Background technology
In recent years, China's rapid economic development, atmosphere polluting problem is further severe, the regional big compression ring of characteristic contamination
Border problem becomes increasingly conspicuous.Natural gas is a kind of clean energy resource, and its main component is methane, and carbon dioxide is generated after methyl hydride combustion
And water, it is substantially not present particle and sulphide staining.But if natural gas burns in a traditional way, extreme temperatures, can largely generate
Heating power nitrogen oxides (NOx) is with fume emission into atmospheric environment.NOx composition is with NO and NO2Based on.NO can enter in an atmosphere
One step is oxidized to NO2.NOx has significant impact to environment and health of human body, and it can form nitric acid and nitre in atmospheric environment
Hydrochlorate particulate matter, accelerate the acidifying of regional acid rain and soil.In addition, NOx is also the arch-criminal to form photochemical fog
One of.
The NOx annual emissions of China have occupied first place in the world.Beijing promulgates within 2015《Boiler Air Pollutant Emission
Standard》(DB11/139-2015), it is desirable to before 1 day April in 2017 with the NOx emission of gas furnace by existing 150mg/m3Drop
To 80mg/m3Hereinafter, and mandatory provisions, the NOx emission of all newly-built gas furnaces should be less than 30mg/m from 1 day April in 20173.Mesh
It is preceding with gas furnace level of NOx emission generally in 100~200mg/m3, therefore existing almost all gas furnace all suffer from doing it is low
The situation of nitrogen discharged transformation.The senior general of the market demand of NOx abatement is unthinkable.
Realize that the low-nitrogen discharged technological approaches of gas furnace mainly there are two:Gas denitrifying technology after burning and aflame
Low NOx generates control technology.The former complex technical process, cost is at a relatively high, and latter techniques' content is high, and cost is relatively low.In burning
Low nitrogen generation control there is also a variety of methods for having certain effect, such as Researched of Air Staging Combustion Burning Pulverized Coal, flue gas recirculating technique etc. to belong to
In the technology of maturation, largely used in the practical application of various industrial furnaces.However, as environmental problem and limit row refer to
Target is increasingly strict, it is necessary to researches and develops a kind of more efficiently combustion gas method for reducing gas furnace NOx emission.
The content of the invention
In order to solve the above problems, present inventor has performed study with keen determination, there is provided a kind of effectively to reduce gas furnace NOx rows
The combustion gas method put, i.e., warming and humidifying is carried out to the combustion air before entering combustion system by the humidification system that heats up, can facilitated
Ground controls ignition temperature below the threshold value for only generating few NOx, in source the control of NOx growing amount minimum, from
And complete the present invention.
It is an object of the invention to provide a kind of combustion gas method for effectively reducing gas furnace NOx emission, the combustion gas method
Including carrying out warming and humidifying processing to the combustion air before entering combustion system by the humidification system that heats up;The combustion-supporting sky after processing
Gas is reacted into combustion system.The heating humidification system includes stokehold spray column, and the combustion air is through into stokehold
Tower bottom is sprayed, with the water reverse heat-exchange that gets off from stokehold spray column top spray and after humidifying, through stokehold spray column top
Air outlet slit flows out, into combustion system.
By a kind of combustion gas method for effectively reducing gas furnace NOx emission provided by the invention, following technology can be reached
Effect:
1st, burner and provided by the invention emission reduction using existing resistance to high humility relatively low to combustion system calls of the invention
Method, it just can reach requirement discharge index, save improvement of manufacturing line cost;
2nd, the high intensity humidification never having in the past is carried out there is provided stokehold spray column, it is warm to suppress to burn in stove with this
Degree, so as to reach from generation NOx source emission reduction purpose, it is easy and effective, this and in the past it is widely used and mature " classification
The technology such as burning ", " flue gas recirculation " is completely different;
The 3rd, heat exchanger is set after combustion system, and using spray column direct contact heat transfer reverse with flue gas after stove and removed
It is wet, realize that final exhaust gas temperature reaches close to environment temperature, this causes the thermal efficiency of combustion system (with the low heat valve of fuel
During calculating) even more than 100% can be approached;
The 4th, one spray column is respectively set before and after combustion system, the shower water of two spray columns is existed by two circulating pumps
The flow circuit of closure is formed between two spray columns, recycling for heat energy and water resource is realized, has saved cost;
5th, this method is that can take into account pollutant emission control and the advanced combustion gas of the aspect technical indicator of the superelevation thermal efficiency two
Scheme, it is the comprehensive integrated technology of cleaning burning and low pollution emission.
