CN107446191A - A kind of sole rubber foams and its application - Google Patents
A kind of sole rubber foams and its application Download PDFInfo
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- CN107446191A CN107446191A CN201710522721.2A CN201710522721A CN107446191A CN 107446191 A CN107446191 A CN 107446191A CN 201710522721 A CN201710522721 A CN 201710522721A CN 107446191 A CN107446191 A CN 107446191A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/0054—Producing footwear by compression moulding, vulcanising or the like; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/12—Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
- B29D35/122—Soles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2421/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of sole rubber foams and its application, its raw material includes the component of following parts by weight：The parts by weight of butadiene rubber 40~60, the parts by weight of butadiene-styrene rubber 10~35, the artificial parts by weight of natural gum 10~35, the parts by weight of 860 rubber of HS 10~40, the parts by weight of EVA7350 10~35, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, the parts by weight of A levels zinc oxide 5~8, the parts by weight of PEG4000 3.0~4.5, the parts by weight of S683 age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, the parts by weight of 08 protective agents of A 1.5~2.5, the parts by weight of 669 coupling agents of SI 1~2, the parts by weight of DM accelerator 1~2, the parts by weight of ACP H2 foaming agents 4~5, the parts by weight of sulphur S 80 1.5~2.5 and appropriate coloring agent.Sole sole made of rubber foams of the present invention is not added with traditional anti-wear agent, while it is only 1.18 ± 0.02 lightening effect to obtain proportion, remains able to obtain good bradyseism and anti-wear performance, rebound performance is good.
Description
Technical field
The invention belongs to Sports shoe sole field of material technology, and in particular to a kind of sole rubber foams and its
Using.
Background technology
With the fast development in sport footwear market, dress experience and the requirement of outward appearance of the people to parts such as soles are increasingly
Height, for sport shoe sole material, not only there is splendid supportive to meet the design requirement of the special constructions such as hollow out, also need
Possesses the feature such as very high bradyseism, high-elastic, wear-resisting.
As the material for sole of shoe of sport footwear, traditional EVA expanded materials can be met general by adding a certain amount of anti-wear agent
Logical wear-resisting demand, as CN105585769A discloses a kind of high abrasion flexible foaming elastomeric material and preparation method thereof, it is special
Sign be the foam rubbery material by rubber composition and the packet of the great achievement of rubber chemicals two into, rubber composition include ethene-
Acetate ethylene copolymer, ethylene propylene diene rubber, SEBS, POE elastomer, ethylene-octene block copolymer, rubber chemicals include resistance to
Grinding agent, foaming agent, vulcanizing agent, softening agent, accelerator, reinforcing agent and other auxiliary agents, preparation method by dispensing, banburying, mixing,
Mill, granulation step obtain finished product；There is compatibility, mutually auxiliary sexual factor in the present invention, make between utilizing all kinds synthetic rubber
Obtaining high abrasion elastic body shoe bed material has high resiliency, high-flexibility, high abrasion, good mechanical performance.But this sole
The universal hardness of material is higher, the poor-performing such as material bradyseism, resilience, and fatigue durability is poor, after a period of time is worn, it may appear that
The problem of recovery is bad such as collapse, while sole follows the string quickly, bradyseism degradation, for the special knot such as some hollow outs
Structure, the Sports shoe sole of this material also can collapse-deformation, have a strong impact on shoes wears experience and surface structure.
The content of the invention
It is an object of the invention to overcome prior art defect, there is provided a kind of sole rubber foams.
Another object of the present invention is to provide the application of above-mentioned sole rubber foams.
Technical scheme is as follows：
A kind of sole rubber foams, its raw material include the component of following parts by weight：The weight of butadiene rubber 40~60
Measure part, the parts by weight of butadiene-styrene rubber 10~35, the parts by weight of artificial natural gum 10~35, the parts by weight of HS-860 rubber 10~40,
The parts by weight of EVA7350 10~35, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, the weight of A levels zinc oxide 5~8
Part, the parts by weight of PEG4000 3.0-~4.5, the parts by weight of S683 age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, A-
The parts by weight of 08 protective agent 1.5~2.5, the parts by weight of SI-669 coupling agents 1~2, the parts by weight of DM accelerator 1~2, ACP-H2 foaming agents
4~5 parts by weight, the parts by weight of sulphur S-80 1.5~2.5 and appropriate coloring agent.
