CN107475861A - A kind of preparation method of the stretch-proof fabric containing chitosan - Google Patents
A kind of preparation method of the stretch-proof fabric containing chitosan Download PDFInfo
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- CN107475861A CN107475861A CN201710646601.3A CN201710646601A CN107475861A CN 107475861 A CN107475861 A CN 107475861A CN 201710646601 A CN201710646601 A CN 201710646601A CN 107475861 A CN107475861 A CN 107475861A
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
- C07H5/04—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to nitrogen
- C07H5/06—Aminosugars
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/06—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
Abstract
The invention discloses a kind of preparation method of the stretch-proof fabric containing chitosan, include the blending of modification of the chitosan to cotton fiber, chitosan cotton fiber and polyketone fiber, chitosan is degraded first with ultrasonic assistant hydrogen peroxide oxidation edman degradation Edman, then chitosan cotton fiber will be obtained in degraded chitosan processing to bafta, finally dispersant, binding agent, softening agent and water will be added in glycan cotton fiber and polyketone fiber carries out blending.The present invention makes fabric obtain unique performance such as chitosan anti-bacteria, environmental protection, biodegradable, and chitosan cotton fiber after polyketone fiber blending with making the more solid stretch-proof of fabric.
Description
Technical field
The present invention relates to the manufacture field of antibacterial stretch-proof fabric, is a kind of stretch-proof containing chitosan specifically
The preparation method of fabric.
Background technology
Cotton fiber has many excellent properties such as water suction, moisture absorption, easy dyeing, soft, comfortable and easy to wear, intensity is suitable
Deng, but simultaneously there is also many shortcomings such as wash and wear is poor, shape-retaining ability is poor, easily shrink, moisture releasing is relatively slow, dyefastness compared with
Difference, product specification are relatively low etc..After bafta chitosan or chitosan derivatives arrange, its defect can be substantially improved, simultaneously
Unique performance can also be obtained.Cotton fiber wrinkle resistance is poor, and in general anti wrinkling agent is taking process after being organized on fabric
In can produce formaldehyde, after being arranged with chitosan solution, the wrinkle resistance of bafta is greatly improved, while antibiotic property, moisture absorption are breathed freely
Property, washing fastness also improve.
Chitosan molecule amount it is general all in hundreds of thousands between millions of, be insoluble in water substantially, it is molten to be only soluble in part diluted acid
In liquid, its application greatly limit.In recent years, people are to the comfortableness of garment material, health, security and the feature of environmental protection
It is more and more to the dress ornament demand of safe and efficient tensile strength etc. requiring more and more higher, but high tensile strength material adds at present
The comparison of ingredients added is single, and the function having is also relatively simple, unified to solve comfortable, stretch-proof, desinsection, absorbing sweat, warming
Etc. function.
By ethene with the polyketone that the repeat unit of carbon monoxide is formed as polyethylene and polyvinyl alcohol, strand can be with
Obtain the conformation of planar zigzag form.Therefore, by stretching strand can be made height-oriented, it can obtain that there is referred to as advanced fibre
Tie up high tensile, the fiber of high tensile modulus of elasticity in region.In addition, the stretching under its high temperature of the polyketone so obtained is strong
Degree, the retentivity of tensile modulus of elasticity and dimensional stability might as well.The viscosity average molecular weigh of polyketone is at 30,000 or so, polyketone solution
Stable thread can not be formed, fibre forming property is very poor, can be into fibre when the viscosity average molecular weigh of polyketone reaches 60,000, but maximal draw ratio is only
Have 1.6, then gradually increase with the increase of viscosity average molecular weigh, maximal draw ratio, spinnability gradually steps up, and viscosity average molecular weigh reaches
During to 200,000 or so, with good spinnability.
The content of the invention
It is an object of the invention to provide a kind of preparation method of the stretch-proof fabric containing chitosan, can overcome it is existing
The stretch-proof that fabric is improved while the inherent shortcomings such as cotton fiber wash and wear is poor in technology, shape-retaining ability is poor, easily shrinks is strong
Degree.
The present invention is achieved through the following technical solutions:A kind of preparation method of the stretch-proof fabric containing chitosan, including
The blending of modification of the chitosan to cotton fiber, chitosan cotton fiber and polyketone fiber.
