CN107446593A - A kind of liquid-crystal composition of compound containing cyclopropyl and methoxyl group and its application - Google Patents
A kind of liquid-crystal composition of compound containing cyclopropyl and methoxyl group and its application Download PDFInfo
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- CN107446593A CN107446593A CN201610383857.5A CN201610383857A CN107446593A CN 107446593 A CN107446593 A CN 107446593A CN 201610383857 A CN201610383857 A CN 201610383857A CN 107446593 A CN107446593 A CN 107446593A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K19/44—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 containing compounds with benzene rings directly linked
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
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- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
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Abstract
The present invention relates to liquid crystal material field, and in particular to a kind of liquid-crystal composition of the compound containing cyclopropyl and methoxyl group, the compound that the compound and at least one formula II that the liquid-crystal composition includes at least one formula I representatives represent；Wherein, the compound that formula I is represented has big negative dielectric anisotropic, the compound that formula II is represented is double cyclics, has low rotary viscosity to contain cyclopropyl and methoxy base class compound simultaneously；The compound that further can also be represented in the composition comprising at least one general formula III, the compound is tricyclic structure neutral compound, has relatively low rotary viscosity and higher clearing point.Liquid-crystal composition of the present invention can be used for the fast-response liquid crystal display of plurality of display modes, and its use in the VA such as VA, MVA, PVA, PSVA mode displays or IPS, FFS mode display can be obviously improved liquid crystal display display effect.
Description
Technical field
The present invention relates to a kind of liquid-crystal composition, and specifically, liquid-crystal composition provided by the present invention has negative Jie
Electrical anisotropy；More precisely, the chemical combination containing cyclopropyl and methoxy based structures in liquid-crystal composition provided by the present invention
Thing.
Background technology
At present, liquid crystal is widely applied in field of information display, while the application in optical communication also achieves one
Fixed progress (S.T.Wu, D.K.Yang.Reflective Liquid Crystal Displays.Wiley, 2001).It is near several
Year, the application field of liquid-crystal compounds significantly widens kinds of displays part, electro-optical device, electronic component, sensor etc.,
Nematic liquid crystal compound obtains most commonly used application in flat-panel monitor, particularly for tft active matrix
In system.
At present, negative liquid crystal is widely used in large-sized TV liquid crystal display, especially the appearance of PSVA technologies,
So that negative liquid crystal is more welcome；In recent years, the display of the mobile device such as mobile phone widely uses negative liquid crystal FFS and shown
Device, because it has high transmitance, the energy that LCD backlight is consumed can be greatly reduced, lift the aobvious of liquid crystal display
Show quality, extend the cruising time of mobile device.
Negative liquid crystal most proposes that it is mainly used in VA patterns, and its major advantage is to contrast earlier than the end of the eighties in last century
Degree is high, and major defect is that visual angle is small, and the response time is slow.As the technologies such as the development of Display Technique, MVA, PVA, PSVA go out in succession
It is existing, solve the problems, such as response time and visual angle.In recent years, as touch-screen turns into the mobile device market mainstream, IPS and FFS
The hard panel type display of class has inborn advantage, IPS and FFS class displays can both use positivity liquid crystal, can also use negativity
Liquid crystal, due to bending electric field present in the class display, positivity liquid crystal arranges along electric field line direction, so as to cause molecule curved
Song, and decline in transmitance；Negative liquid crystal arranges perpendicular to electric field line direction, thus transmitance can be substantially improved, and be current
Lift transmitance, reduce backlight power consumption the best way.But response time problem existing for negative liquid crystal is the weight currently encountered
Hang-up, using negative liquid crystal FFS displays relative to positivity liquid crystal FFS display response times slow 50% or more.
Therefore, how to lift the response time of negative liquid crystal turns into current key problem.
Specifically, the response time of liquid crystal display depends on d2(d is thickness of liquid crystal layer to γ 1/Keff, and γ 1 revolves for liquid crystal
Turn viscosity, Keff is effective elastic constant), therefore, rotary viscosity reduced, reduce thickness of liquid crystal layer and lift elastic constant
To reach the purpose for improving the response time, thickness of liquid crystal layer depends on the design of liquid crystal display；For liquid-crystal composition, reduce
Rotary viscosity and thickness of liquid crystal are most effective.
Liquid-crystal composition provided by the present invention has low rotary viscosity, can be effectively reduced the response of liquid crystal display
Time.
