CN107488494A - 一种动态缓蚀型水基全合成铝合金加工液 - Google Patents
一种动态缓蚀型水基全合成铝合金加工液 Download PDFInfo
- Publication number
- CN107488494A CN107488494A CN201710632455.9A CN201710632455A CN107488494A CN 107488494 A CN107488494 A CN 107488494A CN 201710632455 A CN201710632455 A CN 201710632455A CN 107488494 A CN107488494 A CN 107488494A
- Authority
- CN
- China
- Prior art keywords
- working fluid
- aluminum alloy
- parts
- synthetic aluminum
- water base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 53
- 230000007797 corrosion Effects 0.000 title claims abstract description 44
- 238000005260 corrosion Methods 0.000 title claims abstract description 44
- 230000005764 inhibitory process Effects 0.000 title claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- -1 isobutyl hydramine Chemical compound 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 8
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000006184 cosolvent Substances 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 229940043237 diethanolamine Drugs 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 3
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical group C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043276 diisopropanolamine Drugs 0.000 claims description 3
- 229940102253 isopropanolamine Drugs 0.000 claims description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 3
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 claims description 3
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical group C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 claims description 2
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 claims description 2
- UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 claims description 2
- HBVZPVWFLGXUAU-UHFFFAOYSA-N 5-methyl-1,3-oxazolidine Chemical compound CC1CNCO1 HBVZPVWFLGXUAU-UHFFFAOYSA-N 0.000 claims description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 2
- GZKVWJAFXAUQFK-UHFFFAOYSA-N N1=CC=CC2=CC=CC=C12.CC=1NC=CN1 Chemical compound N1=CC=CC2=CC=CC=C12.CC=1NC=CN1 GZKVWJAFXAUQFK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229960002887 deanol Drugs 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229940043279 diisopropylamine Drugs 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000012972 dimethylethanolamine Substances 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- NYNKJVPRTLBJNQ-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCN(CCCN)CCCN NYNKJVPRTLBJNQ-UHFFFAOYSA-N 0.000 claims description 2
