CN107470358A - A kind of processing method of titanium-alloy thin-plate - Google Patents

A kind of processing method of titanium-alloy thin-plate Download PDF

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Publication number
CN107470358A
CN107470358A CN201710942681.7A CN201710942681A CN107470358A CN 107470358 A CN107470358 A CN 107470358A CN 201710942681 A CN201710942681 A CN 201710942681A CN 107470358 A CN107470358 A CN 107470358A
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CN
China
Prior art keywords
plate
titanium
titanium alloy
steel plate
rolling
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Pending
Application number
CN201710942681.7A
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Chinese (zh)
Inventor
陈炳豊
王荣生
马宝全
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BAOJI YONGSHENGTAI TITANIUM INDUSTRY Co Ltd
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BAOJI YONGSHENGTAI TITANIUM INDUSTRY Co Ltd
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Priority to CN201710942681.7A priority Critical patent/CN107470358A/en
Publication of CN107470358A publication Critical patent/CN107470358A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/28Control of flatness or profile during rolling of strip, sheets or plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • B21B2001/383Cladded or coated products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • B21B2001/386Plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2201/00Special rolling modes
    • B21B2201/06Thermomechanical rolling

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Metal Rolling (AREA)

Abstract

The invention discloses a kind of processing method of titanium-alloy thin-plate, this method is:The closed cladding of titanium alloy sheet is formed by ply rolling bag using the steel plate through over cleaning, then ply rolling bag is rolled, through making annealing treatment and splitting after rolling, finally sanding is carried out and pickling finally gives titanium-alloy thin-plate.The method of the present invention is easily controllable, simple to operate, improves the surface quality of titanium-alloy thin-plate, meets the market demand of the country, is a kind of method for saving, efficiently preparing titanium-alloy thin-plate.

