CN107419511A - The method for bleaching and textile product of textile material - Google Patents

The method for bleaching and textile product of textile material Download PDF

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Publication number
CN107419511A
CN107419511A CN201710813566.XA CN201710813566A CN107419511A CN 107419511 A CN107419511 A CN 107419511A CN 201710813566 A CN201710813566 A CN 201710813566A CN 107419511 A CN107419511 A CN 107419511A
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Prior art keywords
bleaching
textile material
agent
liquid
refining
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CN201710813566.XA
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CN107419511B (en
Inventor
何韵湘
陶亚茹
安志轩
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Guangdong Esquel Textiles Co Ltd
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Guangdong Esquel Textiles Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Detergent Compositions (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to a kind of method for bleaching of textile material and textile product, the method for bleaching comprises the following steps:Refining agent, brightening agent and water are mixed to get refining liquid, textile material is immersed in the refining liquid, and in 80~110 DEG C of 10~60min of isothermal holding;The textile material handled through the refining liquid is immersed in bleaching liquid, and in 90~110 DEG C of 60~120min of isothermal holding.The method for bleaching of the present invention can effectively avoid the generation of the irregular phenomenon of fluorescence, in the case of the 0.0001%~0.3% of the quality of the dosage as little as textile material of brightening agent, the process remains able to ensure that brightening agent is uniform in the absorption of textile material surface, so as to reduce the usage amount of brightening agent, the quality of textile product is improved simultaneously, significantly reduces production cost.

Description

The method for bleaching and textile product of textile material
Technical field
The present invention relates to textile technology field, more particularly to the method for bleaching and textile product of a kind of textile material.
Background technology
Textile industry is the important economic support industry in China, and bleach be yarn fabric dyeing and finishing processing in one it is highly important Link, it can improve the presentation quality of yarn fabric, improve wetability, permeability etc., the quality of Bleaching Quality will directly affect The quality of colour of final products.
At present, with the development of the social economy, people are multifarious to color to require more and more higher, therefore textile industry pair The requirement of textile product whiteness scope also more and more higher.But it is irregular easily to produce fluorescence in traditional bleaching plus white technique Phenomenon, so that the textile product whiteness after bleaching is irregular, the quality of colour for ultimately resulting in product is bad.
The content of the invention
Based on this, it is necessary to provide a kind of method for bleaching for avoiding producing the textile material of the irregular phenomenon of fluorescence.
Specific technical scheme is as follows:
A kind of method for bleaching of textile material, comprises the following steps:
Refining agent, brightening agent and water are mixed to get refining liquid, textile material is immersed in the refining liquid, and in 80~ 110 DEG C of 10~60min of isothermal holding;
By the textile material handled through the refining liquid immerse bleaching liquid in, and in 90~110 DEG C of isothermal holdings 60~ 120min。
In one of the embodiments, in the refining liquid, the concentration of the refining agent is 0.3~1g/L;The increasing The quality of white agent is the 0.0001%~0.3% of the quality of the textile material.
In one of the embodiments, the bath raio of the textile material and the refining liquid is 1:3~1:30.
In one of the embodiments, refining agent, chelating agent, bleaching agent and sodium hydroxide are included in the bleaching liquid.
In one of the embodiments, the bleaching agent is hydrogen peroxide, and hydrogen peroxide stabilizer is also included in the bleaching liquid.
In one of the embodiments, in the bleaching liquid, the concentration of the refining agent is 0.3~1g/L, the chela The concentration of mixture is 0.3~1g/L, and the concentration of the hydrogen peroxide is 10~14g/L, and the concentration of the hydrogen peroxide stabilizer is 0.5 ~1g/L, the concentration of the sodium hydroxide is 1~4g/L.
In one of the embodiments, the bath raio of the textile material and the bleaching liquid handled through the refining liquid is 1:3~1:30.
In one of the embodiments, it is further comprising the steps of:The textile material handled through the bleaching liquid is immersed into water In, and in 90~110 DEG C of 2~10min of isothermal holding, it is then immersed in 5~20min of immersion in acid solution.
In one of the embodiments, the acid solution is aqueous acetic acid, and concentration is 0.2~0.5g/L.
Present invention also offers a kind of textile product being prepared according to above-mentioned method for bleaching.
