CN107416947A - Graphene or CNT hotting mask saline treatment equipment and control method - Google Patents

Graphene or CNT hotting mask saline treatment equipment and control method Download PDF

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Publication number
CN107416947A
CN107416947A CN201710655203.8A CN201710655203A CN107416947A CN 107416947 A CN107416947 A CN 107416947A CN 201710655203 A CN201710655203 A CN 201710655203A CN 107416947 A CN107416947 A CN 107416947A
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cnt
graphene
hotting mask
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brine
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CN107416947B (en
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张英华
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Water Treatment By Sorption (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention discloses a kind of graphene or CNT hotting mask saline treatment equipment and control method.Clarified water pump is extracted into seawater or industrial brine in clarifier-tank by the filtering of screen pack.Seawater or industrial brine of the deodorization pump handle after except algae ungrease treatment are extracted into active carbon deodorizing pond.Pretreatment pump is extracted into the seawater after active carbon deodorizing is handled or industrial brine after microporous ceramic filter filters in quick-fried Sai heating baths.Industrial smoke or hot water heat the seawater in quick-fried Sai heating baths or industrial brine.The sulfur dioxide in flue gas is removed in the limewash in desulfurization pond.Light salt brine pump is pumped into the seawater or industrial brine being exposed to the sun in heating bath in the salt pool of graphene or CNT hotting mask saline treatment film core.Graphene or CNT hotting mask are heated after being passed through direct current or alternating current, and the hydrone in seawater or hot industrial brine reaches fresh water area through graphene or CNT hotting mask, and timing is just rinsed, graphene or CNT hotting mask are led in backwash and blowback.

Description

Graphene or CNT hotting mask saline treatment equipment and control method
Technical field:
The present invention relates to a kind of graphene or CNT hotting mask saline treatment equipment and control method.
Background technology:
At present, the device for generating power by waste heat that we develop directly can be sent out with more than more than 80 DEG C DEG C of waste gas and waste liquid Electricity.So using multi-effect flashing steam method for desalting seawater of the steam turbine engines with 200 DEG C of waste steam and utilize work Industry used heat will eliminate heating of seawater to 70 DEG C of multistage flash evaporation seawater desalting method.Extensive desalinization is only left anti- Penetration sea water desalinization method.Reverse osmosis seawater desalting needs the temperature of seawater to be higher than 20 DEG C, and the seawater in the winter Bohai Sea is minimum Temperature is 0 DEG C.0 DEG C of seawater viscosity is too big, is not suitable for carrying out desalinization with reverse osmosis.Center line project of South-to-North water diversion will Beijing is transferred to from Hubei Danjiangkou Yangtze River Water, the cost of each ton of water is 8 yuan.But Yangtze River Water does not flow to Beijing also, just by City retention on the way is with only.State plan builds the reverse osmosis seawater desalting factory of million tons of a daily output in Tianjin, with pipe Road reverse osmosis freshwater is sent to Beijing.Tianjin is unsuitable to carry out counter-infiltration in Bohai Sea Gulf side, 0 DEG C of the minimum temperature of winter seawater Desalinization.2,000,000 tons 0 DEG C of heating of seawater be to 20 DEG C with industrial waste heat every day it is extremely difficult, Tianjin it is coastal Area does not have so much industrial waste heat.On June 19th, 2017《Reference News》In have an article, American scientist is to nano-sized carbon Pipe is heated, and then allows fresh water contained by the seawater of certain power to obtain concentrating chlorination through the CNT after heating Sodium micro-crystallization concentrated seawater.Concentrated seawater caused by this desalinization, can directly produce salt or electrolytic saltwater production is burnt Alkali, chlorine and hydrogen.Annual October 15 to next year four more 15 days be North of Yangtze River Regional City heating season, Flue gas caused by coal heating boiler causes north city haze.Application for a patent for invention number:201410668643.3 patent of invention Title《The wet desulphurization device and seawater or reclaimed water desulfurizer of minute-pressure flue gas》It is middle to utilize seawater and film be to heating cooker The flue gas of stove carries out desulfurization.
The content of the invention:
Graphene or CNT hotting mask saline treatment equipment of the present invention.A floating pond of ' recessed ' font floating is at sea built, Above ' recessed ' font floating pool clarifier-tank, active carbon deodorizing are divided into covered with solar panel, ' recessed ' font floating pool Pond, sudden and violent Sai heating baths, fresh-water pool, strong brine pond and desulfurization pond, or clarifier-tank, active carbon deodorizing pond, sudden and violent Sai are built on land Heating bath, fresh-water pool, strong brine pond and desulfurization pond, clarifier-tank, active carbon deodorizing pond, sudden and violent Sai heating baths, fresh-water pool, strong brine pond With desulfurization pond 1 above covered with solar panel.Clarified water pump is taken out seawater or industrial brine by the filtering of screen pack Into clarifier-tank, toward clarifier-tank in launch remove algae degreasing agent.Seawater or work of the deodorization pump handle after except algae ungrease treatment Industry salt solution is extracted into active carbon deodorizing pond, removes the peculiar smell of seawater or industrial brine.Pretreatment pump handle passes through active carbon deodorizing Seawater or industrial brine after processing are extracted into quick-fried Sai heating baths after microporous ceramic filter filters.There is one group of section for length Square metal tube runs through quick-fried Sai heating baths, section be rectangular metal tube built with fin, section is rectangular metal Tube outer surface plates tungsten;Section is connected after being pooled together for one end of rectangular metal tube with industrial smoke heat-preserving hose, is cut Face is connected by many slat gum flexible pipes and the short metal pipe being fixed on filter cloth respectively for the other end of rectangular metal tube Connect, filtering fabric envelope is put into metal framework in desulfurization pond on metal framework.Limewash, desulfurization lime are contained with desulfurization pond Limewash in pump handle desulfurization pond beats circulation stirring.Or section for rectangular metal tube one end pool together after with Industrial hot water heat-preserving hose connects, and connects after section pools together for the other end of rectangular metal tube with industrial cycle water pipe Connect.Array graphene or CNT hotting mask saline treatment film are used in graphene or CNT hotting mask saline treatment equipment Core.The structure of graphene or CNT hotting mask saline treatment film core be successively from outside to inside shell, foamed plastics outer layer or Foamed ceramics outer layer, the graphene of outer layer or CNT hotting mask, insulation water permeable membrane, the graphene of internal layer or CNT heat Film, the foamed plastics heart or the foamed ceramics heart, the foamed plastics heart or the foamed ceramics heart are graphene or CNT hotting mask salt The salt pool of membrane for water treatment core, graphene or CNT hotting mask saline treatment film core salt pool are equipped with temperature sensor or temperature Control the probe of switch;Foamed plastics profile or foamed ceramics outer layer are graphene or CNT hotting mask saline treatment film core Fresh water area;Direct current is connected between the graphene or CNT hotting mask of outer layer and the graphene or CNT hotting mask of internal layer Electricity, the graphene or CNT hotting mask of internal layer connect positive pole, and the graphene or CNT hotting mask of outer layer connect negative pole.Or graphite The structure of alkene or CNT hotting mask saline treatment film core is shell, foamed plastics outer layer or foamed ceramics successively from outside to inside Outer layer, the graphene of outer layer or CNT hotting mask, insulation water permeable membrane, the graphene or CNT hotting mask, foam of internal layer The plastics heart or the foamed ceramics heart, the foamed plastics heart or the foamed ceramics heart are graphene or CNT hotting mask saline treatment film The salt pool of core, graphene or CNT hotting mask saline treatment film core salt pool are equipped with temperature sensor or temperature detect switch (TDS) Probe;Foamed plastics profile or foamed ceramics outer layer are the fresh water that electricity has black alkene or CNT hotting mask saline treatment film core Area;Alternating current is connected between the graphene or CNT hotting mask of outer layer and the graphene or CNT hotting mask of internal layer.Internal layer Graphene or CNT hotting mask connect alternating current zero line, the graphene or CNT hotting mask of outer layer connect alternating current fire wire.Or The structure of person's graphene or CNT hotting mask saline treatment film core is shell, foamed plastics outer layer or bubble successively from outside to inside Foam top ceramic layer, graphene or CNT hotting mask, the foamed plastics heart or the foamed ceramics heart, the foamed plastics heart or foam pottery The porcelain heart is the salt pool of graphene or CNT hotting mask saline treatment film core, graphene or CNT hotting mask saline treatment film Probe of the core salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics outer layer are electro-graphitics The fresh water area of alkene or CNT hotting mask saline treatment film core;Graphene or CNT hotting mask both ends are connecing direct current just respectively Pole and negative pole.Or the structure of graphene or CNT hotting mask saline treatment film core is shell, foam plastic successively from outside to inside Expect outer layer either foamed ceramics outer layer, graphene or CNT hotting mask, the foamed plastics heart