CN107587942A - A kind of light decomposes CO2The technology of afterburning dynamical system - Google Patents
A kind of light decomposes CO2The technology of afterburning dynamical system Download PDFInfo
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- CN107587942A CN107587942A CN201610533032.7A CN201610533032A CN107587942A CN 107587942 A CN107587942 A CN 107587942A CN 201610533032 A CN201610533032 A CN 201610533032A CN 107587942 A CN107587942 A CN 107587942A
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- 238000005183 dynamical system Methods 0.000 title claims abstract description 18
- 238000005516 engineering process Methods 0.000 title abstract description 7
- 239000007789 gas Substances 0.000 claims abstract description 31
- 239000012528 membrane Substances 0.000 claims abstract description 23
- 238000000926 separation method Methods 0.000 claims abstract description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003546 flue gas Substances 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000567 combustion gas Substances 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 11
- 238000002485 combustion reaction Methods 0.000 claims description 11
- 230000005611 electricity Effects 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910000859 α-Fe Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052596 spinel Inorganic materials 0.000 claims description 2
- 239000011029 spinel Substances 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims 3
- 238000007906 compression Methods 0.000 claims 3
- 239000000047 product Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 239000013589 supplement Substances 0.000 claims 1
- 239000002918 waste heat Substances 0.000 abstract description 2
- 238000003860 storage Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910016516 CuFe2O4 Inorganic materials 0.000 description 1
- -1 M=Ni Chemical class 0.000 description 1
- 229910000708 MFe2O4 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
A kind of light decomposes CO2The technology of afterburning dynamical system, CO is mainly decomposed by dynamical system and light2System forms.Dynamical system：The present invention is transformed conventional gas turbine, and combustion gas becomes flue gas after being done work in gas turbine, using the waste heat of the flue gas respectively to water and CO2Heated, UF membrane is carried out to flue gas again after heating, obtains CO2、O2With residual gas (mainly N2), the CO isolated2By the flue gas in regenerator, O2Send back to after compressor is compressed and participate in second-time burning, N2Collected as product.Light decomposes CO2System：By the water of flue gas and isolate CO2Mixed, be then heated in groove type solar and be decomposed into O2And hydrocarbon, then enter membrane separation device together and separate, the CO isolated2It is again introduced into trough type solar heat-collector and is decomposed, O2Send back to and burning is participated in compressor compresses, hydrocarbon is sent into gas turbine and carries out afterburning.It is contemplated that expanding the purposes of solar energy, almost CO again is realized while energy rationally utilizes2Zero-emission, and possess stronger expansion, every profession and trade can be widely used in.
Description
Technical field
The present invention relates to a kind of light to decompose CO2Afterburning dynamical system, belongs to technical field of solar.
Background technology
Problem of environmental pollution became increasingly conspicuous in the last few years, and atmosphere pollution is even more urgently to be resolved hurrily, such as：Gas turbine is a kind of
Gas continuously to flow needs to suck substantial amounts of fresh air at work, and arrange as the rotary power machinery of working medium
Substantial amounts of waste gas is released, endangers environment；At the same time, the burning of a large amount of fossil energies it is also proposed sternness to global energy and examine
Test, so research and development innovation and CO of each field by the utilization of new energy, new equipment2Energy-saving and emission-reduction as research weight
Point.Solar energy is as a kind of clean reproducible energy, to reducing fossil energy use and CO2Important in inhibiting is discharged, simultaneously
CO2Decomposition, using being also to realize CO2The new direction of emission reduction.
Light decomposes CO2Core be to utilize solar energy heating CO2And water vapour, pass through catalyst under illumination condition
Ni0.49Cu024Zn0.24Fe2O4Convert it into O2And hydrocarbon.
CO is separated at normal temperatures with hollow fiber membrane device2、O2、N2Technology it is very ripe.
The content of the invention
It is an object of the invention to propose that a kind of light decomposes CO2The technology of afterburning dynamical system, the system can be by CO2Make
For energy storage working medium, the storage to solar energy is realized, is utilization, the CO of solar energy2Enlargement provide new approaches.
To achieve the above object, the present invention, which adopts the following technical scheme that, is achieved：
A kind of light decomposes CO2The technology of afterburning dynamical system, CO is mainly decomposed by dynamical system and light2System forms.Power
System：The present invention is transformed conventional gas turbine, and combustion gas becomes flue gas after being done work in gas turbine, utilizes the flue gas
Waste heat is respectively to water and CO2Heating, UF membrane then is being carried out to flue gas again, is obtaining CO2、O2With residual gas (mainly N2),
The CO isolated2By the flue gas in regenerator, O2Send back to after compressor is compressed and participate in second-time burning, N2As product
Collect.Light decomposes CO2System：By the water of flue gas and isolate CO2Mixed, be then heated in groove type solar
It is decomposed into O2And hydrocarbon, then enter membrane separation device together and separate, the CO isolated2It is again introduced into groove type solar
Decomposed in heat collector, O2Send back to and burning is participated in compressor compresses, hydrocarbon is sent into gas turbine and carries out afterburning.
