CN107434415B - Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof - Google Patents
Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof Download PDFInfo
- Publication number
- CN107434415B CN107434415B CN201710437687.9A CN201710437687A CN107434415B CN 107434415 B CN107434415 B CN 107434415B CN 201710437687 A CN201710437687 A CN 201710437687A CN 107434415 B CN107434415 B CN 107434415B
- Authority
- CN
- China
- Prior art keywords
- boron nitride
- cubic boron
- thermal conductivity
- composite sheet
- thermal stability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910052582 BN Inorganic materials 0.000 title claims abstract description 62
- 239000002131 composite material Substances 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000002245 particle Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 239000010955 niobium Substances 0.000 claims description 9
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 9
- 239000011863 silicon-based powder Substances 0.000 claims description 9
- 230000002194 synthesizing effect Effects 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 abstract description 15
- 239000010959 steel Substances 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 14
- 238000003754 machining Methods 0.000 abstract description 10
- 229910000975 Carbon steel Inorganic materials 0.000 abstract description 8
- 229910001018 Cast iron Inorganic materials 0.000 abstract description 8
- 239000007767 bonding agent Substances 0.000 abstract description 8
- 239000010962 carbon steel Substances 0.000 abstract description 8
- 239000000919 ceramic Substances 0.000 abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 abstract description 8
- 239000010941 cobalt Substances 0.000 abstract description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052721 tungsten Inorganic materials 0.000 abstract description 8
- 239000010937 tungsten Substances 0.000 abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000007747 plating Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/583—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride
- C04B35/5831—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride based on cubic boron nitrides or Wurtzitic boron nitrides, including crystal structure transformation of powder
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/40—Metallic constituents or additives not added as binding phase
- C04B2235/402—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/40—Metallic constituents or additives not added as binding phase
- C04B2235/404—Refractory metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/428—Silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9646—Optical properties
- C04B2235/9661—Colour
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
Abstract
The invention belongs to the technical field of superhard materials, and particularly relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and a production method thereof. The product is obtained by adopting high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertia, and have longer service life, heat resistance and thermal stability in high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
Description
Technical Field
The invention belongs to the technical field of superhard materials, and particularly relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and a production method thereof.
Background
At present, in high-speed finish machining of materials which are difficult to cut, such as quenched steel, cast iron, carbon steel and the like, the cutter machining materials are required to have high thermal stability and good thermal conductivity, and the cutter composite sheet materials such as polycrystalline diamond and the like are easy to break due to overhigh temperature in the cutting process, so that the working efficiency is influenced. The hardness of the cubic boron nitride is second to that of diamond, has high thermal stability and strong chemical stability, and can effectively replace a polycrystalline diamond compact as a material of a ferrous metal machining cutter.
At present, polycrystalline cubic boron nitride cutter manufacturers produced in China basically rely on imported polycrystalline cubic boron nitride composite sheet materials in developed countries in the western world, and the price is high. The existing production process is basically as follows; the polycrystalline cubic boron nitride layer is prepared from the following raw materials in parts by weight: 70-85 parts of cubic boron nitride micro powder, 10-15 parts of metal bonding agent and 5-10 parts of ceramic additive. The production method is carried out according to the following steps: A. mixing uniformly; B. and (3) putting the mixture and the hard alloy matrix into a molybdenum cup isolated by a salt tube shielding layer, heating and synthesizing. However, the thermal stability and thermal conductivity of the polycrystalline cubic boron nitride composite sheet produced by the existing process are to be further improved, so that there is a need for further research on the production process of the polycrystalline cubic boron nitride composite sheet.
Disclosure of Invention
The invention aims to provide a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and a production method thereof, so as to improve the thermal stability and the thermal conductivity of the polycrystalline cubic boron nitride composite sheet.
In order to solve the technical problems, the invention adopts the following technical scheme:
the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity is prepared from the following raw materials: 80-87% of nickel-plated cubic boron nitride particles, 1-3% of aluminum powder, 1-3% of metal niobium, 1-5% of vanadium carbide and the balance of silicon powder.
Preferably, the nickel plated cubic boron nitride particles have a particle size of 2 to 4 microns.
Preferably, the diameter of the aluminum powder is less than 5 microns.
The invention relates to a production method of a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: preparing raw materials by using a formula of 80-87% of nickel-plated cubic boron nitride particles, 1-3% of aluminum powder, 1-3% of metal niobium, 1-5% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 8-15 hours, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 90-100MPa and 1400-1600 ℃ after assembly for 30-50 minutes.
The invention has the following beneficial effects:
1. the product obtained by adopting high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic has the advantages of large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance, high chemical inertness, longer service life, higher heat resistance and higher thermal stability in high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
2. The invention adopts tungsten, cobalt, aluminum and other diversified catalyst systems to synthesize the cubic boron nitride crystal, which can increase the reaction activity of the system and promote the growth speed of the cubic boron nitride crystal.