Description

A kind of processing method of titanium-alloy thin-plate
Technical field
The invention belongs to metal material processing technical field, is related to a kind of processing method of titanium-alloy thin-plate.
Background technology
Titanium alloy not only has less density, good room temperature, high temperature, cryogenic mechanics performance, and in a variety of media With excellent corrosion resistance, the series of advantages such as solderable, cold/hot shaped, therefore in Aero-Space, petrochemical industry, shipbuilding, vapour The application that the departments such as car, medicine all succeed.With the development of the industrial technologies such as Aeronautics and Astronautics and ship, titanium alloy is surpassed The demand of thin plate increasingly increases.At present, domestic titanium alloy plate is in terms of production technology, product quality and specification, with Japan, Europe Mei Deng developed countries depend on import in the presence of very big gap, especially some ultra-thin titanium alloy plates, far from satisfaction The domestic market demand.
Method of the titanium-alloy thin-plate frequently with pack ply-rolling is produced at present, i.e., using multiple 4mm-6mm hot rolling titanium alloy sheets Superposition, welded with steel plate surrounding jacket, then carry out hot rolling.The titanium-alloy thin-plate surface orange peel phenomenon that the method is produced is tight Weight, follow-up surface treatment is next difficult, but also needs cold rolling again, tedious process, and plate shape is difficult to control, and is significantly impacted Plate surface quality, even result in scrapping for sheet material.
The content of the invention
It is an object of the invention to provide a kind of processing method of titanium-alloy thin-plate, solves and prepares titanium-alloy thin-plate surface matter The problem of amount is poor, complex procedures.
The technical solution adopted in the present invention is a kind of processing method of titanium-alloy thin-plate, specifically real according to following steps Apply:
Step 1, the spot of steel plate and titanium alloy sheet surface cleaned out;
Step 2, laminated titanium-alloy plate is superimposed to form titanium alloy stacking, the titanium alloy stacking after superposition it is upper Lower two sides is respectively covered with the steel plate after cleaning, and is covered with side seal steel plate strip in titanium alloy stacking avris;
Step 3, steel plate and steel plate strip are welded envelope titanium alloy stacking, form ply rolling bag;
Step 4, ply rolling bag described in step 3 is placed in heating furnace it is heated to 860 DEG C -1000 DEG C, reaches the humidity province Between the warm 30min of follow-up continuation of insurance come out of the stove, ply rolling bag is rolled using 2800mm four-roller reversible hot milling roll group after coming out of the stove, rolled During control pass deformation rate be not more than 30%;
Step 5, the ply rolling bag in step 4 after rolling is made annealing treatment, then by the ply rolling after annealed processing Bag shearing is unpacked, and obtains titanium alloy plate;
Step 6, sanding and pickling processes are carried out to the titanium alloy plate surface obtained in step 5, obtain pack ply-rolling titanium Latten.
The features of the present invention also resides in:
The thickness in monolayer of titanium alloy sheet is 3mm-4mm;Steel plate, the steel of titanium alloy stacking gross thickness and cladding after superposition The thickness of bar is identical.
Uniform passage is left on ply rolling bag side seal board, ventilation hole area accounts for the 15% of whole side seal plate suqare.
The finishing temperature of rolling is 850 DEG C -1100 DEG C, is rolled with 5%-20% reduction in pass, total rolling process Deflection is 45%-85%.
Acid cleaning process uses volumetric concentration as 45% nitric acid, at normal temperatures pickling 15min.
A kind of processing method of titanium-alloy thin-plate of the present invention, titanium alloy plate is coated in outside and surrounding using steel plate, By titanium alloy sheet relative closure in the box body that a steel plate forms, then heating rolling, ensure that the rolling of titanium alloy plate Process is carried out in a metastable temperature, it is ensured that the stability of finished sheet.By completing to roll in certain temperature System can rationally design rolling temperature according to demand, obtain appropriate Phase Proportion, to ensure special performance requirement, and suitable When completing rolling under high temperature, the processing in the absence of metal is hardened, and will not produce texture, the anisotropy very little of material.The present invention By selecting suitable deformation temperature, rational deflection and perfect cladding group material mode, by physical property, chemical property and Room-temperature mechanical property differs greatly steel plate as outsourcing material, using titanium alloy plate as inner core material.Utilize the low price of steel plate Value is rolled down to certain thickness, produces the inside titanium-alloy thin-plate of high value in outside as protection, cladding bag.
The beneficial effects of the invention are as follows the thickness of cladding titanium alloy sheet used to be reduced to 3mm-4mm by 4mm-6mm, reduces The cumulative effect of tangerine hull constitution, and be advantageous to control plate shape.Whole process is easily controllable, simple to operate, solves system The problem of standby titanium-alloy thin-plate surface quality is poor, complex procedures.
Embodiment
With reference to embodiment, the present invention is described in detail.
A kind of processing method of titanium-alloy thin-plate of the present invention, specifically implements according to following steps:
Step 1, the spot of steel plate and titanium alloy sheet surface cleaned out;
Step 2, laminated titanium-alloy plate is superimposed to form titanium alloy stacking, the titanium alloy stacking after superposition it is upper Lower two sides is respectively covered with the steel plate after cleaning, and is covered with side seal steel plate strip in titanium alloy stacking avris;
Step 3, steel plate and steel plate strip are welded envelope titanium alloy stacking, form ply rolling bag;
Step 4, ply rolling bag described in step 3 is placed in heating furnace it is heated to 860 DEG C -1000 DEG C, reaches the humidity province Between the warm 30min of follow-up continuation of insurance come out of the stove, ply rolling bag is rolled using 2800mm four-roller reversible hot milling roll group after coming out of the stove, rolled During control pass deformation rate be not more than 30%;
Step 5, the ply rolling bag in step 4 after rolling is made annealing treatment, then by the ply rolling after annealed processing Bag shearing is unpacked, and obtains titanium alloy plate;
Step 6, sanding and pickling processes are carried out to the titanium alloy plate surface obtained in step 5, obtain pack ply-rolling titanium Latten.
Embodiment 1
0.8 × B of finished size × L mm
