CN107574001B - Water base lubricant for food filling production line - Google Patents
Water base lubricant for food filling production line Download PDFInfo
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- CN107574001B CN107574001B CN201710939288.2A CN201710939288A CN107574001B CN 107574001 B CN107574001 B CN 107574001B CN 201710939288 A CN201710939288 A CN 201710939288A CN 107574001 B CN107574001 B CN 107574001B
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Abstract
For the water base lubricant of food filling production line, it is characterized in that the lubricant is composed of the following components:It is branched 13 carbon Guerbet alcohol polyoxyethylene ether, 35 parts by weight;35 parts by weight of polysorbate40 or polysorbate60;0.7~1.5 parts by weight of oleoyl triethanol amine;7~15 parts by weight of propylene glycol atactic polyether (PPE);The degree of polymerization of 35 parts by weight of polyethylene glycol, the polyethylene glycol is 400~2000;The weight ratio of the sum of water, the water and other all components is 3~3.5.
Description
Technical field
The present invention relates to lubricants, the more particularly, to lubricant of food cans assembling production lines.
Background technology
In existing food filling production line, the movements of food containers by conveyer belt automatic control, continuously run.Its is defeated
Band is sent to be generally stainless steel flat plate chain, it, must be using automatic spray come to stainless steel flat plate chain in order to ensure production line smoothness
It is lubricated.And there is higher stability in hard water, restraining and sterilizing bacteria, foam characteristic, crack resistance and low temperature pumpmg quality.In
State patent CN200710033004X discloses the water base lubricant for food filling production line, using triethanolamine oleate, three
The ingredients such as ethanol amine, although the document this point out its provide water base lubricant have higher stability in hard water, restraining and sterilizing bacteria,
Foam characteristic, crack resistance and low temperature pumpmg quality, but as the running speed of high-speed canning system in recent years is continuously improved, property
It cannot can meet the requirement of high-speed canning system, and in fact, in above-mentioned properties, most important is exactly lubricity
Can, the prescription of various water base lubricants is researched and developed on the basis of greasy property after improving spray.
Chinese document --- propylene glycol polyethers and the tribological Properties of oleoyl triethanol amine compounding aqueous solution are (yellow precious
At Beijing Jiaotong University's Specialized Master Degree paper, in June, 2015) in disclose using propylene glycol polyethers and three ethyl alcohol of oleoyl
The water base lubricant of amine compounding, however public data shows when the concentration of combination solution reaches 5-10% it from the document
Lubricant effect is ideal, but in practical applications, in order to adapt to the requirement of high-speed production lines and reduce use cost, generally all
Need row coating again after lubricant stoste is diluted 100-200 times.Therefore a kind of food filling that can be suitable for newly is provided to give birth to
The water base lubricant of producing line becomes urgent problem to be solved in the prior art.
Invention content
To solve the problems of the prior art, the technical solution adopted by the present invention is:
The water base lubricant for food filling production line is provided, it is characterized in that the lubricant is by following components group
At:It is branched 13 carbon Guerbet alcohol polyoxyethylene ether 3-5 parts by weight;Polysorbate40 or polysorbate60 3-5 parts by weight;Three ethyl alcohol of oleoyl
0.7~1.5 parts by weight of amine;7~15 parts by weight of propylene glycol atactic polyether (PPE);Polyethylene glycol 3-5 parts by weight, the poly- second two
The degree of polymerization of alcohol is 400~2000;The weight ratio of the sum of water, the water and other all components is 3~3.5;The collateralization
The molecular formula of 13 carbon Guerbet alcohol polyoxyethylene ether is as follows:
RO(GH2CH2O)xH;
R=iso-C13H27, x=8,9 or 10.
The water base lubricant for food filling production line, it is characterized in that it is preferred that propylene glycol atactic polyether 9-11 weights
Measure part, 0.9~1.1 parts by weight of oleoyl triethanol amine.
The water base lubricant for food filling production line, it is characterized in that the water is deionized water.
The water base lubricant for food filling production line, it is characterized in that the specification of the propylene glycol atactic polyether
For PPE-1500.
The water base lubricant for food filling production line, it is characterized in that it is preferred that polysorbate60.