- QMHNQZGXPNCMCO-UHFFFAOYSA-N n,n-dimethylhexan-1-amine Chemical compound CCCCCCN(C)C QMHNQZGXPNCMCO-UHFFFAOYSA-N 0.000 claims description 2
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 claims description 2
- 229960002446 octanoic acid Drugs 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003921 pyrrolotriazines Chemical class 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000003242 anti bacterial agent Substances 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical group CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- FSXPZSJEXMUNIU-UHFFFAOYSA-N [S].C=1C=CNC=1 Chemical compound [S].C=1C=CNC=1 FSXPZSJEXMUNIU-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- CASPZMCSNJZQMV-UHFFFAOYSA-N ethane;2-methyloxirane Chemical compound CC.CC1CO1 CASPZMCSNJZQMV-UHFFFAOYSA-N 0.000 claims 1
- 229940031098 ethanolamine Drugs 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 4
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 3
- 238000005461 lubrication Methods 0.000 abstract description 3
- 239000002480 mineral oil Substances 0.000 abstract description 3
- 235000010446 mineral oil Nutrition 0.000 abstract description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 150000002989 phenols Chemical class 0.000 abstract description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 2
- 239000008158 vegetable oil Substances 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 238000005498 polishing Methods 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 7
- 231100000241 scar Toxicity 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005555 metalworking Methods 0.000 description 4
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000000116 mitigating effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000006257 total synthesis reaction Methods 0.000 description 2