Embodiment
Below by the present invention is described in detail, the features and advantages of the invention will become more with these explanations
To be clear, clear and definite.
The purpose of the present invention is to disclose a kind of combustion gas method for effectively reducing gas furnace discharged nitrous oxides, methods described bag
Include following steps:
1) warming and humidifying is carried out to the combustion air before entering combustion system by the humidification system that heats up;
2) combustion air after step 1 processing is reacted into combustion system.
In the present invention, the heating humidification system includes stokehold spray column, and the combustion air enters stokehold spray column bottom
Portion, with spraying the water reverse heat-exchange to get off from the spray column top spray device of stokehold and humidifying, the sky through stokehold spray column top
Gas outlet outflow, into combustion system;
In a preferred embodiment, the combustion air is sent into stokehold by air blower and sprays tower bottom, to protect
Demonstrate,prove stable combustion air flow.
In further preferred embodiment, filler is provided with the stokehold spray column, filler fixed position can be in stove
Preceding spray column internal upper part, middle part, bottom or optional position combination, for increasing the contact area of water and combustion air.It is described to fill out
Material includes regular type filler and dumped packing, and the filler is corrosion-resistant and high temperature resistant material, preferably stainless steel, ceramics and modeling
One or more in material.
In the present invention, the temperature of shower water is 30 DEG C~70 DEG C, preferably 40 DEG C~60 DEG C in the spray column of stokehold;Heating adds
The temperature of combustion air is 30 DEG C~70 DEG C, 40 DEG C~60 DEG C preferably in bulk after wet;Humidity is steam-laden or supersaturation
State.The key factor that amount of NOx size is generated when natural gas fuel system is burnt is ignition temperature.Combustion air is not made to locate
Ignition temperature helps up to 1800 DEG C~1900 DEG C by stokehold spray column warming and humidifying to the combustion air of saturation state during reason
Few NOx 1400 DEG C~less than 1523 DEG C of threshold value is being only generated in ignition temperature is controlled.
In the present invention, the combustion system includes burner and combustion gas furnace body, combustion gas and the combustion-supporting sky for being sent into burner
Gas mixes, and is burnt in combustion gas furnace body internal combustion.Exhaust steam valve and draining valve are set in the combustion gas furnace body, is respectively used to control combustion gas
Caused condensate after gas content and discharge are burnt in furnace body.
Still contain a small amount of NOx, and stokehold after combustion gas and the combustion air mixed combustion of heating and moistening in caused flue gas
The output of continuation water and the recycling of water easily cause the increase of production cost in spray column, further to reduce NOx in flue gas
Content and water use processing cost, while Mist heat recovering, the combustion gas side for reducing gas furnace discharged nitrous oxides
Method also include will burning after flue gas by residual neat recovering system, so that flue gas after burning is cooled and washed.
Residual neat recovering system includes spray column after the heat exchanger being connected with combustion gas furnace body and the stove being connected with heat exchanger, cigarette
Gas after heat exchanger with spraying the water to get off in the spray column top spray device after stove by, into the bottom of spray column after stove, carrying out
Discharged after countercurrent flow and dehumidification after stove at the top of spray column.
Heat exchanger tube is the finned tube of light pipe or pipe outer wall combination fin structure, preferably helical fin in the heat exchanger
Pipe, this structure can enable heat exchange pipe external surface to extend, and improve heat exchange area.Exchanger base is provided with discharge pipe line, by flue gas
Caused condensate discharge, tower bottom is sprayed after being preferably discharged into stove after cooling.
Be provided with filler after the stove in spray column, filler fixed position can after stove spray column internal upper part, middle part, bottom or
Optional position is combined, for increasing the contact area of water and flue gas.After the stove in spray column shower water temperature for 30 DEG C~
50℃.After stove spray column on the one hand make flue gas by with low temperature water direct contact heat-exchanging, flue-gas temperature is reduced to close to environment
Temperature, to ensure that the thermal efficiency of whole combustion system reaches high level;On the other hand, after stove the shower water of spray column also to cigarette
Gas plays a part of fully washing.Due to NOx and CO2There is certain solubility in water, the acid water that bottom of towe can be accumulated
Focus on and reuse, and various pollutants are no longer discharged into atmospheric environment.
