CN107558201A - A kind of preparation method of fabric hydrophobic oleophilic oil agent - Google Patents
A kind of preparation method of fabric hydrophobic oleophilic oil agent Download PDFInfo
- Publication number
- CN107558201A CN107558201A CN201710655183.4A CN201710655183A CN107558201A CN 107558201 A CN107558201 A CN 107558201A CN 201710655183 A CN201710655183 A CN 201710655183A CN 107558201 A CN107558201 A CN 107558201A
- Authority
- CN
- China
- Prior art keywords
- parts
- hydrophobic oleophilic
- oil
- oleophilic oil
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of preparation method of fabric hydrophobic oleophilic oil agent, the fabric hydrophobic oleophilic oil agent is made up of the raw material of following parts by weight:5 10 parts of butyl methacrylate, 24 parts of laurate, 5 10 parts of vegetable oil, 10 20 parts of styrene, 15 parts of hydrophobic oleophilic oil nano particle, 10 20 parts of beeswax, 13 parts of silane coupler, 50 100 parts of n-hexane.After the fabric hydrophobic oleophilic oil agent application fabric of the present invention, the hydrophobic contact angle of fabric reaches more than 130 °, can adsorb the oil of more than 5 times of weight itself.The fabric hydrophobic oleophilic oil agent manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and human body is not stimulated, and volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of fabric hydrophobic oleophilic oil agent.
Background technology
As countries in the world are to the growing of oil demand, oil largely enters ocean as global pollutant,
Considerably beyond other pollutant emission speed.According to statistics, 1/1000 i.e. 3,200,000 be there are about in 3,200,000,000 tons of oil that the whole world produces every year
Ton enters marine environment, and the oil leaked into water body not only brings serious economic loss to us, more to marine ecology ring
Border and periphery seashore cause great pollution, and therefore, effective recovery to ocean water body greasy dirt is one and urgently to be resolved hurrily asked
Topic.
At present, many methods are already used to clear up oil pollution region, such as:Mechanical extraction, situ combustion, chemistry drop
Solution etc..But result is all undesirable.Therefore, a kind of hydrophobic oleophilic oil agent is found, used in general fabric face, can be very good to inhale
Attached greasy dirt, and not polluted source.In addition, fabric can also recycle well.
The content of the invention
It is an object of the invention to provide a kind of fabric hydrophobic oleophilic oil agent and preparation method, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical scheme:
A kind of fabric hydrophobic oleophilic oil agent, include the raw material of following parts by weight:Butyl methacrylate 5-10 parts, laurate
2-4 parts, vegetable oil 5-10 parts, styrene 10-20 parts, hydrophobic oleophilic oil nano particle 1-5 parts, beeswax 10-20 parts, silane coupler
1-3 parts, n-hexane 50-100 parts.
Preferably, described silane coupler is 3- aminopropyl trimethoxysilanes, γ-(2,3- the third oxygen of epoxy) propyl group three
Ethoxysilane, γ-methacryloxypropyl trimethoxy silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy silicon
Any one in alkane, aniline isophorone and γ-aminopropyltriethoxy diethoxy silane or more than one combination.
Preferably, described vegetable oil is soybean oil, rapeseed oil, cottonseed oil, rice bran oil, corn oil, sunflower oil, peanut
Any one in oil or more than one combination.
Preferably, described hydrophobic oleophilic oil nano particle is nano silicon, nano zirconium dioxide, nano-lanthanum fluoride
In one or more than one kinds of mixtures.
Preferably, the making step of described hydrophobic oleophilic oil nano particle is:By 1-5 parts nano particle, 1-2 part octadecanes
Base trichlorosilane, 30-50 part solvents are added in reactor at 40-100 DEG C and react 1-10h, after the cooling of question response product, subtract
Press filtration product simultaneously dries 10-30h at room temperature, and screening of then milling is final to obtain hydrophobic oleophilic oil water nano particle.
Preferably, described solvent is one or more kinds of groups in normal heptane, isopropanol, n-butanol, ethylene glycol
Close.