Above-mentioned chitosan includes to the step of cotton fiber modification:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta.
Above-mentioned steps S1 ultrasonic assistant peroxide passivation oxidative degradation chitosan methods are as follows:The degraded system used is 4%
Chitosan be dispersed in 5% acetic acid solution, stir into homogeneous state, be then 40W in the power of ultrasonic wave, reaction temperature
Under conditions of 40 DEG C, a certain amount of hydrogen peroxide is added dropwise, after the completion of titration, carries out ultrasonic degradation, hydrogen peroxide and chitosan
The amount ratio of material is 1:1, degrade and continue 3h, after the completion of reaction, be neutralized to neutrality with 5% sodium hydroxide, be added dropwise equivalent to reaction
The acetone of thing two volumes, after placing 24 hours, filter, 60 DEG C of vacuum drying.
In order to which the present invention is better achieved, as preferable, preliminary drying condition is 80 DEG C in above-mentioned steps S2,5min, is baked
Condition is 160 DEG C, 2.5min.
Above-mentioned chitosan cotton fiber includes with the step of polyketone fiber blending:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 0.8~1.2G/L desizing enzyme, then temperature control makes at 40~45 DEG C
Cleaned half an hour with clear water, finally dried in dryer, temperature control is at 100~120 DEG C.
In order to preferably realize the present invention, as preferable, dispersant is PAMA in above-mentioned steps A1,
Binding agent is Acrylate Emulsion Adhesive or polyvinyl chloride emulsion, and softening agent is cationic softener or organosilicon flexible
Agent.
In order to preferably realize the present invention, as preferable, desizing enzyme is medium temperature amylase in above-mentioned steps A4.
In order to preferably realize the present invention, further, the blending of above-mentioned chitosan cotton fiber and polyketone fiber includes will
The cloth that step A4 is obtained impregnates 50~70min in sweat absorption and flash drying processing agent, then bakes at 70~80 DEG C, finally shapes
Processing.
In order to preferably realize the present invention, as preferable, above-mentioned sweat absorption and flash drying processing agent is by water-dispersible polyester, poly- ammonia
Carbamate, organosilicon composition.
The present invention compared with prior art, has advantages below and beneficial effect:
(1)Chitosan is degraded using ultrasonic assistant hydrogen peroxide oxidation edman degradation Edman, obtains the low molecule required for us
Chitosan is measured, expands the use range and application field of chitosan, then degraded chitosan is handled onto bafta, makes face
Material obtains unique performance such as chitosan anti-bacteria, environmental protection, biodegradable.
(2)Polyketone has good spinnability, into fibre after have high tensile, high tensile modulus of elasticity, with chitosan
Cotton
Make the more solid stretch-proof of fabric after fiber blend.
Embodiment
With reference to embodiment, the present invention is further illustrated.
Ultrasonic assistant peroxide passivation oxidative degradation chitosan method is as follows in following examples:The degraded system used for
4% chitosan is dispersed in 5% acetic acid solution, stirs into homogeneous state, is then 40W in the power of ultrasonic wave, reaction temperature
Spend under conditions of 40 DEG C, a certain amount of hydrogen peroxide is added dropwise, after the completion of titration, carry out ultrasonic degradation, hydrogen peroxide and chitosan
Material amount ratio be 1:1, degrade and continue 3h, after the completion of reaction, be neutralized to neutrality with 5% sodium hydroxide, be added dropwise equivalent to anti-
The acetone of thing two volumes is answered, after placing 24 hours, is filtered, 60 DEG C of vacuum drying.
Embodiment 1:
A kind of preparation method of the stretch-proof fabric containing chitosan of the present embodiment, including modification of the chitosan to cotton fiber,
The blending of chitosan cotton fiber and polyketone fiber, wherein chitosan are as follows to the modification procedure of cotton fiber:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta;
It is that will roll, and be repeated twice through roll after bafta leaching chitosan that wherein two leachings two, which are rolled, and preliminary drying condition is 80 DEG C, 5min,
It is 160 DEG C to bake condition, 2.5min;
The step of chitosan cotton fiber is with polyketone fiber blending is as follows:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 0.8G/L Thermostable α-Amylase, temperature control is at 40~45 DEG C, so
Afterwards using clear water cleaning half an hour, finally dried in dryer, temperature control is at 100~120 DEG C;
Wherein, dispersant is PAMA, and binding agent is Acrylate Emulsion Adhesive, and softening agent is cationic
Softening agent.