- VYWYYJYRVSBHJQ-UHFFFAOYSA-N 3,5-dinitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 VYWYYJYRVSBHJQ-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- 241001529481 Simian retrovirus 2 Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明提供了一种动态缓蚀型水基全合成铝合金加工液，包括如下重量份数的组分：润滑剂10‑40份；碱值储备剂5‑20份；其他助剂15‑40份；水20‑60份。本发明所述的水基全合成铝合金加工液无毒无害、无污染，具有优异的润滑、冷却、清洗性能，环境友好，不含S、Cl极压剂，不含亚硝酸钠、酚类。碱储备较高，不含矿物油和植物油，有良好的抗菌抑菌性能，生物稳定性好，循环寿命长。
Description
技术领域
本发明属于金属加工液领域，尤其是涉及一种动态缓蚀型水基全合成铝合金加工液。
背景技术
铝合金在航空航天、汽车、机械设备等工业中广泛应用，但由于其强度较低，在加工过程中易出现粘连现象，影响表面质量及加工精度，此外，铝合金化学活性较强，在加工及储存过程中易出现工件氧化变色、黑白斑等问题。
金属加工液可以提供金属加工中的润滑、冷却、清洗、防锈等性能，提高刀具使用寿命及工件表面质量。其中，水基加工液具有一系列显著优势，首先，冷却性能优异，可快速带走金属加工过程产生的热量，减少粘连，提高加工速度；其次，与传统乳化液相比，水基全合成加工液不含矿物油和植物油，有良好的抗菌抑菌性能，不易腐败，生物稳定性更加优良；此外，绿色、节能、环保也是全合成水基加工液的突出特征。
然而，一般水基加工液对铝合金的润滑性能和缓蚀性能欠佳，特别是静态缓蚀性能及润滑性能缺乏良好的协同作用，体现在加工过程中的动态缓蚀性能不足。而一般测试方法对加工液的铝合金缓蚀性能评价只局限于基本的静态缓蚀性能，对其动态缓蚀性能鲜有涉及，无法对动态缓蚀性能进行有效的评价。在加工过程中，工件不断产生新鲜表面，很多静态缓蚀性能合格的水基全合成铝合金加工液无法在刀具和工件新鲜表面产生压力接触摩擦时对工件提供良好的动态缓蚀保护，使工件容易在加工过程中出现腐蚀发黑。
因此，研发具有良好动态缓蚀性能的水基全合成铝合金加工液具有重要的意义。
发明内容
有鉴于此，本发明旨在提出一种水基全合成铝合金加工液，以解决上述问题。
为达到上述目的，本发明的技术方案是这样实现的：
一种水基全合成铝合金加工液，包括如下重量份数的组分：
润滑剂10-40份，
碱值储备剂5-20份，
其他助剂15-40份，
水20-60份。
水的加入量以使所述全合成铝合金加工液能够维持稳定状态、并达到具有良好的流动性能为准，可根据需要进行调整和添加.
进一步的，所述润滑剂为环氧乙烷—环氧丙烷嵌段共聚物(EO-PO)，优选地，所述环氧乙烷—环氧丙烷嵌段共聚物为分子量为1000-3500，浊点为30-55℃的嵌段聚醚。当EO-PO的分子量为1000-3500时，嵌段聚醚可兼具良好的润滑性与良好的水溶性；浊点为30-55℃可保证加工液有良好的储存稳定性，且在加工过程中在工件与刀具接触区形成可进行厚度控制的智能油膜，保证加工液良好的润滑性能。
进一步的，所述碱值储备剂选自乙醇胺、氢氧化钠、氢氧化钾、异丁醇胺、正丁胺、二异丙胺、二乙醇胺、三乙醇胺、异丙醇胺、二甲基乙醇胺、二甲基己胺、正丙醇胺、二异丙醇胺、N-甲基二乙醇胺、二甘醇胺、环己胺、二环己胺、二甲基癸叔胺、乙二胺、己二胺、正丁胺、三丁胺、三辛胺、吗啉中的至少一种；优选为乙醇胺、二乙醇胺、三乙醇胺、吗啉、N-甲基二乙醇胺、二甘醇胺、环己胺、异丙醇胺、正丙醇胺中的一种或两种以上的混合物。该类碱值储备剂可有效调节加工液的pH值和总碱度，并能在一定程度上增加体系稳定性与润滑性。
进一步的，所述其他助剂包括如下重量份数的一种或两种以上组分：腐蚀抑制剂10-25份，助溶剂0-15份，抗菌剂0.2-5份，消泡剂0.2-5份。
进一步的，所述腐蚀抑制剂为有机三元羧酸、碳酸盐、三嗪衍生物、1,2-二乙氧基硅酯基乙烷、石油磺酸盐、二硝基苯甲酸、硫代磷酸酯、季戊四醇酯、脂肪酸酰胺、十二烷基苯磺酸钠、甲基咪唑啉、甲基硅酸钠、硼酸酯、N-酰基氨基酸衍生物、醇醚磷酸酯、甲基苯并三氮唑、硝基苯并三氮唑、氨基磺酸中的一种或两种以上的混合物。使用该腐蚀抑制剂不仅对单种金属有良好的防锈缓蚀作用，还能有效减缓不同金属间的电偶腐蚀。
进一步的，所述助溶剂为正辛酸、异辛酸、正丁醇、异丁醇、吐温、水杨酸、丙三醇、乙二醇醚、丙二醇醚、异壬酸、癸二酸、异丙醇、新癸酸、丙二醇、乙二醇中的一种或两种以上的混合物。该类助溶剂可有效提高体系的稳定性，并在一定程度上提高加工液的润滑性。
进一步的，所述抗菌剂为六氢三嗪化合物、乙二醇二羟甲醚、异噻唑啉酮衍生物、月桂胺二亚丙基二胺、吡硫鎓钠、吡啶硫酮钠、3,3’亚甲基(5-甲基恶唑烷)、四羟甲基甘脲中的一种或两种以上的混合物。该抗菌剂可在较大pH范围内有效抑制细菌、真菌的生长，并对人体和环境未发现明显危害。
进一步的，所述消泡剂为聚醚-硅氧烷共聚物和/或聚硅氧烷。
进一步的，所述加工液的pH值为7.5-9.0。经过试验发现，若加工液PH＜7.5，碱储备值过低，更易滋生腐败菌；而若PH＞9.0，易对铝合金造成腐蚀，同时，对操作者皮肤有一定刺激性。
一种铝合金的加工方法，在铝合金加工过程中使用了上述水基全合成铝合金加工液。
相对于现有技术，本发明所述的水基全合成铝合金加工液具有以下优势：
(1)本发明的水基全合成铝合金加工液无毒无害、无污染，具有优异的润滑、冷却、清洗性能，环境友好，不含S、Cl极压剂，不含亚硝酸钠、酚类。碱储备较高，不含矿物油和植物油，有良好的抗菌抑菌性能，生物稳定性好，循环寿命长；