3. The invention adopts a plurality of catalyst combinations to produce cubic boron nitride crystals with various colors (different grades).
4. The invention can effectively ensure the growth integrity of the cubic boron nitride crystal through high-temperature impurity removal.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: preparing raw materials by using a formula of 80% of nickel-plated cubic boron nitride particles, 1% of aluminum powder, 3% of metal niobium, 5% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 8 hours, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 100MPa and 1600 ℃ after assembly, wherein the synthesis time is 30 minutes.
Wherein the grain size of the cubic boron nitride grain of the cubic nickel plating is 2.5 microns; the diameter of the aluminum powder is 5 microns.
The production method adopts the product obtained by high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertness, and have longer service life, heat resistance and heat stability in the high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
Example 2
The invention relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: preparing raw materials by using a formula of 82% of nickel-plated cubic boron nitride particles, 1.4% of aluminum powder, 1.8% of metal niobium, 2.5% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 0111 hour, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 92MPa and 1450 ℃ after assembly, wherein the synthesis time is 40 minutes.
Wherein the grain size of the cubic boron nitride grain of the cubic nickel plating is 3.5 microns; the diameter of the aluminum powder is 4.9 microns.
The production method adopts the product obtained by high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertness, and have longer service life, heat resistance and heat stability in the high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
Example 3
The invention relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: preparing raw materials by using a formula of 84% of nickel-plated cubic boron nitride particles, 1.8% of aluminum powder, 2.6% of metal niobium and 2% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 14 hours, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 94MPa and 1540 ℃ after assembly, wherein the synthesis time is 50 minutes.
Wherein the grain size of the cubic boron nitride grain of the cubic nickel plating is 2 microns; the diameter of the aluminum powder is 3.9 microns.
The production method adopts the product obtained by high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertness, and have longer service life, heat resistance and heat stability in the high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
Example 4
The invention relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: preparing raw materials according to a formula of 85% of nickel-plated cubic boron nitride particles, 2.2% of aluminum powder, 2% of metal niobium, 3% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 15 hours, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 98MPa and 1400 ℃ after assembly, wherein the synthesis time is 35 minutes.
Wherein the grain size of the cubic boron nitride grain of the cubic nickel plating is 2.8 microns; the diameter of the aluminum powder is 4.5 microns.
The production method adopts the product obtained by high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertness, and have longer service life, heat resistance and heat stability in the high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
Example 5
The invention relates to a polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity, which comprises the following steps: the preparation method comprises the steps of preparing raw materials according to a formula that 87% of nickel-plated cubic boron nitride particles, 3% of aluminum powder, 1% of niobium metal, 4% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 2111 hour, assembling, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 90MPa and 1500 ℃ for 45 minutes.
Wherein the grain size of the cubic boron nitride grain of the cubic nickel plating is 3 microns; the diameter of the aluminum powder is 4 microns.
The production method adopts the product obtained by high-content nickel-plated cubic boron nitride particles and a bonding agent such as tungsten, cobalt, aluminum or aluminum ceramic, the nickel-plated cubic boron nitride particles have large granularity, high thermal conductivity, high concentration, excellent fracture toughness and impact resistance and high chemical inertness, and have longer service life, heat resistance and heat stability in the high-speed finish machining of difficult-to-cut materials such as quenched steel, cast iron, carbon steel, die steel and the like.
It is to be understood that the exemplary embodiments described herein are illustrative and not restrictive. While one or more embodiments of the present invention have been described, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims.
