CN107446334A - A kind of manufacture method of temperature-sensitive slide fastener - Google Patents

A kind of manufacture method of temperature-sensitive slide fastener Download PDF

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Publication number
CN107446334A
CN107446334A CN201710751767.1A CN201710751767A CN107446334A CN 107446334 A CN107446334 A CN 107446334A CN 201710751767 A CN201710751767 A CN 201710751767A CN 107446334 A CN107446334 A CN 107446334A
Authority
CN
China
Prior art keywords
slide fastener
temperature
manufacture method
raw material
heat discoloration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710751767.1A
Other languages
Chinese (zh)
Inventor
庄巧妮
柯祥龙
朱松峰
张田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Jinjiang xunxing zipper Technology Co. Ltd.
Original Assignee
Fujian SBS Zipper Science and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian SBS Zipper Science and Technology Co Ltd filed Critical Fujian SBS Zipper Science and Technology Co Ltd
Priority to CN201710751767.1A priority Critical patent/CN107446334A/en
Publication of CN107446334A publication Critical patent/CN107446334A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00Slide fasteners
    • A44B19/24Details
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Slide Fasteners (AREA)

Abstract

The invention discloses a kind of manufacture method of temperature-sensitive slide fastener, the manufacture method is to be well mixed polycarbonate resin, modifier, toughener, lubricant, composite antioxidant and heat discoloration pigment injection raw material is made, and is then molded using the injection raw material on zipper cloth belt and forms the PC transparent resin chain tooths with temperature effect;Mass fraction shared by each composition is in described injection raw material:Polycarbonate resin is 82 85%, and modifier is 6 8%, and toughener is 5 6%, and lubricant is 1 1.5%, and composite antioxidant is 0.6 1%, and heat discoloration pigment is 0.4 3.0%.Using delrin zippers with pulllers made of the inventive method, PC transparent resin chain tooths transparency on slide fastener is high, photosensitive phenomenon is obvious, with good temperature effect, with the change of slide fastener environment temperature, the color of PC transparent resin chain tooths can show the change being of different shades, and delrin zippers with pulllers product is with more personalization.

