CN107501806A - 一种耐磨高硬的塑胶鞋底制品 - Google Patents

一种耐磨高硬的塑胶鞋底制品 Download PDF

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CN107501806A
CN107501806A CN201710926703.0A CN201710926703A CN107501806A CN 107501806 A CN107501806 A CN 107501806A CN 201710926703 A CN201710926703 A CN 201710926703A CN 107501806 A CN107501806 A CN 107501806A
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申乾成
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Abstract

本发明涉及塑胶鞋，具体的，涉及一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：塑胶料50‑68份、塑胶改性剂3‑8份、橡胶料15‑24份、共混改性助剂5‑10份、增塑剂10‑25份、稳定剂1‑5份、润滑剂0.1‑2份、发泡剂0.5‑3份、无机填充粒子2‑7份、玻璃纤维2‑10份；所述的塑胶改性剂为苯乙烯‑丁二烯‑苯乙烯三元嵌段共聚物、乙烯‑醋酸乙烯共聚物和乙烯‑辛烯共聚物混配而成；本发明提供的塑胶鞋底制品，通过塑胶与橡胶的共混改性，兼具韧性与硬度的优势，确保得到的塑胶鞋底制品具有优异的耐磨和高硬度的特点；所述的塑胶经改性处理，改善了低温脆性的缺点，提高了塑胶鞋底的使用温度范围。