or the foamed ceramics heart, foamed plastics The heart or the foamed ceramics heart are the salt pool of graphene or CNT hotting mask saline treatment film core, graphene or CNT heat Probe of the film saline treatment film core salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics Outer layer is the fresh water area of graphene or CNT hotting mask saline treatment film core;Graphene or CNT hotting mask both ends difference Connect the live wire and zero line of alternating current.After the seawater or industrial brine being exposed to the sun in heating bath are extracted out with light salt brine pump, pass through successively The cold passage of overrich brine regeneration heater, the cold passage of fresh water regenerative heater, the light salt brine Pneumatic butterfly valve of each group and light salt Water threeway enters graphite from the top center of the vertically-mounted graphene of each group or CNT hotting mask saline treatment film core 1 The salt pool of alkene or CNT hotting mask saline treatment film core.From each group graphene or CNT hotting mask saline treatment film core 1 Strong brine four-way, the strong brine successively Jing Guo each group of concentrated seawater or strong brine that comes out of bottom centre position salt pool it is pneumatic Pooled together after butterfly valve, be then transported to strong brine pond by the passage of heat of strong brine regenerative heater again.From Roots blower The wind that machine comes out passes through each group wind Pneumatic butterfly valve, enters from the upper end of each group graphene or CNT hotting mask saline treatment film core 1 Enter the fresh water area of each group graphene or CNT hotting mask saline treatment film core 1.From each group graphene or CNT hotting mask salt The fresh water that membrane for water treatment core lower end fresh water area comes out pools together after the threeway of each group fresh water and fresh water Pneumatic butterfly valve successively, Then flowed to by the passage of heat of fresh water regenerative heater in fresh-water pool.Backwashing pump is anti-by each group from fresh-water pool extraction fresh water Rinse the 3rd interface that Pneumatic butterfly valve is sent into each group fresh water threeway.3rd interface and energy regenerating of each group strong brine four-way Each group energy regenerating water inlet Pneumatic butterfly valve is housed, between recuperator and the 3rd interface of each group light salt brine threeway between device Equipped with each group energy regenerating water outlet Pneumatic butterfly valve.The compressed air that air compressor extrudes enters air accumulator by check valve, from The compressed air that gas storage pot bottom comes out enters the 4th interface of each group strong brine four-way by each group electromagnetic gas valve.Energy returns Receive device to be made up of big pipe, big piston, connecting rod, small pipe, valve piston, the arrival end of big pipe passes through energy regenerating described in each group Water inlet Pneumatic butterfly valve is connected connection with the 3rd interface of strong brine four-way described in each group, and the arrival end and strong brine of big pipe are again Drainpipe is housed between the passage of heat of raw heater, the pneumatic butterfly of draining is housed on drainpipe, the port of export of small pipe passes through each group The energy regenerating water outlet Pneumatic butterfly valve is connected connection, big piston and small work with the 3rd interface of light salt brine threeway described in each group Plug is connected together by connecting rod, and big piston is equipped with big hydrostatic seal circle, valve piston is in small pipe inside big pipe in big work Face, small hydrostatic seal circle is housed on valve piston.The metal of all exposed graphene or CNT hotting mask saline treatment equipment Part will coat insulated paint or be isolated with plastic wire, avoid someone from getting an electric shock.
The control method of graphene or CNT hotting mask saline treatment equipment.Clarified water pump is seawater or industrial brine Be extracted into by the filtering of screen pack in clarifier-tank, toward clarifier-tank in launch remove algae degreasing agent.Deodorization pump handle is by removing algae degreasing Seawater or industrial brine after processing are extracted into active carbon deodorizing pond, remove the peculiar smell of seawater or industrial brine.Pretreatment Seawater after active carbon deodorizing is handled or industrial brine are extracted into quick-fried Sai and added by pump after microporous ceramic filter filters In hot pond.Industrial smoke is that one end of rectangular metal tube into section is rectangular metal tube from section, is from section The short metal pipe that the flue gas that the other end of rectangular metal tube comes out is entered on filter cloth by many slat gum flexible pipes respectively, Flue gas is blown into the sulfur dioxide removed in the limewash in desulfurization pond in flue gas from short metal pipe, in desulfurization lime pump handle desulfurization pond Limewash beat circulation stirring.Or industrial hot water from section be rectangular metal tube one end into section be rectangular Metal, after then being come out from section for the other end of rectangular metal tube, section is entered for the other end of rectangular metal tube Enter industrial cycle water pipe.After the hot sea water being exposed to the sun in heating bath or hot industrial brine are extracted out with light salt brine pump, pass through successively The cold passage of strong brine regenerative heater, the cold passage of fresh water regenerative heater, the light salt brine Pneumatic butterfly valve and light salt brine of each group Threeway enters graphene from the top center of vertically-mounted each group graphene or CNT hotting mask saline treatment film core 1 Or the salt pool of CNT hotting mask saline treatment film core 1.The graphene or CNT hotting mask of internal layer connect direct current positive pole, outside The graphene or CNT hotting mask 103 of layer connect direct current negative pole, and computer controller is according to graphene or CNT hotting mask salt The brine temp information that probe of the salt pool of membrane for water treatment core 1 equipped with temperature sensor or temperature detect switch (TDS) detects, regulation The voltage of direct current between the graphene or CNT hotting mask 103 of internal layer and the graphene or CNT hotting mask of outer layer. The anionic metal in the salt pool of graphene or CNT hotting mask saline treatment film core 1 is in the graphene or nanometer close to internal layer It is ostracised during carbon pipe hotting mask positive pole, metal molecules of salt can not pass through the graphene or CNT hotting mask positive pole and outer layer of internal layer Graphene or CNT hotting mask negative pole.The graphene or nanometer of the internal layer of graphene or CNT hotting mask saline treatment film core Although accompanying insulation water permeable membrane between carbon pipe hotting mask positive pole and the graphene or CNT hotting mask negative pole of outer layer, in Contain a small amount of salt in the graphene of layer or the fresh water of CNT hotting mask positive pole, be the very big conductor of resistance, the graphene of internal layer Or after the graphene or CNT hotting mask negative pole of CNT hotting mask positive pole and outer layer connect direct current, can be in the graphite of internal layer Electric current is produced between alkene or the graphene or CNT hotting mask negative pole of CNT hotting mask positive pole and outer layer, heats the stone of internal layer The graphene or CNT hotting mask of black alkene or CNT hotting mask and outer layer, heat graphene or CNT close to internal layer The seawater or industrial brine of hotting mask and the close graphene of outer layer or the fresh water of CNT hotting mask, seawater and industrial brine quilt Reduce the viscosity of seawater or industrial brine after heating, the hydrone in hot sea water or hot industrial brine is easily through interior The graphene or the graphene or CNT hotting mask of CNT hotting mask and outer layer of layer reach graphene or CNT hotting mask The fresh water area of saline treatment film core, the graphene or CNT hotting mask of the internal layer after heating and the graphene or nano-sized carbon of outer layer The micropore of pipe hotting mask becomes penetrating, the hydrone in hot sea water or hot industrial brine easily through internal layer graphene or receive Rice carbon pipe hotting mask and the graphene of outer layer or the micropore of CNT hotting mask.Or graphene or CNT hotting mask in outer layer Connect the live wire of alternating current, the graphene or CNT hotting mask of internal layer connect alternating current zero line, computer controller according to graphene or Seawater that probe of the salt pool of CNT hotting mask saline treatment film core 1 equipped with temperature sensor or temperature detect switch (TDS) detects or Person's industrial brine temperature information, adjust the graphene or the graphene or CNT hotting mask of CNT hotting mask and internal layer of outer layer Between the voltage of alternating current that is passed through, the graphene or CNT hotting mask of outer layer and the graphene or CNT hotting mask of internal layer Although insulation water permeable membrane is accompanied between, through internal layer graphene or CNT hotting mask fresh water containing a small amount of salt, It is the very big conductor of resistance, the graphene or CNT hotting mask of outer layer and the graphene or CNT hotting mask of internal layer are passed through friendship After stream electricity, electricity can be produced between the graphene or CNT hotting mask of outer layer and the graphene or CNT hotting mask of internal layer Stream, the graphene or the graphene or CNT hotting mask of CNT hotting mask and internal layer of outer layer are heated, heated close to internal layer The seawater or industrial brine of graphene or CNT hotting mask and the close graphene of outer layer or the fresh water of CNT hotting mask, Seawater either reduces the viscosity of seawater or industrial brine after industrial brine is heated, in hot sea water or hot industrial brine Hydrone reaches stone easily through the graphene or CNT hotting mask of internal layer and the graphene or CNT hotting mask of outer