CN107413532A - A kind of copper ore floatation agent - Google Patents
A kind of copper ore floatation agent Download PDFInfo
- Publication number
- CN107413532A CN107413532A CN201710915362.7A CN201710915362A CN107413532A CN 107413532 A CN107413532 A CN 107413532A CN 201710915362 A CN201710915362 A CN 201710915362A CN 107413532 A CN107413532 A CN 107413532A
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- copper
- copper ore
- ore floatation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
Abstract
The invention discloses a kind of copper ore floatation agent, it is made up of the raw material of following parts by weight：30~60 parts of copper sulphate, 45~70 parts of sodium isobutyl xanthan, 20~40 parts of ammonium dibutyl dithiophosphate, 14~20 parts of neopelex, 8~16 parts of nonyl sodium xanthogenate, 4~8 parts of sodium metasilicate, 9~14 parts of calgon, 10~24 parts of vulcanized sodium, 1.5~2.5 parts of polyoxylethylene abietate, 5.5~9.2 parts of dimethicone, 15~30 parts of butyl ammonium aerofloat, 10~30 parts of second class xanthate, 10~20 parts of terpenic oil, 2~8 parts of ethyl ammonia sulfate.The copper ore floatation agent of the present invention, flotation speed is fast, and foam is few and tiny, favourable mineral recovery, while the flotation agent prescription constituent source is sufficient and cheap, and use is cost-effective, and the scope of application is wide.
Description
Technical field
The present invention relates to flotation agent technical field, and in particular to a kind of copper ore floatation agent.
Background technology
Flotation is to utilize the difference of mineral surfaces hydrophobic-hydrophilic, a kind of method being processed to mineral.Utilize mineral
The physical chemical differences on surface sort the process of mineral grain, are once called as floating separation, are most widely used beneficiation methods.
Almost all of ore can all be sorted with flotation.As gold mine, silver ore, galena, zincblende, chalcopyrite, vitreous copper, molybdenite,
The sulfide minerals such as pentlandite are malachite, cerussite, smithsonite, smithsonite and bloodstone, cassiterite, wolframite, ilmenite, green
The oxide mineral such as pillar, spodumene and rare-earth mineral, uranium ore sorts.Graphite, sulphur, diamond, quartz, mica,
The nonmetallic minerals such as feldspar and the nonmetallic saline minerals such as silicate mineral and fluorite, apatite, barite and sylvite, rock salt etc.
Solubility salt mineral sort.Although sorting for ore can also be carried out using the hydrophobic nature of mineral, generally all make
With floating agent to increase or reduce the hydrophobicity of mineral surfaces, adjustment controls the flotation behavior of mineral.It is thin that flotation is suitable to processing
Grain and fine granule material, it is difficult to fine mineral particle of the recovery less than 10 μm with other beneficiation methods, can be also handled with floatation.Some
The flotation technology of special disposal superfine particle, recyclable granularity lower limit is lower, ultra-fine flotation and ion flotation technology can reclaim from
Colloidal solid in molecule, ionic condition all kinds of materials.Flotation can also sort the intermediate products of pyrometallurgy, volatile matter and stove
The precipitated product of useful component in slag, processing hydrometallurgy leached mud and displacement, recovery chemical products (live by such as paper pulp, surface
Property material etc.) and inorganic matter and organic matter in waste water.
Floating agent substantially belongs to a special part of applied chemistry.Utilize chemicals, particularly organic chemistry
Physics occurs for medicine and specific mineral surfaces or chemical absorption, is reached and other mineral or gangue point by method for floating
From purpose.
The content of the invention
It is an object of the invention to provide a kind of copper ore floatation agent, the flotation agent can have collecting ability it is relatively strong, to hydraulic
Degree is more sensitive, not oxidizable, foaming power is strong, detergency is high, easy and various additive compounds, lower-cost feature.