Preferably, according to parts by weight, it is prepared from the following components:5 parts of butyl methacrylate, 2 parts of laurate, plant
5 parts of thing oil, 10 parts of styrene, 1 part of hydrophobic oleophilic oil nano particle, 10 parts of beeswax, 1 part of silane coupler, 50 parts of n-hexane.
Preferably, according to parts by weight, it is prepared from the following components:8 parts of butyl methacrylate, 3 parts of laurate, plant
8 parts of thing oil, 15 parts of styrene, 3 parts of hydrophobic oleophilic oil nano particle, 15 parts of beeswax, 2 parts of silane coupler, 75 parts of n-hexane.
Preferably, according to parts by weight, it is prepared from the following components:10 parts of butyl methacrylate, 4 parts of laurate,
10 parts of vegetable oil, 20 parts of styrene, 5 parts of hydrophobic oleophilic oil nano particle, 20 parts of beeswax, 3 parts of silane coupler, 100 parts of n-hexane.
Preferably, a kind of preparation method of fabric hydrophobic oleophilic oil agent, it is characterised in that:Comprise the following steps that:
Step 1,1-5 parts nano particle, 1-2 parts octadecyl trichlorosilane alkane, 30-50 part solvents are added in reactor
1-10h is reacted at 40-100 DEG C, after the cooling of question response product, product is filtered under diminished pressure and dries 10-30h at room temperature, then
Mill screening, it is final to obtain hydrophobic oleophilic oil water nano particle.
Step 2, beeswax 10-20 parts are added in a kettle, are warming up to 80-100 DEG C and are caused beeswax dissolving;
Step 3, n-hexane 50-100 parts, vegetable oil 5-10 parts will be first added, with ultrasonic vibration 10-20 minutes, will be obtained
Even solution;
Step 4, the homogeneous solution of step 3 is added in the solution of step 2,500-1000 revs/min, 20-30 points of stirring
Clock;
Step 5, butyl methacrylate 5-10 parts, styrene 10-20 parts, silane coupler 1-3 parts, 1000- are added
3000 revs/min, stir 20-30 minutes;
Step 6, it is cooled to 20-30 DEG C, adds laurate 2-4 parts, hydrophobic oleophilic oil nano particle 1-5 parts, 500-1000 turns/
Minute, stir 20-30 minutes;
Step 7, stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
Step 8, stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, after fabric hydrophobic oleophilic oil agent application fabric of the invention, the hydrophobic contact angle of fabric reaches more than 130 °, can
To adsorb the oil of more than 5 times of weight itself.
2nd, fabric hydrophobic oleophilic oil agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic
It is harmless, human body is not stimulated, volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
3rd, mutual compatibility, synergy, collectively constituting property between various raw materials used in fabric hydrophobic oleophilic oil agent of the invention
The excellent product of energy.
4th, the addition of beeswax, the fabric oleophylic performance of fabric is improved.
5th, technique is simplified, safe operation is simple, is easy to industrialized production.
6th, fabric hydrophobic oleophilic oil coating construction is simple of the invention, can by impregnating, spraying, roller coat etc. applied,
Production efficiency improves.
7th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of fabric hydrophobic oleophilic oil agent, according to important number, it is prepared from the following components:Methyl-prop
Olefin(e) acid butyl ester 5-10 parts, laurate 2-4 parts, vegetable oil 5-10 parts, styrene 10-20 parts, hydrophobic oleophilic oil nano particle 1-5 parts,
Beeswax 10-20 parts, silane coupler 1-3 parts, n-hexane 50-100 parts.
Present invention also offers a kind of preparation method of fabric hydrophobic oleophilic oil agent, comprise the following steps that:
(1) by 1-5 parts nano particle, 1-2 parts octadecyl trichlorosilane alkane, 30-50 part solvents be added in reactor in
1-10h is reacted at 40-100 DEG C, after the cooling of question response product, product is filtered under diminished pressure and dries 10-30h at room temperature, then grind
Mill screening, it is final to obtain hydrophobic oleophilic oil water nano particle.
