CN1075944C - 掺有无水擦洗手的清洁剂的清洁制品及其制备方法 - Google Patents
掺有无水擦洗手的清洁剂的清洁制品及其制备方法 Download PDFInfo
- Publication number
- CN1075944C CN1075944C CN94102913A CN94102913A CN1075944C CN 1075944 C CN1075944 C CN 1075944C CN 94102913 A CN94102913 A CN 94102913A CN 94102913 A CN94102913 A CN 94102913A CN 1075944 C CN1075944 C CN 1075944C
- Authority
- CN
- China
- Prior art keywords
- weight
- hand
- hand towel
- cleaning
- hands
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K7/00—Body washing or cleaning implements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Biomedical Technology (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Oncology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Communicable Diseases (AREA)
- Detergent Compositions (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Cosmetics (AREA)
Abstract
一种擦洗手的清洁制品包含有擦洗表面并且能吸收和保留液体的底物,在该底物中的吸收的非擦洗含水的手清洁剂,手清洁剂包含一种或两种溶剂和表面活性剂,并由此通过溶剂或表面活性剂达到清洁作用,通过底物的擦洗表面达到擦洗清洁作用。该底物可包括织物类擦手巾。在连续滚动的圆筒上提供许多这类擦手巾,该圆筒放在可选择封闭的气密的容器内。该容器盖上的开口使使用者取出在其上含有适当量清洁剂的单张擦毛巾。
Description
本发明大体上涉及清洁组合物,尤其涉及无水手清洁剂。
手清洁制剂一般含有增溶或乳化各人皮肤或手上污垢的表面活性剂。当污垢乳化性或溶解本领仅仅用作清洁机理时,这些制剂本身清除污垢有限。当在清洁组合物中仅使用了与非侵蚀性溶剂洗涤剂相结合的表面活性剂时,如果有顽垢或嵌入的污垢存在,则该组合物的清洁能力是不充分的。如果化学配方侵蚀性就其增溶或乳化能力而言太强,则由于其天然油的脱脂,尤其是当重复使用清洁剂时,皮肤可能受到损伤。
当前市场上销售的多种清洁制剂还含有轻度擦洗皮肤表面以有助于除去嵌入污垢的磨料颗粒。所使用的磨料颗粒的一些实例是浮石,二氧化硅和硅藻土。这些制剂可以是“无水”性质的。该术语是指在清洁手过程中无须加入水。但是,因为这种磨料颗粒一般是难溶的,在清洁手后必须用水冲洗,以使手上无残余物存在,即没有细磨料颗粒,该细磨料颗粒如果不冲洗掉将保留在皮肤上。
洗涤或冲洗之后,常常是用擦手巾或织物擦干手,而不是用空气干燥,其目的是为了快速和方便,同时也有助于机械地除去保留在皮肤上的任何顽垢。然而,使用擦手巾或织物而不首先用水清洗已用擦洗手清洁剂洗过的皮肤,将不能有效地除去皮肤上所有的残余磨料。
目前市场上销售的无磨料无水的手清洁剂具有凝胶状或膏状高粘度稠度。这些清洁剂经常掺有极性和非极性组份以除去皮肤表面上的各种污垢。使这类无水清洁剂成为凝胶状的凝胶表面活性剂也起基质作用,以基本上与清洁组份的乳剂持久地结合在一起。这种凝胶稠度主要使无水手清洁剂成膏状,以便于当使用者为了充分地增溶污垢直到使之从皮肤表面除去为止而在皮肤上使用和重复使用该清洁剂时,由于清洁剂和皮肤之间延长了接触而使它们达到要求清洁效果所需的持续清洁作用。如果清洁剂是液体的而不是凝胶状的,那么由于清洁剂和皮肤之间不能延长接触而使与无水清洁剂相关的所需持续洗涤的作用不能达到。液体清洁剂的粘度低也致使清洁剂从手上流掉,由此易于造成清洁剂可能的浪费。因此,凝胶状或高粘度性质的无水手清洁剂与液体清洁剂比较具有许多优点。无水手清洁剂的一个明显的缺点是要使用擦手巾或织物等类似物以除去皮肤上过剩的清洁剂。另一个缺点是当将磨料颗粒掺入到无水手清洁制剂中时,当需要从皮肤上除去所述颗粒时需要用水清洗,通过机械冲洗以确保完全除去难溶的磨料颗粒。
因此,有必要提供一种无水手清洁制品,它具有擦洗特性,而无须使用磨料颗粒并没有凝胶状表面活性剂,也无须另外的擦干织物或擦手巾。
因此,本发明的一个目的是提供一种含无水手清洁剂的擦洗手的清洁制品,该清洁制品不含磨料颗粒,但它结合到擦洗底物中,以便通过该底物的擦洗作用以达到擦洗嵌入的污垢而无须冲洗以除去皮肤上残留的磨料颗粒。
本发明的另一个目的是提供一种液体态无水手清洁组合物,该组合物结合到擦手巾或织物类底物中,而无须使用起载带基质作用的凝胶状或膏状表面活性剂,从而在清洁之后不必使用另外的擦干或擦净织物以除去皮肤上的清洁剂。
本发明的再一个目的是提供一种含液态无水手清洁剂的擦洗手的清洁制品,它是将液态无水手清洁剂结合到擦手巾或织物类底物上,以便在清洁过程中可延长清洁剂和皮肤之间的接触,由于提供的持续的清洁作用,从而增强了清洁剂的效率和清洁能力。
本发明的最后一个目的是提供一种含液体清洁剂的擦洗手的清洁制品,从而达到增强清洁作用,而无须使用能损伤皮肤的粗糙化学配方。
为了达到这些和其它有关的本发明的目的,提供了一种擦洗手的清洁剂制品,该制品包含底物如织物类擦手巾(该擦手巾有一个擦洗表面和能够吸收和保留液体)和在底物中吸收的无擦洗的水相无水手清洁剂,所述的手清洁剂包含一种或两种溶剂和表面活性剂,由此通过该溶剂或表面活性剂而达到清洁作用,以及通过底物的擦洗表面而达到擦洗清洁作用。该制品还包含在装在密闭容器中的连续滚动的圆筒中所提供的许多擦手巾,圆筒的轴在容器内基本上以垂直取向,与容器相连的盖和一个开口以容纳擦手巾通过。含水的手清洁剂的一个优选的实施方案含有2~40%(重量)的有机溶剂,2~20%(重量)表面活性剂,和60~95%(重量)水。