The present invention principle and have the beneficial effect that:
Brightening agent is a kind of organic compound that can improve the whiteness such as fabric and paper, also known as Optical Bleaching Agent, glimmering Optical brightener, white dye etc., effect are that the sightless ultraviolet radiation that product absorbs is transformed into indigo fluorescence spoke Penetrate, complementary color turns into white light each other with the radiation of original gold-tinted, improves the whiteness of product in the sunlight.
The present invention is by researching and analysing discovery, and traditional bleaching adds in white technique, due to being directly added into bleaching liquid Brightening agent, and brightening agent has stronger affinity in the presence of bleaching liquid to textile material, thus will promptly adsorb In textile material, the brightening agent for easily causing subregion to be adsorbed is more, and the brightening agent of other regions absorption is less so that pole It is also easy to produce that textile product whiteness is irregular, the bad situation of quality of colour, can only so improves and increase by increasing the dosage of brightening agent The saturation degree of white agent, to reduce the problem of textile product whiteness is irregular.
The method for bleaching of the present invention is innovative on the basis of rationally control refining stage and bleaching stage technological parameter Brightening agent is added in the refining stage of textile material first, now because absorption of the textile material to brightening agent is also weaker, because This brightening agent can progressively reach uniform adsorption in the dynamic process of continuation adsorption-desorption, avoid producing that fluorescence is irregular shows As, in ensuing bleaching process, adsorb uniform brightening agent and then combined closely with textile material, it is equal so as to obtain whiteness Even product.In the case of the 0.0001%~0.3% of the quality of the dosage as little as textile material of brightening agent, the process Remain able to ensure that brightening agent is uniform in the absorption of textile material surface, so as to reduce the usage amount of brightening agent, improve simultaneously The quality of textile product, significantly reduces production cost.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases The arbitrary and all combination of the Listed Items of pass.
The method for bleaching of the textile material of an embodiment of the present invention, comprises the following steps S1~S2:
S1, refining agent, brightening agent and water is mixed to get refining liquid, textile material is immersed in refining liquid, and in 80~ 110 DEG C of 10~60min of isothermal holding.
Alternatively, in refining liquid, the concentration of refining agent is 0.3~1g/L, and the quality of brightening agent is the matter of textile material The 0.0001%~0.3% of amount.
Alternatively, the bath raio of textile material and refining liquid is 1:3~1:30.
Specifically, textile material refers to fiber, yarn, fabric and its compound etc..
S2, the textile material for handling refined liquid are immersed in bleaching liquid, and in 90~110 DEG C of isothermal holdings 60~ 120min。
Specifically, refining agent, chelating agent, bleaching agent and sodium hydroxide are included in bleaching liquid.
In one embodiment, bleaching agent is hydrogen peroxide, and hydrogen peroxide stabilizer is also included in bleaching liquid.
Specifically, in bleaching liquid, the concentration of refining agent is 0.3~1g/L, and the concentration of chelating agent is 0.3~1g/L, double The concentration of oxygen water is 10~14g/L, and the concentration of hydrogen peroxide stabilizer is 0.5~1g/L, and the concentration of sodium hydroxide is 1~4g/L.
Alternatively, the textile material of refined liquid processing and the bath raio of bleaching liquid are 1:3~1:30.
In one embodiment, it is further comprising the steps of:The textile material handled through bleaching liquid is immersed in the water, and in 90 ~110 DEG C of 2~10min of isothermal holding, it is then immersed in 5~20min of immersion in acid solution.
Alternatively, acid solution is aqueous acetic acid, and concentration is 0.2~0.5g/L.
It is appreciated that brightening agent in the present invention, refining agent, the specific species of chelating agent and bleaching agent can be entered as needed Row selection, such as diphenyl ethylene derivatives, Phenylpyrazole quinoline derivant, benzimidizole derivatives, benzene pyrazole derivatives, cumarin The brightening agent such as derivative and Naphthalamide derivatives, neopelex, SAS and fatty alcohol ether sulphur The refining agents such as hydrochlorate, inorganic polyphosphate, aminocarboxylic acid type chelating agent, hydroxycarboxylic acid type chelating agent and organic phosphate etc. chelate The bleaching agent such as agent, hydrogen peroxide, sodium hypochlorite, sodium peroxide and calcium hypochlorite, is not limited herein.
Brightening agent is a kind of organic compound that can improve the whiteness such as fabric and paper, also known as Optical Bleaching Agent, glimmering Optical brightener, white dye etc., effect are that the sightless ultraviolet radiation that product absorbs is transformed into indigo fluorescence spoke Penetrate, complementary color turns into white light each other with the radiation of original gold-tinted, improves the whiteness of product in the sunlight.
