CN107574031A - A kind of glass cleaner for cold environment - Google Patents

A kind of glass cleaner for cold environment Download PDF

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Publication number
CN107574031A
CN107574031A CN201710902261.6A CN201710902261A CN107574031A CN 107574031 A CN107574031 A CN 107574031A CN 201710902261 A CN201710902261 A CN 201710902261A CN 107574031 A CN107574031 A CN 107574031A
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CN
China
Prior art keywords
glass
glass cleaner
cleaner
cold environment
cleaning
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Withdrawn
Application number
CN201710902261.6A
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Chinese (zh)
Inventor
丁伟
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Chengdu Iding Industry Product Design Co Ltd
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Chengdu Iding Industry Product Design Co Ltd
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Priority to CN201710902261.6A priority Critical patent/CN107574031A/en
Publication of CN107574031A publication Critical patent/CN107574031A/en
Withdrawn legal-status Critical Current

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Abstract

The invention discloses a kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:Neopelex 5 7%, propylene glycol monomethyl ether 3 4%, ethanol 55 65%, nonionic surfactant 3 5%, Nano titanium dioxide 3 5%, isopropanol 0.5 1%, auxiliary agent 0.5 1%, surplus is deionized water.By adding Nano titanium dioxide into glass cleaner, the cleaning capacity and cleaning quality of glass cleaner are improved significantly, the freezing time and icing degree for making the glass surface after cleaning are improved, the addition of glass dust can improve the cleaning performance of glass cleaner, the spot of strength attachment on the glass surface can be removed, the addition of ethanol can effectively prevent the ice formation issues of glass cleaner, glass cleaner is set to keep liquid condition under the environment of cold, enter without carrying out the pre-heat treatment to glass cleaner, improve adaptability of the glass cleaner to environment.

