CN107474763A - A kind of heat-resistant adhesive and preparation method thereof - Google Patents
A kind of heat-resistant adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN107474763A CN107474763A CN201710818167.2A CN201710818167A CN107474763A CN 107474763 A CN107474763 A CN 107474763A CN 201710818167 A CN201710818167 A CN 201710818167A CN 107474763 A CN107474763 A CN 107474763A
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- China
- Prior art keywords
- parts
- heat
- resistant adhesive
- weight
- crosslinking agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J181/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
- C09J181/06—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of heat-resistant adhesive and preparation method thereof, belong to chemical technology field.Its its be made up of the raw material of following parts by weight：2~10 parts of 6~16 parts of terpene resin, 4~10 parts of polyvinyl alcohol, 3~9 parts of expoxy propane phenyl ether, 4~10 parts of silicone acrylic emulsion, 1~5 part of methyl acetate, 4~10 parts of polysulfone resin, 3~9 parts of hydroxypropyl PASELLI EASYGEL, 2~6 parts of dibutyl phthalate, 2~6 parts of N methyl pyrrolidones, 3~9 parts of polyethylene, 4~10 parts of triisopropanolamine, 4~10 parts of antioxidant and crosslinking agent.The adhesive of the present invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, and bond effect is good, and preparation is simple, cost is cheap, function admirable.
Description
Technical field
The present invention relates to a kind of heat-resistant adhesive and preparation method thereof, belong to chemical technology field.
Background technology
Adhesive, refer to homogeneity or the technology that heterogeneous body surface is linked together with adhesive, there is stress distribution to connect
The features such as continuous, in light weight, technological temperature is low.It is glued especially suitable for unlike material, different-thickness, ultra-thin specification and complex component
Connection.Splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide.The sorting technique of adhesive is a lot, can be divided into heat by application process
Curable type, heat molten type, room temperature curing type, pressure sensitive etc.；It is divided into structural type, non-configuration or special gelatin by application；Connecing form can
It is divided into water-soluble, emulsion type, solvent-borne type and various solid-state versions etc.；Traditional adhesive production cost is high, and using effect is bad.
The content of the invention
The purpose of the present invention is to make up the deficiencies in the prior art, there is provided a kind of heat-resistant adhesive and preparation method thereof.This hair
Bright adhesive has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, bonds
Effect is good, and preparation is simple, cost is cheap, function admirable.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of heat-resistant adhesive, by following parts by weight
Raw material is made：6~16 parts of terpene resin, 4~10 parts of polyvinyl alcohol, 3~9 parts of expoxy propane phenyl ether, silicone acrylic emulsion 4~10
Part, 1~5 part of methyl acetate, 4~10 parts of polysulfone resin, 3~9 parts of hydroxypropyl PASELLI EASYGEL, dibutyl phthalate 2
~6 parts, 2~6 parts of 1-METHYLPYRROLIDONE, 3~9 parts of polyethylene, 4~10 parts of triisopropanolamine, 4~10 parts of antioxidant and friendship
Join 2~10 parts of agent.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, it is made up of the raw material of following parts by weight：11 parts of terpene resin, 7 parts of polyvinyl alcohol, expoxy propane phenyl
6 parts of ether, 7 parts of silicone acrylic emulsion, 3 parts of methyl acetate, 7 parts of polysulfone resin, 6 parts of hydroxypropyl PASELLI EASYGEL, phthalic acid two
6 parts of 4 parts of butyl ester, 4 parts of 1-METHYLPYRROLIDONE, 6 parts of polyethylene, 7 parts of triisopropanolamine, 7 parts of antioxidant and crosslinking agent.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
A kind of preparation method of heat-resistant adhesive, comprises the following steps：
(1) raw material of following parts by weight is weighed：6~16 parts of terpene resin, 4~10 parts of polyvinyl alcohol, expoxy propane benzene
3~9 parts of base ether, 4~10 parts of silicone acrylic emulsion, 1~5 part of methyl acetate, 4~10 parts of polysulfone resin, hydroxypropyl PASELLI EASYGEL 3
~9 parts, 2~6 parts of dibutyl phthalate, 2~6 parts of 1-METHYLPYRROLIDONE, 3~9 parts of polyethylene, triisopropanolamine 4~
10 parts, add in reactor, progressively heat up, and be slowly stirred, start timing, insulation 20~40 when temperature rises to 90~96 DEG C
Minute, while at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds antioxidant and 2~10 parts of crosslinking agent that parts by weight are 4~10 parts,
After stirring, the heat-resistant adhesive is produced.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the parts by weight of step (1) described raw material are：11 parts of terpene resin, 7 parts of polyvinyl alcohol, expoxy propane
6 parts of phenyl ether, 7 parts of silicone acrylic emulsion, 3 parts of methyl acetate, 7 parts of polysulfone resin, 6 parts of hydroxypropyl PASELLI EASYGEL, O-phthalic
4 parts of dibutyl phthalate, 4 parts of 1-METHYLPYRROLIDONE, 6 parts of polyethylene, 7 parts of triisopropanolamine.
