038 A CN 107638038A
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- heat
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- preservation liner
- screw thread
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Abstract
The invention discloses a kind of drop resistant heat-preservation liner formula cup, and it includes cup lid and cup, and described cup has heat-preservation liner, there is external screw thread on the outside of heat-preservation liner, the inwall of cup has internal thread, and heat-preservation liner is connected with cup by screw thread, and the bottom of heat-preservation liner has buffer spring.External screw thread on the outside of heat-preservation liner is quality of rubber materials, is fitted on the outside of heat-preservation liner.The cup of the present invention uses dismountable heat-preservation liner; dismounting, change easily; there is buffer spring can be good at resisting influenceing for the impulsive force that is longitudinally subject to for the bottom of heat-preservation liner; external screw thread on the outside of heat-preservation liner is quality of rubber materials; it is fitted on the outside of heat-preservation liner; protected by the external screw thread of quality of rubber materials; the destructiveness that lateral impact forces are brought can greatly be resisted; secondly heat-preservation liner of the present invention is prepared using shock resistance thermos cup nano material; itself there is extraordinary insulation and shock resistance, be highly suitable for cup inner bag use.
Description
Technical field
The present invention relates to a kind of drop resistant heat-preservation liner formula cup.
Background technology
Insulating cup can cause the drink long period of inner bag storage inside to keep one due to the heat preservation property of its inner bag
Fixed temperature, it is convenient that the life to people is brought, it is not necessary to is heated up water temporarily when needing hot drink or the moment is changed in cup
Drink is to keep its temperature.And people are to ensure the heat insulation effect of insulating cup, or even can be by heat-preservation liner and cup
Vacuum layer is arranged between shell, the effect that insulating cup pins internal drink heat is substantially increased, effectively extends insulation
Cup is to the soaking time of hot drink, and the drop resistant performance of current heat-preservation liner is bad, and by the impact of external force, inner bag is easy to
Rupture.
The content of the invention
For above-mentioned problem, the present invention provides a kind of drop resistant heat-preservation liner formula cup, easy to use, can facilitate
Inner bag is dismantled, and it has good drop resistant performance and heat-insulating property.
To achieve these goals, technical scheme provided by the invention is：A kind of drop resistant heat-preservation liner formula cup, it includes
Cup lid and cup, described cup have heat-preservation liner, have external screw thread on the outside of heat-preservation liner, the inwall of cup has interior spiral shell
Line, described heat-preservation liner are connected with cup by screw thread, and the bottom of described heat-preservation liner has buffer spring.
External screw thread on the outside of described heat-preservation liner is quality of rubber materials, is fitted on the outside of heat-preservation liner.
Described cup place suitable for reading has screen pack.
Described heat-preservation liner is prepared using shock resistance thermos cup nano material.
Described shock resistance thermos cup nano material is with MOF-SO3@SBA-15 nano materials, epoxy acrylic resin, water
Zirconium oxychloride, 2-sulfonic acid para-phthalic sodium, N-N-dimethyl acetamide, methylcellulose and talcum powder are closed as main original
Material, the nano molecular sieve compound particle modified by the metal organic framework of sulfonate radical functionalization（MOF-SO3@SBA-15）, will
It is doped in the polymer hybrid proton insulation film being modified in polymer with MOF-SO3@SBA-15 processed, improves the heat insulating ability of material
Energy.
The cup of the present invention uses dismountable heat-preservation liner, dismounting, changes easily, and the bottom of heat-preservation liner is with slow
Rush spring and can be good at resisting influenceing for the impulsive force that is longitudinally subject to, the external screw thread on the outside of heat-preservation liner is quality of rubber materials, patch
Close on the outside of heat-preservation liner, so, protected by the external screw thread of quality of rubber materials, can greatly resist what lateral impact forces were brought
Destructiveness, next heat-preservation liner of the present invention are prepared using shock resistance thermos cup nano material, and itself has extraordinary guarantor
Gentle shock resistance, it is highly suitable for cup inner bag use.
