CN107601972A - A kind of true mineral varnish - Google Patents
A kind of true mineral varnish Download PDFInfo
- Publication number
- CN107601972A CN107601972A CN201710643921.3A CN201710643921A CN107601972A CN 107601972 A CN107601972 A CN 107601972A CN 201710643921 A CN201710643921 A CN 201710643921A CN 107601972 A CN107601972 A CN 107601972A
- Authority
- CN
- China
- Prior art keywords
- parts
- mineral varnish
- true mineral
- sand
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of true mineral varnish, belong to metope building material technical field.True mineral varnish prepared by the present invention is made up of the raw material of following parts by weight：10~20 parts of emulsions, 10~20 parts of water, 60~80 parts of modified natural coloured silk sand, 0.3~0.5 part of coalescents, 6~10 parts of agar solutions, 0.1~0.3 part of thickener, 0.1~0.2 part of defoamer, 0.2~0.6 part of bactericide, 0.8~1.5 part of antifreezing agent, 0.03~0.05 part of pH buffer, wherein modified natural coloured silk sand are to freeze natural colour sand and lichens homogenate, after illumination constant temperature and humidity culture circulation, then are obtained through charing and quenching.The true mineral varnish of products obtained therefrom of the present invention can substrate surface be formed densification film layer, prevent inside and out moisture by so as to effectively improve the water-whitening resistance of product.
Description
Technical field
The invention discloses a kind of true mineral varnish, belong to metope building material technical field.
Background technology
Lithotome due to colorful, texture day into outward appearance and be often used as building and ornament materials, but its lack
Point is heavier mass, increases the heavy burden of wall, complicated and easy embrittlement of constructing, many unsafe factors be present, this all makes its application
Receive certain limitation.True mineral varnish be using natural granite, rubble and stone flour as aggregate, using synthetic resin emulsion as base-material simultaneously
It is aided with the SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS that a variety of auxiliary agents are formulated, not only has and exactly like marble, granite
Decorative effect, give graceful, harmonious, serious aesthetic feeling, and there is preferable fire-proof and water-proof, resistance to acids and bases, stain resistance,
And the features such as cohesive force is strong, colour fading is light.Erosion of the extraneous adverse circumstances to building cement basic layer can be effectively prevented, extension is built
Build the life-span of thing；Easy construction, it is easily dry time saving.It is deep by numerous owners and builder in external wall of high-rise building external decoration engineering
Favor.But run into rainy day water suction whiting and turn into a big drawback of true mineral varnish.
True mineral varnish coating easily occurs meeting water whiting after drying, and especially dries initial stage（<24h）, rainy weather is run into,
Washed away for a long time by rainwater, coating will soften and turn white.The addition of the hydroaropic substances such as emulsion water suction, cellulose ether can all be led
Cause the appearance of whiting.On the one hand it is that true mineral varnish coating is thicker, moisture evaporation is slower, and especially environment temperature is low（<10℃）、
Relative humidity is big（>80%）When, moisture can not volatilize completely, turn white；On the other hand it is that moisture passes through coating, enters paint
Inside film.These are relevant with emulsion, first, the activity that water inside and outside emulsion paint film be present is poor, the water outside its promotion internally expands
Dissipate, and absorbed by the water-soluble component in paint film；Second, emulsion particle molten bonding film forming is incomplete, moisture easily passes through emulsion particle
The capillary in gap and penetrate into, particularly in the case where emulsifier concentration is higher, moisture can be with the intergranular hydrophily of molten bonding
Spread into as passage at interface.
Simple production process, the cost of true mineral varnish are low, excellent performance, wide to more high-grade DEVELOPMENT PROSPECT, are in one
The good chance of individual development, and the water-whitening resistance problem of true mineral varnish is a big factor of developmental limitation.Therefore, it is resistance to true mineral varnish
The research of water-white property is particularly significant.