Description

A kind of manufacture method of temperature-sensitive slide fastener
Technical field
The present invention relates to delrin zippers with pulllers manufacturing field, more particularly to a kind of manufacture method of temperature-sensitive slide fastener.
Background technology
In existing slide fastener production technology, the chain tooth of delrin zippers with pulllers is used made of acetal resin (POM raw materials), by Application directly can not be mixed with POM raw materials in heat discoloration pigment, thus manufactured delrin zippers with pulllers, its slide fastener coupling element do not possess sense The temperature effect of temperature discoloration, current in the market do not have the delrin zippers with pulllers of heat discoloration yet, and the personalization of delrin zippers with pulllers is also more It is single;Thus it is necessary to carry out existing plastic fastener manufacture method research and development improvement, temperature-sensitive slide fastener can be manufactured by developing Method, it to meet demand of the market to the delrin zippers with pulllers with temperature-sensing discoloration function, while can have more delrin zippers with pulllers product There is personalization.
The content of the invention
For the above-mentioned problems in the prior art, the technical problems to be solved by the invention are to provide a kind of temperature-sensitive The manufacture method of slide fastener, using delrin zippers with pulllers made of the inventive method, the PC transparent resin chain tooths transparency on slide fastener is high, sense Optical phenomenon is obvious, has good temperature effect, and with the change of slide fastener environment temperature, the color of PC transparent resin chain tooths can be in Reveal the change being of different shades, delrin zippers with pulllers product is with more personalization.
Technical scheme is as follows:A kind of manufacture method of temperature-sensitive slide fastener, the manufacture method are by polycarbonate resin Fat, modifier, toughener, lubricant, composite antioxidant and heat discoloration pigment are well mixed to be made injection raw material, then It is molded using the injection raw material on zipper cloth belt and forms the PC transparent resin chain tooths with temperature effect.
Further, mass fraction shared by each composition is in described injection raw material:Polycarbonate resin is 82-85%, Modifier is 6-8%, toughener 5-6%, lubricant 1-1.5%, composite antioxidant 0.6-1%, heat discoloration Pigment is 0.4-3.0%.
Further, described heat discoloration pigment is heat discoloration powder, and heat discoloration powder accounts for the quality point of injection raw material Number is more preferably 0.6-2.0%.
Further, described composite antioxidant is that Hinered phenols antioxidant 1010 is pressed with phosphite ester kind antioxidant 168 Mass ratio 3:1 compounding is made.
Further, described modifier is polystyrene resin.
Further, described toughener is methyl methacrylate-butadiene-styrene resin.
Further, described lubricant is silicone releasing agent.
The beneficial effects of the invention are as follows:Using delrin zippers with pulllers made of the inventive method, the PC transparent resin chains on slide fastener Tooth transparency is high, and photosensitive phenomenon is obvious, has good temperature effect, with the change of slide fastener environment temperature, PC transparent resins The color of chain tooth can show the change being of different shades, and delrin zippers with pulllers product is with more personalization;In addition, using the present invention Slide fastener made of method, the PC transparent resin chain tooths on slide fastener are also equipped with good mechanical strength and antioxygenic property.
Embodiment
It preferred embodiments of the present invention will be described in detail below.
A kind of manufacture method of temperature-sensitive slide fastener, the manufacture method be by polycarbonate resin (PC raw materials), modifier, Toughener, lubricant, composite antioxidant and heat discoloration pigment are well mixed to be made injection raw material, then using the injection raw material Injection forms the PC transparent resin chain tooths with temperature effect on zipper cloth belt.
Mass fraction shared by each composition is in described injection raw material:Polycarbonate resin is 82-85%, modifier For 6-8%, toughener 5-6%, lubricant 1-1.5%, composite antioxidant 0.6-1%, heat discoloration pigment is 0.4- 3.0%.Described heat discoloration pigment is preferably heat discoloration powder, and the mass fraction that heat discoloration powder accounts for injection raw material is further Preferably 0.6-2.0%;Described composite antioxidant is by Hinered phenols antioxidant 1010 and phosphite ester kind antioxidant 168 Both antioxidant in mass ratio 3:1 compounding is made;Described modifier is preferably polystyrene resin (PS raw material);Institute The toughener stated is methyl methacrylate-butadiene-styrene resin (MBS raw materials);Described lubricant is preferably silicone Class releasing agent.
In a preferred embodiment of the present invention, mass fraction shared by each composition is in preferably described injection raw material:It is poly- Carbonate resin is 84%, polystyrene resin 7%, methyl methacrylate-butadiene-styrene resin 5.5%, silicon Ketone releasing agent is 1.2%, composite antioxidant 0.8%, and heat discoloration powder is 1.5%.
In addition, the color category of heat discoloration powder used in the inventive method there can be the selection compared with multiple types, pass through From the heat discoloration powder of different colours species, the PC transparent resin chain tooths that injection is formed can be caused to possess different colors, Such as:Blackish green, Green, peacock green, grass green, black, sea blue color, royalblue, golden yellow, golden red, large red, rose Rare red, glassy yellow, brownish black, pink or orange red etc..The PC transparent resin chain tooths of any color made of injection The change being of different shades can be showed with the change of environment temperature.
The beneficial effects of the invention are as follows:Using delrin zippers with pulllers made of the inventive method, the PC transparent resin chains on slide fastener Tooth transparency is high, and photosensitive phenomenon is obvious, has good temperature effect, with the change of slide fastener environment temperature, PC transparent resins The color of chain tooth can show the change being of different shades, and delrin zippers with pulllers product is with more personalization;In addition, using the present invention Slide fastener made of method, the PC transparent resin chain tooths on slide fastener are also equipped with good mechanical strength and antioxygenic property.
These are only the preferable embodiment of the present invention, but protection scope of the present invention is not limited thereto, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in Within the scope of.