In a preferred embodiment of the invention, its raw material includes the component of following parts by weight：The weight of butadiene rubber 45
Measure part, the parts by weight of butadiene-styrene rubber 15, the parts by weight of artificial natural gum 15, the parts by weight of HS-860 rubber 10, the parts by weight of EVA7350 15,
The parts by weight of white carbon 22, the parts by weight of stearic acid 0.5, the parts by weight of A levels zinc oxide 5, the parts by weight of PEG4000 3, the weight of S683 age resistor 1
Measure part, the parts by weight of S6064 age resistor 0.5, the parts by weight of A-08 protective agents 1.5, the parts by weight of SI-669 coupling agents 1, DM accelerator 1.5
Parts by weight, the parts by weight of ACP-H2 foaming agents 4.2, the parts by weight of sulphur S-80 1.8 and appropriate coloring agent.
In a preferred embodiment of the invention, it is made up of the component of following parts by weight：The weight of butadiene rubber 40~60
Measure part, the parts by weight of butadiene-styrene rubber 10~35, the parts by weight of artificial natural gum 10~35, the parts by weight of HS-860 rubber 10~40,
The parts by weight of EVA7350 10~35, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, the weight of A levels zinc oxide 5~8
Part, the parts by weight of PEG4000 3.0-~4.5, the parts by weight of S683 age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, A-
The parts by weight of 08 protective agent 1.5~2.5, the parts by weight of SI-669 coupling agents 1~2, the parts by weight of DM accelerator 1~2, ACP-H2 foaming agents
4~5 parts by weight, the parts by weight of sulphur S-80 1.5~2.5 and appropriate coloring agent.
It is further preferred that it is made up of the component of following parts by weight：The parts by weight of butadiene rubber 45, the weight of butadiene-styrene rubber 15
Part, the parts by weight of artificial natural gum 15, the parts by weight of HS-860 rubber 10, the parts by weight of EVA7350 15, the parts by weight of white carbon 22, tristearin
Sour 0.5 parts by weight, the parts by weight of A levels zinc oxide 5, the parts by weight of PEG4000 3, the parts by weight of S683 age resistor 1, S6064 age resistor 0.5
Parts by weight, the parts by weight of A-08 protective agents 1.5, the parts by weight of SI-669 coupling agents 1, the parts by weight of DM accelerator 1.5, ACP-H2 foaming agents
4.2 parts by weight, the parts by weight of sulphur S-80 1.8 and appropriate coloring agent.
Another technical scheme of the present invention is as follows：
A kind of Sports shoe sole, it is made up of above-mentioned sole of rubber foams.
The preparation method of above-mentioned Sports shoe sole, comprises the following steps：
(1) each component is weighed by weight；
(2) 5~10min is kneaded after each component in addition to sulphur is sufficiently mixed, in 128 DEG C of temperature below dischargings；
(3) step (2) resulting material is gone out after 5~8min of cooling dispersion milling is carried out in mill according to 4~6mm thickness
Piece simultaneously cools down at least 24h；
(4) step (3) resulting material is carried out on a mill plus sulphur operation is to add sulphur, then the thickness according to needed for
Carry out slice；
(5) sanctioned after step (4) resulting material being cooled down at least 4h to obtain cut-parts；
(6) by above-mentioned cut-parts according to actual mould on 155~162 DEG C of hot press carry out 3~4min hot-pressing processing, obtain
Head product；
(7) the stable ripe processing of 5~8h is carried out in sulfur dioxide baking oven after above-mentioned head product being carried out into deburring arrangement,
Produce the Sports shoe sole.
In a preferred embodiment of the invention, the step (2) is：Each component in addition to sulphur is fully mixed
6min is kneaded after conjunction, in 128 DEG C of temperature below dischargings.
In a preferred embodiment of the invention, the step (3) is：By step (2) resulting material in mill
On cool after dispersion milling 6min according to 5mm thickness slice and cool down at least 24h.
In a preferred embodiment of the invention, the step (6) is：By above-mentioned cut-parts with actual mould in 160
DEG C hot press on carry out 3.5min hot-pressing processing, obtain head product.