Further, the parts by weight of step (2) described antioxidant are 7 parts, and the parts by weight of the crosslinking agent are 6 parts.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
The beneficial effects of the invention are as follows：
(1) adhesive of the invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has very
Good caking property, bond effect are good.
(2) it is of the invention to prepare that simple, cost is cheap, function admirable, it is adapted to large-scale production.
Embodiment
The principle and feature of the present invention are described below in conjunction with specific embodiment, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1：
The heat-resistant adhesive of the present embodiment, it is made up of the raw material of following weight：Terpene resin 6kg, polyvinyl alcohol 10kg, ring
Ethylene Oxide phenyl ether 3kg, silicone acrylic emulsion 10kg, methyl acetate 1kg, polysulfone resin 10kg, hydroxypropyl PASELLI EASYGEL 3kg,
Dibutyl phthalate 6kg, 1-METHYLPYRROLIDONE 2kg, polyethylene 9kg, triisopropanolamine 4kg, vitamin E oil 10kg and
Glyoxal 2kg.
The preparation method of the heat-resistant adhesive of the present embodiment, comprises the following steps：
(1) raw material of following weight is weighed：Terpene resin 6kg, polyvinyl alcohol 10kg, expoxy propane phenyl ether 3kg, silicon third
Emulsion 10kg, methyl acetate 1kg, polysulfone resin 10kg, hydroxypropyl PASELLI EASYGEL 3kg, dibutyl phthalate 6kg,
1-METHYLPYRROLIDONE 2kg, polyethylene 9kg, triisopropanolamine 4kg, add in reactor, progressively heat up, and be slowly stirred, treat
Temperature starts timing when rising to 90 DEG C, be incubated 20 minutes, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds 10kg vitamin E oil and 2kg glyoxal, after stirring, produces institute
State heat-resistant adhesive.
Embodiment 2：
The heat-resistant adhesive of the present embodiment, it is made up of the raw material of following weight：Terpene resin 11kg, polyvinyl alcohol 7kg, ring
Ethylene Oxide phenyl ether 6kg, silicone acrylic emulsion 7kg, methyl acetate 3kg, polysulfone resin 7kg, hydroxypropyl PASELLI EASYGEL 6kg, neighbour
Dibatyl phithalate 4kg, 1-METHYLPYRROLIDONE 4kg, polyethylene 6kg, triisopropanolamine 7kg, vitamin E oil 7kg and second
Dialdehyde 6kg.
The preparation method of the heat-resistant adhesive of the present embodiment, comprises the following steps：
(1) raw material of following weight is weighed：Terpene resin 11kg, polyvinyl alcohol 7kg, expoxy propane phenyl ether 6kg, silicon third
Emulsion 7kg, methyl acetate 3kg, polysulfone resin 7kg, hydroxypropyl PASELLI EASYGEL 6kg, dibutyl phthalate 4kg, N-
Methyl pyrrolidone 4kg, polyethylene 6kg, triisopropanolamine 7kg, add in reactor, progressively heat up, and be slowly stirred, treat temperature
Degree starts timing when rising to 93 DEG C, be incubated 30 minutes, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds 7kg vitamin E oil and 6kg glyoxal, after stirring, produces institute
State heat-resistant adhesive.
Embodiment 3：
The heat-resistant adhesive of the present embodiment, it is made up of the raw material of following weight：Terpene resin 16kg, polyvinyl alcohol 4kg, ring
Ethylene Oxide phenyl ether 9kg, silicone acrylic emulsion 4kg, methyl acetate 5kg, polysulfone resin 4kg, hydroxypropyl PASELLI EASYGEL 9kg, neighbour
Dibatyl phithalate 2kg, 1-METHYLPYRROLIDONE 6kg, polyethylene 3kg, triisopropanolamine 10kg, vitamin E oil 4kg and second
Dialdehyde 10kg.
The preparation method of the heat-resistant adhesive of the present embodiment, comprises the following steps：
(1) raw material of following weight is weighed：Terpene resin 16kg, polyvinyl alcohol 4kg, expoxy propane phenyl ether 9kg, silicon third
Emulsion 4kg, methyl acetate 5kg, polysulfone resin 4kg, hydroxypropyl PASELLI EASYGEL 9kg, dibutyl phthalate 2kg, N-
Methyl pyrrolidone 6kg, polyethylene 3kg, triisopropanolamine 10kg, add in reactor, progressively heat up, and be slowly stirred, treat
Temperature starts timing when rising to 96 DEG C, be incubated 40 minutes, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds 4kg vitamin E oil and 10kg glyoxal, after stirring, produces institute
State heat-resistant adhesive.
Comparative example
The adhesive of certain domestic producer is taken, it includes the raw material of following weight：Terpene resin 8kg, triethanolamine 5kg, ring
Ethylene Oxide phenyl ether 7kg, phenolic resin 2kg, methyl acetate 6kg, polysulfone resin 5kg, hydroxypropyl PASELLI EASYGEL 8kg, stone
Cotton powder 2kg, with embodiment 1-3 obtained by resistant to elevated temperatures adhesive contrast, viscous material phase same material fine powder 300kg.Contrast
As a result it is as shown in table 1.
