CN107397686A - One kind is continuously from composition, foam and its application - Google Patents

One kind is continuously from composition, foam and its application Download PDF

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Publication number
CN107397686A
CN107397686A CN201710594975.5A CN201710594975A CN107397686A CN 107397686 A CN107397686 A CN 107397686A CN 201710594975 A CN201710594975 A CN 201710594975A CN 107397686 A CN107397686 A CN 107397686A
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China
Prior art keywords
composition
foam
parts
present
continuously
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CN201710594975.5A
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Chinese (zh)
Inventor
崔黎
徐印飞
谢茹玉
洪国珊
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Guangzhou Green Technology Co Ltd
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Guangzhou Green Technology Co Ltd
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Priority to CN201710594975.5A priority Critical patent/CN107397686A/en
Publication of CN107397686A publication Critical patent/CN107397686A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to one kind continuously from composition, foam and its application.The component that following weight percentage is included from composition, foam of the present invention:Grease 1-15%, thickener 0.3-3%, self foaming agent 2-10% and surfactant 2-15%;Contain the medicine and cosmetics from composition, foam present invention also offers a kind of.It is provided by the present invention from composition, foam be a kind of with skin cleaning and the composition of massage effect, it is applied to the environmental toxin on clean skin, removing aging cutin cell and absorption skin, skin smooth is made after, pale, water is tender, moist, not tight.

Description

One kind is continuously from composition, foam and its application
Technical field
The present invention relates to a kind of composition and its application, and in particular to one kind is continuously from composition, foam and its application.
Background technology
Contain surfactant in cleaning cosmetics, it significantly reduces the surface tension of solution, changes the surface shape of system State, so as to produce a series of effects such as wetting, emulsification, foaming, solubilising, play and remove aging cutin cell, skin metabolism thing, dirt The effect of cosmetics residual on dirt and skin.Foaming agent easily discharges because vapour pressure is high in open space.Work as coating When on skin, continuously interacted from the surfactant in composition, foam and foaming agent because foaming agent continue outwards, Evaporated to open space, discharge and drive surfactant to form abundant bubble.Abundant closely knit bubble contributes to skin to clean, Bring the refrigerant impression releived.Cleaning products clean skin, remove dirt while, inevitably wash away sebum, destroy Skin barrier, increase skin trans epidermal water loss, make dry skin, it is tight, do not feel like oneself.
This continuously contains a large amount of greases from composition, foam, supplements grease immediately for the skin after washing, is brought to skin Moisturizing, make skin feel comfortable, not tight.In addition, according to the similar principle that mixes, can be by grease during washing one's face The oil-soluble filth of dissolving face, while assign this and continuously from the effectively gentle cleaning capacity of composition, foam and moisten comfortable Skin sense.Because surface-active objects system contain a large amount of greases can cause system it is unstable, layering, use of this composition through sieve The thickener of choosing and its appropriate ratio stably contain the surfactant system of a large amount of greases.
The content of the invention
A kind of continuously from composition, foam it is an object of the invention to be provided in place of overcome the deficiencies in the prior art, it is suitable Cosmetics are remained on clean skin, removing aging cutin cell, skin metabolism thing, dirt and skin, and skin is made after It is smooth, pale, water is tender, moist, not tight.
To achieve the above object, the technical scheme taken of the present invention is:One kind is continuously from composition, foam, comprising following heavy Measure the component of percentage:Grease 1-15%, thickener 0.3-3%, self foaming agent 2-10% and surfactant 2-15%.
Self foaming agent and thickener are with the addition of in the composition of the present invention, cosmetics made of the composition of the present invention are applied Smear after skin, can spontaneously, continuously produce bubble, abundant closely knit bubble makes skin cleaning become easy and gentle, And provide moisten comfortable skin sense, its be applied to clean skin, removing aging cutin cell, skin metabolism thing, dirt and Cosmetics remain on skin, skin smooth are made after, pale, water is tender, moist, not tight.
As of the present invention continuously from the preferred embodiment of composition, foam, the thickener accounts for described continuous spontaneous The percentage by weight of foaming composition is 1.8-3%.As of the present invention continuously from the more preferably embodiment party of composition, foam Formula, it is continuously 2% from the percentage by weight of composition, foam that the thickener, which accounts for described,.