layer The fresh water area of black alkene or CNT hotting mask saline treatment film core, the graphene or CNT hotting mask of the outer layer after heating and interior The graphene of layer or the micropore of CNT hotting mask become penetrating, and the hydrone in hot sea water or hot industrial brine is easy to wear Cross the micropore of the graphene of internal layer or the graphene or CNT hotting mask of CNT hotting mask and outer layer.Or the stone to individual layer Black alkene or CNT hotting mask is passed through direct current, heats the graphene or CNT hotting mask and neighbouring seawater or work of individual layer Industry salt solution and fresh water, computer controller are equipped with TEMP according to graphene or CNT hotting mask saline treatment film core salt pool The seawater or industrial brine temperature information that the probe of device either temperature detect switch (TDS) detects, adjust the graphene or nano-sized carbon of individual layer The voltage for the direct current that pipe hotting mask is passed through, the graphene or CNT hotting mask of individual layer are heated the graphene or nanometer of rear individual layer The micropore of carbon pipe hotting mask becomes penetrating, and either industrial brine is heated the viscosity reduction of rear seawater or industrial brine, cloth to seawater Bright motion increases, graphene or CNT hotting mask of the hydrone in hot sea water or hot industrial brine easily through individual layer Micropore.Or the graphene or CNT hotting mask of individual layer are passed through alternating current, the graphene or CNT heat of individual layer are heated Film and neighbouring seawater or industrial brine and fresh water, computer controller is according to graphene or CNT hotting mask saline treatment film The seawater or industrial brine temperature information that probe of the core salt pool equipped with temperature sensor either temperature detect switch (TDS) detects, are adjusted The voltage for the alternating current that the graphene or CNT hotting mask of individual layer are passed through, the graphene or CNT hotting mask of individual layer are heated The micropore of the graphene of individual layer or CNT hotting mask becomes penetrating afterwards, and either industrial brine is heated rear seawater or work to seawater The viscosity of industry salt solution reduces, graphene or CNT of the hydrone in hot sea water or industrial brine easily through individual layer The micropore of hotting mask.After graphene or CNT hotting mask saline treatment film core use setting time, graphene or CNT The seawater or industrial brine concentration in the salt pool of hotting mask saline treatment film core reach setting value, and computer controller can be given to open and be somebody's turn to do Group strong brine Pneumatic butterfly valve, goes out from the bottom centre position salt pool of this group of graphene or CNT hotting mask saline treatment film core The concentrated seawater or strong brine come is successively by this group of strong brine four-way, this group of strong brine Pneumatic butterfly valve and strong brine regeneration heating The passage of heat heating brackish water of device is transported to strong brine pond again.Hydrone in seawater or industrial brine passes through the bilayer of the group Or single-layer graphene or CNT hotting mask fresh water area, then from this group of graphene or CNT hotting mask saline treatment film core Lower end fresh water area come out after heat successively Jing Guo this group of fresh water threeway, this group of fresh water Pneumatic butterfly valve and fresh water regenerative heater lead to Road is flowed in fresh-water pool.Graphene or CNT hotting mask saline treatment film core operation a bit of time will block a little, need Just to rinse once, periodically open positive flushing group electromagnetic gas valve, the compressed air in air accumulator is successively by positive flushing group Electromagnetic gas valve, strong brine four-way enter positive rinse from the bottom centre position of graphene or CNT hotting mask saline treatment film core The salt pool of group graphene or CNT hotting mask saline treatment film core, then pass through positive flushing group bilayer or single-layer graphene Or the micropore of CNT hotting mask.Graphene or CNT hotting mask saline treatment film core use setting time to block, Need once to backwash graphene or CNT hotting mask saline treatment film core:The light salt brine for closing backwash group is pneumatic Butterfly valve, concentrated seawater Pneumatic butterfly valve and fresh water Pneumatic butterfly valve, open backwash Pneumatic butterfly valve, the energy regenerating influent gas of backwash group Dynamic butterfly valve.The backwash Pneumatic butterfly valve and energy regenerating water inlet Pneumatic butterfly valve of energy regenerating group are closed, opens energy regenerating group Energy regenerating water outlet Pneumatic butterfly valve.Backwashing pump extracts fresh water from fresh-water pool, and the backwash Pneumatic butterfly valve by backwash group enters Enter the graphene of backwash group or the fresh water area of CNT hotting mask saline treatment film core, then pass through backwash group bilayer or The micropore of person's single-layer graphene or CNT hotting mask reaches backwash group graphene or CNT hotting mask saline treatment film core Salt pool.The concentrated seawater or dense salt come out from the salt pool of backwash group graphene or CNT hotting mask saline treatment film core Water enters in the big pipe of recuperator by backwash group energy regenerating water inlet Pneumatic butterfly valve promotes big piston to move, big living Plug drives valve piston movement the energy regenerating of the seawater in small pipe or industrial brine Jing Guo energy regenerating group by connecting rod Water outlet Pneumatic butterfly valve is pressed into the salt pool of energy regenerating group graphene or CNT hotting mask saline treatment film core, then seawater or The micropore of hydrone through the double-deck revolution single-layer graphene of energy regenerating group or CNT hotting mask in person's industrial brine reaches Fresh water area.Energy regenerating closes backwash group energy regenerating water inlet Pneumatic butterfly valve after terminating, open draining Pneumatic butterfly valve and energy Recovery group light salt brine Pneumatic butterfly valve, the light salt brine Pneumatic butterfly valve and energy regenerating of seawater or industrial brine Jing Guo energy regenerating group Water outlet Pneumatic butterfly valve, which enters in the small pipe of recuperator, promotes valve piston movement, and valve piston drives living greatly move by connecting rod Dynamic, big piston enters the concentrated seawater in big pipe or strong brine by draining Pneumatic butterfly valve the heat of strong brine regenerative heater Passage, is then shut off draining Pneumatic butterfly valve and energy regenerating group energy regenerating water outlet Pneumatic butterfly valve, and drainage procedure terminates.When one After graphene or the number of CNT hotting mask saline treatment film core backwash reach setting number, the graphene or CNT Hotting mask saline treatment film core needs blowback of progress to lead to:Close the backwash Pneumatic butterfly valve of the logical group of blowback, fresh water Pneumatic butterfly valve, Light salt brine Pneumatic butterfly valve, energy regenerating water outlet Pneumatic butterfly valve and energy regenerating water inlet Pneumatic butterfly valve, open the general mood of the logical group of blowback Dynamic butterfly valve and strong brine Pneumatic butterfly valve.From the wind that Roots blower comes out by the logical group wind Pneumatic butterfly valve of blowback, lead to group from blowback The upper end of graphene or CNT hotting mask saline treatment film core enters at the logical group graphene of blowback or CNT hotting mask salt solution The fresh water area of film core is managed, then passes through the logical group bilayer of blowback or the micropore of single-layer graphene or CNT hotting mask.Blowback is led to After end, close the wind Pneumatic butterfly valve and concentrated water Pneumatic butterfly valve of the logical group of blowback, open the logical group of blowback light salt brine Pneumatic butterfly valve and Fresh water Pneumatic butterfly valve, restart desalinization or industrial brine processing.
Positive infiltration:Fresh water and seawater are separated with permeable membrane, fresh water molecule can pass through permeable membrane enter seawater in, fresh water with Osmotic pressure between seawater be present, the concentration more hyperosmosis of seawater is bigger.Counter-infiltration:Want to allow hydrone in seawater through oozing Permeable membrane enters fresh water it is necessary to the pressure certain to seawater, and the hydrone in seawater could be allowed to pass through permeable membrane, the moisture in seawater After son enters fresh water through permeable membrane, the concentration of seawater constantly improves, in concentrated seawater required for hydrone through permeable membrane Pressure improves constantly, and remaining 1/3rd concentrated seawater have to be discharged into sea.The present invention cans be compared between fresh-water pool and seawater pond Pipeline on a valve is housed, this valve is exactly graphene or CNT hotting mask, and graphene or CNT hotting mask lead to It is heated valve after electricity to be opened, as long as to the point pressure of seawater one in seawater pond, the hydrone in seawater, which will pass through, to be powered Graphene or CNT hotting mask this valve arrival fresh-water pool afterwards.Also can even if the hydrone in dense concentrated seawater Through the graphene after energization or CNT hotting mask, so the present invention being capable of the very high industrial brine of concentration for the treatment of.
Brief description of the drawings:
Further specific detailed description is done to the present invention with reference to the accompanying drawings and detailed description.
Fig. 1 is graphene or the structure principle chart of CNT hotting mask saline treatment equipment in the present invention.
Fig. 2 is the schematic cross-section of graphene or CNT hotting mask saline treatment film core in the present invention.
Fig. 3 is the structure principle chart of recuperator in the present invention.