The steel plate of cladding is Q235, and its thickness is 6mm;The titanium alloy sheet of steel plate cladding is TC4 titanium alloy plates, individual layer Thickness 3mm, 2 titanium alloy sheets are superimposed, the titanium alloy stacking gross thickness of superposition is 6mm;First by steel plate and titanium alloy sheet table The spot in face is cleaned out;Again 2 titanium alloy sheets are superimposed to form titanium alloy stacking, the titanium alloy stacking after superposition Upper and lower surface be respectively covered with the steel plate after cleaning, and be covered with side seal steel plate strip in titanium alloy stacking avris;By steel plate and steel plate strip Weld and envelope titanium alloy stacking, form ply rolling bag;Uniform through hole, via area are left on ply rolling bag surrounding side seal board Account for the 15% of whole side seal plate suqare.
Ply rolling bag is heated into 860 DEG C to be rolled, rolled with 10%-30% reduction in pass, by 66% Deflection make TC4 plate rollings to finished product thickness 1.0mm, steel is with the total rolling process deflection of titanium alloy sheet in 45%-55%.
Ply rolling bag after rolling is made annealing treatment;
Ply rolling bag shearing after annealed processing is unpacked, obtains titanium alloy plate;
Sanding and pickling processes are carried out to the titanium alloy plate surface after unpacking, both obtain 0.8mm pack ply-rolling TC4 titanium alloys Thin plate.
Embodiment 2
1.0 × B of finished size × L mm
The steel plate of cladding is Q235, and its thickness is 9mm;The titanium alloy sheet of steel plate cladding is TC4 titanium alloy plates, individual layer Thickness 3mm, 3 titanium alloy sheets are superimposed, the titanium alloy stacking gross thickness of superposition is 9mm;First by steel plate and titanium alloy sheet table The spot in face is cleaned out;Again 3 titanium alloy sheets are superimposed to form titanium alloy stacking, the titanium alloy stacking after superposition Upper and lower surface be respectively covered with the steel plate after cleaning, and be covered with side seal steel plate strip in titanium alloy stacking avris;By steel plate and steel plate strip Weld and envelope titanium alloy stacking, form ply rolling bag;Uniform through hole, via area are left on ply rolling bag surrounding side seal board Account for the 15% of whole side seal plate suqare.
Ply rolling bag is heated into 900 DEG C to be rolled, rolled with 10%-30% reduction in pass, by 65% Deflection make TC4 plate rollings to finished product thickness 1.1mm, steel is with the total rolling process deflection of titanium alloy sheet in 55%-65%.
Ply rolling bag after rolling is made annealing treatment;
Ply rolling bag shearing after annealed processing is unpacked, obtains titanium alloy plate;
Sanding and pickling processes are carried out to the titanium alloy plate surface after unpacking, both obtain 1.0mm pack ply-rolling TC4 titanium alloys Thin plate.
Embodiment 3
0.9 × B of finished size × L mm
The steel plate of cladding is Q235, and its thickness is 7mm;The titanium alloy sheet of steel plate cladding is TC4 titanium alloy plates, individual layer Thickness 3.5mm, 2 titanium alloy sheets are superimposed, the titanium alloy stacking gross thickness of superposition is 7mm;First by steel plate and titanium alloy sheet The spot on surface is cleaned out;Again 2 titanium alloy sheets are superimposed to form titanium alloy stacking, the titanium alloy heap after superposition The upper and lower surface of pile is respectively covered with the steel plate after cleaning, and is covered with side seal steel plate strip in titanium alloy stacking avris;By steel plate and steel plate Bar, which welds, envelopes titanium alloy stacking, forms ply rolling bag;Uniform through hole, through-hole face are left on ply rolling bag surrounding side seal board Product accounts for the 15% of whole side seal plate suqare.
Ply rolling bag is heated into 950 DEG C to be rolled, rolled with 10%-30% reduction in pass, by 70% Deflection make TC4 plate rollings to finished product thickness 1.1mm, steel is with the total rolling process deflection of titanium alloy sheet in 65%-70%.
Ply rolling bag after rolling is made annealing treatment;
Ply rolling bag shearing after annealed processing is unpacked, obtains titanium alloy plate;
Sanding and pickling processes are carried out to the titanium alloy plate surface after unpacking, both obtain 0.9mm pack ply-rolling TC4 titanium alloys Thin plate.
Embodiment 4
1.0 × B of finished size × L mm
The steel plate of cladding is Q235, and its thickness is 8mm;The titanium alloy sheet of steel plate cladding is TC4 titanium alloy plates, individual layer Thickness 4mm, 2 titanium alloy sheets are superimposed, the titanium alloy stacking gross thickness of superposition is 8mm;First by steel plate and titanium alloy sheet table The spot in face is cleaned out;Again 2 titanium alloy sheets are superimposed to form titanium alloy stacking, the titanium alloy stacking after superposition Upper and lower surface be respectively covered with the steel plate after cleaning, and be covered with side seal steel plate strip in titanium alloy stacking avris;By steel plate and steel plate strip Weld and envelope titanium alloy stacking, form ply rolling bag;Uniform through hole, via area are left on ply rolling bag surrounding side seal board Account for the 15% of whole side seal plate suqare.
Ply rolling bag is heated into 1000 DEG C to be rolled, rolled with 10%-30% reduction in pass, by 70% Deflection make TC4 plate rollings to finished product thickness 1.2mm, steel is with the total rolling process deflection of titanium alloy sheet in 65%-70%.
Ply rolling bag after rolling is made annealing treatment;
Ply rolling bag shearing after annealed processing is unpacked, obtains titanium alloy plate;
Sanding and pickling processes are carried out to the titanium alloy plate surface after unpacking, both obtain 1.0mm pack ply-rolling TC4 titanium alloys Thin plate.
Embodiment 5
0.8 × B of finished size × L mm
The steel plate of cladding is Q235, and its thickness is 12mm;The titanium alloy sheet of steel plate cladding is TC4 titanium alloy plates, single Thickness degree 4mm, 3 titanium alloy sheets are superimposed, the titanium alloy stacking gross thickness of superposition is 12mm;First by steel plate and titanium alloy sheet The spot on surface is cleaned out;Again 3 titanium alloy sheets are superimposed to form titanium alloy stacking, the titanium alloy heap after superposition The upper and lower surface of pile is respectively covered with the steel plate after cleaning, and is covered with side seal steel plate strip in titanium alloy stacking avris;By steel plate and steel plate Bar, which welds, envelopes titanium alloy stacking, forms ply rolling bag;Uniform through hole, through-hole face are left on ply rolling bag surrounding side seal board Product accounts for the 15% of whole side seal plate suqare.
Ply rolling bag is heated into 1100 DEG C to be rolled, rolled with 10%-30% reduction in pass, by 75% Deflection make TC4 plate rollings to finished product thickness 1mm, steel is with the total rolling process deflection of titanium alloy sheet in 65%-70%.
Ply rolling bag after rolling is made annealing treatment;
Ply rolling bag shearing after annealed processing is unpacked, obtains titanium alloy plate;
Sanding and pickling processes are carried out to the titanium alloy plate surface after unpacking, both obtain 0.8mm pack ply-rolling TC4 titanium alloys Thin plate.