所提供的清洁制品包含擦洗底物和渗入其中的无水手清洁剂。优选实施方案的擦洗底物包括织物类擦手巾,与1989年5月23日出版的题为“Uniformly Moist Abrasive Wips”Kimberly-Clark的美国专利US4,83 3,003类似,它以全文引入本文作为参考。包括在本发明范围内的擦手巾有两个相对的表面,有擦洗组分持久地附着在上或至少其一个表面的整体部份,虽然在擦手巾的两个表面都可以有擦洗组分。该擦洗组分包含表面组织,该表面组织能使擦手巾在皮肤上产生一种轻微擦洗作用,以除掉嵌入的污垢,同时不会因擦伤等而损伤皮肤。为了获得最佳效果,本发明的擦洗组分可占擦手巾擦洗侧表面积最小为10%,最大为90%,剩余侧面具有平滑表面用于拭干。可以预料到擦手巾的两侧都可有渗入其中的擦洗组分,在每侧上擦洗组分的百分率按需要可不同。
另外,该擦手巾必须能吸收和保持预定量的流体,如本文涉及的含水清洁制剂,它足以提供均匀地湿润擦手巾。这里所指的擦手巾的吸收特性是通过吸收和紧密地保持含水制剂的孔隙和微孔如通过毛细管作用实现的。该擦手巾在使用时还应该能易于释放该流体。擦手巾结构的比孔隙或微孔体积调节了擦手巾中可保持的流体的量。
渗入到擦手巾中的无水手清洁剂是能除去皮肤上各种污垢的含水制剂。含水制剂具有足以通过毛细管作用而易于被吸入到擦手巾的孔隙和小孔中的粘度。优选实施方案的无水手清洁剂包含:2~40%(重量)的有机溶剂;2~20%(重量)的表面活性剂;40~96%(重量)的载体;和0~3%(重量)的惰性组分。优选的溶剂是一种能增溶油腻性污垢、油质污垢的物质如脂族溶剂,二价酸酯,石油,植物油,醇,乙二醇,乙二醇醚,糠基类,石油馏出物和多元醇。优选的表面活性剂是非离子的、阴离子的或两性的以促进各组分的水/油单相乳化,并且乳化和悬浮溶剂。载体包含不易燃的赋形剂,该赋形剂也起水溶性污垢的溶剂作用。惰性组分可包括香料,防腐剂,润肤剂,抗氧化剂和杀微生物剂。
本发明的一种擦洗手的清洁制品,其中所述的含水的手清洁剂包含:
2~40%重量的有机溶剂;
2~20%重量的表面活性剂;
60~95%重量的载体;和
0~8%重量的惰性组分。
前款所述的清洁制品,其中所述的含水手清洁剂包含:
1~20%重量d一苎烯;
1~20%重量溶剂油;和
60~95%重量水。
前款所述的清洁制品,包括1~20%的非离子表面活性剂。
本发明更优选的无水手清洁剂,含有1~20%(重量)d一苎烯、1~20%(重量)溶剂油,60~95%(重量)水、2~20%(重量)非离子表面活性剂、0.1~0.5%(重量)杀菌剂、0.1~0.5%(重量)杀真菌剂/防霉剂、0.5~5%(重量)润肤剂、0.01~1%(重量)抗氧化剂和0.01~0.5%(重量)杀菌制剂。
本发明最优选的无水手清洁剂,含有:9.5%(重量)d一苎烯、4.7%(重量)溶剂油、77.1%(重量)水、7%(重量)非离子表面活性剂、0.3%(重量)杀菌剂、0.2%(重量)杀真菌/防霉剂、1%(重量)润肤剂、0.05%(重量)抗氧化剂和0.1%(重量)杀菌制剂。
一种用于制备手清洁制品的方法,该方法包括:
在连续滚动的圆筒中有经穿孔线分开的许多织物类擦手巾,所述的擦手巾能吸收和保留液体,
将非擦洗的,含水的手清洁剂渗入到所述的擦手巾上,
有一个可选择封闭的内部空心的容器,其中装有所述的擦手巾的圆筒,所述容器有一个带开口的盖子,和与其相连的可选择封闭的盖板,
将所述的擦手巾的圆筒放入所述容器的内部,并且圆筒的轴基本上沿垂直方向取向,
将所述的清洁剂加入到在所述容器中的擦手巾的圆筒上,从而用预定量的所述清洁剂适当地湿润所述的擦手巾,和
将所述容器上的盖子封闭以提供基本上一个气密的容器。
本发明优选制剂的具体实例如下,该例表明了各组分优选的和可接受的范围:
组分 优选的 可接受的
重量% 重量%范围1、d一苎烯 9.50 1.00~20.002、无臭的一种溶剂油 4.70 1.00~20.003、柠檬(Lemon)1061 0.05 0.01~0.504、Tergitol/15-S-5 3.00 1.00~10.005、水 77.10 60.00~95.006、月桂基硫酸钠 4.00 1.00~10.007、防腐剂 0.30 0.10~0.508、山梨酸钾 0.20 0.10~0.509、山梨糖醇 1.00 0.50~5.00 10、丁基化羟基甲苯(BHT) 0.05 0.01~1.0011、杀菌剂 0.10 0.01~0.50
Tergitol/15-S-5是非离子表面活性剂的一种商标。
该含水乳剂配方包括离子和非离子组分以乳化和悬浮各种污垢,以及润肤剂和杀菌剂和杀真菌剂/杀霉菌剂。以前,这类无水手清洁剂制剂需要一种凝胶状表面活性剂,作为添加剂,以起基质或底物作用,将离子和非离子组分一起结合在一种基本上持久的悬浮剂中。值得注意的是,当擦手巾本身起保留清洁制剂的各组分于悬浮剂中的基质或底物作用时,在本发明中就不需要现有技术的凝胶状表面活性剂。
在优选实施方案的手清洁制品的制备中,有许多擦洗巾其优选地是连续的,穿孔的,滚动式的圆筒形擦手巾。穿孔线是一种弱线,通过该穿孔线可容易地将所述的擦手巾分开。将所述的擦手巾竖着***可选择地重新密封的,优选的是圆筒形容器内,圆筒的轴基本上是垂直取向的。当然,可以预料本发明另一种优选的实施方案可提供一叠单独的擦手巾,而不是连续的圆筒或卷状的擦手巾。然后将含水配方加入到容器中,优选地倒在圆筒形擦手巾的上面,在容器内用清洁制剂湿润擦手巾。上文讨论的擦手巾的与孔隙容积有关的毛细管作用致使含水清洁制剂均匀地遍布到圆筒形擦手巾上。
装擦手巾的合适的容器的例子主要包括位于容器顶部的气密的盖子,该盖子可选择性地封闭,所述的盖子有一个活叶盖板,其下有一个开口。该开口可使擦手巾通过开口从封闭的容器内通过,从而通过抽出擦手巾并且在位于各单张擦手巾中间的穿孔线处扯断擦手巾而从内圆筒中取出单张擦手巾。该开口的大小适当,当将擦手巾从容器中取出时,它能除去各单张擦手巾上的过量液体。