The viscosity of formula is generally lifted in cosmetics using thickener, it is therefore an objective to change mobility and the surrender of product Value, it is often more important that lift the stability of product.Therefore thickener is widely used as a kind of important source material in cosmetics. Different types of thickener has its respective dose-effect relationship, though heavy dose of thickener can make product stable, also deposits simultaneously Negatively affecting, such as product appearance, provoking property and skin sense in terms of its performance.It is suitable by testing screening of the invention Thickener and optimize dosage, find when thickener account for it is described continuously from the percentage by weight of composition, foam for 1.8- 3%, when more preferably 2%, the resultant effect of stability and outward appearance, skin sense economy in product etc. is best.
Continuously gather as of the present invention from the preferred embodiment of composition, foam, the thickener including acrylate At least one of compound, natural polysaccharide, natural polysaccharide derivative, clay mineral, Modification of Clay Minerals product.
Continuously gather as of the present invention from the preferred embodiment of composition, foam, the thickener selected from acrylate Compound, cellulose gum, hydroxyethyl cellulose, modified starch, xanthans, carragheen, Magnesiumaluminumsilicate, lithium magnesium silicate, sodium magnesium silicate At least one of.As of the present invention continuously from the more preferably embodiment of composition, foam, the thickener is propylene Acid ester polymer.
Thickener in the present invention is hydrophilic thickeners, and source includes acrylate polymer, natural polysaccharide and its spread out Biology and clay mineral and its modified product, specifically selected from acrylate polymer, cellulose gum, modified starch, alumina silicate Magnesium, lithium magnesium silicate and sodium magnesium silicate.Thickener is preferably acrylate polymer.The present invention is it is demonstrated experimentally that alone acrylate Polymer just can stabilising system well.
As of the present invention continuously from the preferred embodiment of composition, foam, the self foaming agent account for it is described it is continuous from The percentage by weight of composition, foam is 5-7%.
Continuously perfluoro butyl is selected from as of the present invention from the preferred embodiment of composition, foam, the self foaming agent Methyl ether, methylperfluoroisobutylether, ethyl perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor isohexane, Decafluoropentane, two At least one of polysiloxanes.It is described spontaneous as of the present invention continuously from the more preferably embodiment of composition, foam Infusion is Decafluoropentane and two polysiloxanes.
The self foaming agent of the present invention uses volatility perfluoro alkane and dimethyl silicone polymer, the vapour pressure of these organic matters Height, easily discharged in open space.The present invention's is selected from perfluoro butyl methyl ether, methyl perfluoro isobutyl group using self foaming agent Ether, ethyl perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor isohexane, Decafluoropentane and two polysiloxanes, it is therefore preferable to ten Amyl fluoride and two polysiloxanes.The latent value (ODP) of the ozone-depleting of Decafluoropentane is 0, and the latent value (GWP) of greenhouse effects is 0.25, boiling Point:55 DEG C (lit.), flash-point:>125 DEG C, for the non-ignitable organic matter of environmental protection.The heat of evaporation of two polysiloxanes is low, will not make skin Cool rapidly and do not feel well.
As of the present invention continuously from the preferred embodiment of composition, foam, the grease be selected from animal and plant fat, At least one of Guerbet alcohol, ester, ether, hydrocarbon and silicone oil;The surfactant is selected from anion surfactant, both sexes At least one of surfactant, nonionic surfactant.
The grease of the present invention is Occlusive grease, and Occlusive grease forms continuous oil film on skin, softens nothing The cuticula of elasticity, avoid skin surface dehydration or at least partly keep the moisture of skin surface, delay the loss of top layer moisture, So as to cause the rehydrated of cuticula.Grease described in the present composition is Occlusive grease, selected from animal and plant fat, gill At least one of Bert alcohol, ester, ether, hydrocarbon and silicone oil, consider from cost and formulation stability, it is preferable that the grease is pungent Acid/Triglyceride DDD, ethylhexyl palmitate, isopropyl palmitate, isopropyl myristate and Dormant oils.
