CN107557504A - A kind of leather and fur products environmentally friendly jasmine fragrance Antisepticize and mildew preventive and preparation method thereof - Google Patents

A kind of leather and fur products environmentally friendly jasmine fragrance Antisepticize and mildew preventive and preparation method thereof Download PDF

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Publication number
CN107557504A
CN107557504A CN201710771769.7A CN201710771769A CN107557504A CN 107557504 A CN107557504 A CN 107557504A CN 201710771769 A CN201710771769 A CN 201710771769A CN 107557504 A CN107557504 A CN 107557504A
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China
Prior art keywords
parts
leather
antisepticize
mildew preventive
environmentally friendly
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CN201710771769.7A
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Chinese (zh)
Inventor
龚晓东
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Taicang Xiongying Leather Product Co Ltd
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Taicang Xiongying Leather Product Co Ltd
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Priority to CN201710771769.7A priority Critical patent/CN107557504A/en
Publication of CN107557504A publication Critical patent/CN107557504A/en
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Abstract

The invention discloses a kind of leather and fur products environmentally friendly jasmine fragrance Antisepticize and mildew preventive and preparation method thereof, the Antisepticize and mildew preventive includes the composition of following parts by weight:Palm wax, OIT, mould inhibitor, refined jasmine oil, polymethyl siloxane, neopelex, sorbic acid, phenol, dimethicone, vinylacetate, hydroxyethyl cellulose, antistatic additive, antioxidant, plasticizer, deionized water.The mould inhibitor is efficient, safety, wide spectrum, and being spun suitable for later stage product handling system prevents from going mouldy, and is widely used in the surface spraying fungus-resistant such as leather shoes, leather sofa, suitcase, fur clothing, leather glove, Animal Skin, artificial leather are general, do not injure surface and color.