(2)本发明的加工液pH值较低，呈弱碱到中性，碱值温和、对人体友好，操作人员更易接受；
(3)本发明的加工液有优异的动态缓蚀性能，可在加工过程产生的工件新鲜表面与刀具产生压力接触摩擦时对工件表面起到良好的实时缓蚀保护作用，防止工件在加工过程中腐蚀发黑。
附图说明
图1是采用对比例1加工液所得动态缓蚀磨斑形貌图；
图2是采用对比例2加工液所得动态缓蚀磨斑形貌图；
图3是采用对比例3加工液所得动态缓蚀磨斑形貌图；
图4是采用实施例1加工液所得动态缓蚀磨斑形貌图；
图5是采用实施例2加工液所得动态缓蚀磨斑形貌图；
图6是采用实施例3加工液所得动态缓蚀磨斑形貌图；
图7是采用实施例4加工液所得动态缓蚀磨斑形貌图；
图8是采用实施例5加工液所得动态缓蚀磨斑形貌图；
具体实施方式
除有定义外，以下实施例中所用的技术术语具有与本发明所属领域技术人员普遍理解的相同含义。以下实施例中所用的试验试剂，如无特殊说明，均为常规生化试剂；所述实验方法，如无特殊说明，均为常规方法。
下面结合实施例来详细说明本发明。
1、加工液制备方法：
(1)在装有回流冷凝管、搅拌器和温度计的反应釜中加入去离子水、碱值储备剂和腐蚀抑制剂，搅拌升温至70℃，继续搅拌至完全溶解；
(2)移除热源，加入润滑剂、助溶剂，继续搅拌至体系均匀；
(3)持续搅拌至体系冷却至室温，加入杀菌剂和消泡剂搅拌均匀，即得到动态缓蚀型全合成铝合金加工液原液。
具体的，实施例1-6的加工液各组分及含量见表1。
表1实施例1-6加工液组成
对比例1-3的组分如下：
对比例1为空白例，为去离子水；
对比例2：商用半合成金属加工液马斯特TRIM SC550，采用去离子水稀释20倍后使用，稀释液pH值为9.4；
对比例3：商用全合成金属加工液Castrol Syntilo9913，采用去离子水稀释20倍后使用，稀释液pH值为7.5。
2、对实施例1-5和对比例1-3的动态缓蚀性能进行评价
1)评价方法和指标
使用的主要设备为多功能摩擦磨损试验机SRV-2，摩擦副：GCr15钢球-7A60铝盘；负载：20N；行程：2.5mm；频率：20Hz；温度：25℃；加工液浓度：5％(即将浓缩液原液使用去离子水稀释20倍)。
评价方法：
首先用1200号砂纸均匀打磨7A60铝盘表面，然后用酒精将其擦拭干净，先后将GCr15钢球及7A60铝盘固定在SRV试验机上，用滴管将待测液涂布到铝盘表面并保持接触区浸润，调整试验机参数到指定值，进行SRV摩擦磨损实验，实验时间为5min。
实验结束后，将铝盘在酒精中超声清洗10min，使用金相显微镜观察磨痕表面腐蚀情况并测量磨痕宽度，以对测试液动态缓蚀性能进行评价。
2)实验结果：见表2
表2实施例1-5和对比例1-3的磨痕腐蚀及磨痕宽度结果
| 配方 | pH值 | 磨痕宽度/mm | 磨痕腐蚀情况 |
| 实施例1 | 8.4 | 0.46 | 磨痕光亮，无腐蚀 |
| 实施例2 | 7.5 | 0.42 | 磨痕光亮，无腐蚀 |
| 实施例3 | 7.7 | 0.51 | 磨痕小部分发生腐蚀 |
| 实施例4 | 7.8 | 0.35 | 磨痕光亮，无腐蚀 |
| 实施例5 | 7.6 | 0.49 | 磨痕小部分发生轻微腐蚀 |
| 对比例1 | 7.3 | 2.10 | 磨痕整体严重腐蚀 |
| 对比例2 | 9.4 | 0.62 | 磨痕整体腐蚀，程度较浅 |
| 对比例3 | 7.5 | 0.87 | 磨痕大部分区域严重腐蚀 |
由表2可以看出，对比例2和3的商用加工液，其5wt％稀释液的在7A60铝盘表面的动态缓蚀效果较去离子水(见图1)有显著改善，主要体现在磨痕宽度大幅变小，且磨痕处腐蚀情况变好，然而对比例2和3的磨痕处仍整体或大部分发生腐蚀(见图2、图3)，表明二者在铝件新鲜表面受到压力接触摩擦时没有起到足够的动态缓蚀保护作用，其中，由于对比例2是半合成加工液，含有一定的油性成分，动态缓蚀相对较好，腐蚀情况较轻。
而本发明实施例1-5所得加工液均表现出了良好的动态缓蚀效果，磨痕宽度不同程度地减小，其中，实施例4的磨痕宽度与对比例1相比减小近50％(见图7)，且磨痕处腐蚀情况也得到显著改善，达到表面光亮完全无腐蚀(实施例1、2，见图4、5)或腐蚀面积减小(实施例3，见图6)或腐蚀程度较浅(实施例5，见图8)。由此可以基本解决铝件加工过程中动态缓蚀性能不足的问题，为加工过程中的铝件提供足够的动态缓蚀保护，保证铝加工件的光亮无腐蚀。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (10)
1.一种动态缓蚀型水基全合成铝合金加工液，其特征在于：所述加工液包括如下重量份数的组分：
润滑剂 10-40份；
碱值储备剂 5-20份；
其他助剂 15-40份；
水 20-60份。
2.根据权利要求1所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述润滑剂为环氧乙烷—环氧丙烷嵌段共聚物(EO-PO)。
3.根据权利要求2所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述环氧乙烷—环氧丙烷嵌段共聚物为分子量为1000-3500，浊点为30-55℃的嵌段聚醚。
