A kind of use in waste water treatment water purification agent and its production method and its application method
Technical field
The present invention relates to technical field of sewage, more specifically to a kind of use in waste water treatment water purification agent and its life
Production method and its application method.
Background technology
It is the target pursued all the time in industry that effective purified treatment how is carried out to sewage and waste water, especially recently as
The fast development of Chinese aquaculture, the fowl poultry kind aquaculture wastewater of high pollution cannot be handled effectively, cause plant's periphery soil
The pollution in wide area of earth and natural water area, the safety of local underground water is seriously affected.How to high pollutions such as cultivation classes
The purified treatment that waste water carries out high efficiency, low cost is even more the emphasis of research in industry, in view of pig poultry and cowboying industry are substantially all
Area in mountain area, city suburbs etc. without basic sewage collecting facility, thus be more badly in need of a kind of small investment, fast onset,
Treatment effect can reach State Ministry of Environmental Protection's livestock and poultry cultivation standard of drainage and not produce the sewage purification technology of secondary pollution.
Coagulating treatment is one of key link in current sewage disposal, can go turbid decontamination, reduces sewage subsequent treatment
Pollutional load, and water purification agent (flocculant) is the key factor for determining coagulating treatment effect, operation conditions to follow-up process,
Final outflow water water quality and cost etc. have important influence.Although in the market in the presence of the flocculant of a large amount of distincts
Product, but its using effect is uneven, and the flocculant product for not producing secondary pollution again for high efficiency low cost still lacks very much.
Through retrieval, a large amount of patents disclose the research on flocculant, such as Chinese Patent Application No.:
2015104467421, the applying date:On July 23rd, 2015, invention and created name are:It is a kind of for steviol glycoside impurity removal process
Flocculant, this application case disclose a kind of flocculant for steviol glycoside impurity removal process, and its raw material includes by weight:It is modified
Chitosan 10-20 parts, modified lignin resin 15-25 parts, bodied ferric sulfate 30-40 parts, aluminium citrate 25-35 parts, magnesium sulfate 10-15
Part, ferric-polysilicate 20-30 parts, expanded perlite powder 3-5 parts, zeolite powder 4-6 parts;This application case flocculation reaction is fast, and flocculates
Body particle is big, is easily isolated;But this application case is more suitable for steviol glycoside removal of impurities, is not particularly suited for the high pollutant effluents such as livestock and poultry
Processing.
The content of the invention
1. invention technical problems to be solved
It is an object of the invention to overcome the shortcomings of that cost of sewage disposal is higher in the prior art, clean-up effect is bad, carry
A kind of use in waste water treatment water purification agent and its production method and its application method are supplied, water purification agent of the invention is directed to various microorganisms
The high pollution waste water energy for being difficult to degrade carries out efficient flocculating processing, and cost of manufacture is relatively low, and the flocculate precipitate after use may be used also
Direct secondary use processing, realize that complete alternation utilizes and do not produce secondary pollution.
2. technical scheme
To reach above-mentioned purpose, technical scheme provided by the invention is:
A kind of use in waste water treatment water purification agent of the present invention, including the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder.
Further, in addition to zeolite powder and crushed crude pearlite.
Further, each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:50-70 parts
Zeolite powder:10-20 parts
Crushed crude pearlite:15-25 parts
Graphite phyllite powder:5-10 parts.
A kind of production method of use in waste water treatment water purification agent of the present invention, aluminium carbonate system composite calcium silicic acid is added in the feed
Salt and graphite phyllite powder.
Further, following steps are specifically included:
Step 1:The compound calcium-silicate of oxide spinel aluminium system, zeolite powder, crushed crude pearlite and graphite phyllite powder are distinguished into powder
It is broken to and is no more than 60 mesh;
Step 2: the zeolite powder of 10-20 mass parts is taken to uniformly mix to obtain A with the crushed crude pearlite of 15-25 mass parts
Mixture;
Step 3: the graphite phyllite powder of 5-10 mass parts and A mixtures is taken to uniformly mix to obtain B mixtures;
Produced Step 4: taking the compound calcium-silicate of aluminium carbonate system of 50-70 mass parts to be uniformly mixed with B mixtures.
Further, each raw material components are crushed to 60 mesh respectively in step 1.
Further, the mixing time is not less than 10min every time, mixes speed every time and is not less than 60n/min.