To achieve the above object, the invention provides a kind of copper ore floatation agent, it is made up of the raw material of following parts by weight：Sulfuric acid
30~60 parts of copper, 45~70 parts of sodium isobutyl xanthan, 20~40 parts of ammonium dibutyl dithiophosphate, DBSA
14~20 parts of sodium, 8~16 parts of nonyl sodium xanthogenate, 4~8 parts of sodium metasilicate, 9~14 parts of calgon, 10~24 parts of vulcanized sodium,
1.5~2.5 parts of polyoxylethylene abietate, 5.5~9.2 parts of dimethicone, 15~30 parts of butyl ammonium aerofloat, second class xanthate 10~
30 parts, 10~20 parts of terpenic oil, 2~8 parts of ethyl ammonia sulfate.
Preferably, the copper ore floatation agent is made up of the raw material of following parts by weight：40~50 parts of copper sulphate, isobutyl group xanthan
Sour 50~60 parts of sodium, 25~35 parts of ammonium dibutyl dithiophosphate, 16~18 parts of neopelex, nonyl xanthic acid
10~14 parts of sodium, 5~7 parts of sodium metasilicate, 11~13 parts of calgon, 15~20 parts of vulcanized sodium, polyoxylethylene abietate 1.8
~2.4 parts, 6.5~8.2 parts of dimethicone, 20~28 parts of butyl ammonium aerofloat, 15~25 parts of second class xanthate, terpenic oil 12~18
Part, 4~6 parts of ethyl ammonia sulfate.
Preferably, the copper ore floatation agent is made up of the raw material of following parts by weight：45 parts of copper sulphate, sodium isobutyl xanthan
55 parts, 30 parts of ammonium dibutyl dithiophosphate, 17 parts of neopelex, 12 parts of nonyl sodium xanthogenate, sodium metasilicate 6
Part, 12 parts of calgon, 17 parts of vulcanized sodium, 2.2 parts of polyoxylethylene abietate, 6.9 parts of dimethicone, butyl ammonium aerofloat 24
Part, 20 parts of second class xanthate, 15 parts of terpenic oil, 5 parts of ethyl ammonia sulfate.
Preferably, the copper ore floatation agent using when be configured to volume fraction be 35%~50% the aqueous solution.
The copper ore floatation agent of the present invention, flotation speed is fast, and foam is few and tiny, favourable mineral recovery, while the flotation agent
Formula constituent source is sufficient and cheap, and use is cost-effective, and the scope of application is wide.
Embodiment
The present invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1
A kind of copper ore floatation agent, is made up of the raw material of following parts by weight：30 parts of copper sulphate, 45 parts of sodium isobutyl xanthan,
20 parts of ammonium dibutyl dithiophosphate, 14 parts of neopelex, 8 parts of nonyl sodium xanthogenate, 4 parts of sodium metasilicate, six is inclined
9 parts of sodium phosphate, 10 parts of vulcanized sodium, 1.5 parts of polyoxylethylene abietate, 5.5 parts of dimethicone, 15 parts of butyl ammonium aerofloat, second class
10 parts of xanthate, 10 parts of terpenic oil, 2 parts of ethyl ammonia sulfate.
The copper ore floatation agent using when be configured to volume fraction be 35% the aqueous solution.
Embodiment 2
A kind of copper ore floatation agent, is made up of the raw material of following parts by weight：40 parts of copper sulphate, 50 parts of sodium isobutyl xanthan,
25 parts of ammonium dibutyl dithiophosphate, 16 parts of neopelex, 10 parts of nonyl sodium xanthogenate, 5 parts of sodium metasilicate, six is inclined
11 parts of sodium phosphate, 15 parts of vulcanized sodium, 1.8 parts of polyoxylethylene abietate, 6.5 parts of dimethicone, 20 parts of butyl ammonium aerofloat, second class
15 parts of xanthate, 12 parts of terpenic oil, 4 parts of ethyl ammonia sulfate.
The copper ore floatation agent using when be configured to volume fraction be 38% the aqueous solution.
