CN107418135A - A kind of flame-retardant resin tile - Google Patents
A kind of flame-retardant resin tile Download PDFInfo
- Publication number
- CN107418135A CN107418135A CN201710471309.2A CN201710471309A CN107418135A CN 107418135 A CN107418135 A CN 107418135A CN 201710471309 A CN201710471309 A CN 201710471309A CN 107418135 A CN107418135 A CN 107418135A
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- China
- Prior art keywords
- parts
- flame
- unsaturated polyester
- retardant resin
- resin tile
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/324—Alkali metal phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of flame-retardant resin tile, the resin tile includes the raw material of following parts by weight：20 30 parts of unsaturated polyester resin of the unsaturated polyester resin 30 50 parts, No. 3301 of phenolic resin 80 100 parts, No. 196,0.5 2 parts of antioxidant BHT, 25 parts of chlorinated paraffin, 0.5 2 parts of antimony oxide, 0.8 1.5 parts of silica, 38 parts of sodium pyrophosphate, 15 parts of PIC, 10 30 parts of alumina fibre, 0.2 1 parts of γ methacryloxypropyl trimethoxy silanes, 234 0.5 2 parts of ultra-violet absorber UV.The resin tile of the present invention select materials safety is nontoxic, reasonable mixture ratio, and stability and corrosion resistance are strong, excellent flame retardancy, are adapted to large-scale production.
Description
Technical field
The present invention relates to building material field, and in particular to a kind of flame-retardant resin tile.
Background technology
Resin tile is generally divided into natural resin watt and synthetic resin watt, at present using it is relatively broad be synthetic resin watt.
Synthetic resin watt is the New Building Materials developed using high-new chemical Chemical Engineering Technology, is that China is vigorously advocated with promoting
Lightweight material of new generation, there are a variety of good characteristics such as in light weight, intensity is big, waterproof and dampproof, antiseptic fire-retardation, sound-insulating and heat-insulating, it is general
All over suitable for development zone flat-changed-into-sloping, the market of farm produce, market, residential quarters, new countryside construction resident Deluxe villa, canopy, sunshade
Paulin, building in the style of the ancients etc..
The applicable environment construction of the synthetic resin watt that uses at present is very extensive, and the report of preparation method is also a lot, authorizes
Notification number CN103965567B reports a kind of PVC synthetic resin watt, and light quality, anti-load-carrying ability are strong, but in stabilizer
It is middle used toxicity it is larger contain Pb stabilizer, be not suitable for large-scale production.Therefore, it is necessary to choose comparatively safe nontoxic conjunction
The resin tile of multifunctionality is synthesized to meet the needs of building material industry into material.
The content of the invention
The defects of for prior art, it is an object of the invention to provide the original that a kind of flame-retardant resin tile, the resin tile are selected
Expect safe and non-toxic, reasonable mixture ratio, and stability and corrosion resistance are strong, excellent flame retardancy, are adapted to large-scale production.
The present invention solves technical problem and adopted the following technical scheme that：
The invention provides a kind of flame-retardant resin tile, include the raw material of following parts by weight：Phenolic resin 80-100 parts, No. 196 not
Saturated polyester resin 30-50 parts, No. 3301 unsaturated polyester resin 20-30 parts, antioxidant BHT 0.5-2 parts, chlorinated paraffin 2-5
Part, antimony oxide 0.5-2 parts, silica 0.8-1.5 parts, sodium pyrophosphate 3-8 parts, PIC 1-5 parts, aluminum oxide are fine
Tie up 10-30 parts, γ-methacryloxypropyl trimethoxy silane 0.2-1 parts, ultra-violet absorber UV-234 0.5-2
Part.
Preferably, the raw material of following parts by weight is included：Phenolic resin 85 parts, No. 196 36 parts of unsaturated polyester resins, 3301
Number 22 parts of unsaturated polyester resin, 1 part of antioxidant BHT, 3.5 parts of chlorinated paraffin, 1.2 parts of antimony oxide, silica 1 part,
5 parts of sodium pyrophosphate, 2 parts of PIC, 18 parts of alumina fibre, γ-methacryloxypropyl trimethoxy silane 0.6
Part, 1.4 parts of ultra-violet absorber UV-234.