The content of the invention
The present invention provides a kind of negative dielectric anisotropy liquid crystal composition of fast-response, and the liquid-crystal composition includes one kind
Or the compound of a variety of formula I (simultaneously containing cyclopropyl and methoxyl group)：
And at least one compounds of formula II：
Wherein, R1、R2、R3C is represented independently of one another1~C12Straight chained alkyl or unbranched alkoxy or C2~C12Straight chain
Alkenyl；N represents 0 or 1 independently of one another；M represents 0~10 integer independently of one another；Z represents O or singly-bound independently of one another；
A1、A2Represent independently of one another：
Or：
A3、A4Trans Isosorbide-5-Nitrae-cyclohexyl or Isosorbide-5-Nitrae-phenylene are represented independently of one another.
Compound representated by formula I is the compound containing cyclopropyl class, and such compound has big negative dielectric each
Anisotropy.
In liquid-crystal composition provided by the invention, preferably each liquid crystal components sum is 100%；Compound described in formula I exists
Content in composition is 10~95%, preferably 15~90%, more preferably 62~90%, 20~87%, 62~90%, 62
~87%, 15~62%, 20~62%, 15~69%, 20~68%, 55~90%, 60~87%, 60~90%, 64~
87%th, 15~75%, 20~68%.
Specifically, one or more of the compounds of formula I in Formulas I A~Formulas I C:
Wherein, R1C is represented independently of one another1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl；Z is represented independently of one another
O or singly-bound；M represents 0~4 integer independently of one another.
Preferably, one or more of the formula I provided by the present invention chemical combination in Formulas I A1~Formulas I H48：
Preferably, compounds of formula I provided by the present invention be selected from Formulas I A26, IA28, IA29, IA30, IA34,
IB20、IB21、IB22、IB23、IB26、IC1、IC2、IC25、IC26、IC27、IC28、IC29、IC30、IC33、IC34、
ID25、ID26、ID27、ID28、ID33、ID34、ID35、IE25、IE26、IE27、IE33、IE34、IF25、IF26、IF27、
One or more in IG1, IG2, IG19, IG20, IG21, IH19, IH20, IH21, IH26.
The compound that formula II of the present invention is represented is dicyclic compound, and such compound has low rotary viscosity, for
The rotary viscosity for reducing liquid-crystal composition is highly effective.In liquid-crystal composition provided by the invention, preferably each liquid crystal components sum
For 100%；The content of compound in the composition described in formula II be 1~65%, preferably 10~55,13~52%, 10~
38%th, 13~36%, 25~55%, 27~52%, 31~55%, 10~31%, 13~31%, 10~40%, 13~36%,
15~55%, 19~52%, 24~36%, 13~19%, 19~34%, 34% or 50~52%.
The compound that formula II of the present invention is represented is specific as follows：
Wherein, R2、R3C is represented independently of one another1~C12Straight chained alkyl or unbranched alkoxy or C2~C12Straight chain alkene
Base；A3、A4Trans Isosorbide-5-Nitrae-cyclohexyl or Isosorbide-5-Nitrae-phenylene are represented independently of one another.
Preferably, one or more of the compounds of formula II provided by the present invention in Formula II A~Formula II C：
Wherein, R2C is represented independently of one another1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl；R3Generation independently of one another
Table C1~C7Straight chained alkyl, unbranched alkoxy or C2~C7Straight-chain alkenyl.
Preferably, one or more of the compounds of formula II provided by the present invention in Formula II A1~Formula II C24：
It is highly preferred that compounds of formula II provided by the present invention be selected from Formula II A2, IIA6, IIA14, IIA18,
One or more in IIA22, IIA23, IIA28, IIB10, IIB14, IIC2, IIC4, IIC15, IIC20.
Liquid-crystal composition provided by the present invention can also include the compound that at least one general formula III represents.General formula III
Compound be tricyclic structure neutral compound, the class formation has relatively low rotary viscosity, and higher clearing point.The present invention
In the liquid-crystal composition of offer, preferably each liquid crystal components sum is 100%；The content of compound in the composition described in formula I
For 0~50%, preferably 0~30%, more preferably 0~20%, 0~15%, 5~35%, 9~30%, 0~40%, 1~
35%th, 5~30%, 5~16%, 23% or 20~30%.
