CN107523146A - A kind of preparation method of the resistance to bubble paint of surface of metal product - Google Patents
A kind of preparation method of the resistance to bubble paint of surface of metal product Download PDFInfo
- Publication number
- CN107523146A CN107523146A CN201710777388.XA CN201710777388A CN107523146A CN 107523146 A CN107523146 A CN 107523146A CN 201710777388 A CN201710777388 A CN 201710777388A CN 107523146 A CN107523146 A CN 107523146A
- Authority
- CN
- China
- Prior art keywords
- resistance
- metal product
- bubble
- preparation
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/10—Homopolymers or copolymers of propene
- C09D123/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention discloses a kind of preparation method of the resistance to bubble paint of surface of metal product, including following operating procedure：（1）By molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride according to mass ratio be 8 10:3:It is standby after ball mill ball-milling treatment 23 hours after 2 ratio mixing；（2）After acrylic resin emulsion, titanyl sulfate, fluoroform aniline sulfonic acid, 2 nonenyl succinic acid acid anhydrides are mixed, after persistently stirring 40 50min, thickener, defoamer are added thereto, continue after stirring 20min, mixed resin is made；（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 30 50min, the resistance to bubble paint of surface of metal product is made.The resistance to bubble paint of surface of metal product prepared by the present invention, can effectively lift anti-wear performance, the decay resistance of surface of metal product, after coating is dried, the hardness of face coat is larger, every excellent in mechanical performance, especially has extremely excellent water soak resistance energy.
Description
Technical field
The invention belongs to surface of metal product japanning technical field, and in particular to a kind of resistance to bubble paint of surface of metal product
Preparation method.
Background technology
Metallic article is during use, the breakoff phenomenons such as surface is highly prone to wear, corroded, in order to extend metal system
Product service life, often need to carry out japanning processing to metallic article.Molybdenum sulfide has excellent performance and wide application prospect,
So both at home and abroad to nanometer MoS2Prepare and application has all carried out substantial amounts of research.MoS2It can be carried by natural method, i.e. molybdenite concentrate
Prepared by pure method, the method is that the molybdenum concntrate of high-quality pass through into certain physics and chemical action, remove in molybdenite concentrate it is sour not
The impurity such as molten thing, SiO2, Fe, Cu, Ca, Pb, is further refined, and obtains nanometer MoS2.Climax molybdenums company of the U.S. is just
It is to employ this method production MoS2.Nanometer MoS made of this method2, natural MoS can be kept2Crystalline form, lubrication
Better performances, it is adapted to lubricant is made.Molybdenum sulfide is added in high polymer material as lubricant at present has obtained extensive fortune
With, but be applied in coating, because it is poor with remaining COMPONENTS COMPATIBILITY in coating, therefore cause obtained coating
Water resistance is poor, after coating soaks in water, the phenomenon to come off easily occurs.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of preparation method of the resistance to bubble paint of surface of metal product.
The present invention is achieved by the following technical solutions.
A kind of preparation method of the resistance to bubble paint of surface of metal product, including following operating procedure：
（1）According to mass ratio it is 8-10 by molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride:3:After 2 ratio mixing, using ball mill
It is standby after ball-milling treatment 2-3 hours；
（2）By weight, by 60-68 part acrylic resins emulsion, 2-4 parts titanyl sulfate, 3-6 part fluoroform sulphophenyls
After amine, the mixing of 1-2 part 2- nonenyl succinic acids acid anhydride, after persistently stirring 40-50min, 3-6 parts thickener, 1-2 parts are added thereto
Defoamer, continue after stirring 20min, mixed resin is made；
（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 30-50min, surface of metal product is made
Resistance to bubble paint.
Specifically, the Average Particle Diameters of above-mentioned molybdenum sulfide are 200-250 mesh.
Specifically, above-mentioned steps（1）The rotating speed of middle ball milling is 500r/min.
Specifically, above-mentioned steps（2）In, the rotating speed of stirring is 300r/min.
