CN107498943A - A kind of heat-preservation clothing material based on graphene and preparation method thereof - Google Patents

A kind of heat-preservation clothing material based on graphene and preparation method thereof Download PDF

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Publication number
CN107498943A
CN107498943A CN201710648731.0A CN201710648731A CN107498943A CN 107498943 A CN107498943 A CN 107498943A CN 201710648731 A CN201710648731 A CN 201710648731A CN 107498943 A CN107498943 A CN 107498943A
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graphene
heat
parts
layer
clothing material
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许炳初
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/08—Animal fibres, e.g. hair, wool, silk
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/023—Silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C08K7/20—Glass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to functional fabric technical field, particularly relate to a kind of heat-preservation clothing material based on graphene and preparation method thereof, the described heat-preservation clothing material based on graphene includes the rubberised layer of internal layer and/or outer layer coated in base cloth layer, the thickness of rubberised layer is 10 20 μm, and EVA adhesive film is also pasted with described rubberised layer；Described rubberised layer includes the material of following parts by weight：20 45 parts of macromolecule resin glue, 0.1 3 parts of rutile type titanium white, 28 parts of glass microballoon, 0.2 1.5 parts of graphene, 0.2 1 parts of polysilicon, the rutile type titanium white being rich in rubberised layer effectively can be reflected spectrum, light is avoided through rise temperature, infrared light is especially reflected away, reduces the effect of heating；Described glass microballoon has hollow structure simultaneously, effectively reduces thermal conductivity factor；The performance of the super radiating of graphene in itself, it is set to become the heating material of high-efficiency environment friendly energy-conservation when environment temperature is relatively low.