使用时如上所述将单张擦手巾从容器中取出。当适当地制备时,擦手巾包含的清洁剂量足以充分地清洁使用者的皮肤。在将擦手巾擦在皮肤上时,擦手巾释放出液体清洁剂,并可以使它具有延长与皮肤的接触时间,并且还提供连续清洁,而无须添加另外的清洁剂。擦手巾的擦洗特性易于除去嵌入的污垢,而在皮肤上不留下任何擦洗残余物,用另外方法其残留物在清洁过程后,将必须用水冲洗皮肤,以彻底除去所述擦洗残留物。因此,提供的无水清洁制品是没有现有技术中传统的无水手清洁剂的负作用。
当将适当量的清洁剂施于个别使用时,本发明的手清洁剂也确保有效地使用清洁剂。其它低粘度液体清洁剂易于被浪费掉,这是因为这类洗涤剂的低粘度常常造成洗涤剂从皮肤上流掉。凝胶状清洁剂也难以有效地使用,当使用者用得太少,需要重复使用,使用太多则需要用织物或擦手巾除去废弃的过量部分。
此外,本发明的擦手巾不仅起清洁制剂的底物作用并起擦洗组分的赋形剂作用,而且在使用清洁剂以及部分清洁剂从擦手巾上蒸发掉后,它还起擦干皮肤的作用。
由上文所述可见,本发明适当地达到所有的和上文所述的目的以及其它的优点,这些优点是明显的并且是结构本身固有的。
应该清楚,某些特征和局部组合是有用的,并可使用而无须参考其它特征和局部组合。这些可以预料并且是在本发明权利要求的范围内。
由于本发明有许多可能的实施方案可实施而不脱离本发明的范围,因此,应该清楚本文陈述的全部应理解为说明而不是限制。
Claims (10)
1、一种擦洗手的清洁制品包含:
一种呈现擦洗表面且能吸收和保留液体在其中的底物;和
一种吸收在底物的含水的手清洁剂,所述的手清洁剂包含一种或两种溶剂和表面活性剂,
通过所述的溶剂或表面话性剂达到清洁作用,通过所述底物的擦洗表面达到擦洗清洁作用。
2、如权利要求1的擦洗手的清洁制品,其中所述的底物包括擦手巾。
3、如权利要求2 的擦洗手的清洁制品,其中所述的擦手巾有两个擦洗表面。
4、如权利要求1的擦洗手的清洁制品,其中所述的含水的手清洁剂包含:
2~40%重量的有机溶剂;
2~20%重量的表面活性剂;
60~95%重量的载体;和
0~8%重量的惰性组分。
5、如权利要求1的擦洗手的清洁制品,其中所述的含水手清洁剂包含:
1~20%重量d一苎烯;
1~20%重量溶剂油;和
60~95%重量水。
6、如权利要求5的擦洗手的清洁制品,包括1~20%的非离子表面活性剂。
7、如权利要求1的擦洗手的清洁制品,其中所述的含水的手清洁剂包含:
1~20%重量d一苎烯;
1~20%重量溶剂油;
60~95%重量水;
2~20%重量非离子表面活性剂;
0.1~0.5%重量杀菌剂;
0.1~0.5%重量杀真菌/防霉剂,
0.5~5%重量润肤剂;
0.01~1%重量抗氧化剂;和
0.01~0.5%重量杀菌制剂。
8、如权利要求1的擦洗手的清洁制品,其中所述的含水手清洁剂包含:
9.5%重量d一苎烯;
4.7%重量溶剂油;
77.1%重量水;
7%重量非离子表面活性剂;
0.3%重量杀菌剂;
0.2%重量杀真菌/防霉剂;
1%重量润肤剂;
0.05%重量抗氧化剂;和
0.1%重量杀菌制剂。
9、一种擦洗手的清洁制品包含:
一种包括织物类擦手巾的底物,它有擦洗表面,并且能吸收和保留液体在其上,
一种吸收在擦手巾的非擦洗的含水的手清洁剂,所述手清洁剂包含一种或两种溶剂和表面活性剂,由此通过所述的溶剂或表面活性剂实现清洁作用,通过所述擦手巾的擦洗表面实现擦洗清洁作用,
以连续的滚动的圆筒提供的许多所述的擦手巾,在各个所述擦手巾之间的穿孔线上分离,和
一种选择性封闭的,基本上气密的内部空心的容器,其中装有所述的擦手巾圆筒,所述圆筒的轴在所述容器内主要是沿着垂直方向取向的,和与其有关的盖子,所述的盖子有一个开口用于容纳所述的擦手巾通过,所述的开口有一个与其相连的可选择封闭的盖板。
因而单张掺有所述液体清洁剂的所述擦手巾可以通过所述开口由所述容器的内部取出,并通过沿穿孔线撕下而与圆筒分开。
10、一种用于制备手清洁制品的方法,该方法包括:
在连续滚动的圆筒中有经穿孔线分开的许多织物类擦手巾,所述的擦手巾能吸收和保留液体,
将非擦洗的,含水的手清洁剂渗入到所述的擦手巾上,
有一个可选择封闭的内部空心的容器,其中装有所述的擦手巾的圆筒,所述容器有一个带开口的盖子,和与其相连的可选择封闭的盖板,
将所述的擦手巾的圆筒放入所述容器的内部,并且圆筒的轴基本上沿垂直方向取向,
将所述的清洁剂加入到在所述容器中的擦手巾的圆筒上,从而用预定量的所述清洁剂适当地湿润所述的擦手巾,和
将所述容器上的盖子封闭以提供基本上一个气密的容器。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3301293A | 1993-03-18 | 1993-03-18 | |
US08/033,012 | 1993-03-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1097300A CN1097300A (zh) | 1995-01-18 |
CN1075944C true CN1075944C (zh) | 2001-12-12 |
Family
ID=21868082
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94102913A Expired - Fee Related CN1075944C (zh) | 1993-03-18 | 1994-03-17 | 掺有无水擦洗手的清洁剂的清洁制品及其制备方法 |
Country Status (14)
Country | Link |
---|---|
US (1) | US5683971B1 (zh) |
EP (1) | EP0615720B1 (zh) |
JP (1) | JPH0753352A (zh) |
KR (1) | KR100309307B1 (zh) |
CN (1) | CN1075944C (zh) |
AT (1) | ATE184171T1 (zh) |
AU (1) | AU674919B2 (zh) |
CA (1) | CA2117243C (zh) |
DE (1) | DE69420441T2 (zh) |
DK (1) | DK0615720T3 (zh) |
ES (1) | ES2136162T3 (zh) |