The concrete structure of compounds of formula III of the present invention is as follows：
Wherein, R4C is represented independently of one another1~C12Straight chained alkyl or C2~C12Straight-chain alkenyl；R5Generation independently of one another
Table C1~C12Straight chained alkyl or unbranched alkoxy；A5Trans Isosorbide-5-Nitrae-cyclohexyl or Isosorbide-5-Nitrae-phenylene are represented independently of one another.
Preferably, the one kind of the compound representated by general formula III provided by the present invention in formula III A~formula III B
It is or a variety of：
Wherein, R4C is represented independently of one another2~C7Straight chained alkyl or straight-chain alkenyl, R5C is represented independently of one another1~C7
Straight chained alkyl or straight-chain alkenyl.
It is highly preferred that the one kind or more of compounds of formula III in IIIA1~IIIA18, IIIB1~IIIB20
Kind：
It is further preferred that compounds of formula III be selected from formula III A2, IIIA6, IIIA10, IIIA13, IIIA16,
One or more in IIIB2, IIIB6, IIIB8, IIIB15, IIIB17.
In order that playing synergy in liquid-crystal composition between each component, and meets the needs of different (as reduced rotation
Viscosity etc.), the present invention further defines the ideal formulations of the liquid-crystal composition：
Specifically, liquid-crystal composition provided by the present invention includes following components in percentage by weight：
(1), the compound representated by 10~95% formula I；
(2), the compound representated by 1~65% formula II；
(3), the compound representated by 0~50% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 15~90% formula I；
(2), the compound representated by 10~55% formula II；
(3), the compound representated by 0~30% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 20~87% formula I；
(2), the compound representated by 13~52% formula II；
(3), the compound representated by 0~30% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 62~90% formula I；
(2), the compound representated by 10~38% formula II；
(3), the compound representated by 0~15% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 62~87% formula I；
(2), the compound representated by 13~36% formula II；
(3), the compound representated by 0~16% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 15~62% formula I；
(2), the compound representated by 25~55% formula II；
(3), the compound representated by 5~35% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 20~62% formula I；
(2), the compound representated by 27~52% formula II；
(3), the compound representated by 9~30% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 15~69% formula I；
(2), the compound representated by 31~55% formula II；
(3), the compound representated by 0~40% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 20~68% formula I；
(2), the compound representated by 31~52% formula II；
(3), the compound representated by 0~30% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 55~90% formula I；
(2), the compound representated by 10~31% formula II；
(3), the compound representated by 0~20% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 60~87% formula I；
(2), the compound representated by 13~31% formula II；
(3), the compound representated by 0~16% general formula III.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 60~90% formula I；
(2), the compound representated by 10~40% formula II.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 64~87% formula I；
(2), the compound representated by 13~36% formula II.
Preferably, liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 15~75% formula I；
(2), the compound representated by 15~55% formula II；
(3), the compound representated by 1~35% general formula III.
It is highly preferred that liquid-crystal compounds provided by the present invention includes the component of following mass percent：
(1), the compound representated by 20~68% formula I；
(2), the compound representated by 19~52% formula II；
(3), the compound representated by 5~30% general formula III.
The preferably liquid-crystal composition of the invention is made up of the component of the percentage by weight.
As the preferred scheme of the present invention, the percentage by weight sum of the component is 100%.
Further, when liquid-crystal composition of the present invention is made up of two kinds of components, preferably described liquid-crystal composition bag
Component containing following mass percent：
(1), the compound representated by 64~76% formula I；
(2), the compound representated by 24~36% formula II；
Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, IC21,
ID17、ID18、IE17、IE18、IF17、IF18、IG18、IH18；Compound representated by formula II be selected from IIA2, IIA6,
One or more in IIC20；
Or, include the component of following mass percent：
(1), the compound representated by 64~70% formula I；
(2), the compound representated by 30~36% formula II；
Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, ID18,
IE18、IF18、IG18、IH18；One or more of the compound in IIA2, IIA6, IIA20 representated by formula II, most
It is preferred that IIA2.
