CN107427435A - Use the method for the dense hair of pyridinedicarboxylic acid compound cosmetic treatments - Google Patents
Use the method for the dense hair of pyridinedicarboxylic acid compound cosmetic treatments Download PDFInfo
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- CN107427435A CN107427435A CN201680015294.2A CN201680015294A CN107427435A CN 107427435 A CN107427435 A CN 107427435A CN 201680015294 A CN201680015294 A CN 201680015294A CN 107427435 A CN107427435 A CN 107427435A
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- hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of method for the dense hair of cosmetic treatments, the method for being particularly used for the dense hair of cosmetic treatments Asian, it is included using the cosmetic composition for including pyridinedicarboxylic acid compound.
Description
The present invention relates to using one or more dense hairs of pyridinedicarboxylic acid compound cosmetic treatments method, especially
The method of cosmetic treatments Asian's hair.
Hair can be by chemical treatment as dyed, bleaching, permanent curly hair, softening and the effect washed repeatedly and be damaged
It is or brittle.Hair becomes sensitive, therefore is compromised by these various processing, and can become drying for a long time, coarse, hair
It is crisp, matt, bifurcated or soft.
In order to overcome these shortcomings, usual settling mode is hair care processing, satisfied esthetics by providing using being intended to
Matter and the suitably composition of conditioning hair.These hair care compositions can be, for example, conditioning shampoo, hair-conditioning
Agent, send out film or hair-cream.However, generally in continuously hair washing operating process, the conditioning effect obtained generally becomes less to show
Write, and gratifying persistence is not showed for hair washing.This is particularly true for dense hair.
Therefore, it is necessary to method for cosmetic treatments hair, particularly dense hair, especially sensitive dense hair,
This method can carry out continuing conditioning to it, be particularly used for assigning its good manageability and good gloss, advantageously,
Conditioning effect is still lasting after one or many hair washing operations are carried out on the hair through processing.
Applicant company has been found that the pyridinedicarboxylic acid compound that will be defined as below allows to applied to dense hair
The cosmetic properties of good manageability and hair mass and gloss are obtained, and there is lasting effect over time
Fruit, especially after one or more hair washing operations.
Therefore, subject of the present invention is the method for the dense hair of cosmetic treatments, and it is included comprising the one kind being defined as below
Or the cosmetic composition of a variety of pyridinedicarboxylic acid compounds is applied to the hair.
Especially, the hair of the method according to the invention processing keeps good state, because curling is not observed
In the presence of.Therefore, hair is neatly and smooth；In addition, it has more preferable surface quality, more tough, more difficult fracture, performance is more
Small fragility.In addition, processed hair is also brighter.
The method according to the invention has hair washing, reinforcement and the toughness of these properties for assigning fiber quality well to keep
The advantages of property.Therefore, the hair of processing is strengthened in a manner of lasting, protected, even repaired.
Therefore, the method according to the invention makes it possible it, especially, improves the quality of hair, protects hair, add
Strong hair, it is become more flexible and less fragility, or even hair is repaired in damage.
Patent application FR 2 838 336 is disclosed using pyridinedicarboxylic acid compound to prevent and treat alopecia.However, this document
In be not described or suggest using such compound to nurse one's health, protect or strengthen dense hair.
Dense hair is understood to mean hair, and wherein hair is with least 90 microns, preferably at least 100 microns, especially
It is 90 to 120 microns, or even the individual between 100 to 120 microns（individual）Diameter.
Preferably, dense hair is, very especially, the dense hair of Asian.
Therefore, in a specific embodiment, the present invention includes the cosmetic treatment method for the dense hair of Asian,
Cosmetic composition including applying from the pyridinedicarboxylic acid compound being defined as below comprising one or more to the hair.
The 2,4 pyridine dicarboxylic acid compound used according to the invention is to be selected from following formula（I）Compound：
Wherein R1 and R2 represents OH, OR' ,-NH independently of one another2,-NHR ' or-NR'R'', wherein R' and R'' are only each other
On the spot represent saturated or unsaturated and straight or branched C1-C18Alkyl, it is optionally selected from OH, C by least one1-C6Alkane
Epoxide, C1-C6Acyloxy, amino,（C1-C6）Alkoxy carbonyl or（C1-C6）The group substitution of alkyl amino, or C6-C10Aryl,
And their salt.