Beneficial effects of the present invention：
1st, sole sole made of rubber foams of the invention is not added with traditional anti-wear agent, is obtaining proportion only
For 1.18 ± 0.02 lightening effect while, remain able to obtain good bradyseism and anti-wear performance, rebound performance is good.
2nd, the HS-860 rubber in the present invention has good compatibility and foaminess with rubber-like and EVA material.
Embodiment
Technical scheme is further detailed and described below by way of embodiment.
Embodiment 1
A kind of Sports shoe sole, its preparation method comprise the following steps：
(1) each component is weighed by following parts by weight：The parts by weight of butadiene rubber 40~60, the parts by weight of butadiene-styrene rubber 10~35,
The artificial parts by weight of natural gum 10~35, the parts by weight of HS-860 rubber 10~40, the parts by weight of EVA7350 10~35, white carbon 20~
The parts by weight of 30 parts by weight, the parts by weight of stearic acid 0.5~1, the parts by weight of A levels zinc oxide 5~8, PEG4000 3.0-~4.5, S683
The parts by weight of age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, the parts by weight of A-08 protective agents 1.5~2.5, SI-669 are even
Join the parts by weight of agent 1~2, the parts by weight of DM accelerator 1~2, the parts by weight of ACP-H2 foaming agents 4~5, the weights of sulphur S-80 1.5~2.5
Measure part and appropriate coloring agent；
(2) 6min is kneaded after each component in addition to sulphur is sufficiently mixed, in 128 DEG C of temperature below dischargings；
(3) by step (2) resulting material after the dispersion milling 6min of carrying out cooling in mill according to 5mm thickness slice and cold
But at least 24h；
(4) step (3) resulting material is carried out on a mill plus sulphur operation is to add sulphur, then the thickness according to needed for
Carry out slice；
(5) sanctioned after step (4) resulting material being cooled down at least 4h to obtain cut-parts；
(6) by above-mentioned cut-parts with actual mould on 160 DEG C of hot press carry out 3.5min hot-pressing processing, obtain primiparity
Product；
(7) above-mentioned head product is subjected to deburring and arranges the stable ripe processing of the progress 6h in sulfur dioxide baking oven, produced
The Sports shoe sole, specific physical index are as shown in the table：
| Hardness (A) | Proportion (g/cm3) | DIN wears away (mm3) |
| Test condition | Test condition | Test condition |
| Normal temperature | Normal temperature | Normal temperature |
| 55±2 | 1.18±0.02 | ≤150 |
Those of ordinary skill in the art understand, when technical scheme changes in following ranges, remain able to
To same as the previously described embodiments or similar technical scheme, protection scope of the present invention is still fallen within：
A kind of Sports shoe sole, it is made up of sole of rubber foams.
Specifically comprise the following steps：
(1) each component is weighed with the formula of rubber foams by sole：The parts by weight of butadiene rubber 40~60, butylbenzene rubber
The parts by weight of glue 10~35, the parts by weight of artificial natural gum 10~35, the parts by weight of HS-860 rubber 10~40, the weights of EVA7350 10~35
Measure part, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, the parts by weight of A levels zinc oxide 5~8, PEG4000 3.0-~
4.5 parts by weight, the parts by weight of S683 age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, the weight of A-08 protective agents 1.5~2.5
Measure part, the parts by weight of SI-669 coupling agents 1~2, the parts by weight of DM accelerator 1~2, the parts by weight of ACP-H2 foaming agents 4~5, sulphur S-
80 1.5~2.5 parts by weight and appropriate coloring agent；
(2) 5~10min is kneaded after each component in addition to sulphur is sufficiently mixed, in 128 DEG C of temperature below dischargings；
(3) step (2) resulting material is gone out after 5~8min of cooling dispersion milling is carried out in mill according to 4~6mm thickness
Piece simultaneously cools down at least 24h；
(4) step (3) resulting material is carried out on a mill plus sulphur operation is to add sulphur, then the thickness according to needed for
Carry out slice；
(5) sanctioned after step (4) resulting material being cooled down at least 4h to obtain cut-parts；
(6) by above-mentioned cut-parts with actual mould on 155~162 DEG C of hot press carry out 3~4min hot-pressing processing, obtain
Head product：
(7) the stable ripe processing of 5~8h is carried out in sulfur dioxide baking oven after above-mentioned head product being carried out into deburring arrangement,
Produce the Sports shoe sole.