(2) beeswax 10-20 parts are added in a kettle, are warming up to 80-100 DEG C and are caused beeswax dissolving;
(3) n-hexane 50-100 parts, vegetable oil 5-10 parts will be first added, with ultrasonic vibration 10-20 minutes, will be obtained uniformly molten
Liquid;
(4) homogeneous solution of step (3) is added in the solution of step (2), 500-1000 revs/min, 20-30 points of stirring
Clock;
(5) butyl methacrylate 5-10 parts, styrene 10-20 parts, silane coupler 1-3 parts, 1000-3000 are added
Rev/min, stir 20-30 minutes;
(6) it is cooled to 20-30 DEG C, adds laurate 2-4 parts, hydrophobic oleophilic oil nano particle 1-5 parts, 500-1000 revs/min
Clock, stir 20-30 minutes;
(7) stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
(8) stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of fabric hydrophobic oleophilic oil agent, according to important number, it is prepared from the following components:Methyl-prop
5 parts of olefin(e) acid butyl ester, 2 parts of laurate, 5 parts of vegetable oil, 10 parts of styrene, 1 part of hydrophobic oleophilic oil nano particle, 10 parts of beeswax, silane
1 part of coupling agent, 50 parts of n-hexane.
Present invention also offers a kind of preparation method of fabric hydrophobic oleophilic oil agent, comprise the following steps that:
(1) 1 part of nano particle, 1 part of octadecyl trichlorosilane alkane, 30 parts of solvents are added in reactor at 40 DEG C instead
1h is answered, after the cooling of question response product, product is filtered under diminished pressure and dries 10h at room temperature, screening of then milling, finally obtain hydrophobic
Oleophylic water nano particle.
(2) 10 parts of beeswax is added in a kettle, is warming up to 80 DEG C and is caused beeswax dissolving;
(3) 50 parts of n-hexane, 5 parts of vegetable oil will be first added, with ultrasonic vibration 10 minutes, obtains homogeneous solution;
(4) homogeneous solution of step (3) is added in the solution of step (2), 500 revs/min, stirred 20 minutes;
(5) 5 parts of butyl methacrylate, 10 parts of styrene, 1 part of silane coupler are added, 1000 revs/min, stirs 20
Minute;
(6) 20 DEG C are cooled to, 2 parts of laurate, 1 part of hydrophobic oleophilic oil nano particle is added, 500 revs/min, stirs 20 points
Clock;
(7) stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
(8) stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of fabric hydrophobic oleophilic oil agent, according to important number, it is prepared from the following components:Methyl-prop
8 parts of olefin(e) acid butyl ester, 3 parts of laurate, 8 parts of vegetable oil, 15 parts of styrene, 3 parts of hydrophobic oleophilic oil nano particle, 15 parts of beeswax, silane
2 parts of coupling agent, 75 parts of n-hexane.
Present invention also offers a kind of preparation method of fabric hydrophobic oleophilic oil agent, comprise the following steps that:
(1) 3 parts of nano particles, 1.5 parts of octadecyl trichlorosilane alkanes, 40 parts of solvents are added in reactor at 70 DEG C
6h is reacted, after the cooling of question response product, product is filtered under diminished pressure and dries 20h at room temperature, screening of then milling, finally dredged
Water oleophylic water nano particle.
(2) 15 parts of beeswax is added in a kettle, is warming up to 90 DEG C and is caused beeswax dissolving;
(3) 75 parts of n-hexane, 8 parts of vegetable oil will be first added, with ultrasonic vibration 15 minutes, obtains homogeneous solution;
(4) homogeneous solution of step (3) is added in the solution of step (2), 750 revs/min, stirred 25 minutes;
(5) 8 parts of butyl methacrylate, 15 parts of styrene, 2 parts of silane coupler are added, 2000 revs/min, stirs 25
Minute;
(6) 25 DEG C are cooled to, 3 parts of laurate, 3 parts of hydrophobic oleophilic oil nano particle is added, 750 revs/min, stirs 25 points
Clock;
(7) stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
(8) stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of fabric hydrophobic oleophilic oil agent, according to important number, it is prepared from the following components:Methyl-prop
10 parts of olefin(e) acid butyl ester, 4 parts of laurate, 10 parts of vegetable oil, 20 parts of styrene, 5 parts of hydrophobic oleophilic oil nano particle, 20 parts of beeswax, silicon
3 parts of alkane coupling agent, 100 parts of n-hexane.