More specifically, R1 and R2 represent OH or OR' independently of one another, wherein R' represents saturation and straight or branched C1-
C12Alkyl, it is optionally by least one OH, C1-C4Alkoxy, C1-C4Acyloxy,（C1-C4）Alkoxy carbonyl or（C1-C4）Alkane
Base amino substitutes, or phenyl.
In particularly preferred mode, R1 and R2 represent OH or OR' independently of one another, and R' represent saturation and straight chain
Or side chain C1-C6Alkyl, it is optionally by least one OH, C1-C4Alkoxy, C1-C4Acyloxy,（C1-C4）Alkoxy carbonyl or
（C1-C4）Alkyl amino substitutes, or phenyl, or the salt of one of these compounds.
Following 2,4 pyridine dicarboxylic acid derivatives are preferable in the full text of the present invention：
- 2,4 pyridine dicarboxylic acid（Compound 2）Or one of its salt, especially, its disodium salt（Compound 1）
The dimethyl ester of -2,4 pyridine dicarboxylic acid（Compound 3）
The diethylester of -2,4 pyridine dicarboxylic acid（Compound 4）
The 2- ethyl esters of -2,4 pyridine dicarboxylic acid（Compound 8）
The 4- ethyl esters of -2,4 pyridine dicarboxylic acid（Compound 10）
The diisopropyl ester of -2,4 pyridine dicarboxylic acid（Compound 6）
The two of -2,4 pyridine dicarboxylic acid（N-propyl）Acid amides
The 2- isopropyl esters of -2,4 pyridine dicarboxylic acid（Compound 7）
The methyl glycollate of -2,4 pyridine dicarboxylic acid
| Compound 1 | |
| Compound 2 | |
| Compound 3 | |
| Compound 4 | |
| Compound 5 | |
| Compound 6 | |
| Compound 7 | |
| Compound 8 | |
| Compound 9 | |
| Compound 10 |
It should be understood that formula（I）The salt of compound refers to the formula according to the present invention（I）The organic or inorganic salt of compound, these
Salt is acceptable in a physiologically.It can be mentioned that：Inorganic salts, sodium salt or sylvite and zinc（Zn2+）, calcium（Ca2+）, copper（Cu2 +）, iron（Fe2+）, strontium（Sr2+）, magnesium（Mg2+）Or manganese（Mn2+）Salt；Hydroxide, carbonate and halide, especially chlorination
Thing.It may be mentioned that as organic salt, triethanolamine, MEA, diethanol amine, hexadecylamine, N, N, N', N'- tetra-（2-
Hydroxypropyl）Ethylenediamine and three（Methylol）The salt of aminomethane.
Formula（I）Compound is known per se；Especially, they and its manufacture are public in patent EP 1 352 629
Open.
Preferably, one or more formulas for the present invention（I）Compound is in cosmetic composition with relative to combination
The content that thing gross weight is 0.1 to 10 weight % is present, preferably 0.5 to 8 weight %, preferably 0.5 to 6 weight %.
Especially, for the present invention cosmetic composition include the acceptable medium of cosmetics, i.e., with human keratin thing
Matter（Such as skin（Body, face, eye contour, scalp）, hair, eyelashes, eyebrow, body hair, nail or lip）Compatible
Medium.
The acceptable medium of cosmetics for the composition in the inventive method advantageously water-bearing media.It can
To be made up of following：For example, the mixture of water or water and the acceptable organic solvent of at least one cosmetics.As organic molten
Agent, it may be mentioned that for example, C2-C4Alcohol, such as ethanol and isopropanol；Polyalcohol, the polyalcohol especially with 2 to 6 carbon atoms,
Such as glycerine, propane diols, butanediol, pentanediol, hexylene glycol, DPG or diethylene glycol (DEG)；Polyol ethers, such as butoxy ethanol,
Propylene glycol monomethyl ether, diethylene glycol monomethyl ether or diethylene glycol monoethyl ether；And its mixture.