4.根据权利要求1所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述碱值储备剂选自乙醇胺、氢氧化钠、氢氧化钾、异丁醇胺、正丁胺、二异丙胺、二乙醇胺、三乙醇胺、异丙醇胺、二甲基乙醇胺、二甲基己胺、正丙醇胺、二异丙醇胺、N-甲基二乙醇胺、二甘醇胺、环己胺、二环己胺、二甲基癸叔胺、乙二胺、己二胺、正丁胺、三丁胺、三辛胺、吗啉中的至少一种；优选为乙醇胺、二乙醇胺、三乙醇胺、吗啉、N-甲基二乙醇胺、二甘醇胺、环己胺、异丙醇胺、正丙醇胺中的一种或两种以上的混合物。
5.根据权利要求1所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述其他助剂包括如下重量份数的一种或两种以上组分：腐蚀抑制剂10-25份，助溶剂0-15份，抗菌剂0.2-5份，消泡剂0.2-5份。
6.根据权利要求5所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述腐蚀抑制剂为有机三元羧酸、碳酸盐、三嗪衍生物、1,2-二乙氧基硅酯基乙烷、石油磺酸盐、二硝基苯甲酸、硫代磷酸酯、季戊四醇酯、脂肪酸酰胺、十二烷基苯磺酸钠、甲基咪唑啉、甲基硅酸钠、硼酸酯、N-酰基氨基酸衍生物、醇醚磷酸酯、甲基苯并三氮唑、硝基苯并三氮唑、氨基磺酸中的一种或两种以上的混合物。
7.根据权利要求5所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述助溶剂为正辛酸、异辛酸、正丁醇、异丁醇、吐温、水杨酸、丙三醇、乙二醇醚、丙二醇醚、异壬酸、癸二酸、异丙醇、新癸酸、丙二醇、乙二醇中的一种或两种以上的混合物。
8.根据权利要求5所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述抗菌剂为六氢三嗪化合物、乙二醇二羟甲醚、异噻唑啉酮衍生物、月桂胺二亚丙基二胺、吡硫鎓钠、吡啶硫酮钠、3,3’亚甲基(5-甲基恶唑烷)、四羟甲基甘脲中的一种或两种以上的混合物。进一步的，所述消泡剂为聚醚-硅氧烷共聚物和/或聚硅氧烷。
9.根据权利要求1或5所述的动态缓蚀型水基全合成铝合金加工液，其特征在于：所述加工液的pH值为7.5-9.0。
10.一种铝合金的加工方法，其特征在于：，在铝合金加工过程中使用了权利要求1-9中任一所述的水基全合成铝合金加工液。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710632455.9A CN107488494A (zh) | 2017-07-28 | 2017-07-28 | 一种动态缓蚀型水基全合成铝合金加工液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710632455.9A CN107488494A (zh) | 2017-07-28 | 2017-07-28 | 一种动态缓蚀型水基全合成铝合金加工液 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107488494A true CN107488494A (zh) | 2017-12-19 |
Family
ID=60644689
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710632455.9A Pending CN107488494A (zh) | 2017-07-28 | 2017-07-28 | 一种动态缓蚀型水基全合成铝合金加工液 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107488494A (zh) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753430A (zh) * | 2018-07-18 | 2018-11-06 | 嘉兴市国龙石油化工有限公司 | 一种水溶性不锈钢攻牙膏 |
| CN108774574A (zh) * | 2018-04-08 | 2018-11-09 | 清华大学天津高端装备研究院 | 一种全合成水基防锈复合剂及其评价方法和应用 |
| CN108822951A (zh) * | 2018-08-23 | 2018-11-16 | 上海添蓝生物科技有限公司 | 一种环保型铝合金全合成液组合物 |
| CN108913316A (zh) * | 2018-07-10 | 2018-11-30 | 钱敏伟 | 一种环保型水基防锈切削液及其制备方法 |
| CN109401827A (zh) * | 2018-10-23 | 2019-03-01 | 常州高特新材料有限公司 | 一种铝散热翅片用冲压液及其制备方法 |
| CN109777591A (zh) * | 2019-04-02 | 2019-05-21 | 陕西省石油化工研究设计院 | 一种全合成切削液及其制备方法及应用 |
| CN110318059A (zh) * | 2019-08-09 | 2019-10-11 | 中北大学 | 一种复配型碳钢酸洗缓蚀剂及其应用 |