Further, temperature is mixed every time more than 25 DEG C.
Further, humidity is mixed every time below 30%.
The application method of a kind of use in waste water treatment water purification agent of the present invention, using above-mentioned use in waste water treatment water purification agent, input
Be thoroughly mixed in waste water, isolate sediment and supernatant, water purification agent dosage for wastewater flow rate 0.1%~
0.3%.
3. beneficial effect
Using technical scheme provided by the invention, compared with prior art, there is following remarkable result:
(1) a kind of use in waste water treatment water purification agent of the invention, including the compound calcium-silicate of aluminium carbonate system, graphite phyllite
Powder, zeolite powder and crushed crude pearlite, it is engaged using various natural rock powder and mineral assemblage, acidproof alkali ability is more prominent,
There is extremely strong absorption and flocculation through engineering verification repeatedly, solid fertilizer can be also directly used as after the sediment dehydration of aggegation
Or used after compost, complete alternation twice laid is realized, does not produce secondary pollution.
(2) a kind of use in waste water treatment water purification agent of the invention, the compound calcium-silicate of aluminium carbonate system of addition have strongly
CO absorption D compositions, phosphorus composition, suspension composition, metal ingredient and the gap and the crystallization knot that save it in this natural rock stone flour
Ability in structure, and there is strong nucleation, the pollutant in water can be caught rapidly and its flocking settling gets off, and protected
Demonstrate,prove the efficient flocculating efficiency of water purification agent.
(3) a kind of use in waste water treatment water purification agent of the invention, coordinates the graphite phyllite powder of addition to have strong absorption
The ability of ammonia and nitrogen components, especially fine particle in water can be adsorbed effectively, bound zeolite powder and crushed crude pearlite are to coarse powder in water
The efficient absorption and precipitation of particle, mutually cooperate between each component, main pollution that can rapidly in Adsorption livestock and poultry sewage
Thing, BOD, COD of contaminant water is set to significantly improve.
(4) a kind of use in waste water treatment water purification agent of the invention, compared with conventional aluminium system agglutinant or iron system agglutinant, it is solidifying
Collection speed, which has, significantly to be lifted, and conventional aluminium system agglutinant or iron system agglutinant need 5-20min to separate, and this water purification agent adds
Add rear aggegation speed to be exceedingly fast, only need 1-2min polymer and processing water i.e. separable.
(5) a kind of use in waste water treatment water purification agent of the invention, compared with conventional polymer coagulant, this water purification agent without using
Sulfuric acid and caustic soda, as long as 1 procedure during use, compared with conventional polymer coagulant needs 2-4 processes, using equipment and
Cost has obvious reduction, and this water purification agent can improve the water quality such as suspended solid material, COD, hexane, and the sludge isolated is thin
Water-based and easy dehydration, is easy to handle.
(6) application method of a kind of use in waste water treatment water purification agent of the invention, water purification agent dosage is only wastewater flow rate
0.1%-0.3%, dosage are greatly decreased, and simple water purification agent dispensing and mixing arrangement are only needed during use, it is not necessary to sewage
Treatment facility, production cost effectively reduce, simple to operate, widely applicable.
Brief description of the drawings
Fig. 1 is a kind of schematic flow sheet of the production method of use in waste water treatment water purification agent of the present invention.
Embodiment
To further appreciate that present disclosure, with reference to accompanying drawing, the present invention is described in detail.
A kind of use in waste water treatment water purification agent of the present invention, including the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder,
Also include zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:50-70 parts
Zeolite powder:10-20 parts
Crushed crude pearlite:15-25 parts
Graphite phyllite powder:5-10 parts.
The compound calcium-silicate of aluminium carbonate system in the present invention includes a variety of hydrous alumino silicates and the compound day of carbonic acid aluminium salt
Right rock dust, it can be processed from strand using the extraordinary natural volcanic ash containing zeolite, quartz and dolomite etc., herein not one by one
Describe;And the control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is (6-12) in the present invention:1,
And the mass parts content of graphite phyllite powder is the 30%-60% of zeolite powder mass parts, crushed crude pearlite and zeolite powder mass parts
Ratio control is (0.8-1.5):1.