GR (1) | GR3031609T3 (zh) |
IL (1) | IL109002A (zh) |
TW (1) | TW311085B (zh) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6103644A (en) | 1993-12-22 | 2000-08-15 | Nordico Marketing Development, Inc. | Impregnated matrix and method for making same |
GB9517924D0 (en) * | 1995-09-01 | 1995-11-01 | Kimberly Clark Ltd | Hand cleanser |
JP3751025B2 (ja) * | 1995-12-15 | 2006-03-01 | ザ デクスター コーポレイション | 研摩性不織繊維ウェブ材料及びその製造方法 |
US5817585A (en) * | 1996-09-24 | 1998-10-06 | Dymon, Inc. | Paint and stain remover in an abrasive applicator for hard surfaces |
US6503136B1 (en) * | 1996-09-24 | 2003-01-07 | Dymon, Inc. | All purpose cleaner and polish in abrasive applicator |
US6338855B1 (en) | 1996-10-25 | 2002-01-15 | The Procter & Gamble Company | Cleansing articles for skin and/or hair which also deposit skin care actives |
US6063397A (en) * | 1996-10-25 | 2000-05-16 | The Procter & Gamble Company | Disposable cleansing products for hair and skin |
US5972361A (en) * | 1996-10-25 | 1999-10-26 | The Procter & Gamble Company | Cleansing products |
KR20000052782A (ko) * | 1996-10-25 | 2000-08-25 | 데이비드 엠 모이어 | 세정 제품 |
US5962112A (en) * | 1996-12-19 | 1999-10-05 | Kimberly-Clark Worldwide, Inc. | Wipers comprising point unbonded webs |
US5813416A (en) * | 1997-04-03 | 1998-09-29 | Rudolph; James M. | File with sanitizing agent |
US5951991A (en) * | 1997-05-22 | 1999-09-14 | The Procter & Gamble Company | Cleansing products with improved moisturization |
US6280757B1 (en) | 1997-05-22 | 2001-08-28 | The Procter & Gamble Company | Cleansing articles for skin or hair |
US6132746A (en) * | 1997-05-22 | 2000-10-17 | The Procter & Gamble Company | Cleansing products with improved moisturization |
GB9716273D0 (en) | 1997-07-31 | 1997-10-08 | Kimberly Clark Ltd | Hand cleanser |
ATE550010T1 (de) | 1997-09-05 | 2012-04-15 | Procter & Gamble | Präparate zur reinigung und konditionierung von haut and haaren mit verbesserter ablagerung von konditionierenden bestandteilen |
ATE226064T1 (de) * | 1997-09-12 | 2002-11-15 | Procter & Gamble | Hautreinigungs- und konditionierungsartikel für haut und haar |
US6251808B1 (en) * | 1997-10-22 | 2001-06-26 | Illinois Tool Works, Inc. | Metal and fiberglass cleaning and polishing article |
US5962001A (en) * | 1997-11-03 | 1999-10-05 | Illinois Tool Works, Inc. | Disinfecting and sanitizing article |
US6548085B1 (en) | 1998-04-15 | 2003-04-15 | Woodstream Corporation | Insecticidal compositions and method of controlling insect pests using same |
US6136775A (en) * | 1998-12-18 | 2000-10-24 | Kimberly-Clark Worldwide, Inc. | Wet wipe with non-aqueous, oil-based solvent for industrial cleaning |
