CN107556990B - It is a kind of to strengthen the organic salt drilling fluid inhibited with sealing characteristics - Google Patents

It is a kind of to strengthen the organic salt drilling fluid inhibited with sealing characteristics Download PDF

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CN107556990B
CN107556990B CN201710853838.9A CN201710853838A CN107556990B CN 107556990 B CN107556990 B CN 107556990B CN 201710853838 A CN201710853838 A CN 201710853838A CN 107556990 B CN107556990 B CN 107556990B
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drilling fluid
organic salt
strengthen
sealing characteristics
inhibited
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CN107556990A (en
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陈安亮
张现斌
张民立
苏君
黄达全
张向明
杨鹏梅
龙涛
魏尽然
刘国
龚纯武
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China National Petroleum Corp
CNPC Bohai Drilling Engineering Co Ltd
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CNPC Bohai Drilling Engineering Co Ltd
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Abstract

The present invention provides a kind of organic salt drilling fluids strengthened and inhibited with sealing characteristics, inhibit sealing agent, 1-4% nanometers of sealing agents, the fluorocarbon alcohol of 0.2-0.5%, 0.5-2.5% polymeric alcohol, 0.5-1% inhibitor polyetheramine, 1-2% crystalline flake graphite, the superfine light calcium carbonate of 3-5%, 190-260% barite including 2-4% antisaline soil, the soda ash of 0.3-0.5%, 30-60% organic salt, 0.2-0.5% extracting and cutting agent, 0.5-2% fluid loss additive, 1-4%;The above percentage composition is in terms of the mass content of water.It is weaker to the shut-off capacity of mud shale microcrack that the drilling fluid solves conventional organic salt drilling fluid, the undesirable problem of surface hydration rejection, there is good inhibition and seal-off effect under the conditions of boring and meeting shale, mudstone stratum, can satisfy requirement of the unconventional oil and gas well construction to water-base drilling fluid.