Present invention also offers a kind of preparation method of fabric hydrophobic oleophilic oil agent, comprise the following steps that:
(1) 5 parts of nano particles, 2 parts of octadecyl trichlorosilane alkanes, 50 parts of solvents are added in reactor at 100 DEG C
10h is reacted, after the cooling of question response product, product is filtered under diminished pressure and dries 30h at room temperature, screening of then milling is final to obtain
Hydrophobic oleophilic oil water nano particle.
(2) 20 parts of beeswax is added in a kettle, is warming up to 100 DEG C and is caused beeswax dissolving;
(3) 100 parts of n-hexane, 10 parts of vegetable oil will be first added, with ultrasonic vibration 20 minutes, obtains homogeneous solution;
(4) homogeneous solution of step (3) is added in the solution of step (2), 1000 revs/min, stirred 30 minutes;
(5) 10 parts of butyl methacrylate, 20 parts of styrene, 3 parts of silane coupler are added, 3000 revs/min, stirs 30
Minute;
(6) 30 DEG C are cooled to, 4 parts of laurate, 5 parts of hydrophobic oleophilic oil nano particle is added, 1000 revs/min, stirs 30 points
Clock;
(7) stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
(8) stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of fabric hydrophobic oleophilic oil agent, according to important number, it is prepared from the following components:Methyl-prop
10 parts of olefin(e) acid butyl ester, 3 parts of laurate, 8 parts of vegetable oil, 10 parts of styrene, 4 parts of hydrophobic oleophilic oil nano particle, 10 parts of beeswax, silane
2 parts of coupling agent, 80 parts of n-hexane.
Present invention also offers a kind of preparation method of fabric hydrophobic oleophilic oil agent, comprise the following steps that:
(1) 4 parts of nano particles, 2 parts of octadecyl trichlorosilane alkanes, 40 parts of solvents are added in reactor at 60 DEG C instead
8h is answered, after the cooling of question response product, product is filtered under diminished pressure and dries 20h at room temperature, screening of then milling, finally obtain hydrophobic
Oleophylic water nano particle.
(2) 10 parts of beeswax is added in a kettle, is warming up to 85 DEG C and is caused beeswax dissolving;
(3) 80 parts of n-hexane, 8 parts of vegetable oil will be first added, with ultrasonic vibration 15 minutes, obtains homogeneous solution;
(4) homogeneous solution of step (3) is added in the solution of step (2), 1000 revs/min, stirred 20 minutes;
(5) 10 parts of butyl methacrylate, 10 parts of styrene, 2 parts of silane coupler are added, 2000 revs/min, stirs 20
Minute;
(6) 20 DEG C are cooled to, 3 parts of laurate, 4 parts of hydrophobic oleophilic oil nano particle is added, 1000 revs/min, stirs 25 points
Clock;
(7) stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;
(8) stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Test case
4 pieces of identical pure cotton cloths are put into the hydrophobic oleophilic oil solution of embodiment 1,2,3,4, roll, dry by two leachings two,
Bake, wash, drying, 4 pieces of cloth with hydrophobic oleophilic oil performance can be obtained.Test result is as follows:
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
- A kind of 1. fabric hydrophobic oleophilic oil agent, it is characterised in that:The fabric hydrophobic oleophilic oil agent includes the raw material of following parts by weight: Butyl methacrylate 5-10 parts, laurate 2-4 parts, vegetable oil 5-10 parts, styrene 10-20 parts, hydrophobic oleophilic oil nano particle 1-5 parts, beeswax 10-20 parts, silane coupler 1-3 parts, n-hexane 50-100 parts.