Brief description of the drawings
Fig. 1 is Intelligent water cup schematic diagram provided in an embodiment of the present invention；
In figure：1st, cup, 2, cup lid, 3, heat-preservation liner, 4, buffer spring, 5, screen pack, 6, external screw thread, 7, internal thread.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made
Embodiment, belong to the scope of protection of the invention.
Referring to Fig. 1, a kind of drop resistant heat-preservation liner formula cup, a kind of drop resistant heat-preservation liner formula cup, it include cup lid 2 with
And cup 1, described cup have heat-preservation liner 3, have external screw thread 6 on the outside of heat-preservation liner, the inwall of cup has internal thread
7, described heat-preservation liner is connected with cup by screw thread, and the bottom of described heat-preservation liner has buffer spring 4.
External screw thread on the outside of described heat-preservation liner is quality of rubber materials, is fitted on the outside of heat-preservation liner.
Described cup place suitable for reading has screen pack 5.
Described heat-preservation liner is prepared using shock resistance thermos cup nano material.
Described shock resistance thermos cup nano material is with MOF-SO3@SBA-15 nano materials, epoxy acrylic resin, water
Zirconium oxychloride, 2-sulfonic acid para-phthalic sodium, N-N-dimethyl acetamide, methylcellulose and talcum powder are closed as main original
Material, the nano molecular sieve compound particle modified by the metal organic framework of sulfonate radical functionalization（MOF-SO3@SBA-15）, will
It is doped in polymer with MOF-SO processed3The polymer hybrid proton insulation film that@SBA-15 are modified, improve the heat insulating ability of material
Energy.
The cup of the present invention uses dismountable heat-preservation liner, dismounting, changes easily, and the bottom of heat-preservation liner is with slow
Rush spring and can be good at resisting influenceing for the impulsive force that is longitudinally subject to, the external screw thread on the outside of heat-preservation liner is quality of rubber materials, patch
Close on the outside of heat-preservation liner, so, protected by the external screw thread of quality of rubber materials, can greatly resist what lateral impact forces were brought
Destructiveness, next heat-preservation liner of the present invention are prepared using shock resistance thermos cup nano material, and itself has extraordinary guarantor
Gentle shock resistance, it is highly suitable for cup inner bag use.Embodiment is as follows：
Embodiment 1
A kind of shock resistance thermos cup preparation method of nano material, comprises the following steps：
Step 1, at room temperature by 26 parts of MOF-SO3@SBA-15 nano materials, 39 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；
Step 2, the mixture after above-mentioned processing and mould are placed in curing oven carrying out curing process, solidification temperature is 260 DEG C,
Soaking time 2h, room temperature is cooled to the furnace after being fully cured；
Step 3, by after above-mentioned solidification material carry out demoulding processing, 800 DEG C are then warming up in Muffle furnace and is carried out at carbonization
Reason, soaking time 2h, furnace cooling after carbonization；
Step 4, the material after carbonization inserted to die for molding, carry out double-face vibration pressurization during shaping to mould, pole power of shaking is
200KN, time of vibration 5 seconds, the blank after shaping are dried to water content and are less than 1Wt%；
Step 5, the blank after above-mentioned drying is placed on to 600 DEG C of vacuum atmosphere resistance furnace inside holding 3h, in 45KPa pressure
Under, 1400 DEG C of sinter moldings are warming up to 25 DEG C/h, obtain the shock resistance thermos cup nano material.