Specifically, above-mentioned steps（3）The rotating speed of middle stirring is 350r/min.
Specifically, above-mentioned thickener is any one in hydroxypropyl methyl cellulose, sodium carboxymethylcellulose.
Specifically, above-mentioned defoamer is any one in dimethyl silicone polymer or polyoxypropylene ethylene oxide glycerin ether
Kind.
Specifically, the usage amount of the resistance to bubble paint of above-mentioned surface of metal product is：Every square metre of surface of metal product sprinkling
650-750ml。
Beneficial effect：
The resistance to bubble paint of surface of metal product prepared by the present invention, it can effectively lift the anti-wear performance, resistance to of surface of metal product
Corrosive nature, after coating is dried, the hardness of face coat is larger, every excellent in mechanical performance, especially has extremely excellent
Water soak resistance energy.In the present invention, by molybdenum sulfide after surface modification treatment, itself and remaining composition in coating can be effectively lifted
Compatibility, and then improve the compactness of obtained coating so that the surface energy of coating surface is relatively low, thus with excellent
Water resistance；Titanyl sulfate, fluoroform aniline sulfonic acid, that 2- nonenyl succinic acids acid anhydride can effectively lift coat inside is intermolecular
Adhesion so that coating is not easy the phenomenon hydrolyzed under conditions of bubble.
Embodiment
Following examples are used for illustrating the present invention, but can not be used for limiting the scope of the present invention, the reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
Embodiment 1
A kind of preparation method of the resistance to bubble paint of surface of metal product, including following operating procedure：
（1）By molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride according to mass ratio be 8:3:After 2 ratio mixing, using ball mill ball milling
It is standby after processing 2 hours；
（2）By weight, by 60 parts of acrylic resin emulsions, 2 parts of titanyl sulfates, 3 parts of fluoroform aniline sulfonic acids, 1 part of 2-
After the mixing of nonenyl succinic acid acid anhydride, after persistently stirring 40min, 3 parts of thickeners, 1 part of defoamer are added thereto, continues to stir
After 20min, mixed resin is made；
（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 30min, it is water-fast that surface of metal product is made
Bubble paint.
Specifically, the Average Particle Diameters of above-mentioned molybdenum sulfide are 200 mesh.
Specifically, above-mentioned steps（1）The rotating speed of middle ball milling is 500r/min.
Specifically, above-mentioned steps（2）In, the rotating speed of stirring is 300r/min.
Specifically, above-mentioned steps（3）The rotating speed of middle stirring is 350r/min.
Specifically, above-mentioned thickener is hydroxypropyl methyl cellulose.
Specifically, above-mentioned defoamer is dimethyl silicone polymer.
Specifically, the usage amount of the resistance to bubble paint of above-mentioned surface of metal product is：Every square metre of surface of metal product sprinkling
650ml。
Paint application will be made in the present embodiment after aluminum alloy surface, put it into 50 DEG C of water and soak 71 hours
Afterwards, coating occurs without softening, the phenomenon to come off.
Embodiment 2
A kind of preparation method of the resistance to bubble paint of surface of metal product, including following operating procedure：
（1）By molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride according to mass ratio be 9:3:After 2 ratio mixing, using ball mill ball milling
It is standby after processing 2.5 hours；
（2）By weight, by 64 parts of acrylic resin emulsions, 3 parts of titanyl sulfates, 5 parts of fluoroform aniline sulfonic acids, 1 part of 2-
After the mixing of nonenyl succinic acid acid anhydride, after persistently stirring 45min, 5 parts of thickeners, 1 part of defoamer are added thereto, continues to stir
After 20min, mixed resin is made；
（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 40min, it is water-fast that surface of metal product is made
Bubble paint.
Specifically, the Average Particle Diameters of above-mentioned molybdenum sulfide are 230 mesh.
Specifically, above-mentioned steps（1）The rotating speed of middle ball milling is 500r/min.