Claims (5)

1. a kind of processing method of titanium-alloy thin-plate, it is characterised in that specifically implement according to following steps:
Step 1, the spot of steel plate and titanium alloy sheet surface cleaned out;
Step 2, laminated titanium-alloy plate is superimposed to form titanium alloy stacking, up and down two of the titanium alloy stacking after superposition Face is respectively covered with the steel plate after cleaning, and is covered with side seal steel plate strip in titanium alloy stacking avris;
Step 3, steel plate and steel plate strip are welded envelope titanium alloy stacking, form ply rolling bag;
Step 4, ply rolling bag described in step 3 is placed in heating furnace it is heated to 860 DEG C -1000 DEG C, after reaches the temperature range Continue insulation 30min to come out of the stove, ply rolling bag is rolled using 2800mm four-roller reversible hot milling roll group after coming out of the stove, the operation of rolling Middle control pass deformation rate is not more than 30%;
Step 5, the ply rolling bag in step 4 after rolling is made annealing treatment, then cut the ply rolling bag after annealed processing Cut and unpack, obtain titanium alloy plate;
Step 6, sanding and pickling processes are carried out to the titanium alloy plate surface obtained in step 5, obtain pack ply-rolling titanium alloy Thin plate.
A kind of 2. processing method of titanium-alloy thin-plate according to claim 1, it is characterised in that the single monolayer thick of titanium alloy sheet Spend for 3mm-4mm;The steel plate of titanium alloy stacking gross thickness after superposition and cladding, the thickness of steel bar are identical.
A kind of 3. processing method of titanium-alloy thin-plate according to claim 1, it is characterised in that the ply rolling bag described in step 3 Uniform passage is left on side seal board, ventilation hole area accounts for the 15% of whole side seal plate suqare.
A kind of 4. processing method of titanium-alloy thin-plate according to claim 1, it is characterised in that the end that the step 4 rolls Temperature is rolled for 850 DEG C -1100 DEG C, is rolled with 10%-30% reduction in pass, total rolling process deflection is 45%- 85%.
A kind of 5. processing method of titanium-alloy thin-plate according to claim 1, it is characterised in that pickling in the step 6 Cheng Caiyong volumetric concentrations are 45% nitric acid, at normal temperatures pickling 15min.
CN201710942681.7A 2017-10-11 2017-10-11 A kind of processing method of titanium-alloy thin-plate Pending CN107470358A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI688440B (en) * 2019-05-06 2020-03-21 中國鋼鐵股份有限公司 Ultra-thin titanium sheet and method for producing the same
CN113333469A (en) * 2021-06-30 2021-09-03 索罗曼(常州)合金新材料有限公司 TC4 titanium alloy sheet hot rolling process
CN115971249A (en) * 2022-12-09 2023-04-18 浙江申吉钛业股份有限公司 Preparation method of ultrathin TC4 titanium alloy plate