Description

一种耐磨高硬的塑胶鞋底制品
技术领域
本发明涉及塑胶鞋，具体的，涉及一种耐磨高硬的塑胶鞋底制品。
背景技术
塑胶主要由碳、氧、氢和氮及其他有机或无机元素所构成，成品为固体，在制造过程中是熔融状的液体，因此可以加热使其熔化、加压力使其流动、冷却使其固化，而形成各种形状。塑胶主要有热塑性和热固性塑胶之分，热塑性塑胶指反复加热仍有可塑性的塑胶：主要有PE/PP/PVC/PS/ABS/PMMA/POM/PC/PA等常用原料。热固性塑胶主要指加热硬化的合成树脂制得的得塑胶，像一些酚醛塑胶及氨基塑胶，不常用。
相比于橡胶鞋底，塑胶鞋底由于其轻便易成型的特点逐渐进入到人们的视野，避免了橡胶鞋底因其密度较大导致的过于笨重的问题。另外，塑胶鞋底在正常干燥的环境中物性非常的好，轻便易发泡，可以做喷涂各种色彩，耐折性优异，橡胶的硬度普遍低于塑胶材料，但是塑胶材料相比于橡胶材料，其耐磨性上稍逊，用于制造塑胶鞋底制品时存在使用寿命较短的不足。
发明内容
本发明的目的在于提供一种耐磨高硬的塑胶鞋底制品。
为了实现上述目的，本发明采用以下技术方案予以实现：一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：塑胶料50-68份、塑胶改性剂3-8份、橡胶料15-24份、共混改性助剂5-10份、增塑剂10-25份、稳定剂1-5份、润滑剂0.1-2份、发泡剂0.5-3份、无机填充粒子2-7份、玻璃纤维2-10份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：(0.5-1)：(0.2-0.8)混配而成；
所述的共混改性助剂包括以下重量份的物质：增塑剂5-23份、相容剂10-35份、粘合剂10-35份、润滑剂1-8份、偶联剂0-10份。
本发明中，通过橡胶与塑胶的共混改性，塑胶进入橡胶网络结构的内部，使其网络结构充分松弛，而塑胶的存在使得橡胶具有更高的强度，二者的共混提高了复合料的整体韧性和强度；同时，所述的塑胶经改性处理，所述的改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物的混合物，极大的提高了塑胶的耐寒性能，改善其低温脆性，提高塑胶材料的使用温度范围。
所述的塑胶为聚氯乙烯、聚乙烯、聚氨酯和乙烯醋酸乙烯中的一种；所述的橡胶为氯丁橡胶、丁腈橡胶、异戊橡胶、丁苯橡胶中的一种或几种混合物。
进一步的，根据本发明，所述的塑胶鞋底制品包括以下重量份物质：塑胶料55-65份、塑胶改性剂4-7份、橡胶料18-22份、共混改性助剂6-9份、增塑剂15-20份、稳定剂2-5份、润滑剂0.5-1.5份、发泡剂1-2份、无机填充粒子3-6份、玻璃纤维5-8份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成。
根据本发明，所述的增塑剂为邻苯二甲酸之类增塑剂。
根据本发明，所述的相容剂为氯化聚烯烃、酸酐接枝改性聚烯烃中的一种。
根据本发明，所述的粘合剂为乙烯-醋酸乙烯酯共聚物。
根据本发明，所述的润滑剂为氯化石蜡、硬脂酸盐和N,N’-乙撑双硬脂酰胺中的一种或几种混合物。
根据本发明，所述的偶联剂为硅烷偶联剂，所述硅烷偶联剂为正癸基三甲氧基硅烷、正癸基三乙氧基硅烷、正癸基三氯硅烷、正辛基三甲氧基硅烷、正辛基三乙氧基硅烷、正辛基三氯硅烷、十二烷基三甲氧基硅烷、十二烷基三乙氧基硅烷、十二烷基三氯硅烷、十七氟癸基三甲氧基硅烷、十七氟癸基三乙氧基硅烷、十七氟癸基三氯硅烷、十三氟辛基三甲氧基硅烷、十三氟辛基三乙氧基硅烷、十三氟癸基三氯硅烷、全氟十二烷基三甲氧基硅烷、全氟十二烷基三乙氧基硅烷、全氟十二烷基三氯硅烷或三氟丙基三甲氧基硅烷中的至少一种。
根据本发明，本发明中所述的稳定剂为钙锌复合稳定剂。
发泡剂有助于实现塑胶材料的发泡，降低整体塑胶鞋底制品的密度；同时，发泡剂引发的泡孔挤压内部空间，使得塑胶与橡胶相互接触更为紧密。本发明中所述的发泡剂为AD发泡剂、ADC发泡剂中的一种。
无机填充粒子和玻璃纤维的作用在于提供补强的作用，具体的，本发明中所述的无机填充粒子可以为钛白粉、碳酸钙、硫酸钡中的一种。
本发明所述的耐磨高硬的塑胶鞋底制品的制备方法为：
(1)将塑胶加入高速混合机中，加入苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物，在90-100℃的条件下搅拌混合，得改性处理的塑胶；
(2)将橡胶料破碎成颗粒状或粉末状，并与共混改性助剂混合均匀；
(3)将步骤(1)中改性处理的塑胶和步骤(2)中的混合物投入密炼机中密炼混合，然后投入增塑剂、稳定剂、润滑剂、发泡剂、无机填充粒子和玻璃纤维，继续密炼3-5min后出料至模具中压制成型，得塑胶鞋底成品。
上述制备方法简单方便，便于大规模工业化生产的进行。
本发明具有以下技术效果：
1、本发明提供的塑胶鞋底制品，通过塑胶与橡胶的共混改性，兼具韧性与硬度的优势，确保得到的塑胶鞋底制品具有优异的耐磨和高硬度的特点；
2、本发明中所述的塑胶经改性处理，改善了低温脆性的缺点，提高了塑胶鞋底的使用温度范围；
3、本发明中所述的橡胶料与塑胶料之间通过共混改性助剂的融合，提高了相容性。
具体实施方式
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐明本发明。
实施例1
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚氯乙烯60份、塑胶改性剂5份、氯丁橡胶20份、共混改性助剂8份、邻苯二甲酸之类增塑剂18份、钙锌复合稳定剂4份、氯化石蜡1份、AD发泡剂1.5份、钛白粉5份、玻璃纤维6份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂15份、氯化聚烯烃20份、乙烯-醋酸乙烯酯共聚物20份、氯化石蜡5份、正癸基三乙氧基硅烷5份。
实施例2
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚乙烯55份、塑胶改性剂4份、丁腈橡胶18份、共混改性助剂6份、邻苯二甲酸之类增塑剂15份、钙锌复合稳定剂2份、硬脂酸盐0.5份、AD发泡剂1份、碳酸钙3份、玻璃纤维5份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂7份、氯化聚烯烃12份、乙烯-醋酸乙烯酯共聚物15份、硬脂酸盐3份、正辛基三乙氧基硅烷2份。
实施例3
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚氨酯65份、塑胶改性剂7份、异戊橡胶22份、共混改性助剂9份、邻苯二甲酸之类增塑剂20份、钙锌复合稳定剂5份、N,N’-乙撑双硬脂酰胺1.5份、AD发泡剂2份、硫酸钡6份、玻璃纤维8份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂20份、酸酐接枝改性聚烯烃30份、乙烯-醋酸乙烯酯共聚物30份、N,N’-乙撑双硬脂酰胺6份、十二烷基三乙氧基硅烷8份。
实施例4
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：乙烯醋酸乙烯50份、塑胶改性剂3份、丁苯橡胶15份、共混改性助剂5份、邻苯二甲酸之类增塑剂10份、钙锌复合稳定剂1份、氯化石蜡0.1份、ADC发泡剂0.5份、钛白粉2份、玻璃纤维2份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.5：0.2混配而成；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂5份、酸酐接枝改性聚烯烃10份、乙烯-醋酸乙烯酯共聚物10份、氯化石蜡1份。
实施例5
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚氯乙烯68份、塑胶改性剂8份、氯丁橡胶24份、共混改性助剂10份、邻苯二甲酸之类增塑剂25份、钙锌复合稳定剂5份、氯化石蜡2份、AD发泡剂3份、硫酸钡7份、玻璃纤维10份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：1：0.8混配而成；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂23份、氯化聚烯烃35份、乙烯-醋酸乙烯酯共聚物35份、氯化石蜡8份、正癸基三氯硅烷10份。
对比例1
本实施例与对比例1中的塑胶鞋底制品的配方相同，不同的是，所述的聚氯乙烯不经改性处理；具体的，
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚氯乙烯60份、氯丁橡胶20份、共混改性助剂8份、邻苯二甲酸之类增塑剂18份、钙锌复合稳定剂4份、氯化石蜡1份、AD发泡剂1.5份、钛白粉5份、玻璃纤维6份；
所述的共混改性助剂包括以下重量份的物质：邻苯二甲酸之类增塑剂15份、氯化聚烯烃20份、乙烯-醋酸乙烯酯共聚物20份、氯化石蜡5份、正癸基三乙氧基硅烷5份。
对比例2
本实施例与对比例1中的塑胶鞋底制品的配方相同，不同的是，所述的氯丁橡胶与聚氯乙烯的混合不经改性处理；具体的，
一种耐磨高硬的塑胶鞋底制品，包括以下重量份的物质：聚氯乙烯60份、塑胶改性剂5份、氯丁橡胶20份、邻苯二甲酸之类增塑剂18份、钙锌复合稳定剂4份、氯化石蜡1份、AD发泡剂1.5份、钛白粉5份、玻璃纤维6份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成；
性能测试：
对实施例1-5、对比例1-2制得的塑胶鞋底制品进行性能测试，并将测试数据记录到表1中。
表1：
以上显示和描述了本发明的基本原理、主要特征和本发明的特点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明的范围内。本发明要求保护的范围由所附的权利要求书及其等效物界定。