When liquid-crystal composition of the present invention is made up of 3 kinds of components, preferably described liquid-crystal composition includes following quality
The component of percentage：
(1), the compound representated by 40~65% formula I；
(2), the compound representated by 19~50% formula II；
(3), the compound representated by 5~23% general formula III；
Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, IC21,
ID17、ID18、IE17、IE18、IF17、IF18、IG18、IH18；Compound representated by formula I is in IIA2 or IIA6
It is one or two kinds of；One or more of the compound in IIIA2, IIIA13, IIIB2, IIIB6 representated by general formula III；
Or the liquid-crystal composition includes the component of following mass percent：
(1), the compound representated by 43~65% formula I；
(2), the compound representated by 19~34% formula II；
(3), the compound representated by 5~23% general formula III；
Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, ID18,
IE18、IF18、IG18、IH18；Compound representated by formula II is one or more optimal in IIA2, IIA6, IIA20
Select IIA2；One or more of the compound in IIIA2, IIIA13, IIIB2, IIIB6 representated by general formula III.
The preparation method of liquid-crystal composition of the present invention can be changed two or more using conventional method without specifically limited
Compound mixing is produced, such as by mixing different component and method soluble in one another preparation at high temperature, wherein, by liquid crystal group
Compound is dissolved in the solvent for the compound and mixed, and then distills out the solvent under reduced pressure；It is or of the present invention
Liquid-crystal composition can be prepared conventionally, and the wherein less component of content is such as dissolved in into content at a higher temperature
In larger key component, or each affiliated component dissolved in organic solvent, such as acetone, chloroform or methanol then will be molten
Liquid mixing obtains after removing solvent.
Liquid-crystal composition of the present invention has low rotary viscosity, the fast-response liquid crystal available for plurality of display modes
Show, its use in the VA such as VA, MVA, PVA, PSVA mode displays or IPS, FFS mode display can be obviously improved liquid crystal
Display display effect.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Unless otherwise indicated, percentage is weight percentage in the present invention；Temperature unit is degree Celsius；△ n represent optics
Anisotropy (25 DEG C)；ε∥And ε⊥Parallel and vertical dielectric constant (25 DEG C, 1000Hz) is represented respectively；△ ε represent dielectric respectively to
Different in nature (25 DEG C, 1000Hz)；γ 1 represents rotary viscosity (mPa.s, 25 DEG C)；Cp represents the clearing point (DEG C) of liquid-crystal composition；
K11、K22、K33Splay, distortion and bend elastic constant (pN, 25 DEG C) are represented respectively.
In following embodiment, unit structure code shown in table 1 represents in liquid-crystal compounds.
Table 1：The group structure code of liquid-crystal compounds
By taking following compound structure as an example：
It is expressed as：1V2CC1OWO3B
It is expressed as：2CGI1OWO3B
In following embodiment, the preparation of liquid-crystal composition uses heat of solution method, comprises the following steps：Pressed with balance
Percentage by weight weighs liquid-crystal compounds, wherein addition sequence is weighed without particular requirement, generally with liquid-crystal compounds fusing point by height
Mixing is weighed successively to low order, heating stirring causes each component to melt uniform then filtered, revolving at 60~100 DEG C,
Finally encapsulate and produce target sample.
In following embodiment, the performance parameter of the weight percent of each component when liquid-crystal composition is shown in liquid-crystal composition
Following table.
Embodiment 1
Table 2：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 2
Table 3：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 3
Table 4：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 4
Table 5：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 5
Table 6：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 6
Table 7：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 7
Table 8：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 8
Table 9：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 9
Table 10：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 10
Table 11：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 11
Table 12：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 12
Table 13：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 13
Table 14：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 14
Table 15：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 15
Table 16：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 16
Table 17：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 17
Table 18：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 18
Table 19：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 19
Table 20：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 20
Table 21：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 21
Table 22：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 22
Table 23：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 23
Table 24：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 24
Table 25：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 25
Table 26：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 26
Table 27：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 27
Table 28：The weight percent of each component when performance parameter in liquid-crystal composition
Comparative example 1
Table 29：The weight percent of each component when performance parameter in liquid-crystal composition
Compared with embodiment 1 is collected with each performance parameter value of the gained liquid-crystal composition of comparative example 1, referring to table 30.
Table 30：The performance parameter of liquid-crystal composition compares
| Δn | Δε | Cp | γ1 | K11 | K22 | K33 | |
| Embodiment 1 | 0.108 | -4.0 | 90 | 87 | 15.4 | 7.7 | 16.7 |
| Comparative example 1 | 0.108 | -3.8 | 90 | 96 | 14.7 | 7.4 | 16.5 |
Through relatively understanding：Compared with comparative example 1, the liquid-crystal composition that embodiment 1 provides has low rotary viscosity, that is, has
There is the faster response time.