The water purification agent of the present invention is engaged using various natural rock powder and mineral assemblage, and acidproof alkali ability is more prominent
Go out, there is extremely strong absorption and flocculation through engineering verification repeatedly, the compound calcium-silicate of aluminium carbonate system of addition has strongly
CO absorption D compositions, phosphorus composition, suspension composition, metal ingredient and the gap and the crystallization that save it in this natural rock stone flour
Ability in structure, and the compound calcium-silicate of aluminium carbonate system has strong nucleation, can catch the pollution in water rapidly
Thing simultaneously gets off its flocking settling;Coordinate the graphite phyllite powder of addition that there is the ability of strong absorption ammonia and nitrogen components simultaneously,
Especially fine particle in water can be adsorbed effectively, bound zeolite powder and crushed crude pearlite to the efficient absorptions of coarse powder particles in water with
Precipitation, mutually cooperate between each component, major pollutants (such as COD compositions, ammonia that can rapidly in Adsorption livestock and poultry sewage
Nitrogen, total phosphorus, suspension, K, Cu, Zn metal class etc.), BOD, COD of contaminant water is significantly improved, and can be to 99%
Sludge carries out precipitation process, and reaction speed is exceedingly fast, and aggegation floccule is big, dehydration property is good, simultaneously because water purification agent is in itself
Neutrality, without being adjusted to the ph values of water after processing, application is more convenient;Secondly, the water purification agent is safe to use without adjuvant
Efficiently, also there is bleaching and deodorising effect, can also be directly used as solid fertilizer after the sediment dehydration of aggegation or make after compost
With realizing complete alternation twice laid, do not produce secondary pollution.
It should also be noted that, being verified through engineering practice repeatedly, water purification agent of the invention is for industrial wastewater, civil engineering
The various high pollution waste water such as the mud muddy water in field, lake pond (blue-green alge) sewage, colony house sludge water, livestock and poultry cultivation class sewage
Have prominent purified treatment effect, water purification agent of the invention compared with conventional aluminium system agglutinant (PAC) or iron system agglutinant,
Its aggegation speed, which has, significantly to be lifted, and conventional aluminium system agglutinant (PAC) or iron system agglutinant need 5-20min to separate, and
Aggegation speed is exceedingly fast after the addition of this water purification agent, only needs 1-2min polymer and processing water i.e. separable;Secondly, conventional agglutinant must
Suitable ph values must be kept, and the acid-alkali-resistant degree of this water purification agent is compatible;Again, this water purification agent is by raw material and day up to standard JIS
Right mineral matter synthesis, is a kind of harmless agglutinant, the water after processing remains with many mineral matters, there is good shadow to environment
Ring, beneficial to the growth of increase aquatic animals and plants group, fish and planktonic organism;Compared with conventional polymer coagulant, this water purification agent
Without using sulfuric acid and caustic soda, as long as 1 procedure during use, compared with conventional polymer coagulant needs 2-4 processes, use
Equipment and cost have obvious reduction, and this water purification agent can improve the water quality such as suspended solid material, COD, hexane, the dirt isolated
Mud is hydrophobicity and easily dehydration, is easy to handle.
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of use in waste water treatment water purification agent of the present embodiment, including the compound calcium-silicate of aluminium carbonate system and graphite phyllite
Powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:50 parts
Zeolite powder:10 parts
Crushed crude pearlite:15 parts
Graphite phyllite powder:5 parts.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 10 in the present embodiment:1, and
The mass parts content of graphite phyllite powder is the 50% of zeolite powder mass parts, and the mass parts ratio of crushed crude pearlite and zeolite powder is
1.5:1.
A kind of production method of use in waste water treatment water purification agent of the present embodiment, aluminium carbonate system composite calcium silicon is added in the feed
Hydrochlorate and graphite phyllite powder, specifically include following steps:
Step 1:The compound calcium-silicate of oxide spinel aluminium system, zeolite powder, crushed crude pearlite and graphite phyllite powder are distinguished into powder
It is broken to 60 mesh;The compound calcium-silicate of aluminium carbonate system nucleation in 60 mesh granularity is especially pronounced, can catch the dirt in water rapidly
Dye thing gets off its flocking settling;
Step 2: the zeolite powder of 10 mass parts and the crushed crude pearlite of 15 mass parts is taken to uniformly mix to obtain A mixtures;
Step 3: the graphite phyllite powder of 5 mass parts and A mixtures is taken to uniformly mix to obtain B mixtures;
Produced Step 4: taking the compound calcium-silicate of aluminium carbonate system of 50 mass parts to be uniformly mixed with B mixtures, and will
Obtained stabilized mixture is positioned over the environment that temperature is less than 5 DEG C and preserved.