Description

It is a kind of to strengthen the organic salt drilling fluid inhibited with sealing characteristics
Technical field
The invention belongs to oil drilling drilling liquid technology fields, and in particular to a kind of organic salt drilling fluid.
Background technique
On long terms, energy relative shortage will be a great difficult problem that China faces.It is supplied in conventional energy resource increasingly tight In the case where, rational exploitation and utilization unconventional energy resource resource is extremely urgent, and in unconventional energy resource, shale gas resource reserve is rich Richness has biggish potentiality to be exploited, however, China is still at an early stage to the development and utilization of shale gas, experience is deficient, technology Immature, policy is left to be desired.Generally there is the mud shale stratum in China high shale content, stratification development, microcrack to develop Feature, exploration and development process be easy to cause borehole well instability, " blood " of the drilling fluid as drilling engineering, and the performance of drilling fluid is right The exploitation success or failure of the unconventional energy resource such as shale gas are most important.
Shale gas drilling well can use oil base drilling fluid and synthetic base drilling fluid, can also use strong rejection capability water-based drilling Liquid, key are to ensure that wellbore stability, lubrication, the cleaning of anti-sticking and wellbore.Country's shale gas drilling well mainly uses oil base to bore at present Well liquid for environmental protection pressure and reduces cost of exploration & development, also has part shale gas well using high performance water-based drilling fluid.But During exploiting the unconventional energy resource such as shale gas, often there is microcrack in mud shale stratum, drilling fluid filtrate is easy pressing Enter stratum along microcrack under difference effect, the pressure of drilling fluid is transmitted in the earth formation, leads to borehole well instability, this is water-based drilling Liquid facing challenges.
Organic salt drilling fluid system has good inhibition, is the drilling fluid system quickly grown in recent years, organic salt Drilling fluid system, filtrate viscosity is high, water activity is low, advantageously reduces capillary pressure, and water is inhibited to penetrate into shale pore throat and microcrack, Be conducive to wellbore stability.But many shale gas stratum are rich in organic matter, and stratum is caused to have not only hydrophilic but also oleophylic characteristic, table The performance of face aquation outstanding problem, conventional organic salt drilling fluid system, seal-off effect and inhibition surface hydration can't be complete Meet the exploitation demand of the unconventional energy resource such as shale gas, application range is restricted.
Summary of the invention
The purpose of the present invention is to provide a kind of organic salt drilling fluid systems strengthened and inhibited with sealing characteristics, widen organic Salt drilling fluid application range, is suitble to the exploitation of the unconventional energy resource such as shale gas, the drilling fluid system have high inhibition, it is strong block, The features such as resistant to high temperatures, high density, system environmental protection, moderate cost.
The invention is realized by the following technical scheme:
A kind of strengthen inhibits and the organic salt drilling fluid system of sealing characteristics, including 2-4% antisaline soil, 0.3-0.5% Soda ash, 30-60% organic salt, 0.2-0.5% extracting and cutting agent, 0.5-2% fluid loss additive, 1-4% inhibit sealing agent, 1-4% nanometers Sealing agent, the fluorocarbon alcohol of 0.2-0.5%, 0.5-2.5% polymeric alcohol, 0.5-1% polyetheramine, 1-2% crystalline flake graphite, 3-5% Superfine light calcium carbonate, 190-260% barite;The above percentage composition is in terms of the mass content of water.
The antisaline soil is modified meerschaum or attapulgite;
The organic salt is potassium formate and/or sodium formate;
The extracting and cutting agent is xanthan gum, welan gum or chitosan;
The fluid loss additive is carboxymethyl cellulose or polyanion cellulose;
The inhibition sealing agent is albino bitumen, sulfonated gilsonite;
The nanometer sealing agent is that vinyl acetate-ethylene copolymerization closes object lotion, butylbenzene nanoemulsions, polycarbonate nano cream One or more of liquid and surface modified nano silicon.
It is that vinyl acetate-ethylene copolymerization of the partial size in 100-200nm closes object that the vinyl acetate-ethylene copolymerization, which closes object lotion, Lotion;Butylbenzene nanoemulsions are styrene-butadiene emulsion of the partial size in 50-100nm;Polycarbonate nano lotion is partial size in 50-100nm Polycarbonate emulsion;Surface modified nano silicon is silica of the modified partial size in surface in 50-80nm.
The fluorocarbon alcohol is tetrafluoro butanediol, five fluorine propyl alcohol or hexafluoroisopropanol.
The superfine light calcium carbonate is the superfine light calcium carbonate of 600 mesh, 1250 mesh and 2500 mesh according to 1:1-2:1-2 Ratio compounds.
Beneficial effects of the present invention: it is provided by the invention to strengthen the organic salt drilling fluid inhibited with sealing characteristics, due to benefit With fluorocarbon alcohol class surfactant, mud shale surface characteristic can be changed, make angle of wetting close to 90 DEG C, reduce organic salt drilling fluid The interfacial tension between mud shale enhances mud shale surface hydrophobicity oleophobic property, the potent inhibitors such as cooperation polyetheramine, effectively inhibition mud Shale permeates aquation and surface hydration effect, keeps mud shale green strength, maintains wellbore stability.Using micro-nano solid phase material Deng closure, consolidating stratum micropore and microcrack, slow pressure transmitting and filtrate intrusion, the firm borehole wall are hindered, cooperation is used in compounding difference The calcium carbonate superfine powder of partial size further improves its seal-off effect.The drilling fluid system that the present invention is formed has high inhibition, strong closure The characteristics of, the system is more environmentally friendly, at low cost compared to oil base drilling fluid, therefore can be attempted in shale gas horizontal well.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in detail, but example is not as to limit of the invention It is fixed.
Embodiment 1
It is a kind of strengthen inhibit and sealing characteristics organic salt drilling fluid system, including 2% modified meerschaum, 0.3% it is pure Alkali, 60% potassium formate, 0.2% xanthan gum, 2% carboxymethyl cellulose, 1.5% albino bitumen, 1% vinyl acetate-ethylene copolymerization close Object lotion (D50 value be 81nm), 1% nano silica (partial size is in 54nm), 0.2% tetrafluoro butanediol, 0.5% polymeric alcohol, 0.5% polyetheramine, 1% crystalline flake graphite, 3% superfine light calcium carbonate, 190% barite;The above percentage composition is with water Mass content meter.The superfine light calcium carbonate is that 600 mesh, 1250 mesh and 2500 mesh are compounded according to mass ratio 1:1:1.? Drilling fluid is prepared according to mode of the present invention under high-speed stirred.
Embodiment 2
It is a kind of strengthen inhibit and sealing characteristics organic salt drilling fluid system, including 4% attapulgite, 0.4% soda ash, 30% sodium formate, 0.5% welan gum, 0.5-2% polyanion cellulose, 2% sulfonated gilsonite, 2% vinyl acetate-ethylene copolymerization Close object lotion (D50 value is 81nm), 1% styrene-butadiene emulsion (D50 value is 90nm), 0.4% 5 fluorine propyl alcohol, 1.5% polymeric alcohol, 1% Polyetheramine, 2% crystalline flake graphite, 5% superfine light calcium carbonate, 220% barite;The above percentage composition is with the mass content of water Meter.The superfine light calcium carbonate is that 600 mesh, 1250 mesh and 2500 mesh are compounded according to mass ratio 1:1:2.In high-speed stirred Under according to mode of the present invention prepare drilling fluid.