Described MOF-SO3@SBA-15 preparation method of nano material is as follows：
Step 1, by 0.3kgSBA-15 zeolite powders, activated at 500 DEG C, will be living after ball milling in the 10L ethanol being distributed to
The mixture for changing zeolite and ethanol is transferred in the three-necked flask equipped with 2L ammoniacal liquor, and temperature is increased into 60 DEG C, heats 1h, so
The 1L added afterwards TEOS, continue to stir 30min, the slurries filtration that will be obtained, washed 3 times with ethanol, finally obtain short chain and change
Property agent be modified SBA-15 filter cakes；
Step 2,15 parts of above-mentioned modified SBA-15 filter cake ultrasonic disperses are taken at 45 parts, N-N-dimethyl acetamide（DMA）In, and
Weigh 50 parts of hydration zirconium oxychlorides respectively afterwards and 8 parts of 2-sulfonic acid para-phthalic sodiums are added in above-mentioned dispersion liquid, then add 11
Part formic acid, ultrasonic disperse 20min, is transferred them in polytetrafluoroethyllining lining, cover lid and being put into reactor seal it is tight
It is close, sustained response 24h in 150 DEG C of constant temperature oven is subsequently placed in, reaction product is come out by centrifuging, first with fresh
DMF solvent is cleaned 3 times, then is repeatedly washed with fresh alcohol solvent, and centrifugation product, which is finally placed in 50 DEG C of baking oven, to be protected
6h is held, that is, obtains MOF-SO3@SBA-15 compound particles；
Step 3, by 20 parts of SPEEK（Sulfonation degree 62%）, 3 parts of DMF are added, dissolving forms SPEEK solution, to above-mentioned polymer
1wt% MOF-SO is added in solution3@SBA-15 compound particles, and ultrasonic 3h and it is uniformly dispersed and the dispersion liquid carefully incline
In mould and it is quickly placed into 60 DEG C of baking ovens, keeps 8h then, rise temperature keeps 8h to 80 DEG C.Finally, at room temperature
Nano material is converted into H with 1mol/L hydrochloric acid acidifying 48h+Type, finally it can obtain final MOF-SO3@SBA-15 nanometers
Material.
Embodiment 2
Step 1, at room temperature by 20 parts of MOF-SO3@SBA-15 nano materials, 31 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 3
Step 1, at room temperature by 16 parts of MOF-SO3@SBA-15 nano materials, 49 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 4
Step 1, at room temperature by 9 parts of MOF-SO3@SBA-15 nano materials, 19 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 5
Step 1, at room temperature by 21 parts of MOF-SO3@SBA-15 nano materials, 14 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 6
Step 1, at room temperature by 30 parts of MOF-SO3@SBA-15 nano materials, 25 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 7
Step 1, at room temperature by 40 parts of MOF-SO3@SBA-15 nano materials, 39 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 8
Step 1, at room temperature by 46 parts of MOF-SO3@SBA-15 nano materials, 10 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 9
Step 1, at room temperature by 18 parts of MOF-SO3@SBA-15 nano materials, 36 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 10
Step 1, at room temperature by 25 parts of MOF-SO3@SBA-15 nano materials, 50 parts of epoxy acrylic resins, 1.5 parts of methyl fibres
Dimension element and 4 parts of talcum powder add magnetic stirrer and are well mixed, and rotating speed 500r/min, the mixture after then handling loads mould
In, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and embodiment 1 is identical.
Embodiment 11
At room temperature by 26 parts of MOF-SO3@SBA-15 nano materials, 8 parts of modified bauxites, 39 parts of epoxy acrylic resins, 1.5
Part methylcellulose and 4 parts of talcum powder add magnetic stirrers and are well mixed, rotating speed 500r/min, the mixture after then handling
It is fitted into mould, the liquid in mixture is separated, obtains the semi-moist mixture of shaping；Remaining is prepared and the phase of embodiment 1
Together.
Described modified Nano bauxite preparation method is as follows：
25 parts of bauxites are put into the liquor alumini chloridi of mass fraction 8% at 90 DEG C and stirred 5 hours, filters, washs to neutrality,
Drying, is dispersed in the deionized water solution of ethanol one, adds 18 parts of octadecylamines in 60 DEG C of stirred in water bath 4 hours, ultrasound
It is scattered 30 minutes, filter, washing, be dried under vacuum to constant weight, grind, sieve and produce modified Nano bauxite.
Reference examples 1
It is with the difference of embodiment 1：MOF-SO3In the step 1 of@SBA-15 nano materials, temperature is increased to 60 DEG C, heating
1h, the 2L then added TEOS, continue to stir 30min, remaining step is identical with embodiment 1.
Reference examples 2
It is with the difference of embodiment 1：MOF-SO3In the step 1 of@SBA-15 nano materials, temperature is increased to 60 DEG C, heating
1h, the 0.1L then added TEOS, continue to stir 30min, remaining step is identical with embodiment 1.