Embodiment:
Shown in Fig. 1, Fig. 2 and Fig. 3, graphene or CNT hotting mask saline treatment equipment.At sea build ' recessed ' word Shape, which floats, floats pond, and clarifier-tank is divided into covered with solar panel, ' recessed ' font floating pool above ' recessed ' font floating pool 3rd, active carbon deodorizing pond 4, sudden and violent Sai heating baths 5, fresh-water pool 7, strong brine pond 6 and desulfurization pond 16, or clarifier-tank is built on land 3rd, active carbon deodorizing pond 4, sudden and violent Sai heating baths 5, fresh-water pool 7, strong brine pond 6 and desulfurization pond 16, clarifier-tank 3, active carbon deodorizing pond 4th, sudden and violent Sai heating baths 5, fresh-water pool 7, strong brine pond 6 and desulfurization pond 16 are above covered with solar panel.Clarified water pump 12 Seawater or industrial brine are extracted into clarifier-tank 3 by the filtering of screen pack, and algae degreasing agent is removed toward the inner dispensing of clarifier-tank 3.Deodorization Water pump 13 is extracted into the seawater after except algae ungrease treatment or industrial brine in active carbon deodorizing pond 4, remove seawater or The peculiar smell of industrial brine.Seawater after active carbon deodorizing is handled or industrial brine are passed through micropore ceramics by pretreatment pump 14 Quick-fried Sai heating baths 5 are extracted into after filter filtering.There is one group of section to run through quick-fried Sai heating baths 5 for rectangular metal tube, section is For rectangular metal tube built with fin, section is that rectangular outer surface of metal pipe plates tungsten;Section is rectangular metal tube One end pool together after be connected with industrial smoke heat-preserving hose, section be rectangular metal tube the other end pass through respectively Many slat gum flexible pipes are connected with the short metal pipe being fixed on filter cloth, and filtering fabric envelope is on metal framework, metal framework It is put into desulfurization pond 16.It is contained with limewash in desulfurization pond 16, the limewash in desulfurization lime pump handle desulfurization pond is played circulation and stirred Mix.Or section pools together for one end of rectangular metal tube and is connected afterwards with industrial hot water heat-preserving hose, section is length The other end of square metal tube is connected after pooling together with industrial cycle water pipe.At graphene or CNT hotting mask salt solution Array graphene or CNT hotting mask saline treatment film core 1 are used in reason equipment.At graphene or CNT hotting mask salt solution The structure for managing film core 1 is shell 101, foamed plastics outer layer or foamed ceramics outer layer 102, the graphite of outer layer successively from outside to inside Alkene or CNT hotting mask 103, insulation water permeable membrane, the graphene of internal layer or CNT hotting mask 103, the foamed plastics heart or The foamed ceramics heart 104, the foamed plastics heart or the foamed ceramics heart 104 are graphene or CNT hotting mask saline treatment film core 1 Salt pool, graphene or the salt pool of CNT hotting mask saline treatment film core 1 are equipped with temperature sensor or temperature detect switch (TDS) Probe;Foamed plastics profile or foamed ceramics outer layer 102 are the light of graphene or CNT hotting mask saline treatment film core 1 Pool;Direct current is connected between the graphene or CNT hotting mask 103 of outer layer and the graphene or CNT hotting mask 103 of internal layer Electricity, the graphene or CNT hotting mask 103 of internal layer connect positive pole, and the graphene or CNT hotting mask 103 of outer layer connect negative pole.Or The structure of person's graphene or CNT hotting mask saline treatment film core 1 be successively from outside to inside shell 101, foamed plastics outer layer or Person's foamed ceramics outer layer 102, the graphene of outer layer or CNT hotting mask 103, insulation water permeable membrane, internal layer graphene or receive Rice carbon pipe hotting mask 103, the foamed plastics heart or the foamed ceramics heart 104, the foamed plastics heart or the foamed ceramics heart 104 are graphenes Or the salt pool of CNT hotting mask saline treatment film core 1, graphene or the salt pool of CNT hotting mask saline treatment film core 1 dress There is the probe of temperature sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics outer layer 102 are graphenes or received The fresh water area of rice carbon pipe hotting mask saline treatment film core 1;The graphene or CNT hotting mask 103 of outer layer and the graphene of internal layer or Alternating current is connected between CNT hotting mask 103.The graphene or CNT hotting mask 103 of internal layer connect alternating current zero line, outer layer Graphene or CNT hotting mask 103 connect alternating current fire wire.Or graphene or CNT hotting mask saline treatment film core 1 Structure is shell 101, foamed plastics outer layer or foamed ceramics outer layer 102, graphene or CNT heat successively from outside to inside Film 103, the foamed plastics heart or the foamed ceramics heart 104, the foamed plastics heart or the foamed ceramics heart 104 are graphene or nano-sized carbon The salt pool of pipe hotting mask saline treatment film core 1, graphene or the salt pool of CNT hotting mask saline treatment film core 1 pass equipped with temperature The probe of sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics outer layer 102 are graphene or CNT heat The fresh water area of film saline treatment film core 1;Graphene or the both ends of CNT hotting mask 103 connect the positive pole and negative pole of direct current respectively. Or the structure of graphene or CNT hotting mask saline treatment film core 1 is shell 101, foamed plastics outer layer successively from outside to inside Either foamed ceramics outer layer 102, graphene or CNT hotting mask 103, the foamed plastics heart or the foamed ceramics heart 104, foam The plastics heart or the foamed ceramics heart 104 are the salt pools of graphene or CNT hotting mask saline treatment film core 1, graphene or are received Probe of the salt pool of rice carbon pipe hotting mask saline treatment film core 1 equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics profile or Person's foamed ceramics outer layer 102 is the fresh water area of graphene or CNT hotting mask saline treatment film core 1;Graphene or nano-sized carbon The both ends of pipe hotting mask 103 connect the live wire and zero line of alternating current respectively.With 15 seawater being exposed to the sun in heating bath 5 of light salt brine pump or work After industry salt solution is extracted out, successively by the cold passage of strong brine regenerative heater 10, the cold passage of fresh water regenerative heater 11, each group Light salt brine Pneumatic butterfly valve 17 and light salt brine threeway from the vertically-mounted graphene of each group or CNT hotting mask saline treatment film The top center of core 1 enters the salt pool of graphene or CNT hotting mask saline treatment film core 1.From each group graphene or The concentrated seawater or strong brine that the bottom centre position salt pool of CNT hotting mask saline treatment film core 1 comes out are successively by each The strong brine four-way of group, pool together after strong brine Pneumatic butterfly valve 18, then pass through the heat of strong brine regenerative heater 10 again Passage is transported to strong brine pond.The wind come out from Roots blower passes through each group wind Pneumatic butterfly valve, from each group graphene or nanometer The upper end of carbon pipe hotting mask saline treatment film core 1 enters the fresh water area of each group graphene or CNT hotting mask saline treatment film core 1. The fresh water come out from each group graphene or the lower end fresh water area of CNT hotting mask saline treatment film core 1 passes through each group fresh water three successively Pool together after logical and fresh water Pneumatic butterfly valve 17, then flowed to by the passage of heat of fresh water regenerative heater 11 in fresh-water pool 7. Backwashing pump 24, which from fresh-water pool 7 extracts fresh water, to be sent into the 3rd of each group fresh water threeway by each group backwash Pneumatic butterfly valve 23 and connects Mouthful.The 3rd of each group strong brine four-way is equipped with each group energy regenerating water inlet Pneumatic butterfly valve 19 between interface and recuperator 2, Each group energy regenerating water outlet Pneumatic butterfly valve 20 is housed between recuperator 2 and the 3rd interface of each group light salt brine threeway.It is empty The compressed air that air compressor 9 extrudes enters air accumulator 8 by check valve 28, the compressed air warp come out from the bottom of air accumulator 8 Cross the 4th interface that each group electromagnetic gas valve 27 enters each group strong brine four-way.Recuperator 2 is by big pipe 201, big piston 203rd, connecting rod 205, small pipe 202, valve piston 204 are formed, and the arrival end of big pipe 201 is intake by energy regenerating described in each group Pneumatic butterfly valve 19 is connected connection, the arrival end and strong brine of big pipe 201 with the 3rd interface of strong brine four-way described in each group Drainpipe is housed between the passage of heat of regenerative heater 10, draining Pneumatic butterfly valve 21, the outlet of small pipe 202 are housed on drainpipe End is connected connection by energy regenerating water outlet Pneumatic butterfly valve 20 described in each group with the 3rd interface of light salt brine threeway described in each group, Big piston 203 is connected together with valve piston 204 by connecting rod 205, and big piston 203 fills on the big the inside of pipe 201, big living 203 There is big hydrostatic seal circle, valve piston 204 is equipped with small hydrostatic seal circle on the small the inside of pipe 202, valve piston 204.It is all exposed Graphene or the metal parts of CNT hotting mask saline treatment equipment to coat insulated paint or be isolated with plastic wire, avoid Someone gets an electric shock.