Description

A kind of glass cleaner for cold environment
Technical field
The present invention relates to cleaning agent technical field, more particularly to a kind of glass cleaner and its preparation for cold environment Method.
Background technology
In the winter of cold, the cleaning to curtain wall is often that a highly difficult thing, particularly temperature are cold less than 0 DEG C Cryogenic region, the difficult performance of cleaning it is particularly evident.In cold environments, because curtain wall internal-external temperature difference is big, can be attached on curtain wall One layer of water smoke simultaneously congeals into ice, and worker to curtain wall when cleaning for cleaning, and it not only needs to expend larger muscle power, scavenging period Also will significantly extend, cleaning performance is barely satisfactory, while when cleaning, due to having used the water of more amount, these water mix with ice Mixture of ice and water is formed after conjunction and cleaning interface is become abnormal wet and slippery, and then increases the potential safety hazard of cleaning worker, and this If a little water are cleared up not in time, it can on the glass surface freeze again, substantially reduce the cleaning performance of curtain wall.
For cleaning robot, curtain cleaning is also faced be stranded with cleaning worker's identical in cold environments Difficulty, power consumption substantially increase, and cleaning performance reduces, and a certain amount of residual stains be present on curtain wall, and using glass cleaner When, due to the water containing more amount in existing glass cleaner, it is necessary to could be used after being preheated to glass cleaner, thus bring Use upper inconvenience, the bad adaptability of glass cleaner.
The content of the invention
The goal of the invention of the present invention is:For above-mentioned problem, there is provided a kind of clearing glass for cold environment Clean dose and preparation method thereof, to solve the problems of existing glass cleaner.
The technical solution adopted by the present invention is as follows:A kind of glass cleaner for cold environment, it is characterised in that with matter Percentages are measured, glass cleaner is composed of the following components:Neopelex 5-7%, propylene glycol monomethyl ether 3-4%, ethanol 55-65%, nonionic surfactant 3-5%, Nano titanium dioxide 3-5%, isopropanol 0.5-1%, auxiliary agent 0.5-1%, surplus are Deionized water.
Further, also containing the glass dust that mass fraction is 0.5-2% in glass cleaner.
Further, the glass dust is mainly made by silica and aluminum oxide after high temperature solid state reaction, obtained glass The particle diameter of powder is 3-10 μm.
Further, the auxiliary agent includes defoamer, and the defoamer is silicone oil.
Further, the auxiliary agent also includes anti-fouling agent, and the anti-fouling agent is dimethyl silicone polymer.
The preparation method of the glass cleaner for cold environment of the present invention, comprises the following steps:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant is added into mixed solution and is helped Agent, produced after being dispersed with stirring uniformly.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows:By into glass cleaner Nano titanium dioxide is added, the cleaning capacity and cleaning quality of glass cleaner are improved significantly, and make the glass after cleaning The freezing time and icing degree on glass surface are improved, and the addition of glass dust can improve the cleaning performance of glass cleaner, The spot of strength attachment on the glass surface can be removed, the addition of ethanol can effectively prevent the icing of glass cleaner from asking Topic, glass cleaner is kept liquid condition under the environment of cold, enter without being carried out to glass cleaner at preheating Reason, facilitates the use of user, improves adaptability of the glass cleaner to environment.
Embodiment
With reference to embodiment, the present invention is described in detail.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1
A kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:12 Sodium alkyl benzene sulfonate 5.6%, propylene glycol monomethyl ether 3.3%, ethanol 58%, nonionic surfactant 4%, Nano titanium dioxide 5%, Isopropanol 1%, auxiliary agent 1%, surplus are deionized water, wherein, auxiliary agent includes defoamer and builder, and defoamer is silicone oil, helps and washes Agent is sodium metasilicate, and the mass ratio of defoamer and builder is 1:1, the glass cleaner is made by following steps:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow are stirred in reactor with deionized water dilution, Ran Houjia Enter in the solution that step 1 obtains and form mixed solution, nonionic surfactant, silicone oil and silicic acid are added into mixed solution Sodium, produced after being dispersed with stirring uniformly.
Embodiment 2
A kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:12 Sodium alkyl benzene sulfonate 5%, propylene glycol monomethyl ether 4%, ethanol 55%, nonionic surfactant 5%, Nano titanium dioxide 5%, isopropyl Alcohol 0.5%, auxiliary agent 0.5%, surplus are deionized water, wherein, auxiliary agent includes defoamer, builder and anti-fouling agent, and defoamer is silicon Oil, builder are sodium metasilicate, and anti-fouling agent is dimethyl silicone polymer, and the mass ratio of three kinds of auxiliary agents is 1:1:3, the glass cleaner It is made by following steps:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant, silicon are added into mixed solution Oil, sodium metasilicate and dimethyl silicone polymer, produced after being dispersed with stirring uniformly.
Embodiment 3
A kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:12 Sodium alkyl benzene sulfonate 7%, propylene glycol monomethyl ether 3%, ethanol 65%, nonionic surfactant 3%, Nano titanium dioxide 3%, glass Powder 0.5%, isopropanol 1%, auxiliary agent 1%, surplus are deionized water, wherein, auxiliary agent includes defoamer and anti-fouling agent, and defoamer is silicon Oil, anti-fouling agent are dimethyl silicone polymer, and the mass ratio of defoamer and anti-fouling agent is 1:4, the glass cleaner passes through following step It is rapid to be made:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant, silicon are added into mixed solution Oil and dimethyl silicone polymer, produced after being dispersed with stirring uniformly, it is desirable to which glass dust is mainly consolidated by silica and aluminum oxide through high temperature It is made after phase reaction, the particle diameter of glass dust is 3-10 μm.
Embodiment 4
A kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:12 Sodium alkyl benzene sulfonate 5.8%, propylene glycol monomethyl ether 3.7%, ethanol 61%, nonionic surfactant 4.5%, Nano titanium dioxide 3.6%, glass dust 2%, isopropanol 0.7%, auxiliary agent 0.6%, surplus is deionized water, wherein, auxiliary agent includes defoamer and builder, Defoamer is silicone oil, and builder is sodium metasilicate, and the mass ratio of defoamer and builder is 1:1, the glass cleaner passes through following Step is made:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant, silicon are added into mixed solution Oil and sodium metasilicate, produced after being dispersed with stirring uniformly, it is desirable to which glass dust is mainly by silica and aluminum oxide after high temperature solid state reaction It is made, the particle diameter of glass dust is 3-10 μm.
Embodiment 5
A kind of glass cleaner for cold environment, by percentage to the quality, glass cleaner is composed of the following components:12 Sodium alkyl benzene sulfonate 6.3%, propylene glycol monomethyl ether 3.4%, ethanol 63%, nonionic surfactant 4.1%, Nano titanium dioxide 3.7%, glass dust 1.3%, isopropanol 0.8%, auxiliary agent 0.8%, surplus is deionized water, and wherein auxiliary agent includes defoamer and antifouling Agent, defoamer are silicone oil, and anti-fouling agent is dimethyl silicone polymer, and the mass ratio of defoamer and anti-fouling agent is 1:3, the cleaning glass Agent is made by following steps:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant, silicon are added into mixed solution Oil and dimethyl silicone polymer, produced after being dispersed with stirring uniformly, it is desirable to which glass dust is mainly consolidated by silica and aluminum oxide through high temperature It is made after phase reaction, the particle diameter of glass dust is 3-10 μm.
Comparative example 1
By 7% neopelex, 2% propylene glycol monomethyl ether, 3% nonionic surfactant, 4% isopropanol and 1% Auxiliary agent be together mixed in deionized water, comparative example 1 is obtained after being uniformly mixed, wherein " % " represent mass percent.
Comparative example 2
By 5.8% neopelex, 1.7% propylene glycol monomethyl ether, 3.1% nonionic surfactant, 2% second two Alcohol, 4% Nano titanium dioxide and 1% auxiliary agent are together mixed in deionized water, and comparative example is obtained after being uniformly mixed 2, wherein " % " represents mass percent.
Major parameter is test:The glass cleaner of embodiment and comparative example is placed in cleaning robot respectively, in 80cm Uniformly one layer of mixture mixed by machine oil and edible oil of coating, and spray a certain amount of ash on × 80cm safety glass Dirt and water, it is subsequently placed in -5 DEG C of environment and stands several minutes, after glass to be toughened surface freezes, manipulation cleaning robot is to upper Contaminated glass is stated to be cleaned(Robot operating power is arranged to identical), time and glass surface that record each group is cleaned Cleaning situation, then the safety glass after cleaning is again placed in -5 DEG C of environment, and water smoke constantly is sprayed to safety glass, The time for starting to freeze of record safety glass and ice condition, as a result as shown in table 1:
Table 1
Note:In upper table, " very small amount ", " a small amount of " and " a certain amount of " is the degree for representing spot amount on safety glass, and It is ordered as by the degree size of spot amount:" very small amount " < " a small amount of " < " a certain amount of ".
As shown in Table 1, can be obtained by the way that Examples 1 and 2 are carried out into contrast with comparative example 1 and 2, when in glass cleaner Containing ethanol and during Nano titanium dioxide, spot amount is reduced, and ice condition is improved, in the absence of borneol and icicle, When particularly containing Nano titanium dioxide, without oil film after cleaning, cleaning quality is improved, thus, ethanol and nanoscale two Titanium oxide can improve the cleaning capacity and cleaning quality of glass cleaner, and glass surface is freezing after can improving cleaning Situation, make glass freezing time and icing degree be improved significantly, indirectly improve glass cleaner cleaning quality;Enter one Step ground says, by embodiment 1-5 is contrasted it can be found that when in glass cleaner it is interior contain glass dust when, the glass after cleaning Glass surface significantly improves without spot, cleaning performance, and cause is probably the frictional force and dirt-carrying that glass dust improves glass cleaner Ability, the spot of strength attachment on the glass surface can be removed, which thereby enhances clean-up capability.
Meanwhile be loaded on embodiment 1-5 and the glass cleaner of comparative example 1 and 2 in 10ml container respectively, then it will hold Device is placed in -5 DEG C of environment and stands 10min, examines the ice condition of each container, as a result as shown in table 2:
Table 2
As can be seen from Table 2, when containing ethanol in glass cleaner, its freezing time is significantly extended, after ice slag is formed, Significant change no longer occurs for glass cleaner, and glass cleaner is integrally in a liquid state, and the glass cleaner for not containing ethanol starts Time of icing is substantially early, and with the extension of freezing time, glass cleaner by settable liquid into solid-state, it is possible thereby to Draw, the addition of ethanol can effectively prevent the ice formation issues of glass cleaner, make glass cleaner energy under the environment of cold Liquid condition is enough kept, is entered without carrying out the pre-heat treatment to glass cleaner, is facilitated the use of user, improve glass Adaptability of the cleaning agent to environment.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (6)