Embodiment 3
A kind of copper ore floatation agent, is made up of the raw material of following parts by weight：45 parts of copper sulphate, 55 parts of sodium isobutyl xanthan,
30 parts of ammonium dibutyl dithiophosphate, 17 parts of neopelex, 12 parts of nonyl sodium xanthogenate, 6 parts of sodium metasilicate, six is inclined
12 parts of sodium phosphate, 17 parts of vulcanized sodium, 2.2 parts of polyoxylethylene abietate, 6.9 parts of dimethicone, 24 parts of butyl ammonium aerofloat, second class
20 parts of xanthate, 15 parts of terpenic oil, 5 parts of ethyl ammonia sulfate.
The copper ore floatation agent using when be configured to volume fraction be 40% the aqueous solution.
Embodiment 4
A kind of copper ore floatation agent, is made up of the raw material of following parts by weight：50 parts of copper sulphate, 60 parts of sodium isobutyl xanthan,
35 parts of ammonium dibutyl dithiophosphate, 18 parts of neopelex, 14 parts of nonyl sodium xanthogenate, 7 parts of sodium metasilicate, six is inclined
13 parts of sodium phosphate, 20 parts of vulcanized sodium, 2.4 parts of polyoxylethylene abietate, 8.2 parts of dimethicone, 28 parts of butyl ammonium aerofloat, second class
25 parts of xanthate, 18 parts of terpenic oil, 6 parts of ethyl ammonia sulfate.
The copper ore floatation agent using when be configured to volume fraction be 45% the aqueous solution.
Embodiment 5
A kind of copper ore floatation agent, is made up of the raw material of following parts by weight：60 parts of copper sulphate, 70 parts of sodium isobutyl xanthan,
40 parts of ammonium dibutyl dithiophosphate, 20 parts of neopelex, 16 parts of nonyl sodium xanthogenate, 8 parts of sodium metasilicate, six is inclined
14 parts of sodium phosphate, 24 parts of vulcanized sodium, 2.5 parts of polyoxylethylene abietate, 9.2 parts of dimethicone, 30 parts of butyl ammonium aerofloat, second class
30 parts of xanthate, 20 parts of terpenic oil, 8 parts of ethyl ammonia sulfate.
The copper ore floatation agent using when be configured to volume fraction be 50% the aqueous solution.
Claims (4)
1. a kind of copper ore floatation agent, it is characterised in that be made up of the raw material of following parts by weight：30~60 parts of copper sulphate, isobutyl group
45~70 parts of sodium xanthogenate, 20~40 parts of ammonium dibutyl dithiophosphate, 14~20 parts of neopelex, nonyl are yellow
8~16 parts of ortho acid sodium, 4~8 parts of sodium metasilicate, 9~14 parts of calgon, 10~24 parts of vulcanized sodium, polyoxylethylene abietate
1.5~2.5 parts, 5.5~9.2 parts of dimethicone, 15~30 parts of butyl ammonium aerofloat, 10~30 parts of second class xanthate, terpenic oil 10~
20 parts, 2~8 parts of ethyl ammonia sulfate.
2. a kind of copper ore floatation agent as claimed in claim 1, it is characterised in that be made up of the raw material of following parts by weight：Sulfuric acid
40~50 parts of copper, 50~60 parts of sodium isobutyl xanthan, 25~35 parts of ammonium dibutyl dithiophosphate, DBSA
16~18 parts of sodium, 10~14 parts of nonyl sodium xanthogenate, 5~7 parts of sodium metasilicate, 11~13 parts of calgon, vulcanized sodium 15~20
Part, 1.8~2.4 parts of polyoxylethylene abietate, 6.5~8.2 parts of dimethicone, 20~28 parts of butyl ammonium aerofloat, second class xanthate
15~25 parts, 12~18 parts of terpenic oil, 4~6 parts of ethyl ammonia sulfate.