Reference examples 3
It is with the difference of embodiment 1：MOF-SO3In the step 2 of@SBA-15 nano materials, 5 parts of above-mentioned modified SBA-15 filters are taken
Cake ultrasonic disperse is at 35 parts, N-N-dimethyl acetamide（DMA）In, remaining step is identical with embodiment 1.
Reference examples 4
It is with the difference of embodiment 1：MOF-SO3In the step 1 of@SBA-15 nano materials, 25 parts of above-mentioned modified SBA-15s are taken
Filter cake ultrasonic disperse is at 15 parts, N-N-dimethyl acetamide（DMA）In, remaining step is identical with embodiment 1.
Reference examples 5
It is with the difference of embodiment 1：MOF-SO3In the step 2 of@SBA-15 nano materials, 30 parts of hydration oxygen chlorine are weighed respectively
Change zirconium and 12 parts of 2-sulfonic acid para-phthalic sodiums are added in above-mentioned dispersion liquid, then 11 parts of formic acid of addition, ultrasonic disperse 20min,
Remaining step is identical with embodiment 1.
Reference examples 6
It is with the difference of embodiment 1：MOF-SO3In the step 2 of@SBA-15 nano materials, 20 parts of hydration oxygen chlorine are weighed respectively
Change zirconium and 8 parts of 2-sulfonic acid para-phthalic sodiums are added in above-mentioned dispersion liquid, then 5 parts of formic acid of addition, ultrasonic disperse 20min, its
Remaining step is identical with embodiment 1.
Reference examples 7
It is with the difference of embodiment 1：MOF-SO3In the step 3 of@SBA-15 nano materials, 30 parts of SPEEK（Sulfonation degree
62%）, 1 part of DMF is added, dissolving forms SPEEK solution, and remaining step is identical with embodiment 1.
Reference examples 8
It is with the difference of embodiment 1：MOF-SO3The step of@SBA-15 nano materials, in 3,14 parts of SPEEK（Sulfonation degree
62%）, 7 parts of DMF are added, dissolving forms SPEEK solution, and remaining step is identical with embodiment 1.
Reference examples 9
It is with the difference of embodiment 1：MOF-SO3In the step 3 of@SBA-15 nano materials, finally, use at room temperature
Nano material is converted into H by 1.5mol/L sulfuric acid acidifying 48h+Type, remaining step is identical with embodiment 1.
Reference examples 10
It is with the difference of embodiment 1：MOF-SO3In the step 3 of@SBA-15 nano materials, finally, use at room temperature
Nano material is converted into H by 0.1mol/L sulfuric acid acidifying 48h+Type, remaining step is identical with embodiment 1.
Choose the shock resistance thermos cup nano composite material being prepared and carry out performance detection respectively, using JB/T
7609-2006 standards carry out material impact strength experiment；
Test result
Test result indicates that shock resistance thermos cup nano composite material provided by the invention has good heat insulation effect, material
Under national standard test condition, impact strength is certain, and thermal conductivity factor is lower, illustrates high insulating effect, conversely, effect is got over
Difference；Embodiment 1 arrives embodiment 10, and thermal conductivity factor is below 1.0W/ (K.M), changes respectively each in insulation nano composite material
The proportioning of raw material composition, has different degrees of influence, in MOF-SO to the heat-insulating property of material3@SBA-15 nano materials and
Epoxy acrylic resin quality proportioning is 13：20, when other dispensing dosages are fixed, heat insulation effect is best；It is it is worth noting that real
Apply example 11 and add modified Nano bauxite, heat insulation effect significantly improves, and illustrates modified Nano bauxite to MOF-SO3@SBA-15
The heat-insulating property of Nano filling structure has more preferable optimization function；Reference examples 1 to reference examples 2 change SBA-15 surface modifiers
TEOS dosage, heat insulation effect are decreased obviously, and illustrate synthetically produced material impact of the dosage to material of Zeolite modifying agent；Control
Example 3 changes the proportioning that zirconium oxychloride and 2-sulfonic acid para-phthalic sodium are hydrated in dispersion liquid, the material of synthesis is led to reference examples 6
Hot coefficient is still very high, and heat-insulating property is bad；Reference examples 7 change the dosage of DMF in SPEEK solution to reference examples 8, and effect is not yet
It is good, illustrate that DMF dosage has a major impact to SPEEK dispersion properties；Reference examples 9 and example 10 are acidified using sulfuric acid, are changed
Become concentration during its acidifying, heat insulation effect substantially reduces, and it is very big to illustrate that the excessive very few thermal conductivity factor on material of acidifying solution influences；
Therefore the shock resistance thermos cup nano composite material prepared using the present invention has good heat insulation effect.