Claims (1)
1. The polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity is characterized by being prepared from the following raw materials: the production method of the polycrystalline cubic boron nitride composite sheet comprises the following steps of 80-87% of nickel-plated cubic boron nitride particles, 1-3% of aluminum powder, 1-3% of metal niobium, l-5% of vanadium carbide and the balance of silicon powder, wherein the diameter of the nickel-plated cubic boron nitride particles is 2-4 microns, the diameter of the aluminum powder is less than 5 microns, and the production method of the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity comprises the following steps: preparing raw materials by using a formula of 80-87% of nickel-plated cubic boron nitride particles, l-3% of aluminum powder, 1-3% of metal niobium, 1-5% of vanadium carbide and the balance of silicon powder, mixing the raw materials together for 8-15 hours, and synthesizing the polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity in a cubic hydraulic press with a cylinder diameter of 750 under the conditions of 90-100MP and 1400-1600 ℃ after assembly for 30-50 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710437687.9A CN107434415B (en) | 2017-06-12 | 2017-06-12 | Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710437687.9A CN107434415B (en) | 2017-06-12 | 2017-06-12 | Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107434415A CN107434415A (en) | 2017-12-05 |
| CN107434415B true CN107434415B (en) | 2020-10-02 |
Family
ID=60458411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710437687.9A Active CN107434415B (en) | 2017-06-12 | 2017-06-12 | Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107434415B (en) |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005132654A (en) * | 2003-10-29 | 2005-05-26 | Sumitomo Electric Ind Ltd | Ceramic composite material and its manufacturing process |
| US20100009839A1 (en) * | 2006-06-09 | 2010-01-14 | Antionette Can | Ultrahard Composite Materials |
| WO2008072180A2 (en) * | 2006-12-11 | 2008-06-19 | Element Six (Production) (Pty) Ltd | Cubic boron nitride compacts |
| CN101560624B (en) * | 2009-05-18 | 2010-12-29 | 河南富耐克超硬材料有限公司 | Method for preparing polycrystalline cubic boron nitride |
| JP6257896B2 (en) * | 2009-08-04 | 2018-01-10 | アロメット コーポレイション | Consolidated high toughness coated hard particles in high toughness matrix materials. |
| CN102834210A (en) * | 2010-04-08 | 2012-12-19 | 株式会社图格莱 | Composite body |
| CN102050633B (en) * | 2010-11-14 | 2013-02-13 | 河南工业大学 | Polycrystalline cubic boron nitride compact toughened by Ni-plated Si3N4 whisker and preparation method thereof |
| WO2013069657A1 (en) * | 2011-11-07 | 2013-05-16 | 株式会社タンガロイ | Cubic boron nitride sintered body |
| JP6082650B2 (en) * | 2013-04-26 | 2017-02-15 | 株式会社タンガロイ | Cubic boron nitride sintered body and coated cubic boron nitride sintered body |
| CN106316403A (en) * | 2016-08-18 | 2017-01-11 | 中南钻石有限公司 | Fine-grained cubic boron nitride blade and preparation method thereof |
-
2017
- 2017-06-12 CN CN201710437687.9A patent/CN107434415B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107434415A (en) | 2017-12-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102140603B (en) | Preparation method of hard alloy using nickel-aluminum intermetallic compound Ni3Al as bonding phase | |
| CN103789596A (en) | Polycrystalline cubic boron nitride cutter material and preparation method thereof | |
| CN102505090A (en) | Preparation method of high-toughness polycrystalline cubic boron nitride compound sheets | |
| CN110819866B (en) | WC-Co-B4Preparation method of C hard alloy | |
| CN101891481B (en) | Method for producing polycrystal cubic boron nitride abrasive materials | |
| CN111809073A (en) | Gradient hard alloy square block and preparation method thereof | |
| CN110524442B (en) | Porous diamond polycrystalline abrasive and preparation method thereof | |
| CN102329975A (en) | Super-hard material and preparation method thereof | |
| CN103433488A (en) | Preparation method of titanium nitride-ferrous metal ceramics | |
| CN105126853B (en) | One kind synthesis high-quality gem grade diamond large single crystal catalyst and preparation method thereof | |
| CN107434415B (en) | Polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and production method thereof | |
| CN107759227B (en) | Method for preparing PcBN cutter material by catalyst method | |
| CN101348870A (en) | Tungsten carbide-titanium carbide-tantalum carbide solid solution powder | |
| CN112239828A (en) | Novel hard alloy material suitable for bow of icebreaker | |
| CN102896311B (en) | Powder-shaped adhesive for diamond composite sheet and preparation method thereof | |
| CN101338383A (en) | Method for preparing high-density cemented carbide | |
| CN102162058A (en) | Hard alloy taking nickel-aluminum intermetallic compound Ni3Al as binding phase and preparation method thereof | |
| CN114774750A (en) | Tungsten carbide material bonded by enhanced high-entropy alloy and preparation method thereof | |
| CN106905922A (en) | Method for producing polycrystal cubic boron nitride abrasive materials | |
| CN110551483B (en) | Method for preparing cubic boron nitride titanium carbide composite abrasive | |
| CN109248690B (en) | Preparation method of cold-pressed metal catalyst for growth of colorless gem grade diamond | |
| CN102660707B (en) | Production method for WC-Al4W pre-alloy powder | |
| CN107382325B (en) | Polycrystalline cubic boron nitride composite sheet for high-end cutter and production method thereof | |
| CN1061918A (en) | Powdered carbonide catalysis for synthesizing fine-granularity diamond | |
| CN110590376A (en) | PCBN cutter material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A polycrystalline cubic boron nitride composite sheet with high thermal stability and good thermal conductivity and its production method Granted publication date: 20201002 Pledgee: Bank of Jinhua Limited by Share Ltd. science and Technology Branch Pledgor: JINHUA ZHONGYE SUPERHARD MATERIAL COMPOSITE Co.,Ltd. Registration number: Y2024980006390 |