Shown in Fig. 1, Fig. 2 and Fig. 3, the control method of graphene or CNT hotting mask saline treatment equipment.Clarified water pump 12 seawater or industrial brine are extracted into clarifier-tank 3 by the filtering of screen pack, and algae degreasing agent is removed toward the inner dispensing of clarifier-tank 3. Deodorization water pump 13 is extracted into the seawater after except algae ungrease treatment or industrial brine in active carbon deodorizing pond 4, removes seawater Or the peculiar smell of industrial brine.Seawater after active carbon deodorizing is handled or industrial brine are passed through micropore by pretreatment pump 14 It is extracted into after ceramic filter filtering in quick-fried Sai heating baths 5.Industrial smoke enters from section for one end of rectangular metal tube to be cut Face is rectangular metal tube, passes through many slat gums respectively from section for the flue gas that the other end of rectangular metal tube comes out The short metal pipe that flexible pipe enters on filter cloth, flue gas are blown into two removed in the limewash in desulfurization pond 16 in flue gas from short metal pipe Sulfur oxide, the limewash in desulfurization lime pump handle desulfurization pond beat circulation stirring.Or industrial hot water is rectangular from section One end of metal tube into section be rectangular metal, then from section for rectangular metal tube the other end come out after, Section enters industrial cycle water pipe for the other end of rectangular metal tube.With 15 heat being exposed to the sun in heating bath 5 of light salt brine pump After seawater or hot industrial brine are extracted out, successively by the cold passage of strong brine regenerative heater 10, fresh water regenerative heater 11 Cold passage, each group light salt brine Pneumatic butterfly valve 17 and light salt brine threeway from vertically-mounted each group graphene or CNT heat The top center of film saline treatment film core 1 enters the salt pool of graphene or CNT hotting mask saline treatment film core 1.It is interior The graphene or CNT hotting mask 103 of layer connect direct current positive pole, and the graphene or CNT hotting mask 103 of outer layer connect direct current Negative pole, computer controller according to the salt pool of graphene or CNT hotting mask saline treatment film core 1 equipped with temperature sensor or The brine temp information that the probe of person's temperature detect switch (TDS) detects, adjust the graphene or CNT hotting mask 103 and outer layer of internal layer Graphene or CNT hotting mask 103 between direct current voltage.Graphene or CNT hotting mask saline treatment film core 1 Salt pool anionic metal close to internal layer graphene or CNT 103 positive pole of hotting mask when be ostracised, metal salinity Son can not be negative through the graphene of internal layer or the graphene or CNT hotting mask 103 of the positive pole of CNT hotting mask 103 and outer layer Pole.The graphene or the positive pole of CNT hotting mask 103 and outer layer of the internal layer of graphene or CNT hotting mask saline treatment film core 1 Although graphene or the negative pole of CNT hotting mask 103 between accompany insulation water permeable membrane, through internal layer graphene or receive Contain a small amount of salt in the fresh water of the positive pole of rice carbon pipe hotting mask 103, be the very big conductor of resistance, graphene or the CNT heat of internal layer After the graphene or the negative pole of CNT hotting mask 103 of the positive pole of film 103 and outer layer connect direct current, can internal layer graphene or receive Electric current is produced between the positive pole of rice carbon pipe hotting mask 103 and the graphene or the negative pole of CNT hotting mask 103 of outer layer, heats the stone of internal layer The graphene or CNT hotting mask 103 of black alkene or CNT hotting mask 103 and outer layer, heat the graphene of close internal layer or receive The seawater or industrial brine and the close graphene of outer layer or the fresh water of CNT hotting mask 103 of rice carbon pipe hotting mask 103, seawater Reduce the viscosity of seawater or industrial brine after being heated with industrial brine, the hydrone in hot sea water or hot industrial brine The graphene or CNT hotting mask 103 of graphene or CNT hotting mask 103 and outer layer easily through internal layer reach stone The fresh water area of black alkene or CNT hotting mask saline treatment film core 1, the graphene or CNT hotting mask 103 of the internal layer after heating Become penetrating with the graphene of outer layer or the micropore of CNT hotting mask 103, the hydrone in hot sea water or hot industrial brine Graphene or CNT hotting mask 103 and the graphene of outer layer or the micropore of CNT hotting mask 103 easily through internal layer. Or connect the live wire of alternating current, the graphene or CNT hotting mask of internal layer in the graphene or CNT hotting mask 103 of outer layer 103 connect alternating current zero line, and computer controller is equipped with temperature according to graphene or the salt pool of CNT hotting mask saline treatment film core 1 The seawater or industrial brine temperature information that the probe of sensor either temperature detect switch (TDS) detects, adjust the graphene of outer layer or receive The voltage for the alternating current being passed through between rice carbon pipe hotting mask 103 and the graphene or CNT hotting mask 103 of internal layer, the graphite of outer layer Although accompanying insulation water permeable membrane between alkene or the graphene or CNT hotting mask 103 of CNT hotting mask 103 and internal layer, Through internal layer graphene or CNT hotting mask 103 fresh water containing a small amount of salt, be the very big conductor of resistance, the stone of outer layer , can be in the stone of outer layer after the graphene or CNT hotting mask 103 of black alkene or CNT hotting mask 103 and internal layer are passed through alternating current Electric current is produced between the graphene or CNT hotting mask 103 of black alkene or CNT hotting mask 103 and internal layer, heats the stone of outer layer The graphene or CNT hotting mask 103 of black alkene or CNT hotting mask 1 and internal layer, heat graphene or nanometer close to internal layer The seawater or industrial brine of carbon pipe hotting mask 103 and close to the graphene of outer layer or the fresh water of CNT hotting mask 103, seawater or Person's industrial brine reduces the viscosity of seawater or industrial brine after being heated, the hydrone in hot sea water or hot industrial brine The graphene or CNT hotting mask 103 of graphene or CNT hotting mask 103 and outer layer easily through internal layer reach stone The fresh water area of black alkene or CNT hotting mask saline treatment film core 1, the graphene or CNT hotting mask 103 of the outer layer after heating Become penetrating with the graphene of internal layer or the micropore of CNT hotting mask 103, the hydrone in hot sea water or hot industrial brine Graphene or CNT hotting mask 103 and the graphene of outer layer or the micropore of CNT hotting mask 103 easily through internal layer. Or graphene to individual layer or CNT hotting mask 103 are passed through direct current, heat the graphene or CNT hotting mask of individual layer 103 and neighbouring seawater or industrial brine and fresh water, computer controller is according to graphene or CNT hotting mask saline treatment The seawater or industrial brine temperature information that probe of the salt pool of film core 1 equipped with temperature sensor either temperature detect switch (TDS) detects, Adjust the voltage for the direct current that the graphene of individual layer or CNT hotting mask 103 are passed through, graphene or the CNT heat of individual layer The graphene of individual layer or the micropore of CNT hotting mask 103 become penetrating after film 103 is heated, and seawater or industrial brine are added The viscosity of seawater or industrial brine reduces after heat, Brownian movement increases, and the hydrone in hot sea water or hot industrial brine is very Easily propagate through the graphene of individual layer or the micropore of CNT hotting mask 103.Or the graphene or CNT hotting mask 103 of individual layer Alternating current is passed through, heats the graphene or CNT hotting mask 103 and neighbouring seawater or industrial brine and fresh water of individual layer, electricity Brain controller is equipped with temperature sensor or temperature detect switch (TDS) according to graphene or the salt pool of CNT hotting mask saline treatment film core 1 The probe seawater or industrial brine temperature information that detect, the graphene or CNT hotting mask 103 for adjusting individual layer be passed through Alternating current voltage, individual layer has black alkene or CNT heat after the graphene or CNT hotting mask 103 of individual layer are heated The micropore of film 103 becomes penetrating, and either the viscosity of the heated rear seawater of industrial brine or industrial brine reduces seawater, hot sea water Or the hydrone in industrial brine is easily through the graphene of individual layer or the micropore of CNT hotting mask 103.Graphene or After CNT hotting mask saline treatment film core 1 uses setting time, graphene or CNT hotting mask saline treatment film core 1 The seawater or industrial brine concentration in salt pool reach setting value, and computer controller can be given and open this group of strong brine Pneumatic butterfly valve 18, from the bottom centre position salt pool of this group of graphene or CNT hotting mask saline treatment film core 1 come out concentrated seawater or Person's strong brine leads to by the heat of this group of strong brine four-way, this group of strong brine Pneumatic butterfly valve 18 and strong brine regenerative heater 10 successively Road heating brackish water is transported to strong brine pond 6 again.Seawater either the hydrone in industrial brine through the double-deck or single of the group Layer graphene or the fresh water area of CNT hotting mask 103, then from this group of graphene or CNT hotting mask saline treatment film core 1 Heat Jing Guo this group of fresh water threeway, this group of fresh water Pneumatic butterfly valve 22 and fresh water regenerative heater 11 successively after lower end fresh water area comes out Passage is flowed in fresh-water pool 7.Graphene or CNT hotting mask saline treatment film core 1, which run a bit of time, to be blocked up a little Plug periodically opens positive flushing group electromagnetic gas valve 27, it is necessary to just rinsing once, and the compressed air in air accumulator 8 is successively by just The electromagnetic gas valve 27 of flushing group, strong brine four-way are from the bottom centre position of graphene or CNT hotting mask saline treatment film core 1 The salt pool into positive flushing group