Embodiment 2:
A kind of preparation method of the stretch-proof fabric containing chitosan of the present embodiment, including modification of the chitosan to cotton fiber,
The blending of chitosan cotton fiber and polyketone fiber, wherein chitosan are as follows to the modification procedure of cotton fiber:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta;
It is that will roll, and be repeated twice through roll after bafta leaching chitosan that wherein two leachings two, which are rolled, and preliminary drying condition is 80 DEG C, 5min,
It is 160 DEG C to bake condition, 2.5min;
The step of chitosan cotton fiber is with polyketone fiber blending is as follows:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 1.2G/L medium temperature amylase, then temperature control makes at 40~45 DEG C
Cleaned half an hour with clear water, finally dried in dryer, temperature control is at 100~120 DEG C;
Wherein, dispersant is PAMA, and binding agent is polyvinyl chloride emulsion, and softening agent is organosilicon flexible
Agent.
Embodiment 3:
A kind of preparation method of the stretch-proof fabric containing chitosan of the present embodiment, including modification of the chitosan to cotton fiber,
The blending of chitosan cotton fiber and polyketone fiber, wherein chitosan are as follows to the modification procedure of cotton fiber:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta;
It is that will roll, and be repeated twice through roll after bafta leaching chitosan that wherein two leachings two, which are rolled, and preliminary drying condition is 80 DEG C, 5min,
It is 160 DEG C to bake condition, 2.5min;
The step of chitosan cotton fiber is with polyketone fiber blending is as follows:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 1.0G/L medium temperature amylase, then temperature control makes at 40~45 DEG C
Cleaned half an hour with clear water, finally dried in dryer, temperature control is at 100~120 DEG C;
Wherein, dispersant is PAMA, and binding agent is Acrylate Emulsion Adhesive, and softening agent is that organosilicon is soft
Soft dose.
Embodiment 4:
A kind of preparation method of the stretch-proof fabric containing chitosan of the present embodiment, including modification of the chitosan to cotton fiber,
The blending of chitosan cotton fiber and polyketone fiber, wherein chitosan are as follows to the modification procedure of cotton fiber:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta;
It is that will roll, and be repeated twice through roll after bafta leaching chitosan that wherein two leachings two, which are rolled, and preliminary drying condition is 80 DEG C, 5min,
It is 160 DEG C to bake condition, 2.5min;
The step of chitosan cotton fiber is with polyketone fiber blending is as follows:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 1.0G/L medium temperature amylase, then temperature control makes at 40~45 DEG C
Cleaned half an hour with clear water, finally dried in dryer, temperature control is at 100~120 DEG C;
A5. the cloth that step A4 is obtained is impregnated into 50~70min in sweat absorption and flash drying processing agent, then roasted at 70~80 DEG C
It is roasting, last heat treatment;
Wherein, dispersant is PAMA in A1, and binding agent is Acrylate Emulsion Adhesive, and softening agent is organic
Silicone softener;Sweat absorption and flash drying processing agent is made up of water-dispersible polyester, polyurethanes, organosilicon in A5.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments.Simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.
Claims (9)
1. a kind of preparation method of the stretch-proof fabric containing chitosan, it is characterised in that change including chitosan to cotton fiber
The blending of property, chitosan cotton fiber and polyketone fiber.
2. the preparation method of a kind of stretch-proof fabric containing chitosan according to claim 1, it is characterised in that described
Chitosan includes to the step of cotton fiber modification:
S1. ultrasonic assistant peroxide passivation oxidative degradation chitosan is used;
S2. gather shell by the way that two leachings two are rolled, preliminary drying, baking flow are handled bafta in chitosan treatment fluid
Sugar is handled onto bafta.