The content of the invention
The present invention solves the technical problem of：Easily occur meeting water whiting after drying for true mineral varnish coating, especially
It is dry initial stage, runs into rainy weather, is washed away for a long time by rainwater, and coating will soften and turn white, and influence the problem of attractive in appearance,
The invention provides a kind of true mineral varnish.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of true mineral varnish, is made up of the raw material of following parts by weight：10~20 parts of emulsions, 10~20 parts of water, 60~80 parts change
Property natural colour sand, 0.3~0.5 part of coalescents, 6~10 parts of agar solutions, 0.1~0.3 part of thickener, 0.1~0.2 part defoaming
Agent, 0.2~0.6 part of bactericide, 0.8~1.5 part of antifreezing agent, 0.03~0.05 part of pH buffer；
The specific method of modifying of modified natural coloured silk sand is as follows：
（1）It is 1 in mass ratio：10~1：20 mix natural colour sand with lichens homogenate, mixed mortar are obtained, by gained mixed mortar
Freeze 3~5h, under illumination condition, constant temperature and humidity culture 3~5 days, so freezing, the culture of illumination constant temperature and humidity circulation 8~
10 times, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture and dry to constant weight, it is broken to obtain natural colour sand
Material；
（2）Natural colour sand particle is carbonized under nitrogen guard mode, and poured into while hot in cold water, then filtered, washing and dry
It is dry, obtain modified natural coloured silk sand.
It is characterized in that：The emulsion is nanometer styrene-acrylic emulsion, any in nanometer pure-acrylic emulsion or nanometer silicone acrylic emulsion
It is a kind of；The emulsion solid content is 20~30%.
The coalescents are any one in propandiol butyl ether, propylene glycol methyl ether acetate, sodium alginate or casein.
It by agar and water quality ratio is 1 that the agar solution, which is,：60~1：80 heating stirrings dissolve to obtain.
The thickener is any one in organobentonite, diatomite, attapulgite or alumina silicate.
The defoamer is any one in dimethyl silicone polymer or polyoxypropylene ethylene oxide glycerin ether.
The bactericide is in Dowicil QK-20 bactericide, the bactericide of Dowicil 75 or the bactericide of Dowicil 96
Any one.
The antifreezing agent is made up of the raw material of following parts by weight：50~60 parts of propane diols, 6~8 parts of glycerine, 6~10 parts
Emulsifier op-10,3~6 parts of Tea Saponins.
The pH buffer is any one in potassium dihydrogen phosphate or dipotassium hydrogen phosphate.
Step（1）The lichens homogenate is obtained by the raw mill of following parts by weight：30~50 parts of lichens, 40~50
Part milk, 80~100 parts of water.
The beneficial effects of the invention are as follows：
（1）For technical solution of the present invention by using nanoemulsions system, emulsion particle diameter can effectively penetrate into matrix in nanoscale
In internal void, so as to which matrix pore structure be filled, and in process of osmosis, modified natural coloured silk sand can be carried and enter hole
In, the further filling to matrix hole is realized, avoids intrinsic silicon moisture from penetrating into film table by the pore structure of matrix
Face, in addition, emulsion particle diameter is smaller, it is finer and close in the film that matrix surface is formed, so as to avoid outside moisture by so as to have
Effect improves the water-whitening resistance after product use；
（2）Color sand is modified processing by technical solution of the present invention, and first, lichens can be produced to natural in metabolic processes
Color sand has the material of weak erosive energy, as moisture penetrates into inside natural colour sand pore structure together, including further
Portion corrodes to form more rich pore structure, is further permeated so as to be advantageous to moisture, furthermore, in refrigerating process, hole knot
Moisture in structure freezes, and volumetric expansion, can effectively widen hole, in follow-up course of defrosting, is easy to more moisture to carry ground
Clothing metabolite enters, and during follow-up Freezing smashing, ice crystal is acted on by external force and causes pore structure to break in pore structure
Split, natural colour sand is fully refined, and thinning process majority can make natural colour sand table caused by fragmentation along pore structure and fragmentation
Organic matter caused by face covering lichens metabolism, then coordinate the organic matter for making covering under nitrogen guard mode to carbonize, on color sand surface
Clad is formed, completes the modification to color sand, after being added in system, the presence of the charing organic matter on modified color sand surface can have
Effect improves its compatibility with matrix emulsion, during subsequent cure, can cooperatively form compact film with nanoemulsions, avoid
Moisture to cause film to soften by turning white.