- 2. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:Described silane coupler is 3- aminopropyls Trimethoxy silane, γ-(oxygen of 2,3- epoxies third) propyl-triethoxysilicane, γ-methacryloxypropyl trimethoxy Silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, aniline isophorone and γ-aminopropyltriethoxy diethoxy Any one in silane or more than one combination.
- 3. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:Described vegetable oil is soybean oil, vegetable seed Any one in oil, cottonseed oil, rice bran oil, corn oil, sunflower oil, peanut oil or more than one combination.
- 4. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:Described hydrophobic oleophilic oil nano particle is to receive One or more than one kinds of mixtures in rice silica, nano zirconium dioxide, nano-lanthanum fluoride.
- 5. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:The system of described hydrophobic oleophilic oil nano particle It is as step:1-5 parts nano particle, 1-2 parts octadecyl trichlorosilane alkane, 30-50 part solvents are added in reactor in 40- 1-10h is reacted at 100 DEG C, after the cooling of question response product, product is filtered under diminished pressure and dries 10-30h, sieve of then milling at room temperature Point, it is final to obtain hydrophobic oleophilic oil water nano particle.
- 6. fabric hydrophobic oleophilic oil agent according to claim 5, it is characterised in that:Described solvent be normal heptane, isopropanol, One or more kinds of combinations in n-butanol, ethylene glycol.
- 7. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:According to parts by weight, by following components system It is standby to form:5 parts of butyl methacrylate, 2 parts of laurate, 5 parts of vegetable oil, 10 parts of styrene, 1 part of hydrophobic oleophilic oil nano particle, 10 parts of beeswax, 1 part of silane coupler, 50 parts of n-hexane.
- 8. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:According to parts by weight, by following components system It is standby to form:8 parts of butyl methacrylate, 3 parts of laurate, 8 parts of vegetable oil, 15 parts of styrene, 3 parts of hydrophobic oleophilic oil nano particle, 15 parts of beeswax, 2 parts of silane coupler, 75 parts of n-hexane.
- 9. fabric hydrophobic oleophilic oil agent according to claim 1, it is characterised in that:According to parts by weight, by following components system It is standby to form:10 parts of butyl methacrylate, 4 parts of laurate, 10 parts of vegetable oil, 20 parts of styrene, hydrophobic oleophilic oil nano particle 5 Part, 20 parts of beeswax, 3 parts of silane coupler, 100 parts of n-hexane.
- 10. the preparation method of any described fabric hydrophobic oleophilic oil agent, its feature exist in a kind of 1-10 using the claims In:Comprise the following steps that:Step 1, by 1-5 parts nano particle, 1-2 parts octadecyl trichlorosilane alkane, 30-50 part solvents be added in reactor in 1-10h is reacted at 40-100 DEG C, after the cooling of question response product, product is filtered under diminished pressure and dries 10-30h at room temperature, then grind Mill screening, it is final to obtain hydrophobic oleophilic oil water nano particle.Step 2, beeswax 10-20 parts are added in a kettle, are warming up to 80-100 DEG C and are caused beeswax dissolving;Step 3, n-hexane 50-100 parts, vegetable oil 5-10 parts will be first added, with ultrasonic vibration 10-20 minutes, will be obtained uniformly molten Liquid;Step 4, the homogeneous solution of step 3 is added in the solution of step 2,500-1000 revs/min, stirs 20-30 minutes;Step 5, addition butyl methacrylate 5-10 parts, styrene 10-20 parts, silane coupler 1-3 parts, 1000-3000 turns/ Minute, stir 20-30 minutes;Step 6, it is cooled to 20-30 DEG C, adds laurate 2-4 parts, hydrophobic oleophilic oil nano particle 1-5 parts, 500-1000 revs/min Clock, stir 20-30 minutes;Step 7, stirring is closed down, the liquid fabric hydrophobic oleophilic oil agent prepared;Step 8, stand and be cooled in stirred tank the agent of liquid fabric hydrophobic oleophilic oil and be less than 20 DEG C, blowing encapsulation, finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710655183.4A CN107558201A (en) | 2017-08-03 | 2017-08-03 | A kind of preparation method of fabric hydrophobic oleophilic oil agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710655183.4A CN107558201A (en) | 2017-08-03 | 2017-08-03 | A kind of preparation method of fabric hydrophobic oleophilic oil agent |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107558201A true CN107558201A (en) | 2018-01-09 |