The present invention is by researching and analysing discovery, and traditional bleaching adds in white technique, due to being directly added into bleaching liquid Brightening agent, and brightening agent has stronger affinity in the presence of bleaching liquid to textile material, thus will promptly adsorb In textile material, the brightening agent for easily causing subregion to be adsorbed is more, and the brightening agent of other regions absorption is less so that pole It is also easy to produce that textile product whiteness is irregular, the bad situation of quality of colour, can only so improves and increase by increasing the dosage of brightening agent The saturation degree of white agent, to reduce the problem of textile product whiteness is irregular.
The method for bleaching of the present invention is innovative on the basis of rationally control refining stage and bleaching stage technological parameter Brightening agent is added in the refining stage of textile material first, now because absorption of the textile material to brightening agent is also weaker, because This brightening agent can progressively reach uniform adsorption in the dynamic process of continuation adsorption-desorption, avoid producing that fluorescence is irregular shows As, in ensuing bleaching process, adsorb uniform brightening agent and then combined closely with textile material, it is equal so as to obtain whiteness Even product.In the case of the 0.0001%~0.3% of the quality of the dosage as little as textile material of brightening agent, the process Remain able to ensure that brightening agent is uniform in the absorption of textile material surface, so as to reduce the usage amount of brightening agent, improve simultaneously The quality of textile product, significantly reduces production cost.
Present invention also offers a kind of textile product being prepared according to above-mentioned method for bleaching.
It is specific embodiment below.
Embodiment 1
One cylinder 40S pure cotton warp beams of dye, yarn weight 522kg, density 0.47g/ are thrown in a diameter of 1800mm dye vat Cm3, bath raio 1:7.72, whiteness requirement is 125~130 degree.
After textile material enters cylinder, a certain amount of water is added in master cylinder, then adds refining agent EPD-C and brightening agent BHT LIQ 115% obtain refining liquid, wherein, refining agent EPD-C concentration is 0.3g/L, brightening agent BHT LIQ's 115% Quality is the 0.12% of the quality of textile material, and the bath raio of textile material and refining liquid is 1:7.72, it is warming up to 100 DEG C of insulation fortune Discharged after row 20min.
Add bleaching liquid in master cylinder, refining agent EPD-C concentration is 0.3g/L, chelating agent LEOUEST in bleaching liquid 98-3 concentration is 0.5g/L, and hydrogen peroxide stabilizer PL concentration is 0.8g/L, and the concentration of 50% liquid caustic soda is 3.8g/L, hydrogen peroxide Concentration be 10g/L, the bath raio of textile material and bleaching liquid is 1:7.72, discharged after being warming up to 100 DEG C of insulation operation 90min.
Hot water is added in master cylinder, be warming up to 100 DEG C insulation operation 5min after discharge, then in master cylinder add hot water and HAc obtains acetum, and wherein HAc concentration is 0.3g/L, is discharged after running 10min.
It is 128.91 to take 40S purified cotton yarns test whiteness value, and yarn whiteness is uniform, and unstressed configuration is not in follow-up weaving process Even feedback.
Embodiment 2
One cylinder 40S pure cotton cylinder yarns of dye, yarn weight 213.15kg, bath raio 1 are thrown in a diameter of 1400MM dye vat: 11.59, whiteness requirement is 110~120 degree.
After textile material enters cylinder, a certain amount of water is added in master cylinder, then adds refining agent EPD-C and brightening agent BHT LIQ 115% obtain refining liquid, wherein, refining agent EPD-C concentration is 0.3g/L, brightening agent BHT LIQ's 115% Quality is the 0.05% of the quality of textile material, and the bath raio of textile material and refining liquid is 1:11.59, it is warming up to 100 DEG C of insulations Discharged after operation 20min.
Add bleaching liquid in master cylinder, refining agent EPD-C concentration is 0.3g/L, chelating agent LEOUEST in bleaching liquid 98-3 concentration is 0.5g/L, and hydrogen peroxide stabilizer PL concentration is 0.8g/L, and the concentration of 50% liquid caustic soda is 3.8g/L, hydrogen peroxide Concentration be 10g/L, the bath raio of textile material and bleaching liquid is 1:11.59, discharged after being warming up to 100 DEG C of insulation operation 90min.