Specifically, above-mentioned steps（2）In, the rotating speed of stirring is 300r/min.
Specifically, above-mentioned steps（3）The rotating speed of middle stirring is 350r/min.
Specifically, above-mentioned thickener is sodium carboxymethylcellulose.
Specifically, above-mentioned defoamer is polyoxypropylene ethylene oxide glycerin ether.
Specifically, the usage amount of the resistance to bubble paint of above-mentioned surface of metal product is：Every square metre of surface of metal product sprinkling
700ml。
Paint application will be made in the present embodiment after aluminum alloy surface, put it into 50 DEG C of water and soak 78 hours
Afterwards, coating occurs without softening, the phenomenon to come off.
Embodiment 3
A kind of preparation method of the resistance to bubble paint of surface of metal product, including following operating procedure：
（1）By molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride according to mass ratio be 10:3:After 2 ratio mixing, using ball mill ball
It is standby after mill processing 3 hours；
（2）By weight, by 68 parts of acrylic resin emulsions, 4 parts of titanyl sulfates, 6 parts of fluoroform aniline sulfonic acids, 2 parts of 2-
After the mixing of nonenyl succinic acid acid anhydride, after persistently stirring 50min, 6 parts of thickeners, 2 parts of defoamers are added thereto, continue to stir
After 20min, mixed resin is made；
（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 50min, it is water-fast that surface of metal product is made
Bubble paint.
Specifically, the Average Particle Diameters of above-mentioned molybdenum sulfide are 250 mesh.
Specifically, above-mentioned steps（1）The rotating speed of middle ball milling is 500r/min.
Specifically, above-mentioned steps（2）In, the rotating speed of stirring is 300r/min.
Specifically, above-mentioned steps（3）The rotating speed of middle stirring is 350r/min.
Specifically, above-mentioned thickener is sodium carboxymethylcellulose.
Specifically, above-mentioned defoamer is polyoxypropylene ethylene oxide glycerin ether.
Specifically, the usage amount of the resistance to bubble paint of above-mentioned surface of metal product is：Every square metre of surface of metal product sprinkling
750ml。
Paint application will be made in the present embodiment after aluminum alloy surface, put it into 50 DEG C of water and soak 82 hours
Afterwards, coating occurs without softening, the phenomenon to come off.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (8)
1. a kind of preparation method of the resistance to bubble paint of surface of metal product, it is characterised in that including following operating procedure：
（1）According to mass ratio it is 8-10 by molybdenum sulfide, paraffin, tetrabutyl ammonium fluoride:3:After 2 ratio mixing, using ball mill
It is standby after ball-milling treatment 2-3 hours；
（2）By weight, by 60-68 part acrylic resins emulsion, 2-4 parts titanyl sulfate, 3-6 part fluoroform sulphophenyls
After amine, the mixing of 1-2 part 2- nonenyl succinic acids acid anhydride, after persistently stirring 40-50min, 3-6 parts thickener, 1-2 parts are added thereto
Defoamer, continue after stirring 20min, mixed resin is made；
（3）By step（1）The mixture of gained is added into mixed resin, and after stirring 30-50min, surface of metal product is made
Resistance to bubble paint.
2. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
The Average Particle Diameters for stating molybdenum sulfide are 200-250 mesh.
3. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
State step（1）The rotating speed of middle ball milling is 500r/min.
4. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
State step（2）In, the rotating speed of stirring is 300r/min.
5. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
State step（3）The rotating speed of middle stirring is 350r/min.
6. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
Thickener is stated as any one in hydroxypropyl methyl cellulose, sodium carboxymethylcellulose.
7. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
Defoamer is stated as any one in dimethyl silicone polymer or polyoxypropylene ethylene oxide glycerin ether.