Negative dielectric anisotropy liquid crystal composition provided by the present invention have low rotary viscosity, high resistivity and
Excellent photostability and heat endurance, suitable for the VA types liquid crystal display such as VA, MVA, PVA, PSVA or IPS and FFS type liquid
Crystal display, it can effectively improve the response time of liquid crystal display.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (10)
- A kind of 1. liquid-crystal composition of the compound containing cyclopropyl and methoxyl group, it is characterised in that the liquid-crystal composition bag The compound represented containing at least one formula I compounds represented and at least one formula II；The formula I is specially：In the formula I, R1Represent C1~C12Straight chained alkyl or unbranched alkoxy or C2~C12Straight-chain alkenyl；N represent 0 or 1；M represents 0~10 integer；Z represents O or singly-bound；Ring A1With ring A2Represent independently of one another：The formula II is specially：In the formula II, R2、R3C is represented independently of one another1~C12Straight chained alkyl or unbranched alkoxy or C2~C12Straight chain Alkenyl；Ring A3With ring A4Trans Isosorbide-5-Nitrae-cyclohexyl or Isosorbide-5-Nitrae-phenylene are represented independently of one another.
- 2. liquid-crystal composition according to claim 1, it is characterised in that the compound that formula I is represented is selected from Formulas I A~formula One or more in IH:In the Formulas I A~Formulas I H, R1Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl；Z represents O or singly-bound；M generations The integer of table 0~4；Preferably, formula I represent chemical combination be selected from Formulas I A1~IA40, IB1~IB40, IC1~IC40, ID1~ID40, IE1~ One or more in IE40, IF1~IF40, IG1~IG40 and IH1~IH40：It is highly preferred that formula I represent compound be selected from Formulas I A26, IA28, IA29, IA30, IA34, IB20, IB21, IB22, IB23、IB26、IC1、IC2、IC25、IC26、IC27、IC28、IC29、IC30、IC33、IC34、ID25、ID26、ID27、 ID28、ID33、ID34、ID35、IE25、IE26、IE27、IE33、IE34、IF25、IF26、IF27、IG1、IG2、IG19、 One or more in IG20, IG21, IH19, IH20, IH21, IH26.
- 3. liquid-crystal composition according to claim 1 or 2, it is characterised in that the compound that formula II is represented is selected from Formula II A One or more in~Formula II C：In the Formula II A~Formula II C, R2Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl；R3Represent C1~C7It is straight Alkyl group, unbranched alkoxy or C2~C7Straight-chain alkenyl；Preferably, the compound that formula II is represented is in Formula II A1~IIA34, IIB1~IIB16 and IIC1~IIC24 It is one or more：It is highly preferred that formula II represent compound be selected from Formula II A2, IIA6, IIA14, IIA18, IIA22, IIA23, IIA28, One or more in IIB10, IIB14, IIC2, IIC4, IIC15, IIC20.
- 4. according to the liquid-crystal composition described in claims 1 to 3 any one, it is characterised in that also included in the composition The compound that at least one general formula III represents；The general formula III is specially：In the general formula III, R4Represent C1~C12Straight chained alkyl or C2~C12Straight-chain alkenyl；R5Represent C1~C12Straight chain Alkyl or unbranched alkoxy；Ring A5Represent trans Isosorbide-5-Nitrae-cyclohexyl or Isosorbide-5-Nitrae-phenylene；Preferably, one or more of the compound that general formula III represents in formula III A, IIIB：In described IIIA, IIIB, R4Represent C2~C7Straight chained alkyl or straight-chain alkenyl, R5Represent C1~C7Straight chained alkyl or straight Alkenyl；It is highly preferred that one or more of the compounds of formula III in IIIA1~IIIA18, IIIB1~IIIB20：It is further preferred that compounds of formula III be selected from formula III A2, IIIA6, IIIA10, IIIA13, IIIA16, IIIB2, One or more in IIIB6, IIIB8, IIIB15, IIIB17.