graphene or CNT hotting mask saline treatment film core 1 is put, it is double-deck to then pass through positive flushing group Or the micropore of single-layer graphene or CNT hotting mask 103.Graphene or CNT hotting mask saline treatment film core 1 use Setting time will be blocked, it is necessary to once be backwashed to graphene or CNT hotting mask saline treatment film core 1:Close anti- Light salt brine Pneumatic butterfly valve 17, concentrated seawater Pneumatic butterfly valve 18 and the fresh water Pneumatic butterfly valve 17 of flushing group, open the recoil of backwash group Wash Pneumatic butterfly valve 23, energy regenerating water inlet Pneumatic butterfly valve 19.Close backwash Pneumatic butterfly valve 23, the energy regenerating of energy regenerating group Water inlet Pneumatic butterfly valve 19, open the energy regenerating water outlet Pneumatic butterfly valve 20 of energy regenerating group.Backwashing pump 24 extracts from fresh-water pool 7 Fresh water, the backwash Pneumatic butterfly valve 23 by backwash group enter the graphene or CNT hotting mask saline treatment of backwash group The fresh water area of film core 1, the bilayer or the micropore of single-layer graphene or CNT hotting mask 103 for then passing through backwash group reach Backwash group graphene or the salt pool of CNT hotting mask saline treatment film core 1.From backwash group graphene or CNT heat The concentrated seawater or strong brine that the salt pool of film saline treatment film core 1 comes out are by backwash group energy regenerating water inlet Pneumatic butterfly valve The 19 inner big pistons 203 of promotion of big pipe 201 for entering recuperator 2 move, and big piston 203 passes through connecting rod 05 and drives valve piston 204 movements are energy regenerating water outlet Pneumatic butterfly valve 20 of the seawater or industrial brine in small pipe 202 Jing Guo energy regenerating group The salt pool of energy regenerating group graphene or CNT hotting mask saline treatment film core 1 is pressed into, then seawater or industrial brine In the micropore of hydrone through the double-deck revolution single-layer graphene of energy regenerating group or CNT hotting mask 103 reach fresh water area. Energy regenerating closes backwash group energy regenerating water inlet Pneumatic butterfly valve 19 after terminating, open draining Pneumatic butterfly valve 21 and energy regenerating Group light salt brine Pneumatic butterfly valve 17, the light salt brine Pneumatic butterfly valve 17 and energy regenerating of seawater or industrial brine Jing Guo energy regenerating group The inner promotion valve piston 204 of small pipe 202 that water outlet Pneumatic butterfly valve 20 enters recuperator 2 moves, and valve piston 204 passes through connecting rod 205 drive big 203 movement living, and big piston 203 enters the concentrated seawater in big pipe 201 or strong brine by draining Pneumatic butterfly valve Enter the passage of heat of strong brine regenerative heater 10, be then shut off draining Pneumatic butterfly valve 21 and energy regenerating group energy regenerating goes out aqueous vapor Dynamic butterfly valve 20, drainage procedure terminates.When the number that a graphene or CNT hotting mask saline treatment film core 1 backwash reaches After setting number, the graphene or CNT hotting mask saline treatment film core 1 need blowback of progress to lead to:Close blowback and lead to group Backwash Pneumatic butterfly valve 23, fresh water Pneumatic butterfly valve 17, light salt brine Pneumatic butterfly valve 17, energy regenerating water outlet Pneumatic butterfly valve 20 and energy Amount recovery water inlet Pneumatic butterfly valve 19, open the wind Pneumatic butterfly valve 25 and strong brine Pneumatic butterfly valve 18 of the logical group of blowback.From Roots blower The wind that machine 26 comes out is by the logical group wind Pneumatic butterfly valve 25 of blowback, from the logical group graphene of blowback or CNT hotting mask saline treatment film The upper end of core 1 enters the fresh water area of the logical group graphene of blowback or the core of CNT hotting mask saline treatment film 1, then passes through blowback and leads to Group bilayer or the micropore of single-layer graphene or CNT hotting mask 103.After the logical end of blowback, the general mood for closing the logical group of blowback is moved Butterfly valve 25 and concentrated water Pneumatic butterfly valve 18, the light salt brine Pneumatic butterfly valve 17 and fresh water Pneumatic butterfly valve 22 of the logical group of blowback are opened, is opened again Beginning desalinization or industrial brine processing.

Claims (6)

1. a kind of graphene or CNT hotting mask saline treatment equipment, it is characterised in that:At sea build ' recessed ' font drift Floating floating pond, covered with solar panel above ' recessed ' font floating pool, ' recessed ' font floating pool be divided into clarifier-tank (3), Active carbon deodorizing pond (4), sudden and violent Sai heating baths (5), fresh-water pool (7), strong brine pond (6) and desulfurization pond (16), or on land Clarifier-tank (3), active carbon deodorizing pond (4), sudden and violent Sai heating baths (5), fresh-water pool (7), strong brine pond (6) and desulfurization pond (16) are built, Clarifier-tank (3), active carbon deodorizing pond (4), sudden and violent Sai heating baths (5), fresh-water pool (7), strong brine pond (6) and desulfurization pond (16) are above Covered with solar panel, seawater or industrial brine are extracted into clarifier-tank by clarified water pump (12) by the filtering of screen pack (3) in, algae degreasing agent is removed toward the inner dispensing of clarifier-tank (3), deodorization water pump (13) the seawater after except algae ungrease treatment or Industrial brine is extracted into active carbon deodorizing pond (4), removes the peculiar smell of seawater or industrial brine, pretreatment pump (14) is through making a living Seawater or industrial brine after property charcoal deodorizing process are extracted into after microporous ceramic filter filters in quick-fried Sai heating baths (5); There is one group of section run through quick-fried Sai heating baths (5) for rectangular metal tube, section is rectangular metal tube built with fin, section Face is that rectangular outer surface of metal pipe plates tungsten;Section pools together rear and industrial smoke for one end of rectangular metal tube Heat-preserving hose connects, and section by many slat gum flexible pipes and is fixed on filter cloth respectively for the other end of rectangular metal tube On short metal pipe connection, filtering fabric envelope on metal framework, metal framework is put into desulfurization pond (16), in desulfurization pond (16) It is contained with limewash, the limewash in desulfurization lime pump handle desulfurization pond beats circulation stirring;Or section is rectangular metal One end of pipe is connected after pooling together with industrial hot water heat-preserving hose, and section collects in for the other end of rectangular metal tube It is connected after together with industrial cycle water pipe;Using array graphene or received in graphene or CNT hotting mask saline treatment equipment Rice carbon pipe hotting mask saline treatment film core (1), takes out the seawater in the heating bath that is exposed to the sun (5) or industrial brine with light salt brine pump (15) After going out, successively by the cold passage of strong brine regenerative heater (10), the cold passage of fresh water regenerative heater (11), each group it is light Salt solution Pneumatic butterfly valve (17) and light salt brine threeway are from the vertically-mounted graphene of each group or CNT hotting mask saline treatment film core (1) top center enters the salt pool of graphene or CNT hotting mask saline treatment film core (1);From each group graphene Or the bottom centre position salt pool of CNT hotting mask saline treatment film core (1) come out concentrated seawater or strong brine pass through successively Cross the strong brine four-way of each group, strong brine Pneumatic butterfly valve pools together after (18), then pass through strong brine regenerative heater again (10) the passage of heat is transported to strong brine pond;The wind come out from Roots blower passes through each group wind Pneumatic butterfly valve, from each group graphite The upper end of alkene or CNT hotting mask saline treatment film core (1) enters each group graphene or CNT hotting mask saline treatment film core (1) fresh water area;The fresh water come out from each group graphene or CNT hotting mask saline treatment film core (1) lower end fresh water area is successively Pooled together after the threeway of each group fresh water and fresh water Pneumatic butterfly valve (17), then by the heat of fresh water regenerative heater (11) It is inner that passage flows to fresh-water pool (7);Backwashing pump (24) extracts fresh water by each group backwash Pneumatic butterfly valve (23) from fresh-water pool (7) It is sent into the 3rd interface of each group fresh water threeway;Filled between the 3rd interface and recuperator (2) of each group strong brine four-way There is each group energy regenerating water inlet Pneumatic butterfly valve (19), between recuperator (2) and the 3rd interface of each group light salt brine threeway Equipped with each group energy regenerating water outlet Pneumatic butterfly valve (20);The compressed air that air compressor (9) extrudes is entered by check valve (28) Enter air accumulator (8), the compressed air come out from air accumulator (8) bottom enters each group strong brine four by each group electromagnetic gas valve (27) The 4th logical interface;Recuperator (2) by big pipe (201), big piston (203), connecting rod (205), small pipe (202), Valve piston (204) forms, and the arrival end of big pipe (201) passes through energy regenerating water inlet Pneumatic butterfly valve (19) and each group described in each group The 3rd interface connection connection of the strong brine four-way, arrival end and the strong brine regenerative heater (10) of big pipe (201) The passage of heat between drainpipe is housed, draining Pneumatic butterfly valve (21) is housed, the port of export of small pipe (202) passes through each on drainpipe The group energy regenerating water outlet Pneumatic butterfly valve (20) is connected connection, big piston with the 3rd interface of light salt brine threeway described in each group (203) connected together with valve piston (204) by connecting rod (205), big piston (203) is inside big pipe (201), big piston (23) big hydrostatic seal circle is housed, valve piston (204) is close equipped with small static pressure on valve piston (204) inside small pipe (202) on Seal;The metal parts of all exposed graphene or CNT hotting mask saline treatment equipment to coat insulated paint or with modeling Material net isolation, avoids someone from getting an electric shock.