Family
ID=60975204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710655183.4A Pending CN107558201A (en) | 2017-08-03 | 2017-08-03 | A kind of preparation method of fabric hydrophobic oleophilic oil agent |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107558201A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105780468A (en) * | 2016-03-28 | 2016-07-20 | 北京易净星科技有限公司 | Super-hydrophobic fabric and preparation method thereof |
CN105970610A (en) * | 2016-05-27 | 2016-09-28 | 黑龙江泰纳科技发展股份有限公司 | Nano-composite fluoride-free waterproof fabric finishing agent and preparation method and application thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
-
2017
- 2017-08-03 CN CN201710655183.4A patent/CN107558201A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105780468A (en) * | 2016-03-28 | 2016-07-20 | 北京易净星科技有限公司 | Super-hydrophobic fabric and preparation method thereof |
CN105970610A (en) * | 2016-05-27 | 2016-09-28 | 黑龙江泰纳科技发展股份有限公司 | Nano-composite fluoride-free waterproof fabric finishing agent and preparation method and application thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103980530A (en) | Method for preparing seaweed cellulose aerogel oil absorption material | |
CN103290733B (en) | A kind of attapulgite modified dehumidifying wallpaper | |
CN110528269A (en) | A kind of preparation method of vine polyphenol modified hydrophobic cotton fabric | |
CN110629554A (en) | Preparation of cotton hydrophilic softening agent used in high-temperature cylinder | |
CN106916515A (en) | A kind of Functional Powder Coating and preparation method thereof | |
CN105755834A (en) | Novel washable flame-retardant coating and preparation method thereof | |
CN113426430A (en) | Intelligent oil-water separation material and preparation method and application thereof | |
CN105133318A (en) | Silicone-modified mudar floss oil absorption material | |
CN107042088A (en) | Preparation method for the modified bentonite adsorbent of waste water decoloration of cation dyes | |
CN108265517A (en) | A kind of preparation method of fold resistant polytetrafluoroethylene (PTFE)/glass fibre membrane material | |
CN107558201A (en) | A kind of preparation method of fabric hydrophobic oleophilic oil agent | |
CN106633112B (en) | A kind of super oleophilic drainage material and the preparation method and application thereof | |
CN105664869B (en) | A kind of lauroylamidopropyl betaine is modified the preparation of palm bark adsorbent | |
CN104032567A (en) | Waterproof agent for textile | |
WO2019006940A1 (en) | Artificial compound staining agent for textiles and preparation method therefor | |
CN108939692B (en) | A kind of super-hydrophobic coat and preparation method thereof for water-oil separating | |
CN105970617A (en) | Textile waterproofing agent and preparation method thereof | |
CN109403070B (en) | Preparation method of radiation-proof heat-preservation composite fabric based on double-sided heterochromatic digital printing | |
CN109610031B (en) | Preparation of biomass carbon-doped nanofiber felt and application of biomass carbon-doped nanofiber felt in separation of oil-water mixture | |
CN107541947A (en) | A kind of preparation method of fabric hydrophilic oleophobic agent | |
CN108084863A (en) | A kind of preparation method of waterborne polyurethane for synthetic leather surface conditioning agent | |
CN111945424B (en) | Novel phosphorus-free cold reactor pretreatment auxiliary agent and application thereof | |
Tarapitakcheevin et al. | Adsorption of acid dye on activated carbon prepared from water hyacinth by sodium chloride activation | |
CN111286999B (en) | Silk floss dyeing method based on metarhizium anisopliae spore powder | |
CN114106288A (en) | Preparation method and application of waterborne polyurethane dispersant |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180109 |
|
RJ01 | Rejection of invention patent application after publication |