Description

A kind of leather and fur products environmentally friendly jasmine fragrance Antisepticize and mildew preventive and preparation method thereof
Technical field
The invention belongs to leather surface processing technology field, and in particular to a kind of environmentally friendly jasmine fragrance anti-corrosion of leather and fur products Mould inhibitor and preparation method thereof.
Background technology
Leather is through the not perishable Animal Skin of denaturation obtained by physics, the chemical process such as depilation and tanning.Leather It is made up of natural protein fibre in three dimensions close weave, there is a kind of special grain layer on its surface, has nature Graining and gloss, comfortable feel.
Commercially popular leather and fur products has corium and the major class of dermatine two, and synthetic leather and artificial leather are by weaving Cloth base or non-woven fabrics base, redoubling is applied using made of special foaming processing with polyurethane respectively, has Surface feel to exactly like very Skin, but gas permeability, wearability, cold resistance are all not so good as corium.
Leather industry covers the main body industry such as process hides, shoemaking, fur clothing, leather goods, fur and its product, and leather The supporting industries such as work, leather hardware, leather machine, auxiliary material.The upstream and downstream degree of association is high, is pulled by market, and product is evergreen, collection wound Converge, enrich people, the characteristics of being integrated of obtaining employment.
Chinese leather industry, optimization structure is adjusted, it is clear and definite, special that a collection of division of labor based on specialization has been preliminarily formed in the whole nation Color is prominent, produces characteristic region and specialized market to the leather for pulling local economy to play very important effect.Their formation, The basis of Chinese leather industry development is established.
In the market environment of competition, it is not easy that Chinese leather industry can obtain such achievement, also thus demonstrate,proves Understand Chinese leather industry vitality it is vigorous with it is powerful.The market potential of leather and leather products is very big, and global leather always needs The amount of asking is about 1.0 hundred million square metres, equivalent to 300,000,000 ox-hides(Standard skin)Yield, it is near that Chinese leather yield converts into standard skin 70000000, account for the 23.33% of global leather yield.But the enterprise of Chinese leather shoemaking and its related industry also should be just Depending on to, 21 century we at many aspects there is also weak point, although China is leather big producer in the world, be not Leather is made the country prosperous, still in weak position, it is necessary to be tempered and changed in overall situation in this market in terms of quality, the value Enter.
Real leather products in humid environment, animal body dirt and temperature height be present under conditions of, often due to mould and ferment The growth of female bacterium, it is severely impacted its quality.Growth of the mould on leather, the lighter can make leather tarnish, severe one The enzyme of mould secretion, can corrode leather fiber, cause grain embrittlement and go rotten, make the physical and mechanical properties of leather reduce, shorten The service life of real leather products.
Existing leather fungicide is to form main body by new high-molecular organic material, in addition also certain aromatic and Leather surface smoothing preparation forms.Main mould inhibitor species be respectively n- dichloroethylene salicylamide and N- octyl group -4- isothiazolines - 3- ketone.
For leather fungicide, the current country is primarily present following patent document:
Publication No. 106834566A Chinese patent discloses a kind of Leather mildew-proof care agent.Include the group of following mass parts Point:Candelila wax 18-22 parts, beeswax 12-16 parts, tea oil 10-12 parts, hydrogenated vegetable oil 5-7 parts, animal oil 5-7 parts, poly- first Radical siloxane 5-7 parts, OTAC 3-5 parts, mould inhibitor 1-3 parts, antistatic additive 1-3 parts, water 30-40 parts; The mould inhibitor is that N- (2,2- dichloroethylene) is in salicylamide, N- octyl group -4- isothiazoline -3- ketone, nano zine oxide It is at least one.The Leather mildew-proof care agent of the present invention, formula is gentle, has preferable vadose solution clean effect, addition tea oil, hydrogen Change vegetable oil, animal oil, while decontamination, strengthen the nourishing to leather, improve water resistance, the elasticity of leather;N- (2,2- bis- Vinyl chloride) the mould proof effect of leather can be significantly improved for salicylamide, N- octyl group -4- isothiazoline -3- ketone, nano zine oxide Fruit, increase the storage-stable of leather.
The content of the invention
To solve above-mentioned problem, prevented it is an object of the invention to provide a kind of leather and fur products with environmentally friendly jasmine fragrance Rotten mould inhibitor and preparation method thereof, the mould inhibitor is efficient, safety, wide spectrum, and being spun suitable for later stage product handling system prevents from going mouldy, extensively General to be used for the surface spraying fungus-resistants such as leather shoes, leather sofa, suitcase, fur clothing, leather glove, Animal Skin, artificial leather are general, do not injure Surface and color.
To reach above-mentioned purpose, the technical scheme is that:
A kind of leather and fur products includes the composition of following parts by weight with environmentally friendly jasmine fragrance Antisepticize and mildew preventive, the Antisepticize and mildew preventive: Palm wax:20 ~ 30 parts, OIT:5 ~ 10 parts, mould inhibitor:5 ~ 10 parts, refined jasmine oil:15 ~ 25 parts, polymethyl siloxane: 10 ~ 15 parts, neopelex:5 ~ 10 parts, sorbic acid:1 ~ 5 part, phenol:5 ~ 10 parts, dimethicone:5 ~ 10 parts, vinegar Vinyl acetate:5 ~ 10 parts, hydroxyethyl cellulose:10 ~ 20 parts, antistatic additive:1 ~ 5 part, antioxidant:5 ~ 10 parts, plasticizer:1~5 Part, deionized water:30 ~ 40 parts.