Present invention also offers a kind of preparation method of flame-retardant resin tile, comprise the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 60-80 DEG C of heating, 30-40 minutes are stirred with 400-600 revs/min of rotating speed,
Obtain mixture A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 80-100
Mesh sieve obtains powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating, Temperature fall after stirring reaction 4-5 hours；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies.
Preferably, the heating-up temperature of the step 1 is 75 DEG C.
Preferably, the rotating speed of the step 1 is 500 revs/min.
Preferably, the step 2 crosses 90 mesh sieves.
Preferably, the step 3 is naturally cooling to 60-80 DEG C.
Preferably, need to place at aeration-drying 1-2 days after the step 4 solidification.
Compared with prior art, the present invention has following beneficial effect：
The flame-retardant resin tile of the present invention is made using phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins
For resin component, phenolic resin has excellent heat-resisting quantity, and chemical resistance is stable, No. 196 unsaturated polyester resins, No. 3301
Unsaturated polyester resin good toughness, it is excellent in cushion effect；In auxiliary element, from antioxidant BHT, dispersant sodium pyrophosphate,
Curing agent PIC, inorfil alumina fibre, coupling agent γ-methacryloxypropyl trimethoxy silane,
Fire retardant chlorinated paraffin, antimony oxide, silica, ultra-violet absorber UV-234.
In terms of fire retardant, three kinds of flame-retardant compositions are with the addition of, chlorinated paraffin has low volatility, anti-flammability, electrical insulating property
Can be good, antimony oxide is a kind of excellent fire retardant with cooperative effect, and silica is even more to be widely used in build
Build in the fire-retardant fireproof of material.To sum up, the resin tile select materials safety is nontoxic, reasonable mixture ratio, and stability and corrosion-resistant
Property strong, excellent flame retardancy, be adapted to large-scale production.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments are merely to illustrate the present invention and not had to
In limitation the scope of the present invention.
Embodiment 1.
The flame-retardant resin tile of the present embodiment, include the raw material of following parts by weight：85 parts, No. 196 unsaturated polyester (UP) trees of phenolic resin
36 parts, No. 3,301 22 parts of unsaturated polyester resins of fat, 1 part of antioxidant BHT, 3.5 parts of chlorinated paraffin, 1.2 parts of antimony oxide,
Silica 1 part, 5 parts of sodium pyrophosphate, 2 parts of PIC, 18 parts of alumina fibre, γ-methacryloxypropyl three
0.6 part of methoxy silane, 1.4 parts of ultra-violet absorber UV-234.
Its preparation method comprises the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 75 DEG C of heating, 30-40 minutes is stirred with 500 revs/min of rotating speed, mixed
Thing A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 90 mesh sieves
Obtain powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating after stirring reaction 4-5 hours, be naturally cooling to 60 DEG C；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies, and places at aeration-drying 1-2 days.
Embodiment 2.
The flame-retardant resin tile of the present embodiment, include the raw material of following parts by weight：80 parts, No. 196 unsaturated polyester (UP) trees of phenolic resin
30 parts, No. 3,301 30 parts of unsaturated polyester resins of fat, 0.5 part of antioxidant BHT, 2 parts of chlorinated paraffin, 0.5 part of antimony oxide,
Silica 1 .5 parts, 8 parts of sodium pyrophosphate, 1 part of PIC, 30 parts of alumina fibre, γ-methacryloxypropyl
1 part of trimethoxy silane, 2 parts of ultra-violet absorber UV-234.
Its preparation method comprises the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 60 DEG C of heating, 30-40 minutes is stirred with 500 revs/min of rotating speed, mixed
Thing A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 100 mesh sieves
Obtain powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating after stirring reaction 4-5 hours, be naturally cooling to 80 DEG C；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies, and places at aeration-drying 1-2 days.
Embodiment 3.