1. a kind of glass cleaner for cold environment, it is characterised in that by percentage to the quality, glass cleaner is by following Component forms:Neopelex 5-7%, propylene glycol monomethyl ether 3-4%, ethanol 55-65%, nonionic surfactant 3-5%, Nano titanium dioxide 3-5%, isopropanol 0.5-1%, auxiliary agent 0.5-1%, surplus are deionized water.
2. it is used for the glass cleaner of cold environment as claimed in claim 1, it is characterised in that also contain in glass cleaner Mass fraction is 0.5-2% glass dust.
3. it is used for the glass cleaner of cold environment as claimed in claim 2, it is characterised in that the glass dust is mainly by oxygen SiClx and aluminum oxide are made after high temperature solid state reaction, and the particle diameter of obtained glass dust is 3-10 μm.
4. it is used for the glass cleaner of cold environment as claimed in claim 1 or 2, it is characterised in that the auxiliary agent includes disappearing Infusion, the defoamer are silicone oil.
5. it is used for the glass cleaner of cold environment as claimed in claim 4, it is characterised in that the auxiliary agent also includes antifouling Agent, the anti-fouling agent are dimethyl silicone polymer.
6. it is used for the preparation method of the glass cleaner of cold environment as claimed in claim 5, it is characterised in that including following Step:
Step 1, neopelex, propylene glycol monomethyl ether and isopropanol are added into the absolute ethyl alcohol measured, stirring is mixed Close uniformly, it is stand-by;
Step 2, the Nano titanium dioxide for weighing design flow and glass dust are equal with deionized water dilution stirring in reactor It is even, then add in the solution that step 1 obtains and form mixed solution, nonionic surfactant is added into mixed solution and is helped Agent, produced after being dispersed with stirring uniformly.
CN201710902261.6A 2017-09-29 2017-09-29 A kind of glass cleaner for cold environment Withdrawn CN107574031A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108949368A (en) * 2018-07-02 2018-12-07 滁州亿扬零部件制造有限公司 A kind of low freezing point automobile windscreen cleaning agent
CN114015517A (en) * 2021-11-25 2022-02-08 北京玻名堂玻璃有限公司 Low-reflection glass cleaning agent for museum showcase and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55102698A (en) * 1979-02-01 1980-08-06 Taiho Kogyo Co Ltd Method of cleaning oilldirty glass surface and glass cleaner
CN1629269A (en) * 2003-12-17 2005-06-22 孙凤红 Automobile glass cleaning agent
CN1796523A (en) * 2004-12-24 2006-07-05 天津市怡佳商贸有限公司 Glass cleaning in use for automobile
CN104388218A (en) * 2014-11-19 2015-03-04 柳州市二和汽车零部件有限公司 Automobile glass water and preparation method thereof
CN105062704A (en) * 2015-08-13 2015-11-18 上海德联化工有限公司 Glass cleaning agent
CN106367217A (en) * 2016-08-24 2017-02-01 苏州恒恩新能源汽车组件有限公司 Anti-ultraviolet self-cleaning water scattering vehicle glass water