Hot water is added in master cylinder, be warming up to 100 DEG C insulation operation 5min after discharge, then in master cylinder add hot water and HAc obtains acetum, and wherein HAc concentration is 0.2g/L, is discharged after running 10min.
Take the 40S purified cotton yarns test ectonexine whiteness value, respectively 114.1 and 119.9, yarn ectonexine whiteness is equal It is even, and the irregular feedback of unstressed configuration in follow-up weaving process.
Embodiment 3
One cylinder 40S pure cotton cylinder yarns of dye, yarn weight 200kg, bath raio 1 are thrown in a diameter of 1400MM dye vat:30, in vain Degree requires to be 130~140 degree.
After textile material enters cylinder, a certain amount of water is added in master cylinder, then add refining agent SAS and Brightening agent Phenylpyrazole quinoline derivant obtains refining liquid, wherein, the concentration of refining agent SAS is 0.5g/L, brightening agent The quality of Phenylpyrazole quinoline derivant is the 0.3% of the quality of textile material, and the bath raio of textile material and refining liquid is 1:30, rise Temperature is discharged after running 30min to 110 DEG C of insulations.
Add bleaching liquid in master cylinder, the concentration of refining agent SAS is 0.5g/L in bleaching liquid, amino carboxylic acid The concentration of type chelating agent is 0.3g/L, and hydrogen peroxide stabilizer PL concentration is 0.5g/L, and the concentration of 50% liquid caustic soda is 4g/L, dioxygen The concentration of water is 12g/L, and the bath raio of textile material and bleaching liquid is 1:30, discharged after being warming up to 110 DEG C of insulation operation 60min.
Hot water is added in master cylinder, be warming up to 110 DEG C insulation operation 2min after discharge, then in master cylinder add hot water and HAc obtains acetum, and wherein HAc concentration is 0.2g/L, is discharged after running 10min.
Take the 40S purified cotton yarns test ectonexine whiteness value, respectively 140 and 135, yarn ectonexine whiteness is uniform, and The irregular feedback of unstressed configuration in follow-up weaving process.
Comparative example 1
One cylinder 40S pure cotton warp beams of dye, yarn weight 200kg, bath raio 1 are thrown in a diameter of 1400MM dye vat:12, in vain Degree requires to be 120~130 degree.
After textile material enters cylinder, a certain amount of water is added in master cylinder, refining agent EPD-C is then added and obtains refining liquid, Wherein, refining agent EPD-C concentration is 0.3g/L, and the bath raio of textile material and refining liquid is 1:12, it is warming up to 100 DEG C of insulation fortune Discharged after row 20min.
A certain amount of water is added in master cylinder, then adds refining agent EPD-C, brightening agent BHT LIQ 115%, chelating agent LEOUEST 98-3, hydrogen peroxide stabilizer PL, 50% liquid caustic soda and hydrogen peroxide, refining agent EPD-C concentration is 0.3g/L in solution, Brightening agent BHT LIQ 115% quality is the 0.3% of the quality of textile material, and chelating agent LEOUEST 98-3 concentration is 0.5g/L, hydrogen peroxide stabilizer PL concentration are 0.8g/L, and the concentration of 50% liquid caustic soda is 3.8g/L, and the concentration of hydrogen peroxide is 10g/ L, bath raio 1:12, discharged after being warming up to 100 DEG C of insulation operation 100min.
Hot water is added in master cylinder, be warming up to 100 DEG C insulation operation 5min after discharge, then in master cylinder add hot water and HAc obtains acetum, and wherein HAc concentration is 0.2g/L, is discharged after running 10min.
It is 139.1 to take 40S purified cotton yarns test outer layer whiteness value, the irregular feedback of fluorescence occurs in follow-up weaving process, Have a strong impact on cloth cover quality of colour.
Comparative example 2
One cylinder 40S pure cotton cylinder yarns of dye, yarn weight 200kg, bath raio 1 are thrown in a diameter of 1400MM dye vat:12, in vain Degree requires to be 120~130 degree.
After textile material enters cylinder, a certain amount of water is added in master cylinder, then adds refining agent EPD-C and brightening agent BHT LIQ 115% obtain refining liquid, wherein, refining agent EPD-C concentration is 0.3g/L, brightening agent BHT LIQ's 115% Quality is the 0.3% of the quality of textile material, and the bath raio of textile material and refining liquid is 1:12, it is warming up to 70 DEG C of insulation operations Discharged after 5min.