2. according to a kind of graphene of claim 1 or CNT hotting mask saline treatment equipment, it is characterised in that:The graphene Or the structure of CNT hotting mask saline treatment film core (1) is shell (101), foamed plastics outer layer or bubble successively from outside to inside Foam top ceramic layer (102), the graphene of outer layer or CNT hotting mask (103), insulation water permeable membrane, internal layer graphene or receive Rice carbon pipe hotting mask (103), the foamed plastics heart or the foamed ceramics heart (104), the foamed plastics heart or the foamed ceramics heart (104) are The salt pool of graphene or CNT hotting mask saline treatment film core (1), graphene or CNT hotting mask saline treatment film core (1) probe of the salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics outer layer (102) are The fresh water area of graphene or CNT hotting mask saline treatment film core (1);The graphene or CNT hotting mask (103) of outer layer Direct current, the graphene or CNT hotting mask of internal layer are connected between the graphene or CNT hotting mask (103) of internal layer (103) positive pole is connect, the graphene or CNT hotting mask (103) of outer layer connect negative pole.
3. according to a kind of graphene of claim 1 or CNT hotting mask saline treatment equipment, it is characterised in that:The graphene Or the structure of CNT hotting mask saline treatment film core (1) is shell (101), foamed plastics outer layer or bubble successively from outside to inside Foam top ceramic layer (102), the graphene of outer layer or CNT hotting mask (103), insulation water permeable membrane, internal layer graphene or receive Rice carbon pipe hotting mask (103), the foamed plastics heart or the foamed ceramics heart (104), the foamed plastics heart or the foamed ceramics heart (104) are The salt pool of graphene or CNT hotting mask saline treatment film core (1), graphene or CNT hotting mask saline treatment film core (1) probe of the salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics profile or foamed ceramics outer layer (102) are The fresh water area of graphene or CNT hotting mask saline treatment film core (1);The graphene or CNT hotting mask (103) of outer layer Alternating current is connected between the graphene or CNT hotting mask (103) of internal layer.The graphene or CNT hotting mask of internal layer (103) alternating current zero line is connect, the graphene or CNT hotting mask (103) of outer layer connect alternating current fire wire.
4. according to a kind of graphene of claim 1 or CNT hotting mask saline treatment equipment, it is characterised in that:The graphene Or the structure of CNT hotting mask saline treatment film core (1) is shell (101), foamed plastics outer layer or bubble successively from outside to inside Foam top ceramic layer (102), graphene or CNT hotting mask (103), the foamed plastics heart or the foamed ceramics heart (104), foam The plastics heart or the foamed ceramics heart (104) are the salt pools of graphene or CNT hotting mask saline treatment film core (1), graphene Or probe of CNT hotting mask saline treatment film core (1) the salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics Profile or foamed ceramics outer layer (102) are the fresh water areas of graphene or CNT hotting mask saline treatment film core (1);Graphite Alkene or CNT hotting mask (103) both ends connect the positive pole and negative pole of direct current respectively.
5. according to a kind of graphene of claim 1 or CNT hotting mask saline treatment equipment, it is characterised in that:The graphene Or the structure of CNT hotting mask saline treatment film core (1) is shell (101), foamed plastics outer layer or bubble successively from outside to inside Foam top ceramic layer (102), graphene or CNT hotting mask (103), the foamed plastics heart or the foamed ceramics heart (104), foam The plastics heart or the foamed ceramics heart (104) are the salt pools of graphene or CNT hotting mask saline treatment film core (1), graphene Or probe of CNT hotting mask saline treatment film core (1) the salt pool equipped with temperature sensor or temperature detect switch (TDS);Foamed plastics Profile or foamed ceramics outer layer (102) are the fresh water areas of graphene or CNT hotting mask saline treatment film core (1);Graphite Alkene or CNT hotting mask (103) both ends connect the live wire and zero line of alternating current respectively.
6. the control method of graphene or CNT hotting mask saline treatment equipment, it is characterised in that:Clarified water pump (12) is sea Water or industrial brine are extracted into clarifier-tank (3) by the filtering of screen pack, are removed algae degreasing agent toward the inner dispensing of clarifier-tank (3), are removed Smelly water pump (13) is extracted into the seawater after except algae ungrease treatment or industrial brine in active carbon deodorizing pond (4), removes sea The peculiar smell of water or industrial brine, pretreatment pump (14) pass through the seawater after active carbon deodorizing is handled or industrial brine It is extracted into after microporous ceramic filter filtering in quick-fried Sai heating baths (5);The one end of industrial smoke from section for rectangular metal tube It is rectangular metal tube into section, passes through many respectively from section for the flue gas that the other end of rectangular metal tube comes out The short metal pipe that slat gum flexible pipe enters on filter cloth, flue gas are blown into the limewash of desulfurization pond (16) from short metal pipe and remove cigarette Sulfur dioxide in gas, the limewash in desulfurization lime pump handle desulfurization pond beat circulation stirring;Or industrial hot water is from section One end of rectangular metal tube is rectangular metal into section, is then the other end of rectangular metal tube from section After out, section enters industrial cycle water pipe for the other end of rectangular metal tube;With light salt brine pump (15) heating of being exposed to the sun After hot sea water or hot industrial brine in pond (5) are extracted out, successively by the cold passage of strong brine regenerative heater (10), fresh water The cold passage of regenerative heater (11), the light salt brine Pneumatic butterfly valve (17) of each group and light salt brine threeway are from vertically-mounted each group stone The top center of black alkene or CNT hotting mask saline treatment film core (1) enters at graphene or CNT hotting mask salt solution Manage the salt pool of film core (1);The graphene or CNT hotting mask (103) of internal layer connect direct current positive pole, the graphene of outer layer or CNT hotting mask (103) connects direct current negative pole, and computer controller is according to graphene or CNT hotting mask saline treatment film core (1) the brine temp information that probe of the salt pool equipped with temperature sensor or temperature detect switch (TDS) detects, the stone of internal layer is adjusted The voltage of direct current between black alkene or CNT hotting mask (103) and the graphene or CNT hotting mask (103) of outer layer, stone The anionic metal in the salt pool of black alkene or CNT hotting mask saline treatment film core (1) is in the graphene or nanometer close to internal layer Be ostracised during carbon pipe hotting mask (103) positive pole, metal molecules of salt can not pass through internal layer graphene or CNT hotting mask (103) just Pole and the graphene or CNT hotting mask (103) negative pole of outer layer;Graphene or CNT hotting mask saline treatment film core (1) Between the graphene or CNT hotting mask (103) positive pole of internal layer and the graphene of outer layer or CNT hotting mask (103) negative pole Although accompanying insulation water permeable membrane, pass through in the graphene of internal layer or the fresh water of CNT hotting mask (103) positive pole containing few Measure salt, be the very big conductor of resistance, the graphene or the graphene or nanometer of CNT hotting mask (103) positive pole and outer layer of internal layer , can be in the graphene or CNT hotting mask (103) positive pole and outer layer of internal layer after carbon pipe hotting mask (103) negative pole connects direct current Electric current is produced between graphene or CNT hotting mask (103) negative pole, heats the graphene or CNT hotting mask (103) of internal layer With the graphene or CNT hotting mask (103) of outer layer, heat close to the graphene of internal layer or the sea of CNT hotting mask (103) Water or industrial brine and the close graphene of outer layer or the fresh water of CNT hotting mask (103), seawater and industrial brine are added Reduce the viscosity of seawater or industrial brine after heat, the hydrone in hot sea water or hot industrial brine is easily through internal layer Graphene or the graphene or CNT hotting mask (103) of CNT hotting mask (103) and outer layer reach graphene or nanometer The fresh water area of carbon pipe hotting mask saline treatment film core (1), the graphene or CNT hotting mask (103) and outer layer of the internal layer after heating Graphene or the micropore of CNT hotting mask (103) become penetrating, the hydrone in hot sea water or hot industrial brine holds very much Easily pass through the micropore of the graphene of internal layer or the graphene or CNT hotting mask (103) of CNT hotting mask (103) and outer layer; Or connect the live wire of alternating current, graphene or the CNT heat of internal layer in the graphene or CNT hotting mask (103) of outer layer Film (103) connects alternating current zero line, and computer controller fills according to graphene or CNT hotting mask saline treatment film core (1) salt pool The seawater or industrial brine temperature information that the probe for having temperature sensor either temperature detect switch (TDS) detects, adjust the graphite of outer layer The voltage for the alternating current being passed through between alkene or the graphene or CNT hotting mask (103) of CNT hotting mask (103) and internal layer, The graphene or CNT hotting mask (103) of outer layer and graphene or the CNT hotting mask (103) of internal layer although between accompany