FR2791880B1 (fr) | 1999-04-09 | 2001-06-22 | Prodene Klint Lab | Article de nettoyage utilise hors proximite d'un point d'eau |
AU5016300A (en) * | 1999-05-17 | 2000-12-05 | Uri Fraiman | Self wetting towels |
US6641591B1 (en) | 1999-08-26 | 2003-11-04 | John H. Shadduck | Instruments and techniques for controlled removal of epidermal layers |
DE10005454B4 (de) * | 2000-02-08 | 2005-08-18 | Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg | Einlagiges, beidseitig abrasives Vlies und Verfahren zu dessen Herstellung |
AU7016101A (en) | 2000-06-26 | 2002-01-08 | Playtex Products Inc | Wipe with improved cleansing |
US6794351B2 (en) | 2001-04-06 | 2004-09-21 | Kimberly-Clark Worldwide, Inc. | Multi-purpose cleaning articles |
US6737068B2 (en) | 2001-10-01 | 2004-05-18 | Playtex Products, Inc. | Wipe formulation |
US6884763B2 (en) | 2001-10-30 | 2005-04-26 | Permatex, Inc. | Waterless hand cleaner containing plant derived natural essential oil |
US20030194937A1 (en) * | 2002-04-10 | 2003-10-16 | Yarron Bendor | Composite abrasive articles and a method for making same |
US7115551B2 (en) | 2002-06-07 | 2006-10-03 | The Procter & Gamble Company | Cleansing articles for skin or hair |
US7829478B2 (en) * | 2002-06-11 | 2010-11-09 | 3M Innovative Properties Company | Consumer scrubbing wipe article and method of making same |
US6906014B2 (en) * | 2002-09-10 | 2005-06-14 | Permatex, Inc. | Stabilized topical composition |
US20050148262A1 (en) * | 2003-12-30 | 2005-07-07 | Varona Eugenio G. | Wet wipe with low liquid add-on |
US20050148264A1 (en) * | 2003-12-30 | 2005-07-07 | Varona Eugenio G. | Bimodal pore size nonwoven web and wiper |
ATE438330T1 (de) * | 2005-02-07 | 2009-08-15 | Procter & Gamble | Scheuertuch zur behandlung einer fläche |
US20070049153A1 (en) * | 2005-08-31 | 2007-03-01 | Dunbar Charlene H | Textured wiper material with multi-modal pore size distribution |
US8258066B2 (en) * | 2005-12-12 | 2012-09-04 | Milliken & Company | Cleaning device |
US8048089B2 (en) | 2005-12-30 | 2011-11-01 | Edge Systems Corporation | Apparatus and methods for treating the skin |
US10172644B2 (en) | 2006-03-29 | 2019-01-08 | Edge Systems Llc | Devices, systems and methods for treating the skin |
US9566088B2 (en) | 2006-03-29 | 2017-02-14 | Edge Systems Llc | Devices, systems and methods for treating the skin |
CA2648564A1 (en) * | 2006-04-20 | 2007-11-01 | The Dial Corporation | Delivery system for a hygienic agent |
US8343908B2 (en) * | 2007-07-12 | 2013-01-01 | Kimberly-Clark Worldwide, Inc. | Foaming hand sponge with color change indicator |
US8440606B2 (en) * | 2007-07-12 | 2013-05-14 | Kimberly-Clark Worldwide, Inc. | Foaming hand sponge for bodily cleansing with color change indicator |