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55102698A (en) * 1979-02-01 1980-08-06 Taiho Kogyo Co Ltd Method of cleaning oilldirty glass surface and glass cleaner
CN1629269A (en) * 2003-12-17 2005-06-22 孙凤红 Automobile glass cleaning agent
CN1796523A (en) * 2004-12-24 2006-07-05 天津市怡佳商贸有限公司 Glass cleaning in use for automobile
CN104388218A (en) * 2014-11-19 2015-03-04 柳州市二和汽车零部件有限公司 Automobile glass water and preparation method thereof
CN105062704A (en) * 2015-08-13 2015-11-18 上海德联化工有限公司 Glass cleaning agent
CN106367217A (en) * 2016-08-24 2017-02-01 苏州恒恩新能源汽车组件有限公司 Anti-ultraviolet self-cleaning water scattering vehicle glass water

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108949368A (en) * 2018-07-02 2018-12-07 滁州亿扬零部件制造有限公司 A kind of low freezing point automobile windscreen cleaning agent
CN114015517A (en) * 2021-11-25 2022-02-08 北京玻名堂玻璃有限公司 Low-reflection glass cleaning agent for museum showcase and preparation method thereof
CN114015517B (en) * 2021-11-25 2024-04-05 北京玻名堂玻璃有限公司 Low-reflection glass cleaner for museum showcase and preparation method thereof

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Application publication date: 20180112