Further, the Antisepticize and mildew preventive includes the composition of following parts by weight:Palm wax:20 ~ 25 parts, OIT:5 ~ 7 parts, mould inhibitor:6 ~ 10 parts, refined jasmine oil:15 ~ 20 parts, polymethyl siloxane:13 ~ 15 parts, neopelex:5~8 Part, sorbic acid:3 ~ 5 parts, phenol:7 ~ 10 parts, dimethicone:5 ~ 8 parts, vinylacetate:6 ~ 10 parts, hydroxyethyl cellulose: 10 ~ 15 parts, antistatic additive:1 ~ 3 part, antioxidant:7 ~ 10 parts, plasticizer:3 ~ 5 parts, deionized water:35 ~ 40 parts.
Preferably, the Antisepticize and mildew preventive includes the composition of following parts by weight:Palm wax:25 parts, OIT:7 parts, Mould inhibitor:8 parts, refined jasmine oil:20 parts, polymethyl siloxane:14 parts, neopelex:5 parts, sorbic acid:3 parts, benzene Phenol:7 parts, dimethicone:8 parts, vinylacetate:6 parts, hydroxyethyl cellulose:15 parts, antistatic additive:2 parts, antioxidant:8 Part, plasticizer:4 parts, deionized water:35 parts.
Preferably, the plasticizer is dibutyl phthalate.
Preferably, the antistatic additive is ethoxylated alkyl acid amide.
Preferably, the mould inhibitor is ethoxyquinoline or nano zine oxide.
Preferably, the antioxidant is butylated hydroxy anisole.
It is described meanwhile the present invention also provides a kind of preparation method of leather and fur products with environmentally friendly jasmine fragrance Antisepticize and mildew preventive Preparation method comprises the following steps:Mixer is taken, by palm wax, OIT, refined jasmine oil, dimethicone, poly- methyl The deionized water order of siloxanes, mould inhibitor and 50wt% adds mixer, is stirred 1 ~ 2 hour at 40 ~ 50 DEG C, mixing speed 500 ~ 600 revs/min;By neopelex, sorbic acid, phenol, vinylacetate, hydroxyethyl cellulose, antistatic additive, Antioxidant, plasticizer and remaining deionized water add mixer, are warming up to 60 ~ 70 DEG C, are stirred under 800 ~ 1000 revs/min of rotating speed Mix 0.5 ~ 1.5 hour, be cooled to room temperature, filter, produce the leather and fur products with environmentally friendly jasmine fragrance Antisepticize and mildew preventive.
The invention has the advantages that:
The mould inhibitor is efficient, safety, wide spectrum, and being spun suitable for later stage product handling system prevents from going mouldy, and is widely used in leather shoes, Pi Sha The surface spraying fungus-resistant such as hair, suitcase, fur clothing, leather glove, Animal Skin, artificial leather are general, do not injure surface and color.
There is extremely strong suppression to kill ability mould, bacterium, do not produce drug resistance, mould proof cycle length.
It is non-volatile, environment is had no effect.
PH accommodations are wide, there is suppression bactericidal effect between pH2 ~ 8.
Easy to operate, good fluidity and nonflammable.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention Scope.
A kind of leather and fur products provided by the present invention is included with environmentally friendly jasmine fragrance Antisepticize and mildew preventive, the Antisepticize and mildew preventive The composition of following parts by weight:Palm wax:20 ~ 30 parts, OIT:5 ~ 10 parts, mould inhibitor:5 ~ 10 parts, refined jasmine oil:15~ 25 parts, polymethyl siloxane:10 ~ 15 parts, neopelex:5 ~ 10 parts, sorbic acid:1 ~ 5 part, phenol:5 ~ 10 parts, two Methyl-silicone oil:5 ~ 10 parts, vinylacetate:5 ~ 10 parts, hydroxyethyl cellulose:10 ~ 20 parts, antistatic additive:1 ~ 5 part, antioxidant: 5 ~ 10 parts, plasticizer:1 ~ 5 part, deionized water:30 ~ 40 parts.
Further, the Antisepticize and mildew preventive includes the composition of following parts by weight:Palm wax:20 ~ 25 parts, OIT:5 ~ 7 parts, mould inhibitor:6 ~ 10 parts, refined jasmine oil:15 ~ 20 parts, polymethyl siloxane:13 ~ 15 parts, neopelex:5~8 Part, sorbic acid:3 ~ 5 parts, phenol:7 ~ 10 parts, dimethicone:5 ~ 8 parts, vinylacetate:6 ~ 10 parts, hydroxyethyl cellulose: 10 ~ 15 parts, antistatic additive:1 ~ 3 part, antioxidant:7 ~ 10 parts, plasticizer:3 ~ 5 parts, deionized water:35 ~ 40 parts.
Preferably, the Antisepticize and mildew preventive includes the composition of following parts by weight:Palm wax:25 parts, OIT:7 parts, Mould inhibitor:8 parts, refined jasmine oil:20 parts, polymethyl siloxane:14 parts, neopelex:5 parts, sorbic acid:3 parts, benzene Phenol:7 parts, dimethicone:8 parts, vinylacetate:6 parts, hydroxyethyl cellulose:15 parts, antistatic additive:2 parts, antioxidant:8 Part, plasticizer:4 parts, deionized water:35 parts.
Preferably, the plasticizer is dibutyl phthalate.
Preferably, the antistatic additive is ethoxylated alkyl acid amide.
Preferably, the mould inhibitor is ethoxyquinoline or nano zine oxide.
Preferably, the antioxidant is butylated hydroxy anisole.
It is described meanwhile the present invention also provides a kind of preparation method of leather and fur products with environmentally friendly jasmine fragrance Antisepticize and mildew preventive Preparation method comprises the following steps:Mixer is taken, by palm wax, OIT, refined jasmine oil, dimethicone, poly- methyl The deionized water order of siloxanes, mould inhibitor and 50wt% adds mixer, is stirred 1 ~ 2 hour at 40 ~ 50 DEG C, mixing speed 500 ~ 600 revs/min;By neopelex, sorbic acid, phenol, vinylacetate, hydroxyethyl cellulose, antistatic additive, Antioxidant, plasticizer and remaining deionized water add mixer, are warming up to 60 ~ 70 DEG C, are stirred under 800 ~ 1000 revs/min of rotating speed Mix 0.5 ~ 1.5 hour, be cooled to room temperature, filter, produce the leather and fur products with environmentally friendly jasmine fragrance Antisepticize and mildew preventive.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention In sharp claimed range.