It is of the present invention continuously to be lived from composition, foam, surfactant selected from anion surfactant, amphoteric surface At least one of property agent, nonionic surfactant.When on coated in skin, the surfactant in the present composition Interacted with foaming agent because foaming agent continue outwards, to open space evaporation, release and to drive surfactant to be formed rich Thick bubble.
Continuously it is selected from as of the present invention from the preferred embodiment of composition, foam, the anion surfactant Alkyl sulfate salt, alkyl, polyether sulfate, isethionic acid ester sodium salt, alkyl sulfosuccinates salt, alkyl, polyether sulfo group amber Amber acid esters salt, alkylamidoalkyl sulfosuccinamic acid ester salt, alkyl phosphate salt, alkyl carboxylate, alkyl, polyether carboxylate, At least one of acyl amino hydrochlorate, acyl sarcosinates, acyl taurine salt, it is preferable that the anion surface active Agent is selected from least one of acyl amino hydrochlorate, acyl sarcosinates, acyl taurine salt;The amphoteric surfactant choosing From carboxylic acid beet alkali ampholytic surface active agent, sulphonic acid betaine amphoteric surfactant, sulfuric ester beet alkali ampholytic surface active At least one in agent, Amphoteric Surfactant Alkylami-dophosphobetaines amphoteric surfactant, alkyl both sexes acetate, alkyl both sexes propionate Kind;The nonionic surfactant be selected from aliphatic alcohol polyether, alkyl phenol polyether, alkylolamides, cithrol, At least one of polyglycerol ester and alkyl glucoside.
Wherein, anion surfactant from mildness consider, it is therefore preferable to acyl amino hydrochlorate, acyl sarcosinates and Acyl taurine salt.Nonionic surfactant is for the impression of consumer and acceptance, it is therefore preferable to polyglycerol ester and alkane Base glucoside.
As of the present invention continuously from least one in the preferred embodiment of composition, foam, following (a)~(c) :
(a) it is continuously 3-8% from the percentage by weight of composition, foam that anion surfactant, which accounts for described,;
(b) it is continuously 2-5% from the percentage by weight of composition, foam that amphoteric surfactant, which accounts for described,;
(c) it is continuously 2-5% from the percentage by weight of composition, foam that nonionic surfactant, which accounts for described,.
Present invention also offers it is a kind of containing above-mentioned continuously from the medicine or cosmetics of composition, foam.
As the preferred embodiment of cosmetics of the present invention, the cosmetics also include auxiliary material;Preferably, describedization Cosmetic is 100 parts by weight.Wherein, refer to can root currently used for the customary adjuvant in cosmetics, those skilled in the art for auxiliary material Formulation and purposes according to prior art and cosmetics etc. select the auxiliary material of Optimum Contents, as long as selected auxiliary material is not for fear of this The desired function of inventive composition is just.Cosmetic can be《Cosmetic material Names Catalogue is used》Find.
As the preferred embodiment of cosmetics of the present invention, the auxiliary material be preservative, chelating agent, essence, grease, At least one of NMF, colouring agent, antioxidant and skin sense conditioning agent.The cosmetics of the present invention can use one kind, two Kind or a variety of different preservatives or the composition with antiseptic effect.