The flame-retardant resin tile of the present embodiment, include the raw material of following parts by weight：100 parts, No. 196 unsaturated polyester (UP) trees of phenolic resin
50 parts, No. 3,301 20 parts of unsaturated polyester resins of fat, 2 parts of antioxidant BHT, 5 parts of chlorinated paraffin, 2 parts of antimony oxide, dioxy
1.5 parts of SiClx, 3 parts of sodium pyrophosphate, 5 parts of PIC, 10 parts of alumina fibre, γ-methacryloxypropyl front three
0.2 part of TMOS, 0.5 part of ultra-violet absorber UV-234.
Its preparation method comprises the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 80 DEG C of heating, 30-40 minutes is stirred with 500 revs/min of rotating speed, mixed
Thing A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 80 mesh sieves
Obtain powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating after stirring reaction 4-5 hours, be naturally cooling to 80 DEG C；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies, and places at aeration-drying 1-2 days.
Embodiment 4.
The flame-retardant resin tile of the present embodiment, include the raw material of following parts by weight：92 parts, No. 196 unsaturated polyester (UP) trees of phenolic resin
40 parts, No. 3,301 25 parts of unsaturated polyester resins of fat, 1.4 parts of antioxidant BHT, 4.2 parts of chlorinated paraffin, antimony oxide 0.5
Part, silica 1 .5 parts, 8 parts of sodium pyrophosphate, 1 part of PIC, 30 parts of alumina fibre, γ-methacryloxy third
1 part of base trimethoxy silane, 2 parts of ultra-violet absorber UV-234.
Its preparation method comprises the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 60 DEG C of heating, 30-40 minutes is stirred with 500 revs/min of rotating speed, mixed
Thing A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 100 mesh sieves
Obtain powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating after stirring reaction 4-5 hours, be naturally cooling to 80 DEG C；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies, and places at aeration-drying 1-2 days.
Embodiment 5.
The flame-retardant resin tile of the present embodiment, include the raw material of following parts by weight：95 parts, No. 196 unsaturated polyester (UP) trees of phenolic resin
45 parts, No. 3,301 30 parts of unsaturated polyester resins of fat, 0.5 part of antioxidant BHT, 2 parts of chlorinated paraffin, 0.5 part of antimony oxide,
Silica 1 .5 parts, 8 parts of sodium pyrophosphate, 1 part of PIC, 20 parts of alumina fibre, γ-methacryloxypropyl
1 part of trimethoxy silane, 2 parts of ultra-violet absorber UV-234.
Its preparation method comprises the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 60 DEG C of heating, 30-40 minutes is stirred with 500 revs/min of rotating speed, mixed
Thing A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 100 mesh sieves
Obtain powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating after stirring reaction 4-5 hours, be naturally cooling to 80 DEG C；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies, and places at aeration-drying 1-2 days.
The resin tile of the present invention select materials safety is nontoxic, reasonable mixture ratio, and stability and corrosion resistance are strong, anti-flammability
Can be excellent, it is adapted to large-scale production.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of flame-retardant resin tile, it is characterised in that include the raw material of following parts by weight：Phenolic resin 80-100 parts, No. 196 not
Saturated polyester resin 30-50 parts, No. 3301 unsaturated polyester resin 20-30 parts, antioxidant BHT 0.5-2 parts, chlorinated paraffin 2-5
Part, antimony oxide 0.5-2 parts, silica 0.8-1.5 parts, sodium pyrophosphate 3-8 parts, PIC 1-5 parts, aluminum oxide are fine
Tie up 10-30 parts, γ-methacryloxypropyl trimethoxy silane 0.2-1 parts, ultra-violet absorber UV-234 0.5-2
Part.
2. flame-retardant resin tile according to claim 1, it is characterised in that include the raw material of following parts by weight：Phenolic resin
85 parts, 36 parts, No. 3,301 22 parts of unsaturated polyester resins of No. 196 unsaturated polyester resins, 1 part of antioxidant BHT, chlorinated paraffin
3.5 parts, 1.2 parts of antimony oxide, silica 1 part, 5 parts of sodium pyrophosphate, 2 parts of PIC, 18 parts of alumina fibre,
0.6 part of γ-methacryloxypropyl trimethoxy silane, 1.4 parts of ultra-violet absorber UV-234.
