CN107400324A - Spraying-free metal effect improves idle call ABS composite material of current mark and preparation method thereof - Google Patents
Spraying-free metal effect improves idle call ABS composite material of current mark and preparation method thereof Download PDFInfo
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
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Abstract
The present invention provides idle call ABS composite material that a kind of spraying-free metal effect improves current mark and preparation method thereof, is related to technical field of polymer materials.The idle call ABS composite material that spraying-free metal effect of the present invention improves current mark includes following raw material：ABS resin, PMMA resins, white oil, glass fibre, Nano filling, metal dust, coupling agent, lubricant, antioxidant, compatilizer, heat stabilizer.The idle call ABS composite material impact strength of spraying-free metal effect improvement current mark of the present invention, heat resistance, tensile strength, thermostabilization are good, weatherability is strong, after the material is prepared into air-conditioning material, has and exempt from spraying, metal effect, improve current mark, beautiful in colour, glossy effect.
Description
Technical field
The present invention relates to technical field of polymer materials, and in particular to a kind of spraying-free metal effect improves the idle call of current mark
ABS composite material and preparation method thereof.
Background technology
Acrylonitrile-butadiene-styrene terpolymer（ABS）Resin is one of five big synthetic resin, its impact resistance,
Heat resistance, lower temperature resistance, chemical proofing and excellent electrical properties, also with easy processing, product size stabilization, lustrous surface
The features such as property is good；Polymethyl methacrylate abbreviation code name is PMMA, is commonly called as lucite, is to synthesize transparent material so far
Middle quality is most excellent, and price is again than convenient kind.Their easy application, colorings, surface metallization, electricity can also be carried out
The secondary operation such as plating, welding, hot pressing and bonding, are widely used in machinery, automobile, electronic apparatus, instrument and meter, weaving and building
Deng industrial circle.
ABS is the engineering plastics of high comprehensive performance, has excellent impact resistance, good cryogenic property and resistance toization
Medicine is learned, high abrasion resistance, good stability of the dimension, lustrous surface is good, easy application and coloring etc., but ABS lacks in the presence of some
Fall into, such as melt viscosity height, poor fluidity, heat endurance and weatherability are bad.
Currently used in the market to exempt to spray high-light ABS resin, processing technology is substantially added using ABS resins
PMMA resins and compatilizer MBS are made, but this ABS resins have following defect in actual production：1）By
It is incompatible with the free acrylonitrile in ABS resins in PMMA, cause PMMA resins to be deposited with ABS resins in microcosmic phase
In phenomenon of phase separation, therefore the alloy material is not homogeneous system, is gone out after causing the dyeing material in the product of injection molding
Existing color spot, therefore product qualification rate is low when the material has injection molding, and substantial amounts of waste material is caused in actual production.2）By
In the opacity of ABS resin in itself, therefore the alloy material is also opaque, so as to cause the process that material dyes in the later stage
In in order to reach beautiful in colour, glossy effect just need to add more toners or even using the higher dyestuff of price, therefore
Substantially increase the cost price using the material.
The content of the invention
In view of the shortcomings of the prior art, the idle call ABS that a kind of spraying-free metal effect of present invention offer improves current mark is compound
Material and preparation method thereof.
To realize object above, technical scheme is achieved by the following technical programs：
A kind of spraying-free metal effect improves the idle call ABS composite material of current mark, and the spraying-free metal effect improves current mark
Idle call ABS composite material be made up of the raw material of following parts by weight：ABS resin 30-70 parts, PMMA resin 20-50 parts, white oil
10-16 parts, glass fibre 12-19 parts, Nano filling 10-19 parts, metal dust 12-16 parts, coupling agent 1-5 parts, lubricant 2-6
Part, antioxidant 0.3-0.8 parts, compatilizer 1-5 parts, heat stabilizer 1-5 parts, and glass fibre is chopped fiber.
It is further preferred that one kind in the coupling agent silane coupler, aluminate coupling agent.
It is further preferred that the ABS resin be MBS, acrylonitrile-
One kind in styrol copolymer, and ABS resin under the conditions of 200 DEG C/5kg, melt index 25-35g/10min.
It is further preferred that the lubricant is stearic acid pentaerythritol ester, stearic acid, calcium stearate, lignite wax, contained
At least one of polyester construction long-chain alcohol ester.
It is further preferred that the metal dust is one kind in tin metal, bismuth metal, sn-bi alloy, leypewter.
It is further preferred that the antioxidant is four (β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid) Ji Wusi
Alcohol ester, β-(4- hydroxy phenyl -3,5- di-t-butyls) positive octadecanol ester of propionic acid, DBPC 2,6 ditertiary butyl p cresol, 4,4'- sulphur
Dai Shuan (the 6- tert-butyl groups -3-（Methyl）At least one of phenol).