Preferably, 50-99.5 weight % water is included relative to the weight of composition, cosmetic composition.
Cosmetic composition used according to the invention can additionally comprise one or more ordinary cosmetics additives, special
Not, selected from nonionic, anion, cation and amphoteric surfactant, vitamin and provitamin（provitamins）,
Including panthenol, sun-screening agent, filler, colouring agent, pearling agent, opacifier, chelating agent（sequestering agents）, polymer
Especially film forming polymer, conditioner, plasticizer, thickener, oil, antioxidant, defoamer, NMF, emollient, infiltration
Agent, spices and preservative.
Cosmetic composition used according to the invention can be provided in the form of being generally used for all formulations of hair administration,
Especially, in aqueous solution, aqueous/alcoholic solution, oil-in-water（O / W）, Water-In-Oil（W / O）It is or multiple（It is triple：W / O /
W or O/W/O）The form of emulsion, aqueous gel or aqueous/alcogel.
Preferably, cosmetic composition is the form of aqueous or aqueous/alcoholic solution or gel.
The method according to the invention can include dense hair being heated at least 100 DEG C, preferably at 100 DEG C to 250 DEG C
Temperature stage.Preferably, the stage of keratin fiber is heated at 150 DEG C to 220 DEG C, it is excellent preferably at 160 DEG C to 220 DEG C
160 DEG C to 200 DEG C are selected in, is especially implemented within the temperature range of 170 DEG C to 190 DEG C.
The heating period, it is that will include one or more compounds when present（I）Cosmetic composition apply
Implement after the stage of keratin fiber.
The heating period, which can aid in, assigns hair good mouldability.The effect of this method can also be optimized, especially
Ground, optimize the persistence of cosmetic property after one or many hair washing operations.
The heating period advantageously uses hair clip（iron ）Implement.
Term " hair clip（iron ）" be understood in the present invention：For heating the device of keratin fiber, the fiber
And heating means touch.
The end of the hair clip contacted with keratin fiber typically exhibits out two flat surfaces.The two surfaces can be by gold
Category or ceramics are made.Especially, the two surfaces can be smooth or ripply or bend.
Heating period can use straight hair hair clip（straightening iron）, curling-tong（curling iron）, ripple
Unrestrained hair clip（crimping iron）Or steam hair clip（steam iron）Implement.Preferably, heating rank is carried out using straight hair hair clip
Section.
As the example of the hair clip available for the straight hair method according to the present invention, it can be mentioned that any kind of flattened
Folder, those described in particularly patent US 5 957 140 and US 5 046 516.
Hair clip can be touched to apply by separated comfort of successive lasting several seconds, or by along keratin fiber
（Especially hair）Hair strand it is gradually mobile or slide and apply.
Preferably, hair clip, especially straight hair hair clip, is passed through with one or many in the method according to the invention（Especially
Ground passes through for two to 20 times）Applied from the root of hair of individual hair to the continuous motion of the hair tip.Hair clip it is each pass through continue
Time can be 2 seconds to 1 minute.
Preferably, the heating period can implement 2 seconds to 30 minutes, preferably 2 seconds to 20 minutes, more preferably 2 seconds to 10 minutes, very
To 3 seconds to 5 minutes, even better was the period of 5 seconds to 2 minutes.
The method according to the invention is additionally may included in using the combination for including one or more pyridinedicarboxylic acid compounds
The additional phase of keratin fiber is dried after thing；It is included at least 100 DEG C of temperature when this method and implements keratin fiber
During the heating period, drying stage is preferably carried out before the heating period.Drying stage can use hand blower or cover
Formula drier（hood dryer）Or carried out by being dried in free air.Drying stage is advantageously in 20 DEG C to 70 DEG C of temperature
Degree is carried out.
After the heating period, keratin fiber optionally can be rinsed with water or shampoo is washed.Keratin fiber
Subsequently optionally dried using hand blower or apron drier, or by being dried in free air.
Treatment in accordance with the present invention method can be implemented on the dense hair of sensitivity, such as bleaching, it is artificially colored,
Softening（relaxed ）Or permanent curly hair dense hair.
The method according to the invention can be implemented on dry hair or wet hair.