Embodiment 3
It is a kind of strengthen inhibit and sealing characteristics organic salt drilling fluid system, including 3% modified meerschaum, 0.5% it is pure Alkali, 30% potassium formate, 30% sodium formate, 0.4% chitosan, 0.5% carboxymethyl cellulose, 1% polyanion cellulose, 4% Albino bitumen, 1% vinyl acetate-ethylene copolymerization close object lotion (D50 value is 81nm), 1% styrene-butadiene emulsion (D50 value is 90nm), 1% Polycarbonate emulsion (D50 value is 65nm), 1% nano silica (partial size 54nm), 0.4% tetrafluoro butanediol, 2.5% gather Close alcohol, 1% polyetheramine, 2% crystalline flake graphite, 4% superfine light calcium carbonate, 260% barite;The above percentage composition is with water Mass content meter.The superfine light calcium carbonate is that 600 mesh, 1250 mesh and 2500 mesh are compounded according to mass ratio 1:1:1. Drilling fluid is prepared according to mode of the present invention under high velocity agitation.
Embodiment 4
It is a kind of strengthen inhibit and sealing characteristics organic salt drilling fluid system, including 2% attapulgite, 0.3% soda ash, 50% potassium formate, 0.3% xanthan gum, 1% carboxymethyl cellulose, 1% polyanion cellulose, 1% sulfonated gilsonite, 1% poly- carbon Acid esters lotion (D50 value is 65nm), 2% nano silica (partial size 54nm), 0.3% hexafluoroisopropanol, 2.5% polymerization Alcohol, 0.5% polyetheramine, 1% crystalline flake graphite, 4% superfine light calcium carbonate, 260% barite;The above percentage composition is with water Mass content meter.The superfine light calcium carbonate is that 600 mesh, 1250 mesh and 2500 mesh are compounded according to mass ratio 1:2:2.? Drilling fluid is prepared according to mode of the present invention under high-speed stirred.
Embodiment 5
It is a kind of strengthen inhibit and sealing characteristics organic salt drilling fluid system, including 4% modified meerschaum, 0.4% it is pure Alkali, 40% sodium formate, 0.4% welan gum, 2% carboxymethyl cellulose, 4% albino bitumen, 1% styrene-butadiene emulsion (D50 value be 90nm), 1% nano silica (partial size 54nm), 0.2% tetrafluoro butanediol, 2% polymeric alcohol, 1% polyetheramine, 1% crystalline flake graphite, 5% superfine light calcium carbonate, 260% barite;The above percentage composition is in terms of the mass content of water.The superthin light carbonic acid Calcium is that 600 mesh, 1250 mesh and 2500 mesh are compounded according to mass ratio 1:2:2.Under high velocity agitation according to of the present invention Mode prepares drilling fluid.
Comparative example 1
A kind of organic salt drilling fluid system, including 2% modified meerschaum, 0.3% soda ash, 60% potassium formate, 0.2% Huang Virgin rubber, 2% carboxymethyl cellulose, 1.5% albino bitumen, 0.5% polymeric alcohol, 1% crystalline flake graphite, 190% barite;The above percentage Content is in terms of the mass content of water.It is identical as 1 dosage of each component of embodiment, only it is not added with polyetheramine, fluorocarbon alcohol and nanometer envelope Blocking agent.Drilling fluid is prepared according to mode of the present invention under high velocity agitation.
The inhibition of the organic salt drilling fluid system of this patent provides for ease of description strong rejection capability and strong seal-off effect With the effect of seal-off effect, the inhibition to each embodiment and seal-off effect have carried out measuring respectively.
Inhibition experiment
To the drilling fluid system of embodiment 1-5 according to " the industrial gas oil drilling fluid laboratory GB/T 29170-2012 Test " in shale specified in 23 chapters " shale roll recycling test " roll dispersion rate of recovery experimental method, have rated drilling fluid The inhibition of system.The core that experiment uses is derived from Sichuan Changning Weiyuan block Longma small stream group stratum, and experiment hot rolls temperature 130 DEG C, rolling rate of recovery data are as shown in table 2.
To the drilling fluid system of embodiment 1-5, using OFITE 150-80-1 high temperature dynamic linear shale expansion instrument, evaluation Its inhibition.Experiment suppresses artificial core using drilling fluid expansion test bentonite (meeting SY/T 5490-2015), in 25 DEG C of measurement expansion rates.Expansion rate data are as shown in table 2.
Each embodiment shale rolling rate of recovery of table 1
Embodiment Comparative example Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Primary recovery 94.2% 99.0% 98.7% 99.1% 98.8% 99.0%
Secondary returning yield 88.2% 98.7% 98.7% 99.0% 98.8% 98.7%
The rate of recovery three times 79.2% 98.5% 98.5% 98.8% 98.5% 98.6%
Each embodiment expansion rate data of table 2
Embodiment Comparative example Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Expansion rate 26.1% 20.1% 15.0% 10.3% 11.2% 11.9%
The inhibition that can be seen that embodiment 1-5 from Tables 1 and 2 data is significantly stronger than comparative example, it was demonstrated that this patent The organic salt drilling fluid system of the strong rejection capability of offer and strong seal-off effect has excellent inhibition.
Seal-off effect evaluation
To the drilling fluid system of embodiment 1-5 according to " the industrial gas oil drilling fluid scene GB/T16783.1-2014 Test part 1: water-base drilling fluid " determine its high temperature and high pressure filter loss, 130 DEG C of experimental temperature.30min filter loss FL (HTHP) as shown in table 3.
Each embodiment high temperature and high pressure filter loss of table 3
According to " GB/T 29170-2012 industrial gas oil drilling fluid laboratory test ", instrument is blocked using permeability Measure the seal-off effect of the drilling fluid system of embodiment 1-5.The potsherd that filtration media used is 400 millidarcy of permeability is tested, Pressure difference 6.9MPa (1000Psi), records 30min filter loss (V by 130 DEG C of experimental temperaturePPT)。
Each embodiment seal-off effect data of table 4
Embodiment Comparative example Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
VPPT/mL 9.0 5.4 4.8 4.2 4.8 5.0
Pressure transportation experiment.Mud shale permeability is extremely low, and micropore is often filled by water flooding, only a small amount of filtrate intrusion, It can lead to Sidewall Surrounding Rock inner pore pressure to significantly improve, then be superimposed with " pressure transmitting " effect, cause country rock pore pressure to improve, drop Low effective stress supporting role aggravates borehole wall mechanics destabilization problems.Using high temperature and pressure borehole wall stability imitative experimental appliance, into Row pressure transportation experiment, test core is put into core holding unit, is pumped on test fluid body and rock core through upstream test solution entrance End face contact, maintains rock core top pressure 2.0MPa, (drilling fluid), and bottom end initial pressure 1.0MPa (normal saline solution) passes through prison Measuring pressure delivery rate, to evaluate its sealing characteristics.
5 pressure of table transmits data
Consolidated statement 3-5 data, which can be seen that embodiment 1-5, can strengthen the seal-off effect of organic salt drilling fluid, and the present invention mentions The organic salt drilling fluid system of the strong rejection capability of confession and strong seal-off effect has outstanding seal-off effect.In conclusion the present invention provides Strong rejection capability and strong seal-off effect organic salt drilling fluid system inhibition sealing characteristics it is excellent, can further widen organic salt The application range of drilling fluid system can satisfy requirement of the unconventional oil and gas well construction to water-base drilling fluid.
Above embodiments are only the several preferred embodiments of the present invention chosen, and are not done in any form to the present invention Limitation, according to the technical essence of the invention, any equivalent modifications to the above embodiments each fall within guarantor of the invention Within the scope of shield.

