CN107540243A - A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently - Google Patents
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently Download PDFInfo
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- CN107540243A CN107540243A CN201710889067.9A CN201710889067A CN107540243A CN 107540243 A CN107540243 A CN 107540243A CN 201710889067 A CN201710889067 A CN 201710889067A CN 107540243 A CN107540243 A CN 107540243A
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- dazzle
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Abstract
The present invention relates to glass reinforced processing technology field, more particularly to a kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently, the technique is first sputter silica separation layer on the glass substrate, then the sputter zinc oxide film on the silica separation layer, then anti-dazzle film layer is formed by acid corrosion, the mixed liquor of titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide is finally sprayed in the anti-dazzle film layer and antireflection film layer is formed after oversintering.Compared with prior art, the present invention causes the multiple diffusing reflection of light by lamination plated film, the silica separation layer of first layer, and the anti-dazzle film layer of the second layer can produce anti-dazzle light effect, the antireflection film layer of third layer is further such that visible reflectance reduction, light can be reflected be down to less than 1%.Therefore, the glass made by the present invention has anti-dazzle and anti-reflective effect concurrently, can control the thickness of each film layer, and manufacture craft is simple and environmentally-friendly, is easy to continuous large-scale production.
Description
Technical field
The present invention relates to glass reinforced processing technology field, and in particular to a kind of system for having anti-dazzle and anti reflection glass concurrently
Make technique.
Background technology
The field of form is used glass as in electron display device packaged glass cover plate, show window etc., due to simple glass
Certain reflected light itself be present and transmit forceful rays from glass, cause often to produce dazzle in general environment,
The vision of people is set to produce fatigue.In order to overcome dazzle, mitigate visual fatigue, it is necessary to reduce or scatter display device is launched
Luminous intensity and the reflected light for reducing glass itself.Theoretical according to Film Optics, the method for reducing glass-reflected light is exactly in glass
One layer of deielectric-coating for being less than glass refraction is plated on glass surface, if re-forming certain hole on the low-index film
Rate, the refractive index of film layer is also low, and the effect of antireflective is more preferable；The simplest method for reducing glass glare phenomenon is exactly in glass
Glass forms matte on surface, light is formed diffusing reflection/transmission, reaches the purpose of anti-dazzle.
At present, the method that antireflective coating is coated with glass mainly has sputtering method, vapour deposition method, wet chemistry method, wherein ripe
Magnetically controlled sputter method plated film, have the characteristics that film uniformity is good, thicknesses of layers is easy to control, film layer and glass are combined,
Through being widely applied in the field of production coated glass；The method that anti-dazzle is produced on glass is exactly to take hydrofluoric acid rotten
The method of erosion, a certain amount of silica is eroded in glass surface, forms the diffusing reflection to light.The characteristics of this method is method letter
Single, corrosion rate is fast.But it is the extremely strong acid of corrosivity that shortcoming, which is hydrofluoric acid, all can to human body, to air, to soil environment
Produce greatly infringement and pollution therefore, urgent need exploitation anti-dazzle and double work(that anti-reflective effect is good and preparation method is simple and environmentally-friendly
Can coated glass.
The content of the invention
Above-mentioned technical problem be present for prior art, it is an object of the invention to provide one kind to have anti-dazzle and anti-reflection concurrently
The manufacture craft of glass is penetrated, the anti-dazzle of the technique is good with anti-reflective effect and preparation method is simple and environmentally-friendly.
To achieve the above object, the present invention provides following technical scheme：
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently is provided, comprised the following steps：
A) glass substrate is carried out to pickling, deionization washing successively, be then dried for standby；
B) sputtering method sputter silica separation layer on glass is used；
C) sputtering method sputter zinc oxide film on the silica separation layer is used, is then 3% with mass concentration
~8% 20~40s of acid corrosion, form anti-dazzle film layer；
D) glass baseplate is subjected to ultrasonic wave cleaning, then dried；
E) by the mixed liquor of titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide, it is sprayed on the anti-dazzling film
On the surface of layer, then sintering forms antireflection film layer.