As the preferred embodiment of cosmetics of the present invention, the preservative is Form aldehyde release body class, nipagin esters Class, containing halogen, quaternary ammonium salt, organic acid, alcohols at least one of the preservatives, it is highly preferred that the preservative is has Machine acids preservative or alcohols preservative;The NMF be glycerine, propane diols, butanediol, 1,2- pentanediols, 1,2- oneself two Alcohol, isoprene, methyl propanediol, dipropylene glycol, pyrrolidone sodium carboxylate, 2-pyrrolidone-5-carboxylic acid's potassium, Sodium Hyaluronate, sugar At least one of class, polyethylene glycol;The antioxidant be tocopherol (vitamin E), tocopherol acetate, Butylated Hydroxytoluene, At least one of parahydroxyacet-ophenone.Preservative, NMF and antioxidant include but is not limited to the preferable material.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion form or cream shape formulation. Consider in terms of performance, the cosmetics are preferably emulsion form.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:9 parts of grease, 2 parts of thickener, surfactant (active matter Meter) 5.9 parts, 6 parts of foaming agent, add water to 100 parts.Grease is 5 parts of 4 parts of caprylic/capric triglyceride and ethylhexyl palmitate, Thickener is polyacrylate cross-linked polymer -6,3.4 parts of surfactant (actives basis) sodium lauroyl glutamate and decyl 2.5 parts of glucoside, foaming agent are two polysiloxanes.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous from composition, foam, it is made up of following components in parts by weight:9 parts of grease, 2 parts of thickener, surfactant (activity Thing meter) 5.9 parts, 6 parts of foaming agent, add water to 100 parts.Grease is 4 parts of caprylic/capric triglyceride and ethylhexyl palmitate 5 Part, thickener is polyacrylate cross-linked polymer -6,3.4 parts of surfactant (actives basis) sodium cocoyl glycinate and the last of the ten Heavenly stems 2.5 parts of base glucoside, foaming agent are two polysiloxanes.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:12 parts of grease, 2 parts of thickener, surfactant (active matter Meter) 10.9 parts, 6 parts of foaming agent, add water to 100 parts.Grease is 5 parts of caprylic/capric triglyceride and ethylhexyl palmitate 7 Part, thickener is polyacrylate cross-linked polymer -6, and surfactant is 4 parts of (actives basis) sodium lauroyl glutamate, the last of the ten Heavenly stems 2.4 parts of 3 parts of base glucoside, 1.5 parts of lauroyl oat amino acid sodium and sodium methyl cocoyl taurate, foaming agent are dimerization silicon Oxygen alkane.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:12 parts of grease, 2 parts of thickener, surfactant (active matter Meter) 10.9 parts, 6 parts of foaming agent, add water to 100 parts.Grease is 5 parts of caprylic/capric triglyceride and ethylhexyl palmitate 7 Part, thickener is polyacrylate cross-linked polymer -6, and surfactant is 4 parts of (actives basis) sodium cocoyl glycinate, the last of the ten Heavenly stems 2.4 parts of 3 parts of base glucoside, 1.5 parts of lauroyl oat amino acid sodium and sodium methyl cocoyl taurate, foaming agent are dimerization silicon Oxygen alkane.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:1 part of grease, 1.8 parts of thickener, surfactant (activity Thing meter) 2 parts, 10 parts of foaming agent, add water to 100 parts.Grease is caprylic/capric triglyceride, and thickener is handed over for polyacrylate Linked polymer -6, surfactant are sodium cocoyl glycinate, and foaming agent is two polysiloxanes.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:1 part of grease, 2 parts of thickener, surfactant (active matter Meter) 15 parts, 2 parts of foaming agent, add water to 100 parts.Grease is caprylic/capric triglyceride, and thickener is crosslinked for polyacrylate Polymer -6, surfactant are 5 parts of sodium cocoyl glycinate (actives basis), 5 parts of Plantacare 818 (actives basis), bay 2 parts of acyl oat amino acid sodium (actives basis), 3 parts of sodium methyl cocoyl taurate (actives basis), foaming agent are dimerization silicon Oxygen alkane.
As the preferred embodiment of cosmetics of the present invention, the cosmetics are emulsion formulation, in the cosmetics Continuous be made up of from composition, foam following components in parts by weight:15 parts of grease, 3 parts of thickener, surfactant (active matter Meter) 5 parts, 2 parts of foaming agent, add water to 100 parts.Grease is 5 parts of caprylic/capric triglyceride, 10 parts of ethylhexyl palmitate, is increased Thick dose is polyacrylate cross-linked polymer -6, and surfactant is 5 parts of sodium cocoyl glycinate (actives basis), and foaming agent is Two polysiloxanes.