3. a kind of copper ore floatation agent as claimed in claim 2, it is characterised in that be made up of the raw material of following parts by weight：Sulfuric acid
45 parts of copper, 55 parts of sodium isobutyl xanthan, 30 parts of ammonium dibutyl dithiophosphate, 17 parts of neopelex, nonyl
12 parts of sodium xanthogenate, 6 parts of sodium metasilicate, 12 parts of calgon, 17 parts of vulcanized sodium, 2.2 parts of polyoxylethylene abietate, dimethyl
6.9 parts of silicone oil, 24 parts of butyl ammonium aerofloat, 20 parts of second class xanthate, 15 parts of terpenic oil, 5 parts of ethyl ammonia sulfate.
A kind of 4. copper ore floatation agent according to claim 1 or 2, it is characterised in that：Match somebody with somebody during the copper ore floatation agent use
The aqueous solution that volume fraction is 35%~50% is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710915362.7A CN107413532A (en) | 2017-09-30 | 2017-09-30 | A kind of copper ore floatation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710915362.7A CN107413532A (en) | 2017-09-30 | 2017-09-30 | A kind of copper ore floatation agent |
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| Publication Number | Publication Date |
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| CN107413532A true CN107413532A (en) | 2017-12-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710915362.7A Pending CN107413532A (en) | 2017-09-30 | 2017-09-30 | A kind of copper ore floatation agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108906334A (en) * | 2018-06-25 | 2018-11-30 | 怀宁县江镇代家凹铜矿有限公司 | A kind of chalcopyrite flotation agent |
| CN111346739A (en) * | 2018-12-22 | 2020-06-30 | 平顶山泰克斯特高级润滑油有限公司 | Environment-friendly high-performance mining flotation agent |
| CN113171880A (en) * | 2021-04-23 | 2021-07-27 | 中国矿业大学 | Flotation composite dispersant for lean and fine chalcopyrite and flotation method for lean and fine chalcopyrite |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103894294A (en) * | 2014-03-12 | 2014-07-02 | 玉门大昌矿业有限公司 | Copper oxide ore flotation agent |
| CN104759354A (en) * | 2015-03-11 | 2015-07-08 | 铜陵鑫腾矿业科技有限公司 | Composite type copper mine flotation agent |
| CN104772221A (en) * | 2015-03-11 | 2015-07-15 | 铜陵鑫腾矿业科技有限公司 | Combined reagent |
| CN105381886A (en) * | 2015-12-14 | 2016-03-09 | 灵宝金源晨光有色矿冶有限公司 | Flotation reagent for gold-containing thiocyanic castaway slag |
| CN106311486A (en) * | 2016-08-24 | 2017-01-11 | 廖继华 | Improved copper-cobalt flotation agent |
-
2017
- 2017-09-30 CN CN201710915362.7A patent/CN107413532A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103894294A (en) * | 2014-03-12 | 2014-07-02 | 玉门大昌矿业有限公司 | Copper oxide ore flotation agent |
| CN104759354A (en) * | 2015-03-11 | 2015-07-08 | 铜陵鑫腾矿业科技有限公司 | Composite type copper mine flotation agent |
| CN104772221A (en) * | 2015-03-11 | 2015-07-15 | 铜陵鑫腾矿业科技有限公司 | Combined reagent |
| CN105381886A (en) * | 2015-12-14 | 2016-03-09 | 灵宝金源晨光有色矿冶有限公司 | Flotation reagent for gold-containing thiocyanic castaway slag |
| CN106311486A (en) * | 2016-08-24 | 2017-01-11 | 廖继华 | Improved copper-cobalt flotation agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108906334A (en) * | 2018-06-25 | 2018-11-30 | 怀宁县江镇代家凹铜矿有限公司 | A kind of chalcopyrite flotation agent |
| CN111346739A (en) * | 2018-12-22 | 2020-06-30 | 平顶山泰克斯特高级润滑油有限公司 | Environment-friendly high-performance mining flotation agent |
| CN113171880A (en) * | 2021-04-23 | 2021-07-27 | 中国矿业大学 | Flotation composite dispersant for lean and fine chalcopyrite and flotation method for lean and fine chalcopyrite |
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| PB01 | Publication | ||
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Application publication date: 20171201 |