CN107460063A - 一种用于大理石表面除锈清洗剂的制备方法 - Google Patents

一种用于大理石表面除锈清洗剂的制备方法 Download PDF

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CN107460063A
CN107460063A CN201710810814.5A CN201710810814A CN107460063A CN 107460063 A CN107460063 A CN 107460063A CN 201710810814 A CN201710810814 A CN 201710810814A CN 107460063 A CN107460063 A CN 107460063A
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李慧芝
卢燕
朱学英
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Abstract

本发明公开了一种用于大理石表面除锈清洗剂的制备方法,其特征在于,(1)按如下组成加入,水:60~66%,二水草酸:12~16%,搅拌溶解后,再加入二胺基环己烷四乙酸盐:2~5%,搅拌溶解后,再加入氟硼酸铵:15~20%,十二烷基二甲基甜菜碱:2~5%,混合均匀,得到透明液体A液;(2)按如下组成加入,水:78~84%,次亚磷酸钠:10~15%,搅拌溶解,再加入液体石蜡:4~8%,混合均匀,即得到液体B液;(3)将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。该清洗剂清洗效果显著,可提高大理石的光亮度,降低大理石再次泛黄的可能性。

Description

一种用于大理石表面除锈清洗剂的制备方法
技术领域
本发明涉及硅酸盐制品的清洗领域,特别涉及一种用于大理石表面除锈清洗剂的制备方法。
背景技术
大理石以其自然古朴的纹理,色泽鲜艳亮丽,而且具有不变形、硬度高、刚性好、耐磨性强、温度变形小、使用寿命长、不会出现划痕、不磁化等优点。因此,大理石是天然建筑装饰石材的一大门类,一般指具有装饰功能,可以加工成建筑石材或工艺品。大理石主要用于加工成各种形材、板材,作建筑物的墙面、地面、台、柱,是家具镶嵌的珍贵材料。还常用于纪念性建筑物如碑、塔、雕像等的材料。大理石在使用过程中会产生锈斑、黄斑而影响大理石的美观和寿命。形成锈斑或黄斑主要有三种原因:第一,由于大理石自身含有某些化学物质如铁矿物被氧化,或者大理石受到外界铁锈如石材在锯、磨、运输过程中粘附和镶嵌在大理石表层的金属铁,在一定的环境条件下与空气中氧作用生成氧化铁(铁锈),造成大理石表面变黄,出现锈斑,严重的甚至锈蚀形成空洞;第二,是相邻物体的侵入,如干挂安装的金属会邻近的水管等腐蚀,腐蚀物雨水等常年冲带而附着和渗入石材表面形成片状黄斑;第三,是接触其它含有有机色素的材料,如草绳、纸板箱、粪便、食物茶水、咖啡、果汁等的污染物,表面也会泛出黄斑,这样不仅影响建筑的美观,改变石质的原貌,还会影响石材的寿命。目前国内外许多去黄斑的清洗剂大多呈酸性。大理石又称云石,是重结晶的石灰岩,主要成分是CaCO3。石灰岩在高温高压下***,并在所含矿物质发生变化时重新结晶形成大理石。主要成分是钙和白云石,颜色很多,通常有明显的花纹,矿物颗粒很多。摩氏硬度在2.5到5之间。由于大理石一般都含有杂质,而且碳酸钙在大气中受二氧化碳、碳化物、水气的作用,也容易风化和溶蚀,而使表面很快失去光泽。
由于大理石的主要成分是碳酸钙如果清洗剂是酸性会多大理石的结构产生破坏,所以大理石除锈清洗剂不能是酸性。
发明内容
本发明的目的是提供一种用于大理石表面除锈清洗剂的制备方法,不仅可以去除大理石表面的油污和锈斑、恢复原色,同时可以提高大理石光泽度的清洗剂,通过以下技术方案实现。
一种用于大理石表面除锈清洗剂的制备方法,其特征在于,该方法具有以下工艺步骤:
(1)A液配制:反应器中,按如下组成质量百分浓度加入,水:60~66%,二水草酸:12~16%,搅拌溶解后,再加入二胺基环己烷四乙酸盐:2~5%,搅拌溶解后,再加入氟硼酸铵:15~20%,十二烷基二甲基甜菜碱:2~5%,各组分之和为百分之百,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,按如下组成质量百分浓度加入,水:78~84%,次亚磷酸钠:10~15%,搅拌溶解,再加入液体石蜡:4~8%,各组分之和为百分之百,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
步骤(2)中所述次亚磷酸钠的有效成分在95%以上。
本发明所得到的用于大理石表面除锈清洗剂使用方法:将大理石表面除锈清洗剂涂在大理石锈斑点上反应20~30min后进行擦洗,再清水冲洗干净,即可。
本发明的优点及效果是:
(1)本发明制得用于大理石表面除锈清洗剂,采用酸性温和的草酸,不会产生酸雾,不会腐蚀大理石的结构,同时草酸还可以提高大理石的光亮度,添加了次亚磷酸钠具有强还原性,还具有与铁的络合作用,添加二胺基环己烷四乙酸盐与铁具有强络合作用促进大理石表面锈斑快速测底除去,清洗效果明显,降低大理石再次泛黄的可能性。
(2)本发明获得用于大理石表面除锈清洗剂,制备工艺简单,条件易于控制,生产成本低,易于工业化生产。
(3)本发明获得用于大理石表面除锈清洗剂,添加了氟硼酸铵含有氟离子提高了去銹能力;加入液体石蜡作为光亮剂和保护剂,提高清洗效果。
具体实施方式
实施例1
(1)A液配制:反应器中,分别加入,水:630 mL,二水草酸:140g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:40g,搅拌溶解后,再加入氟硼酸铵:160g,十二烷基二甲基甜菜碱:30g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:800 mL,次亚磷酸钠:150g,搅拌溶解,再加入液体石蜡:50g,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
实施例2
(1)A液配制:反应器中,分别加入,水:66 mL,二水草酸:12g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:2g,搅拌溶解后,再加入氟硼酸铵:15g,十二烷基二甲基甜菜碱:5g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:84 mL,次亚磷酸钠:10g,搅拌溶解,再加入液体石蜡:6g,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
实施例3
(1)A液配制:反应器中,分别加入,水:63mL,二水草酸:14g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:4g,搅拌溶解后,再加入氟硼酸铵:16g,十二烷基二甲基甜菜碱:3g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:80 mL,次亚磷酸钠:15g,搅拌溶解,再加入液体石蜡:5g,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
实施例4
(1)A液配制:反应器中,分别加入,水:300 mL,二水草酸:80g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:25g,搅拌溶解后,再加入氟硼酸铵:85g,十二烷基二甲基甜菜碱:10g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:390 mL,次亚磷酸钠:70g,搅拌溶解,再加入液体石蜡:10g,室温搅拌溶解,混合均匀,即得B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
实施例5
(1)A液配制:反应器中,分别加入,水:620 mL,二水草酸:130g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:30g,搅拌溶解后,再加入氟硼酸铵:200g,十二烷基二甲基甜菜碱:20g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:820 mL,次亚磷酸钠:110g,搅拌溶解,再加入液体石蜡:70g,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
实施例6
(1)A液配制:反应器中,分别加入,水:64 mL,二水草酸:15g,搅拌溶解后,再加入二胺基环己烷四乙酸盐:2g,搅拌溶解后,再加入氟硼酸铵:15g,十二烷基二甲基甜菜碱:4g,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,分别加入,水:83 mL,次亚磷酸钠:13g,搅拌溶解,再加入液体石蜡:4g,室温搅拌溶解,混合均匀,即得到B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
本发明所得到的大理石表面除锈清洗剂使用方法:将大理石表面除锈清洗剂涂在大理石锈斑点上反应20~30min后进行擦洗,再清水冲洗干净,即可,清洗效果优良,无锈斑痕迹,提高光亮度。