It is further preferred that the compatilizer is maleic anhydride inoculated polypropylene, phenylethylene-maleic anhydride random copolymerization
At least one of thing, chromium of organic acid complex compound, organic coupling agent, titanate coupling agent, aluminate coupling agent.
It is further preferred that the Nano filling is the treated nano level montmorillonite in surface, talcum powder, kaolinite
One kind in soil, calcium carbonate, magnesium hydroxide, aluminium hydroxide, the particle diameter of the Nano filling is 10-150nm.
It is further preferred that the heat stabilizer for styrene-acrylonitrile-GMA ternary without
Advise one kind in copolymer, phosphoric acid salt stabilizer.
A kind of spraying-free metal effect improves the preparation method of the idle call ABS composite material of current mark, comprises the following steps：
S1, according to parts by weight weigh each raw material.
S2, by ABS resin, PMMA resins, glass fibre, Nano filling, lubricant, antioxidant, compatilizer, thermostabilization
It is well mixed in agent input mixer, obtains mixed material A；
S3, toughener, coupling agent, white oil mixed, oil-filled 5-8min adds metal dust, puts into mixer when stirring
Between be 10-15min, obtain mixed material B.
S4, by mixed material A add double screw extruder main feed hopper in, by mixed material B addition twin-screw squeeze
Go out in the hopper of side feeding of machine, extruding pelletization, you can；And each area's temperature of extruder is 210-230 DEG C, when extruder is granulated
Vacuum be 0.2MPa-0.4MPa.
The present invention provides idle call ABS composite material that a kind of spraying-free metal effect improves current mark and preparation method thereof,
Advantage is compared with prior art：
Spraying-free metal effect of the present invention improve the idle call ABS composite material impact strength of current mark, heat resistance, tensile strength,
The performances such as molding shrinkage are obviously improved, and the material melt viscosity is low, and good fluidity, thermostabilization is good, and weatherability is strong, the material system
It is standby into after air-conditioning material, have and exempt from spraying, metal effect, improvement current mark, beautiful in colour, glossy effect.
Spraying-free metal effect of the present invention improves the idle call ABS composite material of current mark, by adding compatilizer in raw material
And toughener improves the adhesion and compatibility between ABS composites resin and PMMA resins, and then improve composite wood
The toughness of material, then by the addition of glass fibre, Nano filling, metal dust come balancing material metal effect, high glaze and
Contradiction between toughness；Composite has the advantages that to exempt from spraying, high glaze, high-impact, can be widely applied for household electrical appliances, sky
Tune, fascia etc. make.
Composite material preparation process of the present invention is simple, and the composite of preparation has a wide range of application.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, with reference to the embodiment of the present invention pair
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, rather than whole embodiments；Based on the embodiment in the present invention, those of ordinary skill in the art are not making wound
The every other embodiment obtained under the premise of the property made work, belongs to the scope of protection of the invention.
Embodiment 1：
The idle call ABS composite material that the present embodiment spraying-free metal effect improves current mark is made up of the raw material of following parts by weight：
30 parts of ABS resin, 20 parts of PMMA resins, 10 parts of white oil, 12 parts of glass fibre, 10 parts of Nano filling, 12 parts of metal dust, coupling
1 part of agent, 2 parts of lubricant, 0.3 part of antioxidant, 1 part of compatilizer, 1 part of heat stabilizer, and glass fibre are chopped fiber；Wherein,
ABS resin is MBS, and ABS resin under the conditions of 200 DEG C/5kg, melting
Index is 25-35g/10min；Coupling agent silane coupler；Lubricant be stearic acid pentaerythritol ester, stearic acid, calcium stearate,
Lignite wax, mix containing polyester construction long-chain alcohol ester；Antioxidant is four (β-(3,5- di-tert-butyl-hydroxy phenyls)
Propionic acid) pentaerythritol ester；Compatilizer is maleic anhydride inoculated polypropylene；Nano filling is the treated nano level illiteracy in surface
De- soil, the particle diameter of the Nano filling is 10nm；Heat stabilizer is the three of styrene-acrylonitrile-GMA
First random copolymer.
Spraying-free metal effect of the present invention improves the preparation method of the idle call ABS composite material of current mark, including following step
Suddenly：
S1, according to parts by weight weigh each raw material.
S2, by ABS resin, PMMA resins, glass fibre, Nano filling, lubricant, antioxidant, compatilizer, thermostabilization
It is well mixed in agent input mixer, obtains mixed material A；
S3, toughener, coupling agent, white oil mixed, oil-filled 5min adds metal dust, puts into mixing time in mixer
For 10min, mixed material B is obtained.
S4, by mixed material A add double screw extruder main feed hopper in, by mixed material B addition twin-screw squeeze
Go out in the hopper of side feeding of machine, extruding pelletization, you can；It is true when extruder is granulated and each area's temperature of extruder is 210 DEG C
Reciprocal of duty cycle is 0.2MPa.