3. the preparation method of a kind of stretch-proof fabric containing chitosan according to claim 2, it is characterised in that described
Step S1 ultrasonic assistant peroxide passivation oxidative degradation chitosan methods are as follows:The degraded system used is disperseed for 4% chitosan
In 5% acetic acid solution, homogeneous state is stirred into, is then 40W in the power of ultrasonic wave, reaction temperature is 40 DEG C of condition
Under, a certain amount of hydrogen peroxide is added dropwise, after the completion of titration, carries out ultrasonic degradation, the amount ratio of the material of hydrogen peroxide and chitosan is
1:1, degrade and continue 3h, after the completion of reaction, be neutralized to neutrality with 5% sodium hydroxide, be added dropwise equivalent to reactant two volumes
Acetone, after placing 24 hours, filter, 60 DEG C of vacuum drying.
4. the preparation method of a kind of stretch-proof fabric containing chitosan according to claim 2, it is characterised in that described
Preliminary drying condition is 80 DEG C, 5min in step S2, and the condition that bakes is 160 DEG C, 2.5min.
A kind of 5. preparation method of stretch-proof fabric containing chitosan according to claim 1, it is characterised in that:It is described
Chitosan cotton fiber includes with the step of polyketone fiber blending:
A1. by chitosan cotton fiber, polyketone fiber at 40~45 DEG C, dispersant, binding agent, softening agent and water, mixing are added
Stir, dry shaping;
A2. functional yams lines are made by blowing, opener, drafting, rove, spun yarn in mixture A1 obtained;
A3. cloth is made in the knitting of above-mentioned functional yarn strip adoption or weaving;
A4. cloth is placed 40~50 minutes in 0.8~1.2G/L desizing enzyme, then temperature control makes at 40~45 DEG C
Cleaned half an hour with clear water, finally dried in dryer, temperature control is at 100~120 DEG C.
A kind of 6. preparation method of stretch-proof fabric containing chitosan according to claim 5, it is characterised in that:It is described
Dispersant is PAMA in step A1, and binding agent is Acrylate Emulsion Adhesive or polyvinyl chloride emulsion,
Softening agent is cationic softener or silicone softening agent.
A kind of 7. preparation method of stretch-proof fabric containing chitosan according to claim 5, it is characterised in that:It is described
Desizing enzyme is Thermostable α-Amylase or medium temperature amylase in step A4.
8. the preparation method of a kind of stretch-proof fabric containing chitosan according to claim 5, it is characterised in that described
The blending of chitosan cotton fiber and polyketone fiber includes step A5:The cloth that step A4 is obtained is soaked in sweat absorption and flash drying processing agent
50~70min of stain, then baked at 70~80 DEG C, last heat treatment.
A kind of 9. preparation method of stretch-proof fabric containing chitosan according to claim 8, it is characterised in that:It is described
Sweat absorption and flash drying processing agent is made up of water-dispersible polyester, polyurethanes, organosilicon.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109162011A (en) * | 2018-08-28 | 2019-01-08 | 上海题桥纺织染纱有限公司 | A kind of polyester fiber that chitosan-is organic-silicon-modified knitting fabric and preparation method thereof |
CN109853108A (en) * | 2018-12-05 | 2019-06-07 | 李霞 | A kind of not hair loss pro-skin flexible material and its manufacture craft of super-strong moisture absorbing function |
CN114875682A (en) * | 2022-05-09 | 2022-08-09 | 广东前进牛仔布有限公司 | Environment-friendly treatment method for reducing shrinkage of elastic fabric and elastic fabric |
Citations (5)
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CN109162011A (en) * | 2018-08-28 | 2019-01-08 | 上海题桥纺织染纱有限公司 | A kind of polyester fiber that chitosan-is organic-silicon-modified knitting fabric and preparation method thereof |
CN109853108A (en) * | 2018-12-05 | 2019-06-07 | 李霞 | A kind of not hair loss pro-skin flexible material and its manufacture craft of super-strong moisture absorbing function |
CN114875682A (en) * | 2022-05-09 | 2022-08-09 | 广东前进牛仔布有限公司 | Environment-friendly treatment method for reducing shrinkage of elastic fabric and elastic fabric |
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