Embodiment
Count in parts by weight, take 30~50 parts of lichens successively, 40~50 portions of milk, 80~100 parts of water, pour into mortar,
20~30min is ground, obtains lichens homogenate；Natural colour sand is added in pulverizer, 120~200 mesh sieves are crossed after crushing, then by quality
Than for 1：10~1：20 add the natural colour sand after sieving and lichens homogenate in beaker, 10 are stirred with glass bar~
20min, mixed mortar is obtained, then gained mixed mortar is evenly laid out in pallet, and pallet is moved into refrigerator, in temperature
Under the conditions of -20~-18 DEG C, pallet is taken out after freezing 3~5h, is 300~400Lx in intensity of illumination, temperature is 12~15
DEG C, under the conditions of humidity is 65~70%, constant temperature and humidity culture 3~5 days, so freezing, illumination constant temperature and humidity culture circulation 8~10
It is secondary, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture, obtain crushing wet feed, and by broken crushing wet feed
It is transferred in baking oven, is dried under the conditions of being 105~110 DEG C in temperature to constant weight, obtain natural colour sand particle；Again by gained natural colour sand
Particle is transferred to retort, and nitrogen is passed through into stove with 100~200mL/min speed, under nitrogen guard mode, with 8~10 DEG C/
Min rate programs are warming up to 500~600 DEG C, after insulation carbonizes 2~4h, and material in retort is poured into temperature for 4~6 while hot
DEG C cold water in, after being stirred 10~15min with glass bar, filtering, obtain filter residue, and filter residue 3~5 is washed with deionized
It is secondary, then the filter residue after washing is transferred in baking oven, dried under the conditions of being 105~110 DEG C in temperature to constant weight, obtain modified natural coloured silk
Sand；Count in parts by weight, 10~20 parts of emulsions, 10~20 parts of water, 60~80 parts of modified natural coloured silks are sequentially added in batch mixer
Sand, 0.3~0.5 part of coalescents, 6~10 parts of agar solutions, 0.1~0.3 part of thickener, 0.1~0.2 part of defoamer, 0.2~
0.6 part of bactericide, 0.8~1.5 part of antifreezing agent, 0.03~0.05 part of pH buffer, in rotating speed be 1500~1800r/min, temperature
Spend under the conditions of 45~55 DEG C, high-speed stirred mixes 2~4h, and discharging is filling, produces true mineral varnish.The emulsion is nanometer phenylpropyl alcohol
Any one in emulsion, nanometer pure-acrylic emulsion or nanometer silicone acrylic emulsion；The emulsion solid content is 20~30%.The film forming
Auxiliary agent is any one in propandiol butyl ether, propylene glycol methyl ether acetate, sodium alginate or casein.The agar solution is by fine jade
Fat and water quality ratio are 1：60~1：80 heating stirrings dissolve to obtain.The thickener is organobentonite, diatomite, concave convex rod
Soil or alumina silicate in any one.The defoamer is in dimethyl silicone polymer or polyoxypropylene ethylene oxide glycerin ether
Any one.The bactericide is in Dowicil QK-20 bactericide, the bactericide of Dowicil 75 or the bactericide of Dowicil 96
Any one.The antifreezing agent is made up of the raw material of following parts by weight：50~60 parts of propane diols, 6~8 parts of glycerine, 6~10
Part emulsifier op-10,3~6 parts of Tea Saponins.The pH buffer is any one in potassium dihydrogen phosphate or dipotassium hydrogen phosphate.
Example 1
Count in parts by weight, take 50 parts of lichens successively, 50 portions of milk, 100 parts of water, pour into mortar, grind 30min, obtain lichens
Homogenate；Natural colour sand is added in pulverizer, 200 mesh sieves are crossed after crushing, then is 1 in mass ratio：20 by the natural color after sieving
Sand is added in beaker with lichens homogenate, is stirred 20min with glass bar, is obtained mixed mortar, then gained mixed mortar is uniform
It is laid in pallet, and pallet is moved into refrigerator, under the conditions of temperature is -18 DEG C, takes out pallet after freezing 5h, in illumination
Intensity is 400Lx, and temperature is 15 DEG C, under the conditions of humidity is 70%, constant temperature and humidity culture 5 days, so freezing, illumination constant temperature and humidity
Culture circulation 10 times, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture, crushing wet feed is obtained, and will be broken
Crushing wet feed be transferred in baking oven, in temperature be 110 DEG C under the conditions of dry to constant weight, obtain natural colour sand particle；Again by gained day
Right color sand particle is transferred to retort, and nitrogen is passed through into stove with 200mL/min speed, under nitrogen guard mode, with 10 DEG C/
Min rate programs are warming up to 600 DEG C, after insulation carbonizes 4h, pour into material in retort in the cold water that temperature is 6 DEG C while hot,
After being stirred 15min with glass bar, filtering, filter residue is obtained, and filter residue is washed with deionized 5 times, then by the filter residue after washing
It is transferred in baking oven, is dried under the conditions of being 110 DEG C in temperature to constant weight, obtain modified natural coloured silk sand；Count in parts by weight, in batch mixer
In sequentially add 20 parts of emulsions, 20 parts of water, 80 parts of modified natural coloured silk sand, 0.5 part of coalescents, 10 parts of agar solutions, 0.3 part of thickening
Agent, 0.2 part of defoamer, 0.6 part of bactericide, 1.5 parts of antifreezing agents, 0.05 part of pH buffer, in rotating speed be 1800r/min, temperature
Under the conditions of 55 DEG C, high-speed stirred mixing 4h, discharging is filling, produces true mineral varnish.The emulsion is nanometer silicone acrylic emulsion；It is described
Emulsion solid content is 30%.The coalescents are propandiol butyl ether.It by agar and water quality ratio is 1 that the agar solution, which is,：60 add
Thermal agitation dissolves to obtain.The thickener is organobentonite.The defoamer is polyoxypropylene ethylene oxide glycerin ether.It is described
Bactericide is the bactericide of Dowicil 96.The antifreezing agent is made up of the raw material of following parts by weight：60 parts of propane diols, 8 parts sweet
Oil, 10 parts of emulsifier op-10s, 6 parts of Tea Saponins.The pH buffer is potassium dihydrogen phosphate.