Claims (9)

1. a kind of strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that including 2-4% antisaline soil, 0.3- 0.5% soda ash, 30-60% organic salt, 0.2-0.5% extracting and cutting agent, 0.5-2% fluid loss additive, 1-4% inhibit sealing agent, 1- 4% nanometer of sealing agent, the fluorocarbon alcohol of 0.2-0.5%, 0.5-2.5% polymeric alcohol, 0.5-1% polyetheramine, 1-2% crystalline flake graphite, Superfine light calcium carbonate, the 190-260% barite of 3-5%;The above percentage composition is in terms of the mass content of water;
The fluorocarbon alcohol is tetrafluoro butanediol, five fluorine propyl alcohol or hexafluoroisopropanol.
2. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the antisaline soil For modified meerschaum or attapulgite;
3. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the organic salt For potassium formate and/or sodium formate;
4. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the extracting and cutting agent For xanthan gum, welan gum or chitosan;
5. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the filtrate reducing Agent is carboxymethyl cellulose or polyanion cellulose;
6. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the inhibition envelope Blocking agent is albino bitumen, sulfonated gilsonite;
7. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the nanometer envelope Blocking agent is that vinyl acetate-ethylene copolymerization closes object lotion, butylbenzene nanoemulsions, polycarbonate nano lotion and surface-modified nano two One or more of silica.
8. as claimed in claim 7 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that the acetic acid second Alkene-ethylene copolymer lotion is that vinyl acetate-ethylene copolymerization of the partial size in 100-200nm closes object lotion;Butylbenzene nanoemulsions It is styrene-butadiene emulsion of the partial size in 50-100nm;Polycarbonate nano lotion is polycarbonate emulsion of the partial size in 50-100nm;Table Face modified manometer silicon dioxide is silica of the modified partial size in surface in 50-80nm.
9. as described in claim 1 strengthen the organic salt drilling fluid inhibited with sealing characteristics, which is characterized in that described ultra-fine light Matter calcium carbonate is that the superfine light calcium carbonate of 600 mesh, 1250 mesh and 2500 mesh is compounded according to 1:1-2:1-2 ratio.
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