Description

A kind of heat-preservation clothing material based on graphene and preparation method thereof
Technical field
The present invention relates to functional fabric technical field, particularly relate to a kind of heat-preservation clothing material based on graphene and its Preparation method.
Background technology
Fabric is exactly the material for making clothes, and as one of clothes three elements, fabric can not only annotate clothes Style and characteristic, and directly left and right the color of clothes, the expression effect of moulding；In clothes big world, the fabric of clothes It is multifarious, make rapid progress.But generally, high-quality, high-grade fabric, mostly with wear is comfortable, sweat-absorbing breathable, The characteristics of several aspects such as well-pressed, vision is noble, tactile is soft and graceful of dangling.With the improvement of living standards, people want to clothes More and more higher is sought, particularly to more urgent with the multi-functional fabric demand such as property, the feature of environmental protection and comfortableness.
Heat-preservation clothing material can maintain the temperature of human body, and keeping temperature, which is not affected by the external environment, to greatest extent raises or drop It is low, the comfortableness of fabric is improved, most constant temperature fabric is mainly heat-preservation clothing material in the market, improves fabric in cold Heat-insulating property in environment, but when being used for hot environment, the sultry phenomenon of human body, that is, the shadow by external high temperature often occurs Ring, the temperature inside heat-preservation clothing material can height, its effect being incubated can not completely cut off high temperature in hot environment and unobvious Effect.
The content of the invention
For the problems of the prior art, it is an object of the invention to provide a kind of heat-preservation clothing material based on graphene, carry The ability that high fabric isolation ambient temperature influences.
To achieve these goals, the present invention is achieved using following technical scheme：A kind of insulation based on graphene Fabric, including the rubberised layer of the internal layer coated in base cloth layer and/or outer layer, the thickness of rubberised layer is 10-20 μm, described gluing EVA adhesive film is also pasted with layer；
Described rubberised layer includes the material of following parts by weight：Macromolecule resin glue 20-45 parts, rutile titanium dioxide Powder 0.1-3 parts, glass microballoon 2-8 parts, graphene 0.2-1.5 parts, polysilicon 0.2-1 parts.
The rutile type titanium white being rich in rubberised layer effectively can be reflected spectrum, avoid light through rise Temperature, infrared light is especially reflected away, reduce the effect of heating；Described glass microballoon has hollow structure simultaneously, has Effect reduces thermal conductivity factor.
Preferably, base cloth layer of the present invention is fine by cotton fiber, silk fiber, flax fiber, bamboo-carbon fibre, wool One or more weavings in dimension obtain.
According to the present invention, the effect of macromolecule resin glue is to consolidate the components such as rutile type titanium white, glass microballoon It is scheduled on base cloth layer, what described macromolecule glue was well known to those skilled in the art, such as acrylic resin glue, polyurethane One kind in resin glue, epoxy resin glue, polyimides glue.
According to the present invention, the average grain diameter of described rutile type titanium white is 0.1-0.3 μm
According to the present invention, the bulk density of described glass microballoon is 80~120kg/m3。
Present invention also offers a kind of preparation method of the heat-preservation clothing material based on graphene, comprise the following steps：
(1) base cloth layer is obtained by carrying out blending to fiber；
(2) by the formula of rubberised layer weigh macromolecule resin glue, rutile type titanium white, glass microballoon, graphene and Polysilicon, mixed in agitator with agitator and combine supersound process 10-30min；
(3) rubberised layer is coated with base cloth layer, is then covered with EVA adhesive film, is placed in 60-80 DEG C of baking 3- in baking oven 4min, produce heat-preservation clothing material.
Wherein, the frequency being ultrasonically treated in described step (2) is 20000-25000Hz.
Compared with prior art, the heat-preservation clothing material provided by the invention based on graphene has the following technical effect that：
1st, graphene acts not only as energy storage device, stores the electric energy of generation, can be generated heat rapidly when it discharges, Plus the performance of the super radiating of graphene in itself, it is set to become the heating of high-efficiency environment friendly energy-conservation when environment temperature is relatively low Material, in addition, the electric conversion efficiency of graphene is high, electromagnetic radiation is small, and to human body non-hazardous, efficient heat generation area is big, and heat is Even property and thermal comfort are good, the small service life length of stable performance changed power, and thickness of thin flexibility is small, hardly space-consuming.
2nd, the glass microballoon of rutile type titanium white and hollow structure can effectively reduce the thermal conductivity factor of rubberised layer, carry The heat-insulating property of high rubberised layer.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is furture elucidated.
Embodiment 1
A kind of heat-preservation clothing material based on graphene, include the gluing of the outer layer for the base cloth layer weaved coated in cotton fiber Layer, the thickness of rubberised layer is 15 μm, and EVA adhesive film is also pasted with described rubberised layer；
Described rubberised layer includes the material of following parts by weight：30 parts of acrylic resin glue, rutile type titanium white 2 Part, 5 parts of glass microballoon, 1 part of graphene, 0.7 part of polysilicon.
Wherein, the average grain diameter of described rutile type titanium white is 0.2 μm；
The bulk density of described glass microballoon is 100kg/m3；
The preparation method of the heat-preservation clothing material based on graphene comprises the following steps：
(1) base cloth layer is obtained by carrying out blending to fiber；
(2) by the formula of rubberised layer weigh acrylic resin glue, rutile type titanium white, glass microballoon, graphene and Polysilicon, mixed in agitator with agitator and combine supersound process 20min, the frequency of described supersound process is 20000Hz；
(3) rubberised layer is coated with the base cloth layer of cotton fiber weaving, is then covered with EVA glued membranes, is placed in 70 in baking oven DEG C baking 3min, produce heat-preservation clothing material.
Embodiment 2
A kind of heat-preservation clothing material based on graphene, include the gluing of the internal layer for the base cloth layer weaved coated in silk fiber Layer, the thickness of rubberised layer is 10 μm, and EVA adhesive film is also pasted with described rubberised layer；
Described rubberised layer includes the material of following parts by weight：20 parts of polyurethane resin glue, rutile type titanium white 0.1 Part, 2 parts of glass microballoon, 0.2 part of graphene, 0.2 part of polysilicon.
Wherein, the average grain diameter of described rutile type titanium white is 0.1 μm；
The bulk density of described glass microballoon is 80kg/m3；
The preparation method of the heat-preservation clothing material based on graphene comprises the following steps：
(1) base cloth layer is obtained by carrying out blending to fiber；
(2) by the formula of rubberised layer weigh polyurethane resin glue, rutile type titanium white, glass microballoon, graphene and Polysilicon, mixed in agitator with agitator and combine supersound process 10min, the frequency of described supersound process is 25000Hz；
(3) rubberised layer is coated with base cloth layer, is then covered with EVA adhesive film, 60 DEG C of baking 3min in baking oven is placed in, produces Heat-preservation clothing material.
Embodiment 3
A kind of heat-preservation clothing material based on graphene, include the gluing of the internal layer for the base cloth layer weaved coated in flax fiber Layer, the thickness of rubberised layer is 20 μm, and EVA adhesive film is also pasted with described rubberised layer；
Described rubberised layer includes the material of following parts by weight：45 parts of epoxy resin glue, 3 parts of rutile type titanium white, 8 parts of glass microballoon, 1.5 parts of graphene, 1 part of polysilicon.
Wherein, the average grain diameter of described rutile type titanium white is 0.3 μm；
The bulk density of described glass microballoon is 120kg/m3；
The preparation method of the heat-preservation clothing material based on graphene comprises the following steps：
(1) base cloth layer is obtained by carrying out blending to fiber；
(2) epoxy resin glue, rutile type titanium white, glass microballoon, graphene and more are weighed by the formula of rubberised layer Crystal silicon, mixed in agitator with agitator and combine supersound process 30min, the frequency of described supersound process is 20000Hz；
(3) rubberised layer is coated with base cloth layer, is then covered with EVA adhesive film, 80 DEG C of baking 4min in baking oven is placed in, produces Heat-preservation clothing material.
General principle, principal character and the features of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement is both fallen within the range of claimed invention.The scope of protection of present invention is by appended claims And its equivalent thereof.