It should be noted that mixing the time in above step every time is not less than 10min, speed is mixed not every time
Less than 60n/min, temperature is mixed every time more than 25 DEG C, humidity is mixed every time below 30%, by mixing
The strict control of order and hybrid technique parameter, it is intrinsic that guarantee can give full play to each group, ultimate guarantee finished product water purification agent energy
It is enough efficiently to play effectiveness.
The application method of a kind of use in waste water treatment water purification agent of the present embodiment, it is only necessary to which simple water purification agent is launched and mixing
Device, it is not necessary to sewage treatment facility, it is widely applicable, and water purification agent dosage is only the 0.1% of wastewater flow rate, root when specifically used
According to proof dry powder feeding device can be used, this water purification agent is put into pipe-line mixer simultaneously with treatment sewage be sufficiently stirred it is mixed
Close, then sediment separate out and supernatant, supernatant directly gets to the wastewater discharge standard of ring protection, and sediment then enters precipitation
Concentration basin, natural sedimentation dehydration after through press filtration by moisture control below 50%, handle aquaculture wastewater caused by sludge it is big
Part is the nutritional ingredient in excrement dirt, can directly be mixed with other argol and carry out compost utilization or as Building woods such as making brick and tile
Material, realize that complete alternation utilizes and do not produce secondary pollution.
It is explained with reference to concrete case:
Case 1:The Pig raising wastewater processing of the double peak mountain Experimental Bases of river nine of Chongqing Academy of Animal Sciences, for Pig dung and urine through natural pond
Caused biogas slurry after gas fermentation, circulation stirring pump is set in biogas slurry lagoon, directly puts into the water purification agent of the present embodiment successively
Powder, while be sufficiently stirred 1 minute;Water purification agent dosage is the 0.21% of processing water.The biogas slurry of before processing detects numerical value:
COD1930ppm, ammonia nitrogen 375ppm, total nitrogen 460ppm, total phosphorus 118ppm;It is COD compositions in sewage, SS compositions, total after processing
Phosphorus composition and heavy metal ion significantly reduce, and result directly reaches Chinese Ministry of Environmental Protection's livestock and poultry cultivation sewage drainage standard
GB18596-2001, measured value are:COD310ppm, ammonia nitrogen 47ppm, total nitrogen 65ppm, total phosphorus 2.7ppm, colourity 50.
Case 2:The river cattle farm biogas slurry waste water of Chongqing dairy industry two, it is biogas slurry COD (2130ppm), ammonia nitrogen (430ppm), total
The index still severe overweights such as nitrogen 530ppm, total phosphorus (166ppm), existing biochemical processing process is difficult up to standard, repeatedly by local ring
Guarantor office orders to rectify and improve;Take stoste to use the water purification agent aqueous solution of the present embodiment in biogas slurry pond, and coordinate and be provided with micro-nano aerator
Be stirred circulation, in reaction 2 minutes, COD is down to below 300ppm, and ammonia nitrogen is down to below 60ppm, total nitrogen be down to 80ppm with
Under, total phosphorus is down to below 2.0ppm.
Embodiment 2
Substantially with embodiment 1, except that, a kind of use in waste water treatment water purification agent of the present embodiment, including aluminium carbonate system
Compound calcium-silicate and graphite phyllite powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:70 parts
Zeolite powder:20 parts
Crushed crude pearlite:25 parts
Graphite phyllite powder:10 parts.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 7 in the present embodiment:1, and
The mass parts content of graphite phyllite powder is the 50% of zeolite powder mass parts, and the mass parts ratio of crushed crude pearlite and zeolite powder is
1.25:1.