| CN111849599A (zh) * | 2020-07-03 | 2020-10-30 | 浙江物得宝尔新材料有限公司 | 一种水溶性润滑液及铝冷轧的加工方法 |
| CN111909769A (zh) * | 2020-07-03 | 2020-11-10 | 浙江物得宝尔新材料有限公司 | 一种水溶性润滑液及铝冷轧的加工方法 |
| CN113072987A (zh) * | 2021-04-19 | 2021-07-06 | 湖南中化油能源集团有限公司 | 一种应用于煤基生物燃料的车船用添加剂及其制备方法 |
| CN113549486A (zh) * | 2021-07-26 | 2021-10-26 | 富兰克科技（深圳）股份有限公司 | 一种组合物的应用及其制备方法 |
| CN113736551A (zh) * | 2021-09-08 | 2021-12-03 | 长沙艾森设备维护技术有限公司 | 一种金属挤压攻丝液 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0959696A (ja) * | 1995-08-24 | 1997-03-04 | Shin Etsu Handotai Co Ltd | 切削液及びワークの切断方法 |
| CN104277902A (zh) * | 2014-09-12 | 2015-01-14 | 广州中机实业有限公司 | 一种重负荷金属加工全合成切削液及其制备方法与应用 |
| CN105482888A (zh) * | 2015-12-23 | 2016-04-13 | 南京科润工业介质股份有限公司 | 一种可满足多类材质加工需求的全合成切削液 |
| CN106929136A (zh) * | 2015-12-29 | 2017-07-07 | 上海众阖环保科技有限公司 | 一种全合成型冷轧辊磨削液及其制备方法 |
-
2017
- 2017-07-28 CN CN201710632455.9A patent/CN107488494A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0959696A (ja) * | 1995-08-24 | 1997-03-04 | Shin Etsu Handotai Co Ltd | 切削液及びワークの切断方法 |
| CN104277902A (zh) * | 2014-09-12 | 2015-01-14 | 广州中机实业有限公司 | 一种重负荷金属加工全合成切削液及其制备方法与应用 |
| CN105482888A (zh) * | 2015-12-23 | 2016-04-13 | 南京科润工业介质股份有限公司 | 一种可满足多类材质加工需求的全合成切削液 |
| CN106929136A (zh) * | 2015-12-29 | 2017-07-07 | 上海众阖环保科技有限公司 | 一种全合成型冷轧辊磨削液及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 邢颖春: "《国内外炼油装置技术现状与进展》", 31 October 2006, 石油工业出版社 * |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108774574A (zh) * | 2018-04-08 | 2018-11-09 | 清华大学天津高端装备研究院 | 一种全合成水基防锈复合剂及其评价方法和应用 |
| CN108774574B (zh) * | 2018-04-08 | 2022-08-19 | 超滑科技(佛山)有限责任公司 | 一种全合成水基防锈复合剂及其评价方法和应用 |
| CN108913316A (zh) * | 2018-07-10 | 2018-11-30 | 钱敏伟 | 一种环保型水基防锈切削液及其制备方法 |
| CN108913316B (zh) * | 2018-07-10 | 2021-11-16 | 富地润滑科技股份有限公司 | 一种环保型水基防锈切削液及其制备方法 |
| CN108753430A (zh) * | 2018-07-18 | 2018-11-06 | 嘉兴市国龙石油化工有限公司 | 一种水溶性不锈钢攻牙膏 |
| CN108822951A (zh) * | 2018-08-23 | 2018-11-16 | 上海添蓝生物科技有限公司 | 一种环保型铝合金全合成液组合物 |
| CN109401827A (zh) * | 2018-10-23 | 2019-03-01 | 常州高特新材料有限公司 | 一种铝散热翅片用冲压液及其制备方法 |
| CN109777591B (zh) * | 2019-04-02 | 2021-09-28 | 陕西省石油化工研究设计院 | 一种全合成切削液及其制备方法及应用 |
| CN109777591A (zh) * | 2019-04-02 | 2019-05-21 | 陕西省石油化工研究设计院 | 一种全合成切削液及其制备方法及应用 |
| CN110318059A (zh) * | 2019-08-09 | 2019-10-11 | 中北大学 | 一种复配型碳钢酸洗缓蚀剂及其应用 |