The foregoing is only a preferred embodiment of the present invention, therefore can not limit the scope that the present invention is implemented according to this, i.e.,
The equivalent changes and modifications made according to the scope of the claims of the present invention and description, all should still it belong in the range of the present invention covers.
Claims (9)
- A kind of 1. sole rubber foams, it is characterised in that：Its raw material includes the component of following parts by weight：Butadiene rubber 40~60 parts by weight, the parts by weight of butadiene-styrene rubber 10~35, the parts by weight of artificial natural gum 10~35, the weight of HS-860 rubber 10~40 Part, the parts by weight of EVA7350 10~35, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, the weight of A levels zinc oxide 5~8 Measure part, the parts by weight of PEG4000 3.0-~4.5, the parts by weight of S683 age resistor 0.5~2, the parts by weight of S6064 age resistor 0.5~2, The parts by weight of A-08 protective agents 1.5~2.5, the parts by weight of SI-669 coupling agents 1~2, the parts by weight of DM accelerator 1~2, ACP-H2 foaming The parts by weight of agent 4~5, the parts by weight of sulphur S-80 1.5~2.5 and appropriate coloring agent.
- A kind of 2. sole rubber foams as claimed in claim 1, it is characterised in that：Its raw material includes following weight The component of part：The parts by weight of butadiene rubber 45, the parts by weight of butadiene-styrene rubber 15, the parts by weight of artificial natural gum 15, the weight of HS-860 rubber 10 Measure part, the parts by weight of EVA7350 15, the parts by weight of white carbon 22, the parts by weight of stearic acid 0.5, the parts by weight of A levels zinc oxide 5, PEG4000 3 parts by weight, the parts by weight of S683 age resistor 1, the parts by weight of S6064 age resistor 0.5, the parts by weight of A-08 protective agents 1.5, SI-669 couplings The parts by weight of agent 1, the parts by weight of DM accelerator 1.5, the parts by weight of ACP-H2 foaming agents 4.2, the parts by weight of sulphur S-80 1.8 and appropriate color Glue.
- A kind of 3. sole rubber foams as claimed in claim 1, it is characterised in that：By the component of following parts by weight It is made：The parts by weight of butadiene rubber 40~60, the parts by weight of butadiene-styrene rubber 10~35, the parts by weight of artificial natural gum 10~35, HS-860 The parts by weight of rubber 10~40, the parts by weight of EVA7350 10~35, the parts by weight of white carbon 20~30, the parts by weight of stearic acid 0.5~1, A The parts by weight of level zinc oxide 5~8 parts by weight, PEG4000 3.0-~4.5, the parts by weight of S683 age resistor 0.5~2, S6064 age resistor 0.5~2 parts by weight, the parts by weight of A-08 protective agents 1.5~2.5, the parts by weight of SI-669 coupling agents 1~2, the weight of DM accelerator 1~2 Part, the parts by weight of ACP-H2 foaming agents 4~5, the parts by weight of sulphur S-80 1.5~2.5 and appropriate coloring agent.
- A kind of 4. sole rubber foams as claimed in claim 3, it is characterised in that：By the component of following parts by weight It is made：The parts by weight of butadiene rubber 45, the parts by weight of butadiene-styrene rubber 15, the parts by weight of artificial natural gum 15, the parts by weight of HS-860 rubber 10, The parts by weight of EVA7350 15, the parts by weight of white carbon 22, the parts by weight of stearic acid 0.5, the parts by weight of A levels zinc oxide 5, the weights of PEG4000 3 Measure part, the parts by weight of S683 age resistor 1, the parts by weight of S6064 age resistor 0.5, the parts by weight of A-08 protective agents 1.5, SI-669 coupling agents 1 Parts by weight, the parts by weight of DM accelerator 1.5, the parts by weight of ACP-H2 foaming agents 4.2, sulphur S-801.8 parts by weight and appropriate coloring agent.
- A kind of 5. Sports shoe sole, it is characterised in that：Foaming rubber is used as the sole described in any claim in Claims 1-4 Glue composition is made.