Add bleaching liquid in master cylinder, refining agent EPD-C concentration is 0.3g/L, chelating agent LEOUEST in bleaching liquid 98-3 concentration is 0.5g/L, and hydrogen peroxide stabilizer PL concentration is 0.8g/L, and the concentration of 50% liquid caustic soda is 3.8g/L, hydrogen peroxide Concentration be 10g/L, the bath raio of textile material and bleaching liquid is 1:12, discharged after being warming up to 80 DEG C of insulation operation 50min.
Hot water is added in master cylinder, be warming up to 100 DEG C insulation operation 5min after discharge, then in master cylinder add hot water and HAc obtains acetum, and wherein HAc concentration is 0.2g/L, is discharged after running 10min.
The 40S purified cotton yarns are taken to test ectonexine whiteness value, respectively 142 and 128, yarn ectonexine whiteness is uneven, after Cloth cover quality of colour is had a strong impact on because fluorescence is irregular in continuous weaving process.
By above-described embodiment 1~3 and comparative example 1~2, method for bleaching of the invention passes through the essence in textile material The refining stage adds brightening agent, and concise and bleaching is carried out under the conditions of certain temperature and time, uniform so as to obtain whiteness Product, it is possible to prevente effectively from the generation of the irregular phenomenon of fluorescence, in the quality of the dosage as little as textile material of brightening agent In the case of 0.0001%~0.3%, the process remains able to ensure that brightening agent is uniform in the absorption of textile material surface, from And the usage amount of brightening agent can be reduced, while the quality of textile product is improved, significantly reduce production cost.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that come for one of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. a kind of method for bleaching of textile material, it is characterised in that comprise the following steps:
Refining agent, brightening agent and water are mixed to get refining liquid, textile material is immersed in the refining liquid, and in 80~110 DEG C 10~60min of isothermal holding;
The textile material handled through the refining liquid is immersed in bleaching liquid, and in 90~110 DEG C of 60~120min of isothermal holding.
2. method for bleaching according to claim 1, it is characterised in that in the refining liquid, the concentration of the refining agent For 0.3~1g/L;The quality of the brightening agent is the 0.0001%~0.3% of the quality of the textile material.
3. method for bleaching according to claim 1, it is characterised in that the bath raio of the textile material and the refining liquid is 1:3~1:30.
4. method for bleaching according to claim 1, it is characterised in that refining agent, chelating agent, drift are included in the bleaching liquid White agent and sodium hydroxide.
5. method for bleaching according to claim 4, it is characterised in that the bleaching agent is hydrogen peroxide, in the bleaching liquid Also include hydrogen peroxide stabilizer.
6. method for bleaching according to claim 5, it is characterised in that in the bleaching liquid, the concentration of the refining agent For 0.3~1g/L, the concentration of the chelating agent is 0.3~1g/L, and the concentration of the hydrogen peroxide is 10~14g/L, the dioxygen The concentration of water stabilizer is 0.5~1g/L, and the concentration of the sodium hydroxide is 1~4g/L.
7. according to the method for bleaching described in any one of claim 1~6, it is characterised in that through described in refining liquid processing The bath raio of textile material and the bleaching liquid is 1:3~1:30.
8. according to the method for bleaching described in any one of claim 1~6, it is characterised in that further comprising the steps of:Will be through described The textile material of bleaching liquid processing is immersed in the water, and in 90~110 DEG C of 2~10min of isothermal holding, is then immersed in acid solution and is soaked Steep 5~20min.
9. method for bleaching according to claim 8, it is characterised in that the acid solution is aqueous acetic acid, concentration 0.2 ~0.5g/L.
10. a kind of textile product, it is characterised in that the method for bleaching according to any one of claim 1~9 is prepared.
CN201710813566.XA 2017-09-11 2017-09-11 Textile material bleaching process and textile products Active CN107419511B (en)

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CN105088741A (en) * 2015-08-13 2015-11-25 上海嘉麟杰纺织品股份有限公司 Method for processing white cotton and wool blended fabric
CN105113283A (en) * 2015-09-14 2015-12-02 广东溢达纺织有限公司 Dyeing method for polyester and cotton blended fabric
CN107119444A (en) * 2017-05-16 2017-09-01 繁昌县清新水洗有限责任公司 A kind of ultrasonic low temperature method for bleaching of cotton-containing fabrics

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