Spray column is carried out inverse with air and flue gas respectively by filler with the direct way of contact after stokehold spray column and stove
Flow caloic to exchange, heat and mass excellent.Showing as this caloic exchange can realize that terminal is almost " zero temperature difference " and relative
Humidity reaches saturation, i.e., in the spray column of stokehold, the air after heating reach with shower water very close to or almost identical temperature,
Humidity reaches the saturation state under relevant temperature;Equally after stove in spray column, flue gas is also cooled to be tapped with shower water ten
Near temperature, and exhaust steam moisture is also the saturation state under corresponding lower temperature.
In the present invention, spray tower bottom is provided with water tank after the stokehold spray tower bottom and stove, and is determined in water tank
Highly place sets overflow valve, it is preferable that the water tank inner surface preservative treatment, makes the erosion resistance of water tank be strengthened.
The water tank of stokehold spray tower bottom is connected to form cold water pipeline by the spray thrower at the top of spray column after pipeline and stove, is sprayed after stove
The spray thrower for drenching top of tower is connected to form hot water line by the water tank of pipeline and preceding spray tower bottom, is set respectively in two pipelines
Circulating pump is put, makes the water route composition closed circulation system of spray column after stokehold spray column and stove, in addition water caused by fuel gas buring,
Therefore in addition to blowdown, spray column water circulation system does not consume water resource substantially after stokehold spray column and stove.
The present invention uses the circulatory system of gas burning system combination water-moist steam, is dropped in original burner or low NO
On the basis of low-nitrogen discharged, higher levels of low-nitrogen discharged index is realized;Carried out simultaneously using water and flue gas by filler straight
The Mass and heat transfer of contact, and the heat recovery heat exchanger of gas furnace afterbody is combined, realize the thermal efficiency of superelevation.
In a preferred embodiment, it is a kind of effectively reduce gas furnace NOx emission gas burning system as shown in figure 1,
Spray thrower 2 and filler 3 be installed, spray thrower 2 sprays after being connected to stove by being connected with the pipeline of circulating pump 4 in stokehold spray column 1
Drench the water tank of the bottom of tower 5.Spray thrower 6 and filler 7 are equally installed, spray thrower 6 is by being connected with circulation after stove in spray column 5
The pipeline of pump 4 is connected to the water tank of the bottom of stokehold spray column 1.Air blower 8 is arranged on the exterior bottom of stokehold spray column 1, will help
Combustion air brings stokehold spray column 1 into and carries out heat water-spraying.Saturated moist air after heat exchange is from the upper end of stokehold spray column 1
It is connected through air duct with burner 9, combustion gas mixes and in the combustion chamber internal combustion of combustion gas furnace body 10 with the combustion air being sent into
Burn, furnace tubing, medium in pipe is reached the temperature of design.Flue gas in fuel chamber first flows through heat exchanger 11, the heat exchange
Device 11 is that fin tube type flue residue heat reclaims heat exchanger, and part water vapour contained in flue gas condenses in the process, cigarette
The part sensible heat and vapor latent heat of gas are tentatively reclaimed.Flue gas after preliminary cooling sprays after entering stove by flue
Tower 5, with the heat exchange of low-temp. spraying water contact and dehumidification, have the function that to wash flue gas simultaneously in the process, further
Reduce the quantity to air discharge NOx and other various pernicious gases.Flue gas after cooling and dehumidification, finally with close to environment
The level of temperature, by the top outlet drain of spray column after stove 5 into air.
The present invention is described in detail above in association with embodiment and exemplary example, but these explanations are simultaneously
It is not considered as limiting the invention.It will be appreciated by those skilled in the art that without departing from the spirit and scope of the invention,
A variety of equivalencing, modification or improvement can be carried out to technical solution of the present invention and embodiments thereof, these each fall within the present invention
In the range of.Protection scope of the present invention is determined by the appended claims.