Example 2
Count in parts by weight, take 50 parts of lichens successively, 50 portions of milk, 100 parts of water, pour into mortar, grind 30min, obtain lichens
Homogenate；Natural colour sand is added in pulverizer, 200 mesh sieves are crossed after crushing, then is 1 in mass ratio：20 by the natural color after sieving
Sand is added in beaker with lichens homogenate, is stirred 20min with glass bar, is obtained mixed mortar, then gained mixed mortar is uniform
It is laid in pallet, and pallet is moved into refrigerator, under the conditions of temperature is -18 DEG C, takes out pallet after freezing 5h, in illumination
Intensity is 400Lx, and temperature is 15 DEG C, under the conditions of humidity is 70%, constant temperature and humidity culture 5 days, so freezing, illumination constant temperature and humidity
Culture circulation 10 times, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture, crushing wet feed is obtained, and will be broken
Crushing wet feed be transferred in baking oven, in temperature be 110 DEG C under the conditions of dry to constant weight, obtain natural colour sand particle；Again by gained day
Right color sand particle is transferred to retort, and nitrogen is passed through into stove with 200mL/min speed, under nitrogen guard mode, with 10 DEG C/
Min rate programs are warming up to 600 DEG C, after insulation carbonizes 4h, pour into material in retort in the cold water that temperature is 6 DEG C while hot,
After being stirred 15min with glass bar, filtering, filter residue is obtained, and filter residue is washed with deionized 5 times, then by the filter residue after washing
It is transferred in baking oven, is dried under the conditions of being 110 DEG C in temperature to constant weight, obtain modified natural coloured silk sand；Count in parts by weight, in batch mixer
In sequentially add 20 parts of emulsions, 20 parts of water, 80 parts of modified natural coloured silk sand, 0.5 part of coalescents, 10 parts of agar solutions, 0.3 part of thickening
Agent, 0.2 part of defoamer, 0.6 part of bactericide, 1.5 parts of antifreezing agents, 0.05 part of pH buffer, in rotating speed be 1800r/min, temperature
Under the conditions of 55 DEG C, high-speed stirred mixing 4h, discharging is filling, produces true mineral varnish.The emulsion is silicone acrylic emulsion；The emulsion
Solid content is 30%.The coalescents are propandiol butyl ether.It by agar and water quality ratio is 1 that the agar solution, which is,：60 heating are stirred
Dissolving is mixed to obtain.The thickener is organobentonite.The defoamer is polyoxypropylene ethylene oxide glycerin ether.The sterilization
Agent is the bactericide of Dowicil 96.The antifreezing agent is made up of the raw material of following parts by weight：60 parts of propane diols, 8 parts of glycerine, 10
Part emulsifier op-10,6 parts of Tea Saponins.The pH buffer is potassium dihydrogen phosphate.