EP2240099B1 (en) | 2008-01-04 | 2018-02-21 | Edge Systems LLC | Apparatus for treating the skin |
WO2009097451A1 (en) | 2008-01-29 | 2009-08-06 | Edge Systems Corporation | Apparatus and method for treating the skin |
US8110608B2 (en) * | 2008-06-05 | 2012-02-07 | Ecolab Usa Inc. | Solid form sodium lauryl sulfate (SLS) pesticide composition |
EP2451367B1 (en) | 2009-07-08 | 2020-01-22 | Edge Systems Corporation | Devices for treating the skin using time-release substances |
US8968757B2 (en) | 2010-10-12 | 2015-03-03 | Ecolab Usa Inc. | Highly wettable, water dispersible, granules including two pesticides |
CA2832451A1 (en) | 2011-04-04 | 2012-10-11 | The Procter & Gamble Company | Home care article |
WO2013025764A1 (en) | 2011-08-15 | 2013-02-21 | The Procter & Gamble Company | Personal care articles having multi-zone compliant personal care compositions |
US8795695B2 (en) | 2011-08-15 | 2014-08-05 | The Procter & Gamble Company | Personal care methods |
US8809255B2 (en) | 2012-01-12 | 2014-08-19 | Illinois Tool Works, Inc. | Low voc content waterless cleaner and article impregnated therewith |
US10238812B2 (en) | 2013-03-15 | 2019-03-26 | Edge Systems Llc | Skin treatment systems and methods using needles |
EP2967633B1 (en) | 2013-03-15 | 2018-04-25 | Edge Systems LLC | Devices for treating the skin |
MX354696B (es) | 2013-06-27 | 2018-03-15 | Procter & Gamble | Articulos para el cuidado personal. |
EP3237055B1 (en) | 2014-12-23 | 2020-08-12 | Edge Systems LLC | Devices and methods for treating the skin using a rollerball or a wicking member |
US10179229B2 (en) | 2014-12-23 | 2019-01-15 | Edge Systems Llc | Devices and methods for treating the skin using a porous member |
US10507566B2 (en) | 2015-03-18 | 2019-12-17 | The Clorox Company | Process for manufacturing scrubby substrates and substrates made therefrom |
KR102628349B1 (ko) | 2015-07-08 | 2024-01-24 | 하이드라페이셜 엘엘씨 | 모발 성장을 촉진하기 위한 디바이스, 시스템 및 방법 |
US10058488B2 (en) * | 2015-10-14 | 2018-08-28 | Illinois Tool Works Inc. | Skin cleansing article impregnated with a low VOC cleaner comprising a 9-decanoic acid methyl ester |
USD1016615S1 (en) | 2021-09-10 | 2024-03-05 | Hydrafacial Llc | Container for a skin treatment device |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0068722A2 (en) * | 1981-06-18 | 1983-01-05 | Unilever Plc | Article suitable for wiping surfaces |
EP0256950A1 (en) * | 1986-08-15 | 1988-02-24 | Kimberly-Clark Corporation | Uniformly moist wipes |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3277013A (en) * | 1963-10-03 | 1966-10-04 | G H Packwood Mfg Company | Waterless skin cleaner and process for producing the same |