| CN110318059B (zh) * | 2019-08-09 | 2021-03-16 | 中北大学 | 一种复配型碳钢酸洗缓蚀剂及其应用 |
| CN111909769A (zh) * | 2020-07-03 | 2020-11-10 | 浙江物得宝尔新材料有限公司 | 一种水溶性润滑液及铝冷轧的加工方法 |
| CN111849599A (zh) * | 2020-07-03 | 2020-10-30 | 浙江物得宝尔新材料有限公司 | 一种水溶性润滑液及铝冷轧的加工方法 |
| CN111909769B (zh) * | 2020-07-03 | 2022-10-28 | 浙江物得宝尔新材料有限公司 | 一种水溶性润滑液及铝冷轧的加工方法 |
| CN113072987A (zh) * | 2021-04-19 | 2021-07-06 | 湖南中化油能源集团有限公司 | 一种应用于煤基生物燃料的车船用添加剂及其制备方法 |
| CN113549486A (zh) * | 2021-07-26 | 2021-10-26 | 富兰克科技（深圳）股份有限公司 | 一种组合物的应用及其制备方法 |
| CN113736551A (zh) * | 2021-09-08 | 2021-12-03 | 长沙艾森设备维护技术有限公司 | 一种金属挤压攻丝液 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107488494A (zh) | 一种动态缓蚀型水基全合成铝合金加工液 | |
| CN108774574B (zh) | 一种全合成水基防锈复合剂及其评价方法和应用 | |
| CN108277077A (zh) | 一种高硬水防锈型水基全合成黑色金属加工液 | |
| CN106479657B (zh) | 一种水基全合成钛合金切削液 | |
| CN105001964A (zh) | 微乳化切削液 | |
| CN104087404A (zh) | 一种高清洁、经济型微乳化金属切削液 | |
| CN109536263A (zh) | 一种金属加工用磨削液及其制备方法 | |
| JP5487516B2 (ja) | 水溶性金属加工油剤 | |
| CN106916615B (zh) | 一种水性切削液的复合缓蚀剂、制备方法及水性切削液 | |
| CN108441293A (zh) | 一种抗硬水半合成金属加工液及其制备方法 | |
| AU2003289934B2 (en) | Lubricant coated sheet metal with improved deformation properties | |
| JP5291292B2 (ja) | 金属加工用油剤及び金属加工方法 | |
| CN107034003A (zh) | 超低泡全合成水基润滑液 | |
| CN103351929A (zh) | 一种防锈金属切削液 | |
| JP4780849B2 (ja) | 水溶性金属加工油剤組成物 | |
| US4670168A (en) | Aqueous metal removal fluid | |
| JP2008291211A (ja) | 金属加工油剤 | |
| EP0192358B1 (en) | Metal working fluid composition | |
| CN106894023B (zh) | 一种铝合金缓蚀组合物及其制备方法 | |
| CN104277898A (zh) | 一种全合成切削液 | |
| CN106637252B (zh) | 一种应用于碱性水基清洗剂中的铝合金缓蚀剂 | |
| JPS591686A (ja) | 冷間圧延鋼板用調質液 | |
| CN108441310A (zh) | 一种金属加工用半合成切削液及其制备方法 | |
| CN108504431A (zh) | 环保防锈水基切削液 | |
| CN109234740A (zh) | 7075铝合金用缓蚀剂、微乳化加工原液及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190613 Address after: 300300 Dongli Lake Resort, Dongli District, Tianjin Applicant after: TSINGHUA UNIVERSITY TIANJIN HIGH-END EQUIPMENT RESEARCH INSTITUTE Applicant after: Tsinghua University Address before: 300300 Dongli Lake Resort, Dongli District, Tianjin Applicant before: TSINGHUA UNIVERSITY TIANJIN HIGH-END EQUIPMENT RESEARCH INSTITUTE |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171219 |
|
| RJ01 | Rejection of invention patent application after publication |