Example 3
Count in parts by weight, take 50 parts of lichens successively, 50 portions of milk, 100 parts of water, pour into mortar, grind 30min, obtain lichens
Homogenate；Natural colour sand is added in pulverizer, 200 mesh sieves are crossed after crushing, then is 1 in mass ratio：20 by the natural color after sieving
Sand is added in beaker with lichens homogenate, is stirred 20min with glass bar, is obtained mixed mortar, then gained mixed mortar is uniform
It is laid in pallet, and pallet is moved into refrigerator, under the conditions of temperature is -18 DEG C, takes out pallet after freezing 5h, in illumination
Intensity is 400Lx, and temperature is 15 DEG C, under the conditions of humidity is 70%, constant temperature and humidity culture 5 days, so freezing, illumination constant temperature and humidity
Culture circulation 10 times, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture, crushing wet feed is obtained, and will be broken
Crushing wet feed be transferred in baking oven, in temperature be 110 DEG C under the conditions of dry to constant weight, obtain natural colour sand particle；In parts by weight
Meter, sequentially adds 20 parts of emulsions, 20 parts of water, 80 parts of natural colour sand particles, 0.5 part of coalescents, 10 parts of agar in batch mixer
Liquid, 0.3 part of thickener, 0.2 part of defoamer, 0.6 part of bactericide, 1.5 parts of antifreezing agents, 0.05 part of pH buffer, it is in rotating speed
1800r/min, under the conditions of temperature is 55 DEG C, high-speed stirred mixing 4h, discharging is filling, produces true mineral varnish.The emulsion is nanometer
Silicone acrylic emulsion；The emulsion solid content is 30%.The coalescents are propandiol butyl ether.The agar solution is by agar and water
Mass ratio is 1：60 heating stirrings dissolve to obtain.The thickener is organobentonite.The defoamer aoxidizes for polyoxypropylene
Ethylene Glycol ether.The bactericide is the bactericide of Dowicil 96.The antifreezing agent is made up of the raw material of following parts by weight：60
Part propane diols, 8 parts of glycerine, 10 parts of emulsifier op-10s, 6 parts of Tea Saponins.The pH buffer is potassium dihydrogen phosphate.
Reference examples：The true mineral varnish of Jiangsu coating Co., Ltd production.
The true mineral varnish of the gained of example 1 to 3 is subjected to performance detection with reference examples product according to JG/T24, emphasis detects the resistance to of it
Water-white property, specific testing result are as shown in table 1：
Table 1
| Detection content | Example 1 | Example 2 | Example 3 | Reference examples |
| Water-whitening resistance | Do not whiten | Slight whiting | There is whiting | More serious whiting |
From the testing result of table 1, there is not whiting in products obtained therefrom of the present invention, and water-whitening resistance is good, for current product
The problem of existing chance water whiting, has obtained effective solution.
Claims (10)
- A kind of 1. true mineral varnish, it is characterised in that：It is made up of the raw material of following parts by weight：10~20 parts of emulsions, 10~20 parts Water, 60~80 parts of modified natural coloured silk sand, 0.3~0.5 part of coalescents, 6~10 parts of agar solutions, 0.1~0.3 part of thickener, 0.1 ~0.2 part of defoamer, 0.2~0.6 part of bactericide, 0.8~1.5 part of antifreezing agent, 0.03~0.05 part of pH buffer；The specific method of modifying of modified natural coloured silk sand is as follows：（1）It is 1 in mass ratio：10~1：20 mix natural colour sand with lichens homogenate, mixed mortar are obtained, by gained mixed mortar Freeze 3~5h, under illumination condition, constant temperature and humidity culture 3~5 days, so freezing, the culture of illumination constant temperature and humidity circulation 8~ 10 times, and by the mixed mortar Freezing smashing of last time illumination constant temperature and humidity culture and dry to constant weight, it is broken to obtain natural colour sand Material；（2）Natural colour sand particle is carbonized under nitrogen guard mode, and poured into while hot in cold water, then filtered, washing and dry It is dry, obtain modified natural coloured silk sand.
- A kind of 2. true mineral varnish according to claim 1, it is characterised in that：The emulsion is nanometer styrene-acrylic emulsion, and nanometer is pure Any one in acrylic emulsion or nanometer silicone acrylic emulsion；The emulsion solid content is 20~30%.
- A kind of 3. true mineral varnish according to claim 1, it is characterised in that：The coalescents are propandiol butyl ether, the third two Any one in alcohol methyl ether acetate, sodium alginate or casein.
- A kind of 4. true mineral varnish according to claim 1, it is characterised in that：The agar solution is to be by agar and water quality ratio 1：60~1：80 heating stirrings dissolve to obtain.
- A kind of 5. true mineral varnish according to claim 1, it is characterised in that：The thickener be organobentonite, diatomite, Any one in attapulgite or alumina silicate.
- A kind of 6. true mineral varnish according to claim 1, it is characterised in that：The defoamer is dimethyl silicone polymer or gathered Any one in oxypropylene ethylene oxide glycerin ether.