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05146802A (en) * 1991-02-25 1993-06-15 Nippon Steel Corp Manufacture of steel plate with gradient of thickness in width direction
CN1069233C (en) * 1995-04-18 2001-08-08 川崎制铁株式会社 Method for rolling joint part of steel sheet during continuous hot rolling process
JP2006167774A (en) * 2004-12-17 2006-06-29 Nippon Steel Corp Equipment for rolling metallic sheet
CN102873094A (en) * 2012-11-05 2013-01-16 西部钛业有限责任公司 Processing method for ultrathin titanium alloy plates
CN106694549A (en) * 2015-11-17 2017-05-24 鞍钢股份有限公司 Method for producing extremely-thick carbon die steel plate
CN106734318A (en) * 2016-12-09 2017-05-31 西部钛业有限责任公司 A kind of Ti2The processing method of AlNb alloy wide sheets
CN107138527A (en) * 2017-05-25 2017-09-08 哈尔滨工业大学 The preparation method of CNTs/Ti biomimetic micro-nano laminated composite materials

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05146802A (en) * 1991-02-25 1993-06-15 Nippon Steel Corp Manufacture of steel plate with gradient of thickness in width direction
CN1069233C (en) * 1995-04-18 2001-08-08 川崎制铁株式会社 Method for rolling joint part of steel sheet during continuous hot rolling process
JP2006167774A (en) * 2004-12-17 2006-06-29 Nippon Steel Corp Equipment for rolling metallic sheet
CN102873094A (en) * 2012-11-05 2013-01-16 西部钛业有限责任公司 Processing method for ultrathin titanium alloy plates
CN106694549A (en) * 2015-11-17 2017-05-24 鞍钢股份有限公司 Method for producing extremely-thick carbon die steel plate
CN106734318A (en) * 2016-12-09 2017-05-31 西部钛业有限责任公司 A kind of Ti2The processing method of AlNb alloy wide sheets
CN107138527A (en) * 2017-05-25 2017-09-08 哈尔滨工业大学 The preparation method of CNTs/Ti biomimetic micro-nano laminated composite materials

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI688440B (en) * 2019-05-06 2020-03-21 中國鋼鐵股份有限公司 Ultra-thin titanium sheet and method for producing the same
CN113333469A (en) * 2021-06-30 2021-09-03 索罗曼(常州)合金新材料有限公司 TC4 titanium alloy sheet hot rolling process
CN113333469B (en) * 2021-06-30 2022-03-08 索罗曼(常州)合金新材料有限公司 TC4 titanium alloy sheet hot rolling process
CN115971249A (en) * 2022-12-09 2023-04-18 浙江申吉钛业股份有限公司 Preparation method of ultrathin TC4 titanium alloy plate

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Application publication date: 20171215