- 6. the preparation method of the Sports shoe sole described in claim 5, it is characterised in that：Comprise the following steps：(1) each component is weighed by weight；(2) 5~10min is kneaded after each component in addition to sulphur is sufficiently mixed, in 128 DEG C of temperature below dischargings；(3) by step (2) resulting material after the dispersion milling 5~8min of carrying out cooling in mill according to 4~6mm thickness slice simultaneously Cool down at least 24h；(4) step (3) resulting material is carried out on a mill plus sulphur operation is to add sulphur, then thickness is carried out according to needed for Slice；(5) sanctioned after step (4) resulting material being cooled down at least 4h to obtain cut-parts；(6) by above-mentioned cut-parts according to actual mould on 155~162 DEG C of hot press carry out 3~4min hot-pressing processing, obtain primiparity Product；(7) the stable ripe processing of 5~8h is carried out in sulfur dioxide baking oven after above-mentioned head product being carried out into deburring arrangement, is produced The Sports shoe sole.
- 7. preparation method as claimed in claim 6, it is characterised in that：The step (2) is：By each component in addition to sulphur 6min is kneaded after being sufficiently mixed, in 128 DEG C of temperature below dischargings.
- 8. preparation method as claimed in claim 6, it is characterised in that：The step (3) is：By step (2) resulting material in Carry out cooling in mill after dispersion milling 6min according to 5mm thickness slice and cool down at least 24h.
- 9. preparation method as claimed in claim 6, it is characterised in that：The step (6) is：By above-mentioned cut-parts with actual mould In the hot-pressing processing that 3.5min is carried out on 160 DEG C of hot press, head product is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522721.2A CN107446191A (en) | 2017-06-30 | 2017-06-30 | A kind of sole rubber foams and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522721.2A CN107446191A (en) | 2017-06-30 | 2017-06-30 | A kind of sole rubber foams and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107446191A true CN107446191A (en) | 2017-12-08 |
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ID=60488490
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| CN201710522721.2A Pending CN107446191A (en) | 2017-06-30 | 2017-06-30 | A kind of sole rubber foams and its application |
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Cited By (4)
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| CN109181041A (en) * | 2018-07-24 | 2019-01-11 | 温州市小林鞋材有限公司 | A kind of ultralight rubber plastic sole material and preparation method thereof |
| CN110041580A (en) * | 2019-04-23 | 2019-07-23 | 昆山多威体育用品有限公司 | A kind of rubber material and its preparation method and application that wear-resisting antiskid intensity is good |
| CN110483853A (en) * | 2019-07-25 | 2019-11-22 | 莆田星昌鞋业有限公司 | A kind of high-elastic damping rubber soles and its processing method |
| CN112358664A (en) * | 2020-12-08 | 2021-02-12 | 佛山市大唐新新橡塑有限公司 | HPE rubber-plastic blended rubber |
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| CN105175831A (en) * | 2015-07-23 | 2015-12-23 | 易宝（福建）高分子材料股份公司 | Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material |
| CN105670052A (en) * | 2016-04-18 | 2016-06-15 | 晋江新绮达鞋材有限责任公司 | Novel high-resilience foamable rubber shoe sole material and preparation method thereof |
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| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN105175831A (en) * | 2015-07-23 | 2015-12-23 | 易宝（福建）高分子材料股份公司 | Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109181041A (en) * | 2018-07-24 | 2019-01-11 | 温州市小林鞋材有限公司 | A kind of ultralight rubber plastic sole material and preparation method thereof |
| CN110041580A (en) * | 2019-04-23 | 2019-07-23 | 昆山多威体育用品有限公司 | A kind of rubber material and its preparation method and application that wear-resisting antiskid intensity is good |
| CN110041580B (en) * | 2019-04-23 | 2022-02-22 | 昆山多威体育用品有限公司 | Rubber material with good wear-resistant and skid-resistant strength, and preparation method and application thereof |
| CN110483853A (en) * | 2019-07-25 | 2019-11-22 | 莆田星昌鞋业有限公司 | A kind of high-elastic damping rubber soles and its processing method |
| CN112358664A (en) * | 2020-12-08 | 2021-02-12 | 佛山市大唐新新橡塑有限公司 | HPE rubber-plastic blended rubber |
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