8. the preparation method painted according to the resistance to bubble of a kind of surface of metal product described in claim 1, it is characterised in that on
Stating the usage amount that the resistance to bubble of surface of metal product paints is：Every square metre of surface of metal product sprays 650-750ml.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710777388.XA CN107523146A (en) | 2017-09-01 | 2017-09-01 | A kind of preparation method of the resistance to bubble paint of surface of metal product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710777388.XA CN107523146A (en) | 2017-09-01 | 2017-09-01 | A kind of preparation method of the resistance to bubble paint of surface of metal product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107523146A true CN107523146A (en) | 2017-12-29 |
Family
ID=60683128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710777388.XA Pending CN107523146A (en) | 2017-09-01 | 2017-09-01 | A kind of preparation method of the resistance to bubble paint of surface of metal product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107523146A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110293805A (en) * | 2019-07-30 | 2019-10-01 | 宁波合力模具科技股份有限公司 | A kind of bionical corrosion-resistant damping tower |
| CN115418141A (en) * | 2022-10-18 | 2022-12-02 | 叶鹏 | Environment-friendly coating and preparation method thereof |
-
2017
- 2017-09-01 CN CN201710777388.XA patent/CN107523146A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110293805A (en) * | 2019-07-30 | 2019-10-01 | 宁波合力模具科技股份有限公司 | A kind of bionical corrosion-resistant damping tower |
| CN115418141A (en) * | 2022-10-18 | 2022-12-02 | 叶鹏 | Environment-friendly coating and preparation method thereof |
| CN115418141B (en) * | 2022-10-18 | 2023-10-20 | 广东百川化工有限公司 | Environment-friendly paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106221458B (en) | Special anticorrosive water paint for steel structure and preparation method thereof | |
| CN102993906B (en) | Water-base epoxy antirust paint and preparation method | |
| CN108129885B (en) | Modified coating sealer of hydroxyl graphene and preparation method thereof | |
| CN103450719A (en) | Long-acting water-soluble and environmentally-friendly steel structural protective coating | |
| CN111117426A (en) | High-corrosion-resistance flash-rust-resistant waterborne epoxy primer and preparation method thereof | |
| CN103421368A (en) | Preparation method of high-modulus potassium silicate inorganic nano-resin | |
| CN107418277A (en) | A kind of water nano long-effective corrosion finish paint and preparation method thereof | |
| CN106189831A (en) | A kind of epoxy-modified polysiloxane coating and preparation method thereof | |
| CN108587441A (en) | A kind of watersoluble plumbago alkene acroleic acid polyurethane coating and preparation method thereof | |
| CN107523146A (en) | A kind of preparation method of the resistance to bubble paint of surface of metal product | |
| CN110845879A (en) | Novel environment-friendly water-based paint and preparation method thereof | |
| CN104725969A (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| CN106554706B (en) | A kind of waterborne epoxy modified acrylic resin aluminium paint using oiliness aluminum paste | |
| CN104725977B (en) | Double-component aqueous epoxy zinc rich primer of heavy antisepsis and preparation method thereof | |
| CN108059890A (en) | It is a kind of for quick-dry type water soluble acrylic acid signal paint of container and preparation method thereof | |
| CN108456466A (en) | A kind of high performance nano paint and preparation method thereof | |
| CN108178965A (en) | A kind of aqueous epoxy resins antirust paint and preparation method thereof | |
| CN112457697A (en) | Superfine slag micro powder antirust primer and preparation method thereof | |
| CN103173050B (en) | A kind of protective system containing ferrocene | |
| CN111440465B (en) | Organic-inorganic hybrid coating and preparation method thereof | |
| CN105802405B (en) | It is a kind of for aqueous finish paint of container and preparation method thereof | |
| CN105368251B (en) | A kind of extra-high voltage coatings and preparation method thereof | |
| CN103695943A (en) | Application method of metal surface treatment agent for forming protective film | |
| CN114539882A (en) | Graphene heavy-duty anticorrosive wear-resistant coating and preparation process thereof | |
| CN110628301B (en) | Special water-based paint for ceramic tiles and application method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171229 |