GB842866A (en) * | 1955-06-20 | 1960-07-27 | G H Packwood Mfg Company | Waterless-in-use skin cleaner and process for producing the same |
US3619251A (en) * | 1969-05-22 | 1971-11-09 | Norman S Stiles Sr | Cleaning and polishing cloth and method of making it |
USRE31885E (en) * | 1977-10-17 | 1985-05-14 | Kimberly-Clark Corporation | Microfiber oil and water wipe |
US4448704A (en) * | 1981-05-29 | 1984-05-15 | Lever Brothers Company | Article suitable for wiping hard surfaces |
US4336151A (en) * | 1981-07-06 | 1982-06-22 | American Cyanamid Company | Disinfectant/cleanser compositions exhibiting reduced eye irritancy potential |
US4665580A (en) * | 1983-11-09 | 1987-05-19 | Mobil Oil Corporation | Scrubbing pad |
GB2179052B (en) * | 1985-08-14 | 1989-03-30 | Procter & Gamble | Nonfoaming cleansing mousse with skin conditioning benefits |
US4666621A (en) * | 1986-04-02 | 1987-05-19 | Sterling Drug Inc. | Pre-moistened, streak-free, lint-free hard surface wiping article |
US4784786A (en) * | 1986-04-16 | 1988-11-15 | Creative Product Resource Associates, Ltd. | Glass cleaning composition containing an EMA resin and a poly(acrylamidomethylpropane) sulfonic acid to reduce friction and streaking |
US4833003A (en) * | 1986-08-15 | 1989-05-23 | Kimberly-Clark Corporation | Uniformly moist abrasive wipes |
US4853281A (en) * | 1986-08-15 | 1989-08-01 | Kimberly-Clark Corporation | Uniformly moist wipes |
US4753844A (en) * | 1986-12-04 | 1988-06-28 | Airwick Industries Inc. | Disposable semi-moist wipes |
US4808328A (en) * | 1987-05-08 | 1989-02-28 | Joseph N. Cooper | Iodine-based antiseptic cleanser composition |
US4927556A (en) * | 1987-06-04 | 1990-05-22 | Minnesota Mining And Manufacturing Company | Aqueous based composition containing dibasic ester and thickening agent for removing coatings |
US5141803A (en) * | 1988-06-29 | 1992-08-25 | Sterling Drug, Inc. | Nonwoven wipe impregnating composition |
US4931201A (en) * | 1988-09-02 | 1990-06-05 | Colgate-Palmolive Company | Wiping cloth for cleaning non-abrasive surfaces |
US5094770A (en) * | 1988-11-15 | 1992-03-10 | Nordico, Inc. | Method of preparing a substantially dry cleaning wipe |
US5234719A (en) * | 1991-06-04 | 1993-08-10 | Ecolab Inc. | Food additive sanitizing compositions |
GB2267680A (en) * | 1992-06-02 | 1993-12-15 | Kimberly Clark Ltd | Absorbent,abrasive composite non-woven web |
-
1994
- 1994-02-25 TW TW083101636A patent/TW311085B/zh active
- 1994-03-08 CA CA002117243A patent/CA2117243C/en not_active Expired - Lifetime
- 1994-03-11 KR KR1019940004753A patent/KR100309307B1/ko not_active IP Right Cessation
