The content of the invention
It is an object of the invention to provide a kind of new color membrane substrates preparation method, by new technique and design of material,
So that flatness layer technique can be made with spacer material together with, process is saved.
To achieve the above object, the present invention provides a kind of preparation method of color membrane substrates, comprises the following steps:
S1, black matrix" is formed on underlay substrate;
S2:Chromatic filter layer is formed on the basis of S1 is formed;
S3:On the basis of S2 is formed, the hyaline layer that the photoresist containing crosslinking agent is formed is covered;
S4:Prebake conditions are carried out to hyaline layer, while crosslinking agent promotes the acrylic resin in photoresist to carry out preliminary heat
Cross-linking reaction;
S5:The hyaline layer on the basis of forming S4 is exposed using mask plate, develops, forms flatness layer, main spacer material
With secondary spacer material;
S6:High-temperature baking is carried out on the basis of the above, solidifies photoresist complete stability.
Embodiments of the invention provide a kind of color membrane substrates and preparation method thereof, by forming black matrix and colored filter
In the case of photosphere, the hyaline layer being made up of the photoresist containing crosslinked at low temperature agent is initially formed, is exposed after prebake conditions, by
It is different in the transmitance of mask plate different zones, after development, form required flatness layer, main spacer material and secondary spacer material.Therefore,
Flatness layer and spacer material portion Integral design, are formed simultaneously, greatly save process, and have good intensity.
Embodiment
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, control is illustrated below
The embodiment of the present invention.It should be evident that drawings in the following description are only some embodiments of the present invention, for
For those of ordinary skill in the art, on the premise of not paying creative work, other can also be obtained according to these accompanying drawings
Accompanying drawing, and obtain other embodiments.
To make simplified form, part related to the present invention is only schematically show in each figure, they are not represented
Its practical structures as product.In addition, so that simplified form readily appreciates, there is identical structure or function in some figures
Part, one of those is only symbolically depicted, or only marked one of those.
Fig. 2 is the structural representation of color membrane substrates embodiment of the present invention, as shown in Fig. 2 the color membrane substrates include a substrate
Substrate 100, the black matrix" 101 being formed on underlay substrate 100 and chromatic filter layer 102 and it is formed at black matrix" 101
With the hyaline layer 103 on chromatic filter layer 102, the hyaline layer is formed by the photoresist containing crosslinking agent, and hyaline layer 103 wraps
Include a flatness layer 104, main spacer material 105 and secondary spacer material 106.
Flatness layer 104 is covered on black matrix" 101 and chromatic filter layer 102, main spacer material 105 and secondary spacer material 106
On flatness layer 104.Flatness layer 104, main spacer material 105 and secondary spacer material 106 are integrally formed.
Photoresist is added with the crosslinking agent of low temperature polymerization wherein used in hyaline layer 103, and this crosslinking agent is used for saturating
Bright layer promotes acrylic resin to carry out preliminary heat cross-linking reaction in 60~130 DEG C of prebake conditions.
Synthesis technology of acrylic is simple, low-cost, while also has the advantages of contrast and high resolution, therefore
It is a kind of conventional photoresist film-forming resin, i.e., there is acrylic resin in photoresist.
Crosslinking agent is that one kind can be in intermolecular bridging action of line style, so that multiple linear molecules are mutually bonded and are cross-linked into
The material of network structure.Crosslinking agent has different calls in different industries, such as:It is referred to as " vulcanizing agent " in rubber industry custom;
It is referred to as " curing agent ", " curing agent ", " curing agent " in plastic industry;It is referred to as " curing agent ", " hardening in adhesive or coating industry
Agent " etc..
In the present invention, by adding crosslinking agent in photoresist, the acrylic resin of photoresist is allowed in low temperature feelings
Heat cross-linking reaction occurs for (60~130 DEG C) of condition.
The color membrane substrates of the embodiment of the present invention are made using following methods, are comprised the following steps:
S1, black matrix" 101 is formed on underlay substrate 100;
S2:Chromatic filter layer 102 is formed on the basis of S1 is formed;
S3:On the basis of S2 is formed, the hyaline layer 103 that the photoresist containing crosslinking agent is formed is covered, such as Fig. 3 institutes
Show;
S4:Prebake conditions are carried out to hyaline layer 103, while crosslinking agent promotes the acrylic resin in photoresist to carry out tentatively
Heat cross-linking reacts;
S5:The hyaline layer 103 on the basis of forming S4 is exposed using mask plate, developed, forms flatness layer 104, master
Spacer material 105 and secondary spacer material 106;
S6:High-temperature baking is carried out on the basis of the above, solidifies photoresist complete stability.
Wherein, in the S1, black matrix" photoresist is coated on underlay substrate 100, passes through the mask with figure
Plate is exposed to the photoresist and develops to obtain black matrix" 101.
In the S2, chromatic filter layer 102 is made using black matrix" identical method is formed with S1 steps.
As shown in figure 4, the S4's is specially:To completing step under selected temperature (the present embodiment is 60~130 DEG C)
S3 hyaline layer carries out the baking of seclected time, and now photoresistance carries out preliminary heat cross-linking reaction, so that photoresist is in whole base
There is certain anti-etching intensity on plate.
As illustrated in figs. 5-7, S5 is specifically included:On the basis of completing step S4, hyaline layer 103 is exposed by mask plate
Light, as shown in figure 5, forming the first exposure region, the second exposure region and the 3rd exposure region, the first exposure region forms flatness layer 104, the
Two exposure regions form secondary spacer material 106, and the 3rd exposure region forms main spacer material 105, and the first exposure region transmitance is 0, is non-exposure
Light area, the second exposure region transmitance are less than the 3rd exposure region, and the 3rd exposure region transmitance is 100%.
Then by developing process, required flatness layer 104, main spacer material 105 and secondary spacer material 106 are formed, such as Fig. 6 institutes
Show.Wherein by the parameter fluid temperature in the etch process that develops, concentration, spray pressure etc., come control flatness layer 104, it is main every
The height of underbed 105 and secondary spacer material 106.
Using the present invention, the manufacture craft of color membrane substrates can be saved, it is cost-effective, while in the color membrane substrates produced
Flat part and spacer material strong bonded, and flat part and spacer material are formed by the photoresist containing crosslinking agent, are had
Preferable intensity.
It should be noted that above-described embodiment can independent assortment as needed.Described above is only the preferred of the present invention
Embodiment, it is noted that for those skilled in the art, do not departing from the premise of the principle of the invention
Under, some improvements and modifications can also be made, these improvements and modifications also should be regarded as protection scope of the present invention.