Claims (7)

  1. A kind of 1. manufacture method of temperature-sensitive slide fastener, it is characterised in that:The manufacture method is by polycarbonate resin, processing modified Agent, toughener, lubricant, composite antioxidant and heat discoloration pigment are well mixed to be made injection raw material, then using the injection Raw material is molded on zipper cloth belt forms the PC transparent resin chain tooths with temperature effect.
  2. A kind of 2. manufacture method of temperature-sensitive slide fastener according to claim 1, it is characterised in that:It is each in described injection raw material Mass fraction is shared by composition:Polycarbonate resin is 82-85%, modifier 6-8%, toughener 5-6%, is lubricated Agent is 1-1.5%, and composite antioxidant 0.6-1%, heat discoloration pigment is 0.4-3.0%.
  3. A kind of 3. manufacture method of temperature-sensitive slide fastener according to claim 1 or 2, it is characterised in that:Described heat discoloration Pigment is heat discoloration powder, and the mass fraction that heat discoloration powder accounts for injection raw material is more preferably 0.6-2.0%.
  4. A kind of 4. manufacture method of temperature-sensitive slide fastener according to claim 1 or 2, it is characterised in that:Described compound antioxygen Agent is Hinered phenols antioxidant 1010 and phosphite ester kind antioxidant 168 in mass ratio 3:1 compounding is made.
  5. A kind of 5. manufacture method of temperature-sensitive slide fastener according to claim 1 or 2, it is characterised in that:Described is processing modified Agent is polystyrene resin.
  6. A kind of 6. manufacture method of temperature-sensitive slide fastener according to claim 1 or 2, it is characterised in that:Described toughener is Methyl methacrylate-butadiene-styrene resin.
  7. A kind of 7. manufacture method of temperature-sensitive slide fastener according to claim 1 or 2, it is characterised in that:Described lubricant is Silicone releasing agent.
CN201710751767.1A 2017-08-28 2017-08-28 A kind of manufacture method of temperature-sensitive slide fastener Pending CN107446334A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710751767.1A CN107446334A (en) 2017-08-28 2017-08-28 A kind of manufacture method of temperature-sensitive slide fastener

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710751767.1A CN107446334A (en) 2017-08-28 2017-08-28 A kind of manufacture method of temperature-sensitive slide fastener

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CN107446334A true CN107446334A (en) 2017-12-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108185590A (en) * 2017-12-20 2018-06-22 福建晋江浔兴拉链科技有限公司 The production technology of slide fastener with luminous effect

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0330171A1 (en) * 1988-02-25 1989-08-30 Yoshida Kogyo K.K. Thermochromic slide fastener parts and method of making the same
CN105820529A (en) * 2015-12-31 2016-08-03 宁波能之光新材料科技有限公司 Polycarbonate-polystyrene alloy material and preparation method thereof
CN106009471A (en) * 2016-06-24 2016-10-12 深圳市同益实业股份有限公司 Resin material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0330171A1 (en) * 1988-02-25 1989-08-30 Yoshida Kogyo K.K. Thermochromic slide fastener parts and method of making the same
CN105820529A (en) * 2015-12-31 2016-08-03 宁波能之光新材料科技有限公司 Polycarbonate-polystyrene alloy material and preparation method thereof
CN106009471A (en) * 2016-06-24 2016-10-12 深圳市同益实业股份有限公司 Resin material and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
原染料化学工业部涂料技术培训班组织编写: "《涂料工艺 第三分册》", 30 June 1989, 化学工业出版社 *
强涛涛: "《合成革化学品》", 31 July 2016, 中国轻工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108185590A (en) * 2017-12-20 2018-06-22 福建晋江浔兴拉链科技有限公司 The production technology of slide fastener with luminous effect

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SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20180413

Address after: Hai Cun Bin Xi Lu, Jinjiang city of Fujian province in 362200 Shenhu town of Quanzhou City, No. 18

Applicant after: Fujian Jinjiang xunxing zipper Technology Co. Ltd.

Address before: 362200 Fujian city of Quanzhou province Jinjiang City Shenhu Ukraine drain ditch East Industrial Zone

Applicant before: Fujian SBS Zipper Science & Technology Co., Ltd.

TA01 Transfer of patent application right
RJ01 Rejection of invention patent application after publication

Application publication date: 20171208

RJ01 Rejection of invention patent application after publication