Wherein, in step a, the acid of the pickling is more than one or both of hydrochloric acid, sulfuric acid, nitric acid and oxalic acid,
The mass concentration of acid is 3%~8%.
Wherein, in step a and d, the temperature of drying is 40~60 DEG C.
Wherein, in step b, the thickness of the silica separation layer is 10~20nm.
Wherein, in step c, the acid of the pickling is more than one or both of hydrochloric acid, sulfuric acid, nitric acid and oxalic acid.
Wherein, in step c, the thickness of the anti-dazzle film layer is 70~100nm.
Wherein, in step e, the titanium dioxide, niobium oxide, zirconium oxide, the mass ratio of tin oxide and zinc oxide are 1~5:
0.5~1:1~3:0.5~1:2~4.
Wherein, in step e, the thickness of the antireflection film layer is 80~110nm.
Wherein, in step e, the temperature of the sintering is 150~180 DEG C.
Beneficial effects of the present invention：
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently of the present invention, the first sputter on the glass substrate of the technique
Silica separation layer, then the sputter zinc oxide film on the silica separation layer, is then formed anti-by acid corrosion
Dazzle film layer, the mixing of titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide is finally sprayed in the anti-dazzle film layer
Liquid, and antireflection film layer is formed after oversintering.Compared with prior art, the present invention passes through lamination plated film, the dioxy of first layer
SiClx separation layer, micropore therein cause the multiple diffusing reflection of light, and the anti-dazzle film layer of the second layer can produce anti-dazzle light effect,
Non-pollution discharge is can reach after weak acid waste liquid used is neutralized, the antireflection film layer of third layer is titanium dioxide, niobium oxide, oxygen
Change zirconium, tin oxide, the complex liquid of zinc oxide through spraying and sintering formation, the antireflection film layer is further such that visible reflectance
Reduce, light can be reflected and be down to less than 1%.Therefore, the glass made by the present invention has anti-dazzle and anti-reflective effect concurrently, can
The thickness of each film layer is controlled, and its manufacture craft is simple and environmentally-friendly, is easy to continuous large-scale production., form a titanium dioxide
Silicon thin layer, when the thickness of film is where appropriate, the light reflected on two faces of film, path length difference are exactly equal to half wavelength, because
And destructive interference can occur.This greatly reduces the reflection loss of light, the intensity of transmitted light is enhanced.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1：
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently is provided, comprised the following steps：
A) glass substrate is used successively mass concentration for 5% chlorohydric acid pickling, deionization washing, then in 60 DEG C of conditions
Under be dried for standby；
B) sputtering method sputter silica separation layer on glass is used, the thickness of silica separation layer is 10nm；
C) sputtering method sputter zinc oxide film on the silica separation layer is used, is then 3% with mass concentration
The mixing corrosion 20s of hydrochloric acid and 5% sulfuric acid, form the anti-dazzle film layer of 70nm thickness；
D) glass baseplate is subjected to ultrasonic wave cleaning, then dried；
E) by titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide according to 1:0.5:1:1:2 mass ratio is made
Mixed liquor, then the mixed liquor is sprayed on the surface of the anti-dazzle film layer, formation is then sintered at a temperature of 150 DEG C subtracts
Reflective coating, the thickness of antireflection film layer is 80nm.
Embodiment 2：
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently is provided, comprised the following steps：
A) glass substrate is used successively mass concentration for 3% nitric acid acidwashing, deionization washing, then in 40 DEG C of conditions
Under be dried for standby；
B) sputtering method sputter silica separation layer on glass is used, the thickness of silica separation layer is 15nm；
C) sputtering method sputter zinc oxide film on the silica separation layer is used, is then 8% with mass concentration
Oxalic acid corrosion 40s, formed 100nm thickness anti-dazzle film layer；
D) glass baseplate is subjected to ultrasonic wave cleaning, then dried；
E) by titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide according to 5:1:3:1:4 mass ratio is made mixed
Liquid is closed, is then sprayed on the mixed liquor on the surface of the anti-dazzle film layer, then sintering forms anti-reflection at a temperature of 180 DEG C
Film layer is penetrated, the thickness of antireflection film layer is 110nm.