The water base lubricant for food filling production line, it is characterized in that the polyethylene glycol is preferably poly- second two
Alcohol 2000.
The water base lubricant for food filling production line, it is characterized in that 13 carbon Guerbet alcohols of the collateralization
Polyoxyethylene ether is preferably in BASF Lutensol TO8, BASF Lutensol TO9, BASF Lutensol TO10
It is one or more of.
The water base lubricant for food filling production line, speciality are that the preparation method of the lubricant is,
The polyethylene glycol of recipe quantity is dissolved in recipe quantity water and obtains polyglycol solution, by oleoyl triethanol amine, propylene glycol atactic polyether,
Be branched 13 carbon Guerbet alcohol polyoxyethylene ether, polysorbate40 or polysorbate60 mixing after under stirring be added polyethylene glycol it is molten
Liquid, continue stirring until it is uniform to obtain the final product.
Provided by the present invention for the water base lubricant of food filling production line, document report propylene glycol polyethers with
On the basis of oleoyl triethanol amine compounds water base lubricant, it is found surprisingly that increasing a small amount of 13 carbon Guerbet alcohol of collateralization gathers
After ethylene oxide ether, polyethylene glycol, polysorbate40 or polysorbate60, the performance of water base lubricant can be significantly improved, will especially lubricated
After agent high dilution, additionally it is possible to keep higher greasy property so that it can the high speed food gone out applied to new development in recent years
Filling production lines.When carrying out option screening it was found that preferred polyethylene glycol 2000 and polysorbate60 can be significantly improved more
The greasy property of lubricant.In addition in experimenting, we find out that, polyethylene glycol, branch only within the scope of addition recipe quantity of the present invention
13 carbon Guerbet alcohol polyoxyethylene ether of chainization, polysorbate40 or polysorbate60 can just significantly improve the greasy property of lubricant, due to
The raw material that water base lubricant provided by the invention uses is nontoxic water-soluble component, can be used for food filling production line.
Specific implementation mode
With reference to specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to
This.
The water-base chain lubricant provided in the embodiment of the present invention is prepared in the following ways
1) polyethylene glycol of recipe quantity (PET) is dissolved in recipe quantity water and obtains polyglycol solution
2) recipe quantity oleoyl triethanol amine (TO), propylene glycol atactic polyether (PPE), 13 carbon Guerbet alcohols of collateralization are poly-
Ethylene oxide ether is mixed with polysorbate40 or polysorbate60
3) mixed liquor of step 2) is added in polyglycol solution under stirring, lasting stirring becomes transparent and homogeneous
Liquid.
Water is deionized water, and the weight ratio of the sum of deionized water and other left and right components is unified for 3.3.
Be branched 13 carbon Guerbet alcohol polyoxyethylene ether be BASF Lutensol TO8, Lutensol TO9,
One or more of Lutensol TO10.
The PPE specifications are PPE-1500.
Example formulations see the table below (unit:g)
It is spare afterwards that the lubricant that embodiment 1~12 is obtained respectively dilutes 30 and 200 times (v/v) with deionized water.Separately take
Oleoyl triethanol amine (TO) is with propylene glycol atactic polyether (PPE) according to 1:3.3 times of weight deionizations are added after 9 weight ratio mixing
As a comparison case 1 after water dilution.
Detect the test of 1. lubricity of embodiment
The measurement of simulation lubricity is carried out on four-ball extreme pressure tester.The grinding defect diameter of ball is measured, grinding defect diameter is smaller
Show that greasy property is better.