It is contemplated that utilize CO2Solar energy is stored, generating of avoiding the peak hour is realized, both rationally make use of solar energy, reduce carbon emission again.
Dynamical system forms：Compressor (1), combustion chamber (2), gas turbine (3), air accumulator A (4), generator (5), return
Hot device A (6), regenerator B (7), membrane separation device A (8) composition.Air and O2Compressed in compressor (1), into combustion chamber
(2) generator (5) is driven to generate electricity with the simultaneously expansion work that burnt after combustion gas mixing in gas turbine (3), flue gas caused by burning
It is divided into two strands, one enters regenerator A (6) heating CO2, another strand enters regenerator B (7) and water is heated to be into vapor, passes through
Flue gas after regenerator A, B separates in membrane separation device A (8), isolates CO2、O2With residual gas (mainly N2), CO2
It is sent to light and decomposes CO2System is decomposed, and excess enthalpy section store is in air accumulator A (4), O2Two are participated in after sending compressor compresses back to
Secondary burning, N2It is collected as product.
Light decomposes CO2System forms：Groove type solar (9), membrane separation device B (10), air accumulator B (11).The slot type sun
The vacuum inside pipe wall attached catalyst Ni of energy (9)0.49Cu0.24Zn0.24Fe2O4, CO2Mixed gas with water vapour is in vacuum tube
It is broken down into O2And hydrocarbon, then pass through membrane separation device B (10) isolated CO2、O2And hydrocarbon, CO2Return
The entrance of groove type solar (9) participates in reaction, O again2Send back to and participate in burning after compressor compresses again, hydrocarbon is storing up
Combustion chamber (2), which is transported to, after gas tank B (11) storages carries out afterburning.
In above-mentioned dynamical system, using regenerator (6) to CO2Heated, smoke evacuation temperature is reduced while controlling its temperature
Degree；The softened water filled into using regenerator (7) to the external world is heated, and exhaust gas temperature is reduced while controlling its temperature.
Advantages of the present invention：
1st, realize and pass through CO2Solar energy is stored, converted.
2nd, the system will decompose CO2Part and vacuum tube be combined together, so as to will not destroy vacuum tube structure and
The course of work.
3rd, light decomposes CO2System selects spinel ferrite MFe2O4(transition metal such as M=Ni, Cu, Zn) makees catalyst,
CO is decomposed with preferable2Activity, wherein CuFe2O4Reduction temperature it is minimum, but structure is easily caved in, and Zn Fe2O4Structure
It is the most stable, its reduction temperature highest, Ni Fe2O4Therebetween, and four metal ferrites have more preferable degrading activity,
So selection Ni0.49Cu0.24Zn0.24Fe2O4As final catalyst.
4th, catalyst n i0.49Cu0.24Zn0.24Fe2O4Particle is attached to the vacuum inside pipe wall of groove type solar (9), catalyst
Not appreciably affect the heat absorption of vacuum tube.
5th, the system uses twin-stage regenerator, heats CO respectively2With the good control of water and realization to its temperature.
6th, the system is realized to CO2Recycle.
7th, system remains to work on during no illumination, equivalent in general gas electricity generator, strong adaptability.
8th, the system expansibility is strong, can be widely applied to the fields such as industry, business.
Brief description of the drawings
Fig. 1 is present system figure.
Fig. 2 is groove type solar sketch of the present invention.
Description of symbols in accompanying drawing：1- compressors；2- combustion chambers；3- combustion gas wheels；4- air accumulators A；5- generators；6- regenerators
A；7- regenerators B；8- membrane separation devices A；9- groove type solars；10- membrane separation devices B；11- air accumulators B.
Embodiment
Dynamical system and light are decomposed CO by the present invention2System combines, and realizes the purpose of the present invention, that is, uses up decomposition
Obtained CO2Carry out afterburning generating and for manufacturing hydrocarbon.
Dynamical system forms：Compressor (1), combustion chamber (2), gas turbine (3), air accumulator A (4), generator (5), return
Hot device A (6), regenerator B (7), membrane separation device A (8).Air and O2 enter after being compressed in compressor (1) combustion chamber (2) with
Combustion gas mixing, burning and expansion work drive generator (5) generating in gas turbine (3) afterwards, and caused flue gas is divided into two
Stock, one enters regenerator A (6) heating CO2, another strand enters regenerator B (7) heating water so that it becomes vapor, by returning
Flue gas after hot device A, B is separated into CO in membrane separation device A (8)2、O2With residual gas (mainly N2), CO2It is sent to light
Decompose CO2System is decomposed or is stored in air accumulator A (4), O2Send back to and participate in burning, N after compressor compresses again2As
Product is collected.
Light decomposes CO2System forms：Groove type solar (9), membrane separation device B (10), air accumulator B (11).The slot type sun
The vacuum inside pipe wall attached catalyst Ni of energy (9)0.49Cu0.24Zn0.24Fe2O4, CO2Mixed gas with water vapour is in vacuum tube
It is broken down into O2And hydrocarbon, then pass through membrane separation device B (10) isolated CO2、O2And hydrocarbon, CO2Return
The entrance of groove type solar (9) participates in reaction, O again2Send back to and participate in burning after compressor compresses again, hydrocarbon is storing up
Combustion chamber (2), which is transported to, after gas tank B (11) storages carries out afterburning.
Further, the no light time decomposes CO2System stalls, the present invention just continue equivalent to general gas turbine
Generated electricity.
Further, CO during no light2It is stored in air accumulator A (4).
CO2Light absorbing radiation when flowing through vacuum tube (1), a portion CO2In Ni0.49Cu0.24Zn0.24Fe2O4Surface
Decompose.
Flue gas is separated CO by membrane separation device A (8)2、O2With residual gas (mainly N2).
Gas after light decomposes is separated CO in membrane separation device B (10)2、O2With residual gas (mainly hydrocarbonization
Compound).
Claims (4)
1. a kind of light decomposes CO2Afterburning dynamical system, it is characterised in that：CO is decomposed by dynamical system and light2System forms；
Described dynamical system is by compressor (1), combustion chamber (2), gas turbine (3), air accumulator A (4), generator (5), backheat
Device A (6), regenerator B (7), membrane separation device A (8) compositions.Air and O2Compressed in compressor (1), into combustion chamber (2)
Simultaneously expansion work drives generator (5) to generate electricity with being burnt after combustion gas mixing in gas turbine (3), and flue gas caused by burning is divided into
Two strands, one enters regenerator A (6) heating CO2, another strand enters regenerator B (7) and water is heated to be into vapor, by backheat
Flue gas after device A, B separates in membrane separation device A (8), isolates CO2、O2With residual gas (mainly N2), CO2It is sent to light
Decompose CO2System is decomposed, and remainder is stored in air accumulator A (4), O2Second-time burning is participated in after sending compressor compresses back to,
N2It is collected as product；Described light decomposes CO2System is by groove type solar (9), membrane separation device B (10), air accumulator B
(11) form, the vacuum inside pipe wall attached catalyst Ni of groove type solar (9)0.49Cu0.24Zn0.24Fe2O4, CO2With water vapour
Mixed gas is broken down into O in vacuum tube in the presence of catalyst2And hydrocarbon, then pass through membrane separation device B
(10) CO is isolated2、O2And hydrocarbon, CO2The entrance for returning to groove type solar (9) continues to participate in reaction, O2Send compression back to
Burning is participated in after machine compression again, hydrocarbon is transported in combustion chamber (2) after being stored in air accumulator B (11) and mended
Combustion.
2. light according to claim 1 decomposes CO2System, it is characterised in that：From spinel ferrite
Ni0.49Cu0.24Zn0.24Fe2O4Catalyst is made, and catalyst granules is attached to the vacuum inside pipe wall of groove type solar (9).
3. a kind of light according to claim 1 decomposes CO2Afterburning dynamical system, it is characterised in that：Membrane separation device A (8) is produced
Raw CO2CO is decomposed as light2The reactant of system, product O2, gas turbine is returned after compression, as oxygen-enriched combusting
Fuel.
4. according to the dynamical system described in claims 1, it is characterised in that：The CO2 that membrane separation device A (8) is isolated passes through
Regenerator (6) is heated, to realize the control to its temperature；The softened water of external world's supplement is heated into water by heater (7)
Steam, and realize the control to its temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610533032.7A CN107587942A (en) | 2016-07-08 | 2016-07-08 | A kind of light decomposes CO2The technology of afterburning dynamical system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610533032.7A CN107587942A (en) | 2016-07-08 | 2016-07-08 | A kind of light decomposes CO2The technology of afterburning dynamical system |
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| Publication Number | Publication Date |
|---|---|
| CN107587942A true CN107587942A (en) | 2018-01-16 |
Family
ID=61046477
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| CN201610533032.7A Pending CN107587942A (en) | 2016-07-08 | 2016-07-08 | A kind of light decomposes CO2The technology of afterburning dynamical system |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112619349A (en) * | 2020-11-30 | 2021-04-09 | 西安西热控制技术有限公司 | Carbon emission reduction system of thermal power plant |
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| 邱丽霞;郝艳红;: "一种耦合燃气轮机的富氧燃烧***技术经济性能分析" * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112619349A (en) * | 2020-11-30 | 2021-04-09 | 西安西热控制技术有限公司 | Carbon emission reduction system of thermal power plant |
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