- 5. according to the liquid-crystal composition described in Claims 1 to 4 any one, it is characterised in that the liquid-crystal composition includes Following components in percentage by weight：(1), the compound representated by 10~95% formula I；(2), the compound representated by 1~65% formula II；(3), the compound representated by 0~50% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 15~90% formula I；(2), the compound representated by 10~55% formula II；(3), the compound representated by 0~30% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 20~87% formula I；(2), the compound representated by 13~52% formula II；(3), the compound representated by 0~30% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 62~90% formula I；(2), the compound representated by 10~38% formula II；(3), the compound representated by 0~15% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 62~87% formula I；(2), the compound representated by 13~36% formula II；(3), the compound representated by 0~16% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 15~62% formula I；(2), the compound representated by 25~55% formula II；(3), the compound representated by 5~35% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 20~62% formula I；(2), the compound representated by 27~52% formula II；(3), the compound representated by 9~30% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 15~69% formula I；(2), the compound representated by 31~55% formula II；(3), the compound representated by 0~40% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 20~68% formula I；(2), the compound representated by 31~52% formula II；(3), the compound representated by 0~30% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 55~90% formula I；(2), the compound representated by 10~31% formula II；(3), the compound representated by 0~20% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 60~87% formula I；(2), the compound representated by 13~31% formula II；(3), the compound representated by 0~16% general formula III；Preferably, the component of following mass percent is included：(1), the compound representated by 60~90% formula I；(2), the compound representated by 10~40% formula II；It is highly preferred that include the component of following mass percent：(1), the compound representated by 64~87% formula I；(2), the compound representated by 13~36% formula II；Preferably, the component of following mass percent is included：(1), the compound representated by 15~75% formula I；(2), the compound representated by 15~55% formula II；(3), the compound representated by 1~35% general formula III；It is highly preferred that include the component of following mass percent：(1), the compound representated by 20~68% formula I；(2), the compound representated by 19~52% formula II；(3), the compound representated by 5~30% general formula III.
- 6. liquid-crystal composition according to claim 5, it is characterised in that the liquid-crystal composition includes following quality percentage The component of ratio：(1), the compound representated by 64~76% formula I；(2), the compound representated by 24~36% formula II；Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, IC21, ID17, ID18、IE17、IE18、IF17、IF18、IG18、IH18；Compound representated by formula II is in IIA2, IIA6, IIC20 One or more；Or, include the component of following mass percent：(1), the compound representated by 64~70% formula I；(2), the compound representated by 30~36% formula II；Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, ID18, IE18, IF18、IG18、IH18；One or more of the compound in IIA2, IIA6, IIA20 representated by formula II, most preferably IIA2。
- 7. liquid-crystal composition according to claim 5, it is characterised in that the liquid-crystal composition includes following quality percentage The component of ratio：(1), the compound representated by 40~65% formula I；(2), the compound representated by 19~50% formula II；(3), the compound representated by 5~23% general formula III；Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, IC21, ID17, ID18、IE17、IE18、IF17、IF18、IG18、IH18；The one kind of compound in IIA2 or IIA6 representated by formula I Or two kinds；One or more of the compound in IIIA2, IIIA13, IIIB2, IIIB6 representated by general formula III；Or the liquid-crystal composition includes the component of following mass percent：(1), the compound representated by 43~65% formula I；(2), the compound representated by 19~34% formula II；(3), the compound representated by 5~23% general formula III；Wherein, the compound representated by formula I be selected from IA18, IA20, IB18, IC17, IC18, IC19, IC20, ID18, IE18, IF18、IG18、IH18；One or more of the compound in IIA2, IIA6, IIA20 representated by formula II are most preferably IIA2；One or more of the compound in IIIA2, IIIA13, IIIB2, IIIB6 representated by general formula III.
- 8. according to the liquid-crystal composition described in claim any one of 5-7, it is characterised in that the percentage by weight of the component it With for 100%.
- 9. application of the liquid-crystal composition in field of liquid crystal display described in claim 1~8 any one.
- 10. application of the liquid-crystal composition in fast-response liquid crystal display device described in claim 1~8 any one, more preferably Application in VA, MVA, PVA, PSVA mode display or IPS, FFS mode display.
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Cited By (3)
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| WO2019116902A1 (en) * | 2017-12-11 | 2019-06-20 | Dic株式会社 | Liquid crystal display element |
| WO2019116901A1 (en) * | 2017-12-11 | 2019-06-20 | Dic株式会社 | Liquid crystal display element |
| CN112645924A (en) * | 2020-12-25 | 2021-04-13 | 阜阳欣奕华材料科技有限公司 | Compound, liquid crystal composition and display device |
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