Embodiment 3：
A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently is provided, comprised the following steps：
A) glass substrate is used to oxalic acid pickling, deionization washing of the mass concentration for 8% successively, then in 50 DEG C of conditions
Under be dried for standby；
B) sputtering method sputter silica separation layer on glass is used, the thickness of silica separation layer is 16nm；
C) sputtering method sputter zinc oxide film on the silica separation layer is used, is then 6% with mass concentration
Hcl corrosion 30s, formed 90nm thickness anti-dazzle film layer；
D) glass baseplate is subjected to ultrasonic wave cleaning, then dried；
E) by titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide according to 3:1:2:0.5:3 mass ratio is made
Mixed liquor, then the mixed liquor is sprayed on the surface of the anti-dazzle film layer, formation is then sintered at a temperature of 160 DEG C subtracts
Reflective coating, the thickness of antireflection film layer is 100nm.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of scope is protected, although being explained with reference to preferred embodiment to the present invention, one of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent substitution, without departing from the reality of technical solution of the present invention
Matter and scope.
Claims (9)
- A kind of 1. manufacture craft for having anti-dazzle and anti reflection glass concurrently, it is characterised in that：Comprise the following steps：A) glass substrate is carried out to pickling, deionization washing successively, be then dried for standby；B) sputtering method sputter silica separation layer on glass is used；C) sputtering method sputter zinc oxide film on the silica separation layer is used, is then 3%~8% with mass concentration 20~40s of acid corrosion, formed anti-dazzle film layer；D) glass baseplate is subjected to ultrasonic wave cleaning, then dried；E) by the mixed liquor of titanium dioxide, niobium oxide, zirconium oxide, tin oxide and zinc oxide, it is sprayed on the anti-dazzle film layer On surface, then sintering forms antireflection film layer.
- A kind of 2. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In a, the acid of the pickling is more than one or both of hydrochloric acid, sulfuric acid, nitric acid and oxalic acid, and sour mass concentration is 3% ~8%.
- A kind of 3. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In a and d, the temperature of drying is 40~60 DEG C.
- A kind of 4. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In b, the thickness of the silica separation layer is 10~20nm.
- A kind of 5. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In c, the acid of the pickling is more than one or both of hydrochloric acid, sulfuric acid, nitric acid and oxalic acid.
- A kind of 6. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In c, the thickness of the anti-dazzle film layer is 70~100nm.
- A kind of 7. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In e, the titanium dioxide, niobium oxide, zirconium oxide, the mass ratio of tin oxide and zinc oxide are 1~5:0.5~1:1~3:0.5~ 1:2~4.
- A kind of 8. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In e, the thickness of the antireflection film layer is 80~110nm.