Embodiment 2：
The idle call ABS composite material that the present embodiment spraying-free metal effect improves current mark is made up of the raw material of following parts by weight：
70 parts of ABS resin, 50 parts of PMMA resins, 16 parts of white oil, 19 parts of glass fibre, 19 parts of Nano filling, 16 parts of metal dust, coupling
5 parts of agent, 6 parts of lubricant, 0.8 part of antioxidant, 5 parts of compatilizer, 5 parts of heat stabilizer, and glass fibre are chopped fiber；Wherein,
ABS resin is acrylonitritrile-styrene resin, and ABS resin under the conditions of 200 DEG C/5kg, melt index 25-35g/
10min；Coupling agent aluminate coupling agent；Lubricant is stearic acid, calcium stearate, lignite wax mix；Antioxidant is
β-(4- hydroxy phenyl -3,5- di-t-butyls) positive octadecanol ester of propionic acid；Compatilizer is phenylethylene-maleic anhydride random copolymerization
Thing；Nano filling is the treated nano level kaolin in surface, and the particle diameter of the Nano filling is 150nm；Heat stabilizer is
Phosphoric acid salt stabilizer.
Spraying-free metal effect of the present invention improves the preparation method of the idle call ABS composite material of current mark, including following step
Suddenly：
S1, according to parts by weight weigh each raw material.
S2, by ABS resin, PMMA resins, glass fibre, Nano filling, lubricant, antioxidant, compatilizer, thermostabilization
It is well mixed in agent input mixer, obtains mixed material A；
S3, toughener, coupling agent, white oil mixed, oil-filled 8min adds metal dust, puts into mixing time in mixer
For 15min, mixed material B is obtained.
S4, by mixed material A add double screw extruder main feed hopper in, by mixed material B addition twin-screw squeeze
Go out in the hopper of side feeding of machine, extruding pelletization, you can；It is true when extruder is granulated and each area's temperature of extruder is 230 DEG C
Reciprocal of duty cycle is 0.4MPa.
Embodiment 3：
The idle call ABS composite material that the present embodiment spraying-free metal effect improves current mark is made up of the raw material of following parts by weight：
50 parts of ABS resin, 35 parts of PMMA resins, 13 parts of white oil, 16 parts of glass fibre, 15 parts of Nano filling, 14 parts of metal dust, coupling
3 parts of agent, 4 parts of lubricant, 0.6 part of antioxidant, 3 parts of compatilizer, 2 parts of heat stabilizer, and glass fibre are chopped fiber；Wherein,
ABS resin is acrylonitritrile-styrene resin, and ABS resin under the conditions of 200 DEG C/5kg, melt index 25-35g/
10min；Coupling agent aluminate coupling agent；Lubricant is lignite wax；Antioxidant is 4,4'- thiobis (the 6- tert-butyl groups -3-
（Methyl）Phenol)；Compatilizer is chromium of organic acid complex compound；Nano filling is the treated nano level talcum powder in surface, should
The particle diameter of Nano filling is 80nm；Heat stabilizer is randomly common for the ternary of styrene-acrylonitrile-GMA
Polymers.
Spraying-free metal effect of the present invention improves the preparation method of the idle call ABS composite material of current mark, including following step
Suddenly：
S1, according to parts by weight weigh each raw material.
S2, by ABS resin, PMMA resins, glass fibre, Nano filling, lubricant, antioxidant, compatilizer, thermostabilization
It is well mixed in agent input mixer, obtains mixed material A.
S3, toughener, coupling agent, white oil mixed, oil-filled 7min adds metal dust, puts into mixer and stirs
Time is 12min, obtains mixed material B.
S4, by mixed material A add double screw extruder main feed hopper in, by mixed material B addition twin-screw squeeze
Go out in the hopper of side feeding of machine, extruding pelletization, you can；It is true when extruder is granulated and each area's temperature of extruder is 220 DEG C
Reciprocal of duty cycle is 0.3MPa.
In summary, the idle call ABS composite material preparation technology of spraying-free metal effect improvement current mark of the present invention is simple,
The performances such as the material impact intensity, heat resistance, tensile strength, molding shrinkage are obviously improved, and the material melt viscosity is low, flowing
Property it is good, thermostabilization is good, and weatherability is strong, after the material is prepared into air-conditioning material, have exempt from spraying, metal effect, improvement current mark, color
Color gorgeous, glossy effect.