- A kind of 7. true mineral varnish according to claim 1, it is characterised in that：The bactericide is sterilized for Dowicil QK-20 Any one in agent, the bactericide of Dowicil 75 or the bactericide of Dowicil 96.
- A kind of 8. true mineral varnish according to claim 1, it is characterised in that：The antifreezing agent by following parts by weight raw material Composition：50~60 parts of propane diols, 6~8 parts of glycerine, 6~10 parts of emulsifier op-10s, 3~6 parts of Tea Saponins.
- A kind of 9. true mineral varnish according to claim 1, it is characterised in that：The pH buffer is potassium dihydrogen phosphate or phosphoric acid Any one in hydrogen dipotassium.
- A kind of 10. true mineral varnish according to claim 1, it is characterised in that：Step（1）The lichens homogenate is by following heavy The raw mill of amount number obtains：30~50 parts of lichens, 40~50 portions of milk, 80~100 parts of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710643921.3A CN107601972A (en) | 2017-07-31 | 2017-07-31 | A kind of true mineral varnish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710643921.3A CN107601972A (en) | 2017-07-31 | 2017-07-31 | A kind of true mineral varnish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107601972A true CN107601972A (en) | 2018-01-19 |
Family
ID=61064218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710643921.3A Withdrawn CN107601972A (en) | 2017-07-31 | 2017-07-31 | A kind of true mineral varnish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107601972A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110981282A (en) * | 2019-12-02 | 2020-04-10 | 安徽富瑞雪化工科技股份有限公司 | Anticorrosive antibacterial stone-like paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
| CN106590268A (en) * | 2016-11-14 | 2017-04-26 | 北京卫星制造厂 | Real-stone paint and preparation method thereof |
-
2017
- 2017-07-31 CN CN201710643921.3A patent/CN107601972A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
| CN106590268A (en) * | 2016-11-14 | 2017-04-26 | 北京卫星制造厂 | Real-stone paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110981282A (en) * | 2019-12-02 | 2020-04-10 | 安徽富瑞雪化工科技股份有限公司 | Anticorrosive antibacterial stone-like paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105439500B (en) | A kind of environment-friendly type flexible clay facing tile prepared using modified waste residue and preparation method thereof | |
| CN102417333B (en) | Waterproof alkali efforescence resistant slurry, waterproof alkali efforescence resistant lightweight decorative building material and production method thereof | |
| CN106187087A (en) | Composite foamed pottery of facing based on granite mine tailing and preparation method thereof | |
| CN105399393B (en) | A kind of wall light spraying slurry of integrated spray and its preparation method and application | |
| CN105801065B (en) | A kind of high intensity plastering gupsum and preparation method thereof | |
| CN104496361B (en) | A kind of bamboo ribs-stalk composite wall body material composition and preparation method thereof | |
| CN104140282B (en) | A kind of method for manufacture of ceramic plate using glass fabric as reinforcing material | |
| CN105384403A (en) | Composite floor tiles having good stain resistance capacity | |
| CN104402301A (en) | Lightweight pottery sand stone-like paint and preparation method thereof | |
| CN108546025A (en) | A kind of gunite concrete and its production method of high tenacity | |
| CN103466985A (en) | Graphene cement reinforcer | |
| CN104710142B (en) | Environment-friendly adhesive mortar for external wall insulation integrated slab | |
| CN104891876B (en) | Imitative clear-water concrete and preparation method thereof | |
| CN106431450B (en) | A kind of Ceramic Tiles of wastewaters with modified calcium sulfate whiskers enhancing | |
| CN104086207B (en) | Production process of heat-insulation ceramic plate | |
| CN105565736A (en) | Preparation method for ultraviolet resistant functional mortar | |
| CN104761287B (en) | A kind of cement flooring crystal hardened agent and preparation method thereof | |
| CN101024748B (en) | Base paint for cultural-relic protection and preparing method therefor | |
| CN107601972A (en) | A kind of true mineral varnish | |
| CN104230277A (en) | Low-alkalinity colorful decorative mortar for interior and exterior walls | |
| CN106278066A (en) | Fast hard impervious gap filler | |
| CN106630980A (en) | An oil-proof antifouling kitchen ceramic tile | |
| CN109320136A (en) | A kind of polyurethane terrazzo | |
| CN112010597A (en) | Multifunctional single-component leveling material for renovating old wall surfaces and old ceramic tiles and construction method thereof | |
| CN103274635A (en) | Facing mortar |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180119 |
|
| WW01 | Invention patent application withdrawn after publication |