Claims (3)

1.一种用于大理石表面除锈清洗剂的制备方法,其特征在于,该方法具有以下工艺步骤:
(1)A液配制:反应器中,按如下组成质量百分浓度加入,水:60~66%,二水草酸:12~16%,搅拌溶解后,再加入二胺基环己烷四乙酸盐:2~5%,搅拌溶解后,再加入氟硼酸铵:15~20%,十二烷基二甲基甜菜碱:2~5%,各组分之和为百分之百,室温搅拌溶解,混合均匀,得到透明液体A液;
(2)B液配制:反应器中,按如下组成质量百分浓度加入,水:78~84%,次亚磷酸钠:10~15%,搅拌溶解,再加入液体石蜡:4~8%,各组分之和为百分之百,室温搅拌溶解,混合均匀,即得到液体B液;
(3)用于大理石表面除锈清洗剂的制备:反应器中,将A液与B液按体积比为1:1混合,即得大理石表面除锈清洗剂。
2.根据权利要求1所述的一种用于大理石表面除锈清洗剂的制备方法,其特征在于,步骤(2)中所述次亚磷酸钠的有效成分在95%以上。
3.根据权利要求1所述的一种用于大理石表面除锈清洗剂的制备方法所制备的大理石表面除锈清洗剂。
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1467280A (zh) * 2002-07-09 2004-01-14 哈尔滨工业大学环保科技股份有限公司 无水洗车、养护液及其生产方法
CN102191142A (zh) * 2011-04-13 2011-09-21 浙江大学 一种中性石材和石质文物表面黄斑清洗剂及其制备方法
KR101099787B1 (ko) * 2011-09-28 2011-12-28 주식회사 스카이원 석재 세정용 조성물
CN103525591A (zh) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 一种环保清洗剂
CN105441967A (zh) * 2015-11-14 2016-03-30 合肥标兵凯基新型材料有限公司 一种易拉罐用表面处理剂及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1467280A (zh) * 2002-07-09 2004-01-14 哈尔滨工业大学环保科技股份有限公司 无水洗车、养护液及其生产方法
CN102191142A (zh) * 2011-04-13 2011-09-21 浙江大学 一种中性石材和石质文物表面黄斑清洗剂及其制备方法
KR101099787B1 (ko) * 2011-09-28 2011-12-28 주식회사 스카이원 석재 세정용 조성물
CN103525591A (zh) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 一种环保清洗剂
CN105441967A (zh) * 2015-11-14 2016-03-30 合肥标兵凯基新型材料有限公司 一种易拉罐用表面处理剂及其制备方法

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