Claims (6)

1.一种耐磨高硬的塑胶鞋底制品，其特征在于：包括以下重量份的物质：塑胶料50-68份、塑胶改性剂3-8份、橡胶料15-24份、共混改性助剂5-10份、增塑剂10-25份、稳定剂1-5份、润滑剂0.1-2份、发泡剂0.5-3份、无机填充粒子2-7份、玻璃纤维2-10份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：(0.5-1)：(0.2-0.8)混配而成；
所述的共混改性助剂包括以下重量份的物质：增塑剂5-23份、相容剂10-35份、粘合剂10-35份、润滑剂1-8份、偶联剂0-10份。
2.根据权利要求1所述的耐磨高硬的塑胶鞋底制品，其特征在于：包括以下重量份物质：塑胶料55-65份、塑胶改性剂4-7份、橡胶料18-22份、共混改性助剂6-9份、增塑剂15-20份、稳定剂2-5份、润滑剂0.5-1.5份、发泡剂1-2份、无机填充粒子3-6份、玻璃纤维5-8份；
所述的塑胶改性剂为苯乙烯-丁二烯-苯乙烯三元嵌段共聚物、乙烯-醋酸乙烯共聚物和乙烯-辛烯共聚物按照重量比1：0.8：0.6混配而成。
3.根据权利要求1所述的耐磨高硬的塑胶鞋底制品，其特征在于：所述的增塑剂为邻苯二甲酸之类增塑剂。
4.根据权利要求1所述的耐磨高硬的塑胶鞋底制品，其特征在于：所述的润滑剂为氯化石蜡、硬脂酸盐和N,N’-乙撑双硬脂酰胺中的一种或几种混合物。
5.根据权利要求1所述的耐磨高硬的塑胶鞋底制品，其特征在于：所述相容剂为氯化聚烯烃、酸酐接枝改性聚烯烃中的一种。
6.根据权利要求1所述的耐磨高硬的塑胶鞋底制品，其特征在于：所述粘合剂为乙烯-醋酸乙烯酯共聚物。
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