Cosmetic composition used according to the invention is advantageously with 0.1 to 10 gram, preferably 0.2 to 5 gram of composition/gram dense
The amount of close hair is applied to dense hair.
After cosmetic composition is applied into dense hair, dense hair can be removed unnecessary combination by dry tack free
Thing, or washed with water or shampoo.
By the cosmetic composition comprising one or more pyridinedicarboxylic acid compounds be applied to after dense hair and
Before carrying out the hair heating period, the composition of administration can keep 1 to 60 minute, preferably 2 to 50 minutes, preferably 5 to 45 points
The period of clock.Indwelling time can be carried out in 15 DEG C to 45 DEG C of temperature, be preferable over environment temperature（25℃）Carry out.
Treatment in accordance with the present invention method can be in the other hairdressing processing method of dense hair（Especially, persistently shaping
（Permanent curly hair or softening）Or dyeing）During and/or after carry out.
Especially, in order to repair hair, after bleaching, artificially colored or softening method and/or permanent curling method
The processing method is used in processing.
In order to repair hair, the method according to the invention can use during cosmetic treatment method.
Treatment in accordance with the present invention method is used for dense hair, especially sensitive dense hair, such as bleaching, dyeing
, the hair of softening or permanent curly hair.
Treatment in accordance with the present invention method can also be used for Asian's hair, especially sensitive Asian's hair, such as float
White, dyeing, the hair of softening or permanent curly hair.
In alternative form, the processing method can by during for the method for the dense hair of cosmetic treatments and/or
Use afterwards, especially：
During-the method in colouring method or forever permed or the method for softening hair and/or afterwards, and
After the method for-bleaching hair.
Claims (14)
1. for the method for the dense hair of cosmetic treatments, including one or more following formulas will be included（I）Pyridinedicarboxylic acid compound
Cosmetic composition be applied to stage of the hair：
Wherein R1 and R2 represents OH, OR' ,-NH independently of one another2,-NHR ' or-NR'R'', wherein R' and R'' are only each other
On the spot represent saturated or unsaturated and straight or branched C1-C18Alkyl, it is optionally selected from OH, C by least one1-C6Alkane
Epoxide, C1-C6Acyloxy, amino,（C1-C6）Alkoxy carbonyl or（C1-C6）The group substitution of alkyl amino, or C6-C10Aryl,
And their salt.
2. method according to claim 1, wherein R1 and R2 represent that OH or OR', wherein R' represent the sum of saturation independently of one another
Straight or branched C1-C12Alkyl, it is optionally by least one OH, C1-C4Alkoxy, C1-C4Acyloxy,（C1-C4）Alkoxy carbonyl
Base or（C1-C4）Alkyl amino substitutes, or phenyl.
3. according to any method of the preceding claims, wherein R1 and R2 represents OH or OR', and R' independently of one another
Represent saturation and straight or branched C1-C6Alkyl, it is optionally by least one OH, C1-C4Alkoxy, C1-C4Acyloxy,
（C1-C4）Alkoxy carbonyl or（C1-C4）Alkyl amino substitutes, or phenyl, or the salt of one of these compounds.
4. according to the method for one of preceding claims, one or more of which formula（I）Compound be selected from：
。
5. according to any method of the preceding claims, wherein one or more formulas（I）Compound is combining
Content in thing using the gross weight relative to composition as 0.1 to 10 weight % is present, and preferably 0.5 to 8 weight %, is preferably
0.5 to 6 weight %.
Dense hair is heated at least 100 DEG C 6. according to any method of the preceding claims, comprising additionally in
The stage of temperature, preferably 100 DEG C to 250 DEG C, preferably 150 DEG C to 220 DEG C, preferably 160 DEG C to 220 DEG C, preferably 160 DEG C extremely
200 DEG C, especially 170 DEG C to 190 DEG C of temperature.
7. method according to claim 6, wherein heating period are comprising one or more formulas（I）The cosmetics group of compound
Implement after the application stages of compound.
8. the method according to claim 6 or 7, wherein using hair clip, especially straight hair hair clip, curling-tong, wave hair clip
Or steam hair clip carries out the heating period.
9. the method according to any one of claim 6 to 8, wherein heating period are by using hair clip, especially directly
Hair clip is sent out, is implemented with one or many root of hairs by from hair to the continuous motion of the hair tip.
10. according to any method of the preceding claims, it is additionally included in using comprising one or more formulas（I）Chemical combination
The additional phase of dense hair is dried after the cosmetic composition of thing.
11. according to any method of the preceding claims, wherein the dense hair has at least 90 microns, preferably
At least 100 microns, especially 90 to 120 microns, or even 100 to 120 microns of individual diameter.
12. according to any method of the preceding claims, its be used to improving the quality of hair, for protect hair,
For strengthening hair, it is set to become more flexible and less fragility, and/or for repairing hair, especially when damaged hair.
13. according to any method of the preceding claims, wherein the dense hair is Asian's hair.
14. according to any method of the preceding claims, wherein the dense hair is sensitive hair.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1552039 | 2015-03-12 | ||
| FR1552039A FR3033497B1 (en) | 2015-03-12 | 2015-03-12 | PROCESS FOR THE COSMETIC TREATMENT OF THICK HAIR WITH A DICARBOXYLIC PYRIDINE ACID COMPOUND |
| PCT/FR2016/050557 WO2016142635A1 (en) | 2015-03-12 | 2016-03-14 | Method for the cosmetic treatment of thick hair with a pyridine dicarboxylic acid compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107427435A true CN107427435A (en) | 2017-12-01 |
Family
ID=53040621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680015294.2A Pending CN107427435A (en) | 2015-03-12 | 2016-03-14 | Use the method for the dense hair of pyridinedicarboxylic acid compound cosmetic treatments |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN107427435A (en) |
| FR (1) | FR3033497B1 (en) |
| WO (1) | WO2016142635A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030223945A1 (en) * | 2002-04-11 | 2003-12-04 | Societe L'oreal S.A. | Administration of pyridinedicarboxylic acid compounds for stimulating or inducing the growth of human keratinous fibers and/or arresting their loss |
| CN102405039A (en) * | 2007-10-05 | 2012-04-04 | 莱雅公司 | Cosmetic or dermatological composition comprising a polymer bearing junction groups, and cosmetic treatment method |
| CN105530914A (en) * | 2013-09-12 | 2016-04-27 | 莱雅公司 | Process for treating keratin fibres with a pyridinedicarboxylic acid compound |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5046516A (en) | 1988-10-31 | 1991-09-10 | George Barradas | Hair curling iron |
| US5957140A (en) | 1998-11-19 | 1999-09-28 | Mcgee; Robert J. | Hair styling iron for straightening and curling |
| FR2838336B1 (en) | 2002-04-11 | 2005-06-03 | USE OF A PYRIDINE-DICARBOXYLATE DERIVATIVE OR ONE OF ITS SALTS TO STIMULATE OR INDUCE HAIR GROWTH AND / OR STOP THEIR FALL |
-
2015
- 2015-03-12 FR FR1552039A patent/FR3033497B1/en active Active
-
2016
- 2016-03-14 CN CN201680015294.2A patent/CN107427435A/en active Pending
- 2016-03-14 WO PCT/FR2016/050557 patent/WO2016142635A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030223945A1 (en) * | 2002-04-11 | 2003-12-04 | Societe L'oreal S.A. | Administration of pyridinedicarboxylic acid compounds for stimulating or inducing the growth of human keratinous fibers and/or arresting their loss |
| CN102405039A (en) * | 2007-10-05 | 2012-04-04 | 莱雅公司 | Cosmetic or dermatological composition comprising a polymer bearing junction groups, and cosmetic treatment method |
| CN105530914A (en) * | 2013-09-12 | 2016-04-27 | 莱雅公司 | Process for treating keratin fibres with a pyridinedicarboxylic acid compound |
Also Published As
| Publication number | Publication date |
|---|---|
| FR3033497B1 (en) | 2018-05-18 |
| WO2016142635A1 (en) | 2016-09-15 |
| FR3033497A1 (en) | 2016-09-16 |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171201 |
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| RJ01 | Rejection of invention patent application after publication |