- A kind of 9. manufacture craft for having anti-dazzle and anti reflection glass concurrently according to claim 1, it is characterised in that：Step In e, the temperature of the sintering is 150~180 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710889067.9A CN107540243A (en) | 2017-09-27 | 2017-09-27 | A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently |
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| CN201710889067.9A CN107540243A (en) | 2017-09-27 | 2017-09-27 | A kind of manufacture craft for having anti-dazzle and anti reflection glass concurrently |
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| CN107540243A true CN107540243A (en) | 2018-01-05 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110927831A (en) * | 2018-08-29 | 2020-03-27 | 北京小米移动软件有限公司 | Terminal equipment front cover glass and terminal equipment |
| CN111499218A (en) * | 2020-03-31 | 2020-08-07 | 东莞泰升玻璃有限公司 | Processing method of anti-glare thin plate glass |
| CN115849730A (en) * | 2022-12-14 | 2023-03-28 | 耀华(秦皇岛)玻璃技术开发有限公司 | Processing method of anti-glare thin plate glass |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839122A1 (en) * | 1996-05-14 | 1998-05-06 | Saint-Gobain Vitrage | Glazing with an anti-reflective coating |
| US20010031317A1 (en) * | 2000-03-07 | 2001-10-18 | Fukuvi Chemical Industry Co., Ltd. | Reflection-reducing film |
| CN1665753A (en) * | 2002-07-03 | 2005-09-07 | 法国圣戈班玻璃厂 | Transparent substrate comprising antiglare coating |
| CN103921487A (en) * | 2014-04-04 | 2014-07-16 | 武汉理工大学 | Dual-function film coated glass capable of realizing anti-dazzle performance and visible light antireflection and preparation method of glass |
| CN105142900A (en) * | 2012-10-12 | 2015-12-09 | 康宁股份有限公司 | Articles with a low-elastic modulus layer and retained strength |
| CN105601120A (en) * | 2016-02-23 | 2016-05-25 | 广州视睿电子科技有限公司 | Anti-reflection permeability-improving glass and preparing method thereof |
| CN105859153A (en) * | 2016-04-01 | 2016-08-17 | 江苏秀强玻璃工艺股份有限公司 | Antifogging antireflection visible-light double-function coated glass and preparation method thereof |
| CN107129159A (en) * | 2017-06-16 | 2017-09-05 | 成都新柯力化工科技有限公司 | A kind of lamination plated film anti reflection glass and preparation method thereof |
-
2017
- 2017-09-27 CN CN201710889067.9A patent/CN107540243A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839122A1 (en) * | 1996-05-14 | 1998-05-06 | Saint-Gobain Vitrage | Glazing with an anti-reflective coating |
| US20010031317A1 (en) * | 2000-03-07 | 2001-10-18 | Fukuvi Chemical Industry Co., Ltd. | Reflection-reducing film |
| CN1665753A (en) * | 2002-07-03 | 2005-09-07 | 法国圣戈班玻璃厂 | Transparent substrate comprising antiglare coating |
| CN105142900A (en) * | 2012-10-12 | 2015-12-09 | 康宁股份有限公司 | Articles with a low-elastic modulus layer and retained strength |
| CN103921487A (en) * | 2014-04-04 | 2014-07-16 | 武汉理工大学 | Dual-function film coated glass capable of realizing anti-dazzle performance and visible light antireflection and preparation method of glass |
| CN105601120A (en) * | 2016-02-23 | 2016-05-25 | 广州视睿电子科技有限公司 | Anti-reflection permeability-improving glass and preparing method thereof |
| CN105859153A (en) * | 2016-04-01 | 2016-08-17 | 江苏秀强玻璃工艺股份有限公司 | Antifogging antireflection visible-light double-function coated glass and preparation method thereof |
| CN107129159A (en) * | 2017-06-16 | 2017-09-05 | 成都新柯力化工科技有限公司 | A kind of lamination plated film anti reflection glass and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 化工百科全书编辑委员会: "《化工百科全书 第15卷 水产养殖-天然树脂》", 31 December 1997, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110927831A (en) * | 2018-08-29 | 2020-03-27 | 北京小米移动软件有限公司 | Terminal equipment front cover glass and terminal equipment |
| CN111499218A (en) * | 2020-03-31 | 2020-08-07 | 东莞泰升玻璃有限公司 | Processing method of anti-glare thin plate glass |
| CN115849730A (en) * | 2022-12-14 | 2023-03-28 | 耀华(秦皇岛)玻璃技术开发有限公司 | Processing method of anti-glare thin plate glass |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 523000 No.8, Daji Industrial Zone, Shipai Avenue, Shipai town, Dongguan City, Guangdong Province Applicant after: Guangdong Xingxing Optoelectronics Technology Co., Ltd. Address before: 523330 Guangdong Province, Dongguan City Shipai town Shipai Road Industrial Zone No. 8 Keelung Applicant before: Guangdong Sinz Optoelectronic Technology Co., Ltd. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180105 |