The comparing result of the prior art of table 1 and the method for the present invention
As can be seen here, adhesive of the invention has good resistance to elevated temperatures, at high temperature can be with normal use, simultaneously
It is good with good caking property, bond effect.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (7)
1. a kind of heat-resistant adhesive, it is characterised in that be made up of the raw material of following parts by weight：6~16 parts of terpene resin, poly- second
4~10 parts of enol, 3~9 parts of expoxy propane phenyl ether, 4~10 parts of silicone acrylic emulsion, 1~5 part of methyl acetate, polysulfone resin 4~10
Part, 3~9 parts of hydroxypropyl PASELLI EASYGEL, 2~6 parts of dibutyl phthalate, 2~6 parts of 1-METHYLPYRROLIDONE, poly- second
2~10 parts of 3~9 parts of alkene, 4~10 parts of triisopropanolamine, 4~10 parts of antioxidant and crosslinking agent.
2. a kind of heat-resistant adhesive according to claim 1, it is characterised in that be made up of the raw material of following parts by weight：
11 parts of terpene resin, 7 parts of polyvinyl alcohol, 6 parts of expoxy propane phenyl ether, 7 parts of silicone acrylic emulsion, 3 parts of methyl acetate, polysulfone resin 7
It is part, 6 parts of hydroxypropyl PASELLI EASYGEL, 4 parts of dibutyl phthalate, 4 parts of 1-METHYLPYRROLIDONE, 6 parts of polyethylene, three different
6 parts of 7 parts of Propanolamine, 7 parts of antioxidant and crosslinking agent.
3. a kind of heat-resistant adhesive according to claim 1 or 2, it is characterised in that the antioxidant is vitamin E
Oil, the crosslinking agent are glyoxal.
4. a kind of preparation method of heat-resistant adhesive, it is characterised in that comprise the following steps：
(1) raw material of following parts by weight is weighed：6~16 parts of terpene resin, 4~10 parts of polyvinyl alcohol, expoxy propane phenyl ether 3
~9 parts, 4~10 parts of silicone acrylic emulsion, 1~5 part of methyl acetate, 4~10 parts of polysulfone resin, hydroxypropyl PASELLI EASYGEL 3~9
Part, 2~6 parts of dibutyl phthalate, 2~6 parts of 1-METHYLPYRROLIDONE, 3~9 parts of polyethylene, triisopropanolamine 4~10
Part, add in reactor, progressively heat up, and be slowly stirred, start timing when temperature rises to 90~96 DEG C, be incubated 20~40 points
Clock, while at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds antioxidant and 2~10 parts of crosslinking agent that parts by weight are 4~10 parts, stirring
After uniformly, the heat-resistant adhesive is produced.
A kind of 5. preparation method of heat-resistant adhesive according to claim 4, it is characterised in that step (1) described raw material
Parts by weight be：11 parts of terpene resin, 7 parts of polyvinyl alcohol, 6 parts of expoxy propane phenyl ether, 7 parts of silicone acrylic emulsion, methyl acetate 3
Part, 7 parts of polysulfone resin, 6 parts of hydroxypropyl PASELLI EASYGEL, 4 parts of dibutyl phthalate, 4 parts of 1-METHYLPYRROLIDONE, gather
6 parts of ethene, 7 parts of triisopropanolamine.
A kind of 6. preparation method of heat-resistant adhesive according to claim 4, it is characterised in that step (2) described antioxygen
The parts by weight of agent are 7 parts, and the parts by weight of the crosslinking agent are 6 parts.
7. according to a kind of heat-resistant adhesive described in claim any one of 4-6, it is characterised in that the antioxidant is given birth to for dimension
Plain E oil, the crosslinking agent is glyoxal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710818167.2A CN107474763A (en) | 2017-09-12 | 2017-09-12 | A kind of heat-resistant adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710818167.2A CN107474763A (en) | 2017-09-12 | 2017-09-12 | A kind of heat-resistant adhesive and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107474763A true CN107474763A (en) | 2017-12-15 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710818167.2A Pending CN107474763A (en) | 2017-09-12 | 2017-09-12 | A kind of heat-resistant adhesive and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467892A (en) * | 2019-08-29 | 2019-11-19 | 昆山博益鑫成高分子材料有限公司 | A kind of crosslinking type aqueous adhesive and preparation method thereof |
| CN111809828A (en) * | 2020-06-15 | 2020-10-23 | 邵俊宇 | Environment-friendly light high-strength large-size terrazzo composite board and preparation process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
-
2017
- 2017-09-12 CN CN201710818167.2A patent/CN107474763A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110467892A (en) * | 2019-08-29 | 2019-11-19 | 昆山博益鑫成高分子材料有限公司 | A kind of crosslinking type aqueous adhesive and preparation method thereof |
| CN111809828A (en) * | 2020-06-15 | 2020-10-23 | 邵俊宇 | Environment-friendly light high-strength large-size terrazzo composite board and preparation process thereof |
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