- 1994-03-14 DK DK94301802T patent/DK0615720T3/da active
- 1994-03-14 EP EP94301802A patent/EP0615720B1/en not_active Revoked
- 1994-03-14 DE DE69420441T patent/DE69420441T2/de not_active Revoked
- 1994-03-14 ES ES94301802T patent/ES2136162T3/es not_active Expired - Lifetime
- 1994-03-14 AT AT94301802T patent/ATE184171T1/de not_active IP Right Cessation
- 1994-03-16 IL IL109002A patent/IL109002A/en not_active IP Right Cessation
- 1994-03-17 CN CN94102913A patent/CN1075944C/zh not_active Expired - Fee Related
- 1994-03-17 AU AU57855/94A patent/AU674919B2/en not_active Expired
- 1994-03-18 JP JP6048072A patent/JPH0753352A/ja active Pending
-
1995
- 1995-03-15 US US08405374 patent/US5683971B1/en not_active Expired - Lifetime
-
1999
- 1999-10-22 GR GR990402707T patent/GR3031609T3/el unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0068722A2 (en) * | 1981-06-18 | 1983-01-05 | Unilever Plc | Article suitable for wiping surfaces |
EP0256950A1 (en) * | 1986-08-15 | 1988-02-24 | Kimberly-Clark Corporation | Uniformly moist wipes |
Also Published As
Publication number | Publication date |
---|---|
KR940020996A (ko) | 1994-10-17 |
DK0615720T3 (da) | 2000-03-20 |
US5683971A (en) | 1997-11-04 |
DE69420441T2 (de) | 2000-01-27 |
CA2117243C (en) | 2002-05-14 |
DE69420441D1 (de) | 1999-10-14 |
TW311085B (zh) | 1997-07-21 |
IL109002A0 (en) | 1994-06-24 |
JPH0753352A (ja) | 1995-02-28 |
ATE184171T1 (de) | 1999-09-15 |
US5683971B1 (en) | 2000-10-24 |
CN1097300A (zh) | 1995-01-18 |
CA2117243A1 (en) | 1994-09-19 |
IL109002A (en) | 1998-02-08 |
KR100309307B1 (ko) | 2001-12-15 |
ES2136162T3 (es) | 1999-11-16 |
AU5785594A (en) | 1994-09-22 |
EP0615720A1 (en) | 1994-09-21 |
AU674919B2 (en) | 1997-01-16 |
GR3031609T3 (en) | 2000-01-31 |
EP0615720B1 (en) | 1999-09-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1075944C (zh) | 掺有无水擦洗手的清洁剂的清洁制品及其制备方法 | |
KR100312371B1 (ko) | 경질 표면에 사용하기 위한 연마 도포구에서의 페인트 및 얼룩제거제 | |
US3297456A (en) | Surface coating and preserving composition | |
KR100323202B1 (ko) | 금속과유리섬유를클리닝하고광택을내는물품 | |
KR100341815B1 (ko) | 연마성 도포구 형태인 다목적 클리너 겸용 광택제 물품과 그 제조방법 | |
JP5295563B2 (ja) | クリーニング組成物 | |
JP4627559B2 (ja) | 洗浄用組成物 | |
JP2001139992A (ja) | 清浄剤 | |
CS276172B6 (cs) | Mycí prostředek na silně znečištěnou pokožku se zdravotně nezávadnou rozpouštěcí složkou | |
KR19980045930A (ko) | 다용도 세정제 조성물 | |
TH42259A3 (th) | สารผสมซักฟอกที่ประกอบรวมด้วยสารแขวนลอยรอยเปื้อนสำหรับใช้กับแผ่นดูดซึมที่ใช้แล้วทิ้งได้ | |
JPS58206695A (ja) | 重質汚れ用ペースト状洗剤 | |
TH42265A3 (th) | สิ่งที่ใช้เช็ดถูเปียกกับตัวทำละลายน้ำมันไม่ใช่น้ำสำหรับทำความสะอาดทางอุตสาหกรรม |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |