CN107586476A - A kind of extra long life ocean engineering anticorrosive paint - Google Patents
A kind of extra long life ocean engineering anticorrosive paint Download PDFInfo
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- CN107586476A CN107586476A CN201710961385.1A CN201710961385A CN107586476A CN 107586476 A CN107586476 A CN 107586476A CN 201710961385 A CN201710961385 A CN 201710961385A CN 107586476 A CN107586476 A CN 107586476A
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- anticorrosive paint
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Abstract
The invention discloses a kind of extra long life extra long life ocean engineering anticorrosive paint, its raw material includes by weight：90 parts of styrene monomer, 20 40 parts of methyl methacrylate, 10 35 parts of trimethylolpropane allyl ether, tertiary 15 25 parts of vinegar milk liquid, 12 18 parts of phenyl glycidyl ether, 15 22 parts of 2-Butoxyethyl acetate, 18 25 parts of Lauxite, 15 22 parts of expanded perlite, 7 10 parts of micaceous iron oxide, 2 10 parts of diatomite, 13 22 parts of nano zine oxide, 25 parts of chitosan, 1.2 4.5 parts of phenyltrimethoxysila,e, 1 2.5 parts of polyphenyl methyl siloxane, 0.2 1 parts of tricresyl phosphate, 0.5 2 parts of polyvinyl alcohol, 25 parts of erbium oxide, 12 26 parts of solvent, 0.6 2.5 parts of wetting agent, 0.3 1 parts of dispersant.Extra long life ocean engineering anticorrosive paint proposed by the present invention, its corrosion resistance is strong, and adhesion strength is high, service life length.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of extra long life ocean engineering anticorrosive paint.
Background technology
Heavy-duty Coatings In Ocean Chemical Industry refers to the anticorrosive coating used in marine environment, and it typically requires good physics
Performance, mechanical property, resistance to cathodic disbonding performance, and good workability is required, can be right under various environmental conditions
Different structure carries out high quality coating decoration.Its performance of the Heavy-duty Coatings In Ocean Chemical Industry in China still suffers from many defects, such as using
Short life, Corrosion Protection difference etc., it is impossible to meet the needs of society.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of extra long life ocean work proposed
Journey anticorrosive paint, its corrosion resistance is strong, and adhesion strength is high, service life length.
To achieve these goals, present invention employs following technical scheme：
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：90 parts of styrene monomer, methyl
Methyl acrylate 20-40 parts, trimethylolpropane allyl ether 10-35 parts, tertiary vinegar milk liquid 15-25 parts, phenyl glycidyl
Ether 12-18 parts, 2-Butoxyethyl acetate 15-22 parts, Lauxite 18-25 parts, expanded perlite 15-22 parts, mica oxidation
Iron 7-10 parts, diatomite 2-10 parts, nano zine oxide 13-22 parts, chitosan 2-5 parts, phenyltrimethoxysila,e 1.2-4.5
It is part, polyphenyl methyl siloxane 1-2.5 parts, tricresyl phosphate 0.2-1 parts, polyvinyl alcohol 0.5-2 parts, erbium oxide 2-5 parts, molten
Agent 12-26 parts, wetting agent 0.6-2.5 parts, dispersant 0.3-1 parts.
Preferably, styrene monomer, methyl methacrylate, trimethylolpropane allyl ether, tertiary vinegar milk liquid.
Preferably, expanded perlite, micaceous iron oxide, diatomite, nano zine oxide.
Preferably, its raw material includes by weight：90 parts of styrene monomer, 38 parts of methyl methacrylate, trihydroxy methyl
22 parts of propane diallyl ether, 12 parts of tertiary vinegar milk liquid, 6 parts of phenyl glycidyl ether, 10 parts of 2-Butoxyethyl acetate, ureaformaldehyde tree
12 parts of fat, 10 parts of expanded perlite, 8.5 parts of micaceous iron oxide, 6 parts of diatomite, 10 parts of nano zine oxide, 3.5 parts of chitosan, benzene
2 parts of base trimethoxy silane, 1.3 parts of polyphenyl methyl siloxane, 0.6 part of tricresyl phosphate, 1 part of polyvinyl alcohol, erbium oxide
3.5 parts, 20 parts of solvent, 1 part of wetting agent, 0.5 part of dispersant.
Preferably, the particle diameter of the nano zine oxide is 20-40nm.
In the present invention, with styrene monomer, methyl methacrylate, trimethylolpropane allyl ether, tertiary vinegar milk liquid
Cooperation is used as film forming matter, and with the addition of phenyl glycidyl ether as diluent, by adjusting its ratio, makes the phase of each raw material
Capacitive is good, and performance collaboration promotes, so as to get film there is strong impact resistance and char forming ability, good corrosion resistance and heat endurance
The characteristics of excellent, it is high with the adhesion strength of matrix, improves the decay resistance of coating；Expanded perlite, micaceous iron oxide,
Diatomite, nano zine oxide coordinate in addition system, improve coating strength and corrosion resistance；Phenyltrimethoxysila,e, gather
In phenyl methyl siloxane addition system, expanded perlite, micaceous iron oxide, diatomite and body are improved after coordinating with chitosan
The contact area of system, it is suppressed that diffusion of the seawater in styrene monomer coating, increase the resistance of epoxy coating, further carry
The high Corrosion Protection of coating.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：90 parts of styrene monomer, methyl
30 parts of methyl acrylate, 30 parts of trimethylolpropane allyl ether, 5 parts of tertiary vinegar milk liquid, 8 parts of phenyl glycidyl ether, second two
It is 5 parts of alcohol monobutyl ether acetate, 15 parts of Lauxite, 5 parts of expanded perlite, 10 parts of micaceous iron oxide, 2 parts of diatomite, nano oxidized
It is 12 parts of zinc, 2 parts of chitosan, 2.5 parts of phenyltrimethoxysila,e, 1 part of polyphenyl methyl siloxane, 1 part of tricresyl phosphate, poly-
2 parts of vinyl alcohol, 5 parts of erbium oxide, 10 parts of solvent, 1.5 parts of wetting agent, 0.2 part of dispersant.
Embodiment 2
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：90 parts of styrene monomer, methyl
50 parts of methyl acrylate, 10 parts of trimethylolpropane allyl ether, 15 parts of tertiary vinegar milk liquid, 2 parts of phenyl glycidyl ether, second two
It is 12 parts of alcohol monobutyl ether acetate, 8 parts of Lauxite, 12 parts of expanded perlite, 7 parts of micaceous iron oxide, 10 parts of diatomite, nano oxidized
3 parts of zinc, 5 parts of chitosan, 1 part of phenyltrimethoxysila,e, 2.5 parts of polyphenyl methyl siloxane, 0.2 part of tricresyl phosphate,
0.5 part of polyvinyl alcohol, 2 parts of erbium oxide, 25 parts of solvent, 0.5 part of wetting agent, 1 part of dispersant.
Embodiment 3
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：30 parts of styrene monomer, bis-phenol
50 parts of F types styrene monomer, 20 parts of hydrogenated styrene monomer, 43 parts of methyl methacrylate, trimethylolpropane allyl
17 parts of ether, 12 parts of tertiary vinegar milk liquid, 5 parts of phenyl glycidyl ether, 10 parts of 2-Butoxyethyl acetate, 11 parts of Lauxite, expansion
10 parts of perlite, 8.5 parts of micaceous iron oxide, 8 parts of diatomite, 7 parts of nano zine oxide, 4.6 parts of chitosan, phenyl trimethoxy silicon
1.8 parts of alkane, 1.9 parts of polyphenyl methyl siloxane, 0.5 part of tricresyl phosphate, 1.7 parts of polyvinyl alcohol, 3 parts of erbium oxide, solvent
21 parts, 0.9 part of wetting agent, 0.9 part of dispersant；Wherein, the epoxide number of the styrene monomer is 0.55.
Embodiment 4
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：30 parts of styrene monomer, hydrogenation
70 parts of styrene monomer, 38 parts of methyl methacrylate, 26 parts of trimethylolpropane allyl ether, 8 parts of tertiary vinegar milk liquid, phenyl
7 parts of glycidol ether, 8 parts of 2-Butoxyethyl acetate, 9 parts of Lauxite, 7 parts of expanded perlite, 9 parts of micaceous iron oxide, silicon
6 parts of diatomaceous earth, 11 parts of nano zine oxide, 3 parts of chitosan, 2.1 parts of phenyltrimethoxysila,e, 2.3 parts of polyphenyl methyl siloxane,
0.8 part of tricresyl phosphate, 1 part of polyvinyl alcohol, 4 parts of erbium oxide, 17 parts of solvent, 1.3 parts of wetting agent, 0.6 part of dispersant；Its
In, the epoxide number of the styrene monomer is 0.3.
Embodiment 5
A kind of extra long life ocean engineering anticorrosive paint, its raw material include by weight：90 parts of styrene monomer, methyl
38 parts of methyl acrylate, 22 parts of trimethylolpropane allyl ether, 12 parts of tertiary vinegar milk liquid, 6 parts of phenyl glycidyl ether, second two
10 parts of alcohol monobutyl ether acetate, 12 parts of Lauxite, 10 parts of expanded perlite, 8.5 parts of micaceous iron oxide, 6 parts of diatomite, nano oxygen
Change 10 parts of zinc, 3.5 parts of chitosan, 2 parts of phenyltrimethoxysila,e, 1.3 parts of polyphenyl methyl siloxane, tricresyl phosphate
0.6 part, 1 part of polyvinyl alcohol, 3.5 parts of erbium oxide, 20 parts of solvent, 1 part of wetting agent, 0.5 part of dispersant；
Wherein, the epoxide number of the styrene monomer is 0.5；
The particle diameter of the nano zine oxide is 20-40nm.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of extra long life ocean engineering anticorrosive paint, it is characterised in that its raw material includes by weight：Styrene monomer
90 parts, methyl methacrylate 20-40 parts, trimethylolpropane allyl ether 10-35 parts, tertiary vinegar milk liquid 15-25 parts, phenyl
Glycidol ether 12-18 parts, 2-Butoxyethyl acetate 15-22 parts, Lauxite 18-25 parts, expanded perlite 15-22 parts,
Micaceous iron oxide 7-10 parts, diatomite 2-10 parts, nano zine oxide 13-22 parts, chitosan 2-5 parts, phenyltrimethoxysila,e
1.2-4.5 parts, polyphenyl methyl siloxane 1-2.5 parts, tricresyl phosphate 0.2-1 parts, polyvinyl alcohol 0.5-2 parts, erbium oxide
2-5 parts, solvent 12-26 parts, wetting agent 0.6-2.5 parts, dispersant 0.3-1 parts.
2. extra long life ocean engineering anticorrosive paint according to claim 1, it is characterised in that styrene monomer, methyl
Methyl acrylate, trimethylolpropane allyl ether, tertiary vinegar milk liquid.
3. extra long life ocean engineering anticorrosive paint according to claim 1, it is characterised in that expanded perlite, mica
Iron oxide, diatomite, nano zine oxide.
4. extra long life ocean engineering anticorrosive paint according to claim 1, it is characterised in that its raw material wraps by weight
Include：90 parts of styrene monomer, 38 parts of methyl methacrylate, 22 parts of trimethylolpropane allyl ether, 12 parts of tertiary vinegar milk liquid,
6 parts of phenyl glycidyl ether, 10 parts of 2-Butoxyethyl acetate, 12 parts of Lauxite, 10 parts of expanded perlite, micaceous iron oxide
8.5 parts, 6 parts of diatomite, 10 parts of nano zine oxide, 3.5 parts of chitosan, 2 parts of phenyltrimethoxysila,e, polyphenyl methyl silica
1.3 parts of alkane, 0.6 part of tricresyl phosphate, 1 part of polyvinyl alcohol, 3.5 parts of erbium oxide, 20 parts of solvent, 1 part of wetting agent, dispersant
0.5 part.
5. extra long life ocean engineering anticorrosive paint according to claim 1, it is characterised in that the styrene monomer is
One or more kinds of mixtures in bisphenol A-type styrene monomer, bisphenol-f type styrene monomer, hydrogenated styrene monomer.
6. according to extra long life ocean engineering anticorrosive paint any one of claim 1-6,
Characterized in that, the particle diameter of the nano zine oxide is 20-40nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961385.1A CN107586476A (en) | 2017-10-17 | 2017-10-17 | A kind of extra long life ocean engineering anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961385.1A CN107586476A (en) | 2017-10-17 | 2017-10-17 | A kind of extra long life ocean engineering anticorrosive paint |
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| CN107586476A true CN107586476A (en) | 2018-01-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861775A (en) * | 2021-09-25 | 2021-12-31 | 上海吉祥家美幕墙材料有限公司 | Corrosion-resistant printing alloy plate and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1814663A (en) * | 2005-02-05 | 2006-08-09 | 广州慧谷化学有限公司 | Thermo-setting acrylic-acid emulsion, its preparing method and paint containing same |
| CN101921362A (en) * | 2010-07-14 | 2010-12-22 | 湖南大学 | Trimethylolpropane diallyl ether modified acrylate micro-gel emulsion and preparation method thereof |
| CN105331253A (en) * | 2015-12-04 | 2016-02-17 | 江苏建中能源科技有限公司 | Heavy-duty anti-corrosion paint for oceanographic engineering |
-
2017
- 2017-10-17 CN CN201710961385.1A patent/CN107586476A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1814663A (en) * | 2005-02-05 | 2006-08-09 | 广州慧谷化学有限公司 | Thermo-setting acrylic-acid emulsion, its preparing method and paint containing same |
| CN101921362A (en) * | 2010-07-14 | 2010-12-22 | 湖南大学 | Trimethylolpropane diallyl ether modified acrylate micro-gel emulsion and preparation method thereof |
| CN105331253A (en) * | 2015-12-04 | 2016-02-17 | 江苏建中能源科技有限公司 | Heavy-duty anti-corrosion paint for oceanographic engineering |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861775A (en) * | 2021-09-25 | 2021-12-31 | 上海吉祥家美幕墙材料有限公司 | Corrosion-resistant printing alloy plate and production process thereof |
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