Spraying-free metal effect of the present invention improves the idle call ABS composite material of current mark, by adding compatilizer in raw material
And toughener improves the adhesion and compatibility between ABS composites resin and PMMA resins, and then improve composite wood
The toughness of material, then by the addition of glass fibre, Nano filling, metal dust come balancing material metal effect, high glaze and
Contradiction between toughness；The composite for being has the advantages that to exempt from spraying, high glaze, high-impact, can be widely applied for household electrical appliances,
Air-conditioning, fascia etc. make.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although ginseng
The present invention is described in detail according to previous embodiment, it will be understood by those within the art that：It still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic；And
These modifications are replaced, and the essence of appropriate technical solution is departed from the spirit and model of various embodiments of the present invention technical scheme
Enclose.
Claims (10)
1. a kind of spraying-free metal effect improves the idle call ABS composite material of current mark, it is characterised in that described to exempt from spray metal
The idle call ABS composite material of effect improved current mark is made up of the raw material of following parts by weight：ABS resin 30-70 parts, PMMA resins
20-50 parts, white oil 10-16 parts, glass fibre 12-19 parts, Nano filling 10-19 parts, metal dust 12-16 parts, coupling agent 1-5
Part, lubricant 2-6 parts, antioxidant 0.3-0.8 parts, compatilizer 1-5 parts, heat stabilizer 1-5 parts, and glass fibre are short fibre
Dimension.
2. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：One kind in the coupling agent silane coupler, aluminate coupling agent.
3. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The ABS resin is one in MBS, acrylonitritrile-styrene resin
Kind, and ABS resin under the conditions of 200 DEG C/5kg, melt index 25-35g/10min.
4. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The lubricant be stearic acid pentaerythritol ester, stearic acid, calcium stearate, lignite wax, containing in polyester construction long-chain alcohol ester
At least one.
5. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The metal dust is one kind in tin metal, bismuth metal, sn-bi alloy, leypewter.
6. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The antioxidant be four (β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol esters, β-(4- hydroxy phenyls-
3,5- di-t-butyls) the positive octadecanol ester of propionic acid, DBPC 2,6 ditertiary butyl p cresol, 4,4'- thiobis (the 6- tert-butyl groups -3-（First
Base）At least one of phenol).
7. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The compatilizer is maleic anhydride inoculated polypropylene, atactic styrene-maleic anhydride copolymer, chromium of organic acid complex compound, had
At least one of machine coupling agent, titanate coupling agent, aluminate coupling agent.
8. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The Nano filling be the treated nano level montmorillonite in surface, talcum powder, kaolin, calcium carbonate, magnesium hydroxide,
One kind in aluminium hydroxide, the particle diameter of the Nano filling is 10-150nm.
9. spraying-free metal effect according to claim 1 improves the idle call ABS composite material of current mark, its feature exists
In：The heat stabilizer is ternary atactic copolymer, the phosphoric acid salt of styrene-acrylonitrile-GMA
One kind in stabilizer.
10. a kind of spraying-free metal effect as described in claim 1-9 is any improves the system of the idle call ABS composite material of current mark
Preparation Method, it is characterised in that comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, PMMA resins, glass fibre, Nano filling, lubricant, antioxidant, compatilizer, heat stabilizer throw
Enter in mixer and be well mixed, obtain mixed material A；
S3, toughener, coupling agent, white oil mixed, oil-filled 5-8min adds metal dust, puts into mixer when stirring
Between be 10-15min, obtain mixed material B；
S4, by mixed material A add double screw extruder main feed hopper in, by mixed material B add double screw extruder
Side feeding hopper in, extruding pelletization, you can；It is true when extruder is granulated and each area's temperature of extruder is 210-230 DEG C
Reciprocal of duty cycle is 0.2MPa-0.4MPa.
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Cited By (6)
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|---|---|---|---|---|
| CN110157138A (en) * | 2018-02-12 | 2019-08-23 | 合肥杰事杰新材料股份有限公司 | One kind is exempted to spray pearly-lustre ABS material and preparation method thereof |
| CN110551367A (en) * | 2019-07-19 | 2019-12-10 | 深圳市高科塑化有限公司 | Piano black mirror surface gloss spray-free glass fiber reinforced PET (polyethylene terephthalate) polyester material and preparation method thereof |
| CN110643136A (en) * | 2019-09-25 | 2020-01-03 | 广东格瑞新材料股份有限公司 | Spraying-free ABS material and preparation method thereof |
| KR20200076231A (en) * | 2018-12-19 | 2020-06-29 | 주식회사 엘지화학 | Thermoplastic resin composition and product using same |
| CN112852098A (en) * | 2021-01-14 | 2021-05-28 | 珠海格力电器股份有限公司 | ABS-PMMA composite material and preparation method and application thereof |
| CN113512265A (en) * | 2021-07-29 | 2021-10-19 | 深圳免喷材料科技有限公司 | Preparation method of anodic oxidation effect imitation spraying-free aesthetic ABS material |
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| CN112852098A (en) * | 2021-01-14 | 2021-05-28 | 珠海格力电器股份有限公司 | ABS-PMMA composite material and preparation method and application thereof |
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