A kind of production method of use in waste water treatment water purification agent of the present embodiment, aluminium carbonate system composite calcium silicon is added in the feed
Hydrochlorate and graphite phyllite powder, specifically include following steps:
Step 1:The compound calcium-silicate of oxide spinel aluminium system, zeolite powder, crushed crude pearlite and graphite phyllite powder are distinguished into powder
It is broken to below 60 mesh;
Step 2: the zeolite powder of 20 mass parts and the crushed crude pearlite of 25 mass parts is taken to uniformly mix to obtain A mixtures;
Step 3: the graphite phyllite powder of 10 mass parts and A mixtures is taken to uniformly mix to obtain B mixtures;
Produced Step 4: taking the compound calcium-silicate of aluminium carbonate system of 70 mass parts to be uniformly mixed with B mixtures.
A kind of application method of use in waste water treatment water purification agent of the present embodiment, water purification agent dosage is only wastewater flow rate
0.2%.
Embodiment 3
Substantially with embodiment 1, except that, a kind of use in waste water treatment water purification agent of the present embodiment, including aluminium carbonate system
Compound calcium-silicate and graphite phyllite powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:60 parts
Zeolite powder:16 parts
Crushed crude pearlite:20 parts
Graphite phyllite powder:7 parts.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 8.6 in the present embodiment:1,
And the mass parts content of graphite phyllite powder is the 47% of zeolite powder mass parts, the mass parts ratio of crushed crude pearlite and zeolite powder is
0.8:1.
A kind of production method of use in waste water treatment water purification agent of the present embodiment, aluminium carbonate system composite calcium silicon is added in the feed
Hydrochlorate and graphite phyllite powder, specifically include following steps:
Step 1:The compound calcium-silicate of oxide spinel aluminium system, zeolite powder, crushed crude pearlite and graphite phyllite powder are distinguished into powder
It is broken to below 60 mesh;
Step 2: the zeolite powder of 16 mass parts and the crushed crude pearlite of 20 mass parts is taken to uniformly mix to obtain A mixtures;
Step 3: the graphite phyllite powder of 7 mass parts and A mixtures is taken to uniformly mix to obtain B mixtures;
Produced Step 4: taking the compound calcium-silicate of aluminium carbonate system of 60 mass parts to be uniformly mixed with B mixtures,
A kind of application method of use in waste water treatment water purification agent of the present embodiment, water purification agent dosage is only wastewater flow rate
0.3%.
Embodiment 4
Substantially with embodiment 1, except that, a kind of use in waste water treatment water purification agent of the present embodiment, including aluminium carbonate system
Compound calcium-silicate and graphite phyllite powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:60 parts
Zeolite powder:17 parts
Crushed crude pearlite:15 parts
Graphite phyllite powder:10 parts.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 6 in the present embodiment:1, and
The mass parts content of graphite phyllite powder is the 60% of zeolite powder mass parts, and the mass parts ratio of crushed crude pearlite and zeolite powder is
1.1:1.
Embodiment 5
Substantially with embodiment 1, except that, a kind of use in waste water treatment water purification agent of the present embodiment, including aluminium carbonate system
Compound calcium-silicate and graphite phyllite powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:59 parts
Zeolite powder:18 parts
Crushed crude pearlite:22 parts
Graphite phyllite powder:5.4 part.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 11 in the present embodiment:1, and
The mass parts content of graphite phyllite powder is the 30% of zeolite powder mass parts, and the mass parts ratio of crushed crude pearlite and zeolite powder is
1.2:1.
Embodiment 6
Substantially with embodiment 1, except that, a kind of use in waste water treatment water purification agent of the present embodiment, including aluminium carbonate system
Compound calcium-silicate and graphite phyllite powder, in addition to zeolite powder and crushed crude pearlite, and each component is formed by following mass parts:
The compound calcium-silicate of aluminium carbonate system:60 parts
Zeolite powder:10 parts
Crushed crude pearlite:15 parts
Graphite phyllite powder:5 parts.
The control of the mass parts ratio of the compound calcium-silicate of aluminium carbonate system and graphite phyllite powder is 12 in the present embodiment:1, and
The mass parts content of graphite phyllite powder is the 50% of zeolite powder mass parts, and the mass parts ratio of crushed crude pearlite and zeolite powder is
1.5:1.
Schematically the present invention and embodiments thereof are described above, this describes no restricted, institute in accompanying drawing
What is shown is also one of embodiments of the present invention, and actual structure is not limited thereto.So if common skill of this area
Art personnel are enlightened by it, without departing from the spirit of the invention, without designing and the technical scheme for creativeness
Similar frame mode and embodiment, protection scope of the present invention all should be belonged to.