3. the preparation method of flame-retardant resin tile according to claim 1 or 2, it is characterised in that comprise the following steps：
Step 1：Phenolic resin, No. 196 unsaturated polyester resins, No. 3301 unsaturated polyester resins are added in reactor,
Then PIC, sodium pyrophosphate are added, 60-80 DEG C of heating, 30-40 minutes are stirred with 400-600 revs/min of rotating speed,
Obtain mixture A；
Step 2：Chlorinated paraffin, antimony oxide, silica, alumina fibre are mixed, pulverizer crushes, and crosses 80-100
Mesh sieve obtains powder particle B；
Step 3：Mixture A, powder particle B are added in autoclave, add antioxidant BHT, γ-methacryloxypropyl
Base propyl trimethoxy silicane, ultra-violet absorber UV-234, it is 2-3MPa to be filled with nitrogen to pressure, is warming up to 120-150 DEG C,
Stop heating, Temperature fall after stirring reaction 4-5 hours；
Step 4：The reactant of step 3 is put into injection machine, is molded at 180-200 DEG C, is placed on tile-type mould
Die mould solidifies.
4. the preparation method of flame-retardant resin tile according to claim 3, it is characterised in that the heating-up temperature of the step 1
For 75 DEG C.
5. the preparation method of flame-retardant resin tile according to claim 3, it is characterised in that the rotating speed of the step 1 is
500 revs/min.
6. the preparation method of flame-retardant resin tile according to claim 3, it is characterised in that the step 2 crosses 90 mesh sieves.
7. the preparation method of flame-retardant resin tile according to claim 3, it is characterised in that the step 3 is naturally cooling to
60-80℃。
8. the preparation method of flame-retardant resin tile according to claim 3, it is characterised in that need to put after the step 4 solidification
Put at aeration-drying 1-2 days.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710471309.2A CN107418135A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-retardant resin tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710471309.2A CN107418135A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-retardant resin tile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107418135A true CN107418135A (en) | 2017-12-01 |
Family
ID=60427293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710471309.2A Withdrawn CN107418135A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-retardant resin tile |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735092A (en) * | 2018-12-27 | 2019-05-10 | 耿佃勇 | Resin tile novel resin material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101734883A (en) * | 2008-11-11 | 2010-06-16 | 马健 | Resin tile with fire-proof function |
| CN102454257A (en) * | 2010-10-22 | 2012-05-16 | 王旗 | Strong flame retardant resin tile and making method thereof |
| CN103540014A (en) * | 2012-07-17 | 2014-01-29 | 辽宁辽杰科技有限公司 | Continuous fiber enhanced resin prepreg as well as preparation method and application thereof |
| CN106284856A (en) * | 2016-09-24 | 2017-01-04 | 成都九十度工业产品设计有限公司 | A kind of corrosion-resisting resin watt |
| CN206245604U (en) * | 2016-09-24 | 2017-06-13 | 孙菲 | A kind of corrosion-resisting resin watt |
-
2017
- 2017-06-20 CN CN201710471309.2A patent/CN107418135A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101734883A (en) * | 2008-11-11 | 2010-06-16 | 马健 | Resin tile with fire-proof function |
| CN102454257A (en) * | 2010-10-22 | 2012-05-16 | 王旗 | Strong flame retardant resin tile and making method thereof |
| CN103540014A (en) * | 2012-07-17 | 2014-01-29 | 辽宁辽杰科技有限公司 | Continuous fiber enhanced resin prepreg as well as preparation method and application thereof |
| CN106284856A (en) * | 2016-09-24 | 2017-01-04 | 成都九十度工业产品设计有限公司 | A kind of corrosion-resisting resin watt |
| CN206245604U (en) * | 2016-09-24 | 2017-06-13 | 孙菲 | A kind of corrosion-resisting resin watt |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735092A (en) * | 2018-12-27 | 2019-05-10 | 耿佃勇 | Resin tile novel resin material and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171201 |
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| WW01 | Invention patent application withdrawn after publication |