Claims (8)

1. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of a kind of leather and fur products, it is characterised in that the Antisepticize and mildew preventive includes as follows The composition of parts by weight:Palm wax:20 ~ 30 parts, OIT:5 ~ 10 parts, mould inhibitor:5 ~ 10 parts, refined jasmine oil:15 ~ 25 parts, Polymethyl siloxane:10 ~ 15 parts, neopelex:5 ~ 10 parts, sorbic acid:1 ~ 5 part, phenol:5 ~ 10 parts, dimethyl Silicone oil:5 ~ 10 parts, vinylacetate:5 ~ 10 parts, hydroxyethyl cellulose:10 ~ 20 parts, antistatic additive:1 ~ 5 part, antioxidant:5~10 Part, plasticizer:1 ~ 5 part, deionized water:30 ~ 40 parts.
2. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that the anti-corrosion Mould inhibitor includes the composition of following parts by weight:Palm wax:20 ~ 25 parts, OIT:5 ~ 7 parts, mould inhibitor:6 ~ 10 parts, jasmine Essential oil:15 ~ 20 parts, polymethyl siloxane:13 ~ 15 parts, neopelex:5 ~ 8 parts, sorbic acid:3 ~ 5 parts, phenol:7~ 10 parts, dimethicone:5 ~ 8 parts, vinylacetate:6 ~ 10 parts, hydroxyethyl cellulose:10 ~ 15 parts, antistatic additive:1 ~ 3 part, Antioxidant:7 ~ 10 parts, plasticizer:3 ~ 5 parts, deionized water:35 ~ 40 parts.
3. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that the anti-corrosion Mould inhibitor includes the composition of following parts by weight:Palm wax:25 parts, OIT:7 parts, mould inhibitor:8 parts, refined jasmine oil:20 Part, polymethyl siloxane:14 parts, neopelex:5 parts, sorbic acid:3 parts, phenol:7 parts, dimethicone:8 parts, Vinylacetate:6 parts, hydroxyethyl cellulose:15 parts, antistatic additive:2 parts, antioxidant:8 parts, plasticizer:4 parts, deionized water: 35 parts.
4. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that the plasticising Agent is dibutyl phthalate.
5. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that described anti-quiet Electric agent is ethoxylated alkyl acid amide.
6. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that described mould proof Agent is ethoxyquinoline or nano zine oxide.
7. the environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products according to claim 1, it is characterised in that the antioxygen Agent is butylated hydroxy anisole.
A kind of 8. preparation side of environmentally friendly jasmine fragrance Antisepticize and mildew preventive of leather and fur products as any one of claim 1 ~ 7 Method, it is characterised in that the preparation method comprises the following steps:Take mixer, by palm wax, OIT, refined jasmine oil, Dimethicone, polymethyl siloxane, mould inhibitor and 50wt% deionized water order add mixer, are stirred at 40 ~ 50 DEG C 1 ~ 2 hour, 500 ~ 600 revs/min of mixing speed;By neopelex, sorbic acid, phenol, vinylacetate, ethoxy Cellulose, antistatic additive, antioxidant, plasticizer and remaining deionized water add mixer, are warming up to 60 ~ 70 DEG C, 800 ~ Stirred 0.5 ~ 1.5 hour under 1000 revs/min of rotating speed, be cooled to room temperature, filtered, it is fragrant with environmentally friendly jasmine to produce the leather and fur products Type Antisepticize and mildew preventive.
CN201710771769.7A 2017-08-31 2017-08-31 A kind of leather and fur products environmentally friendly jasmine fragrance Antisepticize and mildew preventive and preparation method thereof Withdrawn CN107557504A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108484874A (en) * 2018-03-23 2018-09-04 惠州市远安新材料有限公司 A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017898A (en) * 2014-04-22 2015-11-04 王志龙 High-grade coating product for protecting and maintaining leather and production method of high-grade coating product
CN105199609A (en) * 2015-10-09 2015-12-30 湖北穆兰同大科技有限公司 Leather care agent and preparation method thereof
CN105885607A (en) * 2016-06-29 2016-08-24 施美 Leather maintaining finishing agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017898A (en) * 2014-04-22 2015-11-04 王志龙 High-grade coating product for protecting and maintaining leather and production method of high-grade coating product
CN105199609A (en) * 2015-10-09 2015-12-30 湖北穆兰同大科技有限公司 Leather care agent and preparation method thereof
CN105885607A (en) * 2016-06-29 2016-08-24 施美 Leather maintaining finishing agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108484874A (en) * 2018-03-23 2018-09-04 惠州市远安新材料有限公司 A kind of polyurethane material, high-elastic Antibacterial polyurethane class powder puff and preparation method thereof

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Application publication date: 20180109