Claims (7)

  1. A kind of 1. heat-preservation clothing material based on graphene, it is characterised in that：Include the painting of internal layer and/or outer layer coated in base cloth layer Glue-line, the thickness of rubberised layer is 10-20 μm, and EVA adhesive film is also pasted with described rubberised layer；
    Described rubberised layer includes the material of following parts by weight：Macromolecule resin glue 20-45 parts, rutile type titanium white 0.1- 3 parts, glass microballoon 2-8 parts, graphene 0.2-1.5 parts, polysilicon 0.2-1 parts.
  2. 2. the heat-preservation clothing material according to claim 1 based on graphene, it is characterised in that：The base cloth layer is fine by cotton One or more weavings in dimension, silk fiber, flax fiber, bamboo-carbon fibre, wool fiber obtain.
  3. 3. the heat-preservation clothing material according to claim 1 based on graphene, it is characterised in that：Described macromolecule resin glue One kind in acrylic resin glue, polyurethane resin glue, epoxy resin glue, polyimides glue.
  4. 4. the heat-preservation clothing material according to claim 1 based on graphene, it is characterised in that：Described rutile type titanium white Average grain diameter be 0.1-0.3 μm.
  5. 5. the heat-preservation clothing material according to claim 1 based on graphene, it is characterised in that：The accumulation of described glass microballoon Density is 80~120kg/m3。
  6. A kind of 6. preparation method of heat-preservation clothing material based on graphene as described in claim 1-5, it is characterised in that：Including with Lower step：
    (1) base cloth layer is obtained by carrying out blending to fiber；
    (2) macromolecule resin glue, rutile type titanium white, glass microballoon, graphene and polycrystalline are weighed by the formula of rubberised layer Silicon, mixed in agitator with agitator and combine supersound process 10-30min；
    (3) rubberised layer is coated with base cloth layer, is then covered with EVA adhesive film, is placed in 60-80 DEG C of baking 3-4min in baking oven, i.e., Obtain heat-preservation clothing material.
  7. 7. the preparation method of the heat-preservation clothing material according to claim 6 based on graphene, it is characterised in that：Described step (2) frequency being ultrasonically treated in is 20000-25000Hz.
CN201710648731.0A 2017-08-01 2017-08-01 A kind of heat-preservation clothing material based on graphene and preparation method thereof Pending CN107498943A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI651350B (en) * 2018-04-13 2019-02-21 安炬科技股份有限公司 Graphene constant temperature fabric and manufacturing method thereof
CN110172836A (en) * 2019-05-29 2019-08-27 腾飞科技股份有限公司 Dress ornament spring function drape forming technique
CN110774682A (en) * 2019-11-21 2020-02-11 海安锦雅纺织科技有限公司 Composite textile fabric
TWI707906B (en) * 2018-04-13 2020-10-21 安炬科技股份有限公司 Graphene thermostatic fabric

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CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN205112566U (en) * 2015-09-17 2016-03-30 吴江市汉塔纺织整理有限公司 Reflective fabric
WO2016055926A1 (en) * 2014-10-10 2016-04-14 Sabic Global Technologies B.V. Polyetherimide varnish compositions, methods of manufacture, and articles prepared therefrom
CN206242614U (en) * 2016-12-05 2017-06-13 盐城市丝利得茧丝绸有限公司 A kind of Waterproof Breathable silk fabrics
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CN102350841A (en) * 2011-06-22 2012-02-15 中纺新材料科技有限公司 Making technology of sound-proof, thermal insulating and high shading efficiency curtain fabric
WO2016055926A1 (en) * 2014-10-10 2016-04-14 Sabic Global Technologies B.V. Polyetherimide varnish compositions, methods of manufacture, and articles prepared therefrom
CN205112566U (en) * 2015-09-17 2016-03-30 吴江市汉塔纺织整理有限公司 Reflective fabric
CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN206242614U (en) * 2016-12-05 2017-06-13 盐城市丝利得茧丝绸有限公司 A kind of Waterproof Breathable silk fabrics
CN106978027A (en) * 2017-04-12 2017-07-25 孙静 A kind of insulating mold coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI651350B (en) * 2018-04-13 2019-02-21 安炬科技股份有限公司 Graphene constant temperature fabric and manufacturing method thereof
TWI707906B (en) * 2018-04-13 2020-10-21 安炬科技股份有限公司 Graphene thermostatic fabric
CN110172836A (en) * 2019-05-29 2019-08-27 腾飞科技股份有限公司 Dress ornament spring function drape forming technique
CN110774682A (en) * 2019-11-21 2020-02-11 海安锦雅纺织科技有限公司 Composite textile fabric

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Application publication date: 20171222