Claims (5)
1. a kind of drop resistant heat-preservation liner formula cup, it includes cup lid and cup, it is characterised in that described cup has insulation
Inner bag, heat-preservation liner outside have external screw thread, and the inwall of cup has internal thread, and described heat-preservation liner passes through screw thread with cup
It is connected, the bottom of described heat-preservation liner has buffer spring.
2. a kind of drop resistant heat-preservation liner formula cup according to claim 1, it is characterised in that on the outside of described heat-preservation liner
External screw thread be quality of rubber materials, be fitted on the outside of heat-preservation liner.
A kind of 3. drop resistant heat-preservation liner formula cup according to claim 1, it is characterised in that described cup place's tool suitable for reading
There is screen pack.
4. a kind of drop resistant heat-preservation liner formula cup according to claim 1, it is characterised in that described heat-preservation liner uses
Shock resistance thermos cup nano material is prepared.
A kind of 5. drop resistant heat-preservation liner formula cup according to claim 4, it is characterised in that described shock resistance thermos cup
Nano material is with MOF-SO3@SBA-15 nano materials, epoxy acrylic resin, hydration zirconium oxychloride, 2-sulfonic acid terephthaldehyde
Sour sodium, N-N-dimethyl acetamide, methylcellulose and talcum powder are primary raw material, are had by the metal of sulfonate radical functionalization
The nano molecular sieve compound particle of machine backbone modification（MOF-SO3@SBA-15）, it is doped in polymer with MOF-SO processed3@
The polymer hybrid proton insulation film that SBA-15 is modified, improve the heat-insulating property of material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710924745.0A CN107638038A (en) | 2017-10-01 | 2017-10-01 | A kind of drop resistant heat-preservation liner formula cup |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710924745.0A CN107638038A (en) | 2017-10-01 | 2017-10-01 | A kind of drop resistant heat-preservation liner formula cup |
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| Publication Number | Publication Date |
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| CN107638038A true CN107638038A (en) | 2018-01-30 |
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ID=61112078
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|---|---|---|---|
| CN201710924745.0A Pending CN107638038A (en) | 2017-10-01 | 2017-10-01 | A kind of drop resistant heat-preservation liner formula cup |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201529031U (en) * | 2009-11-30 | 2010-07-21 | 付世龙 | Shockproof thermos cup |
| KR20120121077A (en) * | 2011-04-26 | 2012-11-05 | 감기승 | Cup |
| CN204105803U (en) * | 2014-07-28 | 2015-01-21 | 浙江橘花家居用品有限公司 | The anti-broken thermos cup of vibration damping of shell and inner bag Elastic Contact |
| CN206102292U (en) * | 2016-08-23 | 2017-04-19 | 漳州市恩扬工艺品有限公司 | Soft plasticity heat preservation glass holder |
-
2017
- 2017-10-01 CN CN201710924745.0A patent/CN107638038A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201529031U (en) * | 2009-11-30 | 2010-07-21 | 付世龙 | Shockproof thermos cup |
| KR20120121077A (en) * | 2011-04-26 | 2012-11-05 | 감기승 | Cup |
| CN204105803U (en) * | 2014-07-28 | 2015-01-21 | 浙江橘花家居用品有限公司 | The anti-broken thermos cup of vibration damping of shell and inner bag Elastic Contact |
| CN206102292U (en) * | 2016-08-23 | 2017-04-19 | 漳州市恩扬工艺品有限公司 | Soft plasticity heat preservation glass holder |
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