Insulate water permeable membrane, but through internal layer graphene or CNT hotting mask (103) fresh water containing a small amount of salt, be resistance very Big conductor, the graphene or CNT hotting mask (103) of outer layer are passed through with the graphene or CNT hotting mask (103) of internal layer , can be in the graphene or CNT hotting mask (103) of the graphene or CNT hotting mask (103) and internal layer of outer layer after alternating current Between produce electric current, heat the graphene or the graphene or CNT hotting mask of CNT hotting mask (1) and internal layer of outer layer (103), heat close to the graphene of internal layer or the seawater or industrial brine of CNT hotting mask (103) and the stone close to outer layer The fresh water of black alkene or CNT hotting mask (103), seawater either reduce seawater or industrial brine after industrial brine is heated Viscosity, the graphene or CNT hotting mask of hydrone in hot sea water or hot industrial brine easily through internal layer (103) and the graphene of outer layer or CNT hotting mask (103) reach graphene or CNT hotting mask saline treatment film core (1) Fresh water area, the graphene or CNT hotting mask (103) of the outer layer after heating and the graphene or CNT hotting mask of internal layer (103) micropore becomes penetrating, the hydrone in hot sea water or hot industrial brine easily through internal layer graphene or receive Rice carbon pipe hotting mask (103) and the graphene of outer layer or the micropore of CNT hotting mask (103);Or graphene to individual layer or receive Rice carbon pipe hotting mask (103) is passed through direct current, heat individual layer graphene or CNT hotting mask (103) and neighbouring seawater or Industrial brine and fresh water, computer controller is according to graphene or CNT hotting mask saline treatment film core (1) salt pool equipped with temperature The seawater or industrial brine temperature information that the probe of degree sensor either temperature detect switch (TDS) detects, adjust individual layer graphene or The voltage for the direct current that CNT hotting mask (103) is passed through, the graphene or CNT hotting mask (103) of individual layer are heated rear list The graphene or the micropore of CNT hotting mask (103) of layer become penetrating, seawater after either industrial brine is heated seawater or The viscosity of industrial brine reduces, Brownian movement increase, and the hydrone in hot sea water or hot industrial brine is easily through individual layer Graphene or CNT hotting mask (103) micropore;Or the graphene or CNT hotting mask (103) of individual layer are passed through exchange Electricity, heat the graphene or CNT hotting mask (103) and neighbouring seawater or industrial brine and fresh water of individual layer, computer control Instrument is according to the spy of graphene or CNT hotting mask saline treatment film core (1) salt pool equipped with temperature sensor or temperature detect switch (TDS) The head seawater or industrial brine temperature information that detect, adjust the graphene of individual layer or CNT hotting mask (103) is passed through The voltage of alternating current, the graphene or CNT hotting mask (103) of individual layer are heated the graphene or CNT heat of rear individual layer The micropore of film (103) becomes penetrating, and either the viscosity of the heated rear seawater of industrial brine or industrial brine reduces seawater, heat sea Hydrone in water or industrial brine is easily through the graphene of individual layer or the micropore of CNT hotting mask (103);Graphite After alkene or CNT hotting mask saline treatment film core (1) use setting time, graphene or CNT hotting mask saline treatment The seawater or industrial brine concentration in the salt pool of film core (1) reach setting value, and computer controller can be given and open this group of strong brine Pneumatic butterfly valve (18), go out from the bottom centre position salt pool of this group of graphene or CNT hotting mask saline treatment film core (1) The concentrated seawater or strong brine come is successively by this group of strong brine four-way, this group of strong brine Pneumatic butterfly valve (18) and strong brine regeneration The passage of heat heating brackish water of heater (10) is transported to strong brine pond (6) again;Hydrone in seawater or industrial brine is worn Bilayer or single-layer graphene or CNT hotting mask (103) fresh water area of the group are crossed, then from this group of graphene or nano-sized carbon This group of fresh water threeway, this group of fresh water Pneumatic butterfly valve pass through successively after coming out in the lower end fresh water area of pipe hotting mask saline treatment film core (1) (22) and the passage of heat of fresh water regenerative heater (11) to flow to fresh-water pool (7) inner;Graphene or CNT hotting mask saline treatment Film core (1), which runs a bit of time, will block a little, it is necessary to just rinsing once, periodically open positive flushing group electromagnetic gas valve (27), the inner compressed air of air accumulator (8) successively the electromagnetic gas valve (27) Jing Guo positive flushing group, strong brine four-way from graphene or The bottom centre position of CNT hotting mask saline treatment film core (1) enters positive flushing group graphene or CNT hotting mask salt solution The salt pool of process film core (1), then pass through the micro- of positive flushing group bilayer or single-layer graphene or CNT hotting mask (103) Hole;Graphene or CNT hotting mask saline treatment film core (1) use setting time to block, it is necessary to graphene or receive Rice carbon pipe hotting mask saline treatment film core (1) is once backwashed:Close the light salt brine Pneumatic butterfly valve (17) of backwash group, dense sea Water Pneumatic butterfly valve (18) and fresh water Pneumatic butterfly valve (17), backwash Pneumatic butterfly valve (23), the energy regenerating for opening backwash group enter Water Pneumatic butterfly valve (19);Backwash Pneumatic butterfly valve (23), the energy regenerating water inlet Pneumatic butterfly valve (19) of energy regenerating group are closed, is beaten Open the energy regenerating water outlet Pneumatic butterfly valve (20) of energy regenerating group;Backwashing pump (24) extracts fresh water from fresh-water pool (7), by anti- The backwash Pneumatic butterfly valve (23) of flushing group enters the graphene or CNT hotting mask saline treatment film core (1) of backwash group Fresh water area, the bilayer or the micropore of single-layer graphene or CNT hotting mask (1003) for then passing through backwash group reach recoil Wash group graphene or CNT hotting mask saline treatment film core (1) salt pool;From backwash group graphene or CNT hotting mask The concentrated seawater or strong brine that the salt pool of saline treatment film core (11) comes out are by the pneumatic butterfly of backwash group energy regenerating water inlet The big pipe (201) of valve (19) into recuperator (2) is inner to promote big piston (203) mobile, and big piston (203) passes through connecting rod (205) drive valve piston (204) mobile the energy of small pipe (202) inner seawater or industrial brine Jing Guo energy regenerating group Reclaim the salt solution of water outlet Pneumatic butterfly valve (20) press-in energy regenerating group graphene or CNT hotting mask saline treatment film core (1) Area, then the hydrone in seawater or industrial brine is through the double-deck revolution single-layer graphene of energy regenerating group or CNT warm The micropore of film (103) reaches fresh water area, and energy regenerating is closed backwash group energy regenerating water inlet Pneumatic butterfly valve (19) after terminating, beaten Begin to rehearse water Pneumatic butterfly valve (21) and energy regenerating group light salt brine Pneumatic butterfly valve (17), and seawater or industrial brine pass through energy regenerating The light salt brine Pneumatic butterfly valve (17) and energy regenerating water outlet Pneumatic butterfly valve (20) of group enter the small pipe of recuperator (2) (202) inner promotion valve piston (204) is mobile, and valve piston (204) drives big piston (203) mobile by connecting rod (205), big piston (203) the inner concentrated seawater of big pipe (201) or strong brine are entered strong brine regenerative heater by draining Pneumatic butterfly valve (10) the passage of heat, draining Pneumatic butterfly valve (21) and energy regenerating group energy regenerating water outlet Pneumatic butterfly valve (20) are then shut off, arranged Water process terminates;When the number that a graphene or CNT hotting mask saline treatment film core (1) backwash reaches setting number Afterwards, the graphene or CNT hotting mask saline treatment film core (1) need blowback of progress to lead to:Close the recoil of the logical group of blowback Wash Pneumatic butterfly valve (23), fresh water Pneumatic butterfly valve (17), light salt brine Pneumatic butterfly valve (17), energy regenerating water outlet Pneumatic butterfly valve (20) and Energy regenerating water inlet Pneumatic butterfly valve (19), open the wind Pneumatic butterfly valve (25) and strong brine Pneumatic butterfly valve (18) of the logical group of blowback;From The wind that Roots blower (26) comes out is by the logical group wind Pneumatic butterfly valve (25) of blowback, from the logical group graphene of blowback or CNT heat The upper end of film saline treatment film core (1) enters the fresh water of the logical group graphene of blowback or CNT hotting mask saline treatment film (1) core Area, then pass through the logical group bilayer of blowback or the micropore of single-layer graphene or CNT hotting mask (103);After the logical end of blowback, The wind Pneumatic butterfly valve (25) and concentrated water Pneumatic butterfly valve (18) of the logical group of blowback are closed, opens the light salt brine Pneumatic butterfly valve of the logical group of blowback (17) desalinization or industrial brine processing and fresh water Pneumatic butterfly valve (22), are restarted.
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