Method:Steel ball is separately fixed in the upper ball base and oil box of four-ball tester.By lubricant by certain volume multiple into
It is poured into oil box after row dilution, allows it to cover steel ball and reach the joint of pressure ring and nut.The oil box for installing sample and ball
The upper ball base of four-ball extreme pressure tester is placed in center in the following, putting circular disk rack among lubricating cup and guide post, releases load
Lever is simultaneously added to defined load (0kg or 10kg) on ball.After load, starts motor and press stopwatch simultaneously, from starting to
The experimental period of closing is 10 seconds.Every time after experiment, the grinding defect diameter of the both direction in length and breadth of any one steel ball in measuring box,
It is averaged..The GCr15 steel balls that steel ball used is II class precisions are wherein tested, diameter 12.7mm, HRC (Rockwell hardness) are 64-
66, it is produced and is provided by Shanghai Steel Ball Plant
Grinding defect diameter result such as following table (unit under different experimental conditions:mm)
It is above-mentioned the experimental results showed that, using lubricant provided in an embodiment of the present invention, the equal table when being lubricated property is tested
Reveal preferable performance, and when lubricant is diluted to 200 times, greasy property is still good, and from above-mentioned data
As can be seen that being apparently higher than other embodiment using the greasy property for the embodiment 2,3,6,7 being preferably formulated.Comparative example 1~3
Greasy property be significantly lower than each embodiment, illustrate embodiment by optimization formula, be greatly improved based on PPE and TO
The greasy property of lubricant after dilution.Wherein comparative example 2~4 is added without 13 carbon of collateralization respectively on the basis of embodiment 6
Guerbet alcohol polyoxyethylene ether, polysorbate60 and PET6000 can be seen that this hair from the experimental data of comparative example 2~4 is combined
Each component in the side of daylight can generate the lubricant effect that synergistic effect improves lubricant when being lubricated performance test.
Claims (1)
1. for the water base lubricant of food filling production line, it is characterized in that the lubricant is composed of the following components:
It is branched 13 carbon Guerbet alcohol polyoxyethylene ether 3-5 parts by weight;Polysorbate60 3-5 parts by weight;Oleoyl triethanol amine 0.9
~1.1 parts by weight;9~11 parts by weight of propylene glycol atactic polyether (PPE);Polyethylene glycol 3-5 parts by weight, water;The polyethylene glycol
For polyethylene glycol 2000;The weight ratio of the sum of the water and other all components is 3~3.5;13 carbon gerbers of the collateralization
Extra Old polyoxyethylene ether is in BASF Lutensol TO8, BASF Lutensol TO9, BASF Lutensol TO10
It is one or more of;The specification of the propylene glycol atactic polyether is PPE-1500.
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CN108977264A (en) * | 2018-09-04 | 2018-12-11 | 罗粉继 | A kind of total synthesis water-base cutting fluid |
Citations (4)
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CN102482603A (en) * | 2009-09-01 | 2012-05-30 | 慕尼黑克吕伯尔润滑器两合公司 | Water-based lubricants |
CN105886094A (en) * | 2016-04-22 | 2016-08-24 | 广州泰晟生物科技有限公司 | Water-based chain plate lubricating agent for soft beverage packages and preparation method of water-based chain plate lubricating agent |
CN106190522A (en) * | 2016-07-28 | 2016-12-07 | 中国科学院兰州化学物理研究所 | As organic salt that water lubrication additive uses and preparation method thereof |
CN106497667A (en) * | 2016-11-01 | 2017-03-15 | 南通科星化工有限公司 | A kind of water-base cutting fluid and preparation method thereof |
-
2017
- 2017-10-11 CN CN201710939288.2A patent/CN107574001B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102482603A (en) * | 2009-09-01 | 2012-05-30 | 慕尼黑克吕伯尔润滑器两合公司 | Water-based lubricants |
CN105886094A (en) * | 2016-04-22 | 2016-08-24 | 广州泰晟生物科技有限公司 | Water-based chain plate lubricating agent for soft beverage packages and preparation method of water-based chain plate lubricating agent |
CN106190522A (en) * | 2016-07-28 | 2016-12-07 | 中国科学院兰州化学物理研究所 | As organic salt that water lubrication additive uses and preparation method thereof |
CN106497667A (en) * | 2016-11-01 | 2017-03-15 | 南通科星化工有限公司 | A kind of water-base cutting fluid and preparation method thereof |
Non-Patent Citations (1)
Title |
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丙二醇聚醚与油酰三乙醇胺复配水溶液的摩擦学性能研究;黄宝成;《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》;20151015(第10期);第13-18页 * |
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Effective date of registration: 20201222 Address after: 224000 23 / F (b), Huidu building, Xindu West Road, Yandu District, Yancheng City, Jiangsu Province Patentee after: Jiangsu Yandu Baiming Agricultural Co.,Ltd. Address before: Tianjin Agricultural College, 22 Jinjing Road, Xiqing District, Tianjin, 300384 Patentee before: Tianjin Agricultural University |