Compared with prior art, beneficial effects of the present invention are:
The described continuous component that following specified weight parts are included from composition, foam for cosmetics of the present invention:Oil 2-15 parts of 1-15 parts of fat, 0.3-3 parts of thickener, 2-10 parts of self foaming agent and surfactant;Be not any raw material and The effect for having the present invention from foaming composition of ratio, composition provided by the present invention are a kind of with foaming certainly The composition of cleaning effect, it is applicable suitable for clean skin, removing aging cutin cell and absorption environmental toxin, and band To moisten comfortable effect, made after skin smooth, water it is tender, it is pale, rich in gloss.
By by from cosmetics made of composition, foam being emulsion formulation by the continuous of the present invention, it can improve and reduce The sense of discomfort such as the dryings brought of common skin cleaning products, stimulation, tight, brings moist comfortable skin sense, strengthens skin barrier And moisture-retaining capacity.
Can be with simple and efficient stabilising system using the ratio of the thickener by screening and optimization.
Brief description of the drawings
Fig. 1 is the hair that 1 st volunteer the back of the hand portion uses the cosmetic mask containing the present composition in embodiment 18 (2) Steep effect.
Fig. 2 is the hair that 2 st volunteer the back of the hand portions use the cosmetic mask containing the present composition in embodiment 18 (2) Steep effect.
Fig. 3 and unloaded for 3 st volunteer the back of the hand portions in embodiment 18 (3) using the cosmetic cleaning containing the present composition Adornment effect.
Fig. 4 and unloaded for 4 st volunteer the back of the hand portions in embodiment 18 (3) using the cosmetic cleaning containing the present composition Adornment effect.
Embodiment
For the object, technical solutions and advantages of the present invention are better described, below in conjunction with the drawings and specific embodiments pair The present invention is described further.
The screening of the thickener of embodiment 1
Thickener is hydrophilic thickeners, screening scope include acrylate polymer, natural polysaccharide and its derivative and Clay mineral and its modified product, specifically selected from acrylate polymer, cellulose gum, hydroxyethyl cellulose, modified starch, Xanthans, carragheen, Magnesiumaluminumsilicate, lithium magnesium silicate and sodium magnesium silicate.
The addition of the thickener of embodiment 2
For the usage amount of thickener since 0.3% (with actives basis), incrementss are 0.3% (with actives basis), until 3% (with actives basis).If thickener needs to neutralize, add alkali and neutralize.
The basic components of the thickener of embodiment 3 screening
The basic components of the thickener of table 1 screening
The brief technique of this basic components is:Thickener is distributed in 40 parts of water, neutralized if necessary, then adds oil Fat, stir;Surfactant is dissolved with the water of residual share, the mixed phase of foregoing grease and thickener is added to after uniform In, continue to be stirred until homogeneous;Two polysiloxanes and preservative are eventually adding, is stirred.
The system stability of embodiment 4 is evaluated
45 DEG C heat-resisting 30 days, recovers room temperature and water-oil separating does not occur to be stable, it is unstable that water-oil separating, which occurs,.
The thickener the selection result of embodiment 5
The thickener the selection result of table 2
Embodiment 5 selectes the optimization concentration of thickener
SEPIMAXTMDuring ZEN concentrations >=1.8%, stable system can be obtained, from cost, reliability and viscosity Consider, optimal concentration is 2%.
The self foaming agent concentration of embodiment 6 optimizes
Investigate foaming instantaneity, persistence and economy that composition is applied on skin.1 minute moment investigated foaming Instantaneity, emersion continuous uniform bubble is otherwise difference preferably on skin;10 minute moment investigated the persistence of foaming, emersion gas Bleb district domain can retain more than 60% preferably, be otherwise difference;Reach the minimum density of foaming agent economy of above-mentioned standard preferably.Optimization Concentration be exactly the concentration of economy preferably.Foaming agent uses two polysiloxanes.
The basic components of the foaming agent concentration of embodiment 7 optimization
The basic components of the self foaming agent concentration of table 3 optimization
The brief technique of this basic components is:Thickener is distributed in 40 parts of water, grease is then added, stirs;With The water dissolving surfactant of residual share, is added in the mixed phase of foregoing grease and thickener after uniform, continues stirring extremely Uniformly;Two polysiloxanes and preservative are eventually adding, is stirred.
The self foaming agent of embodiment 8 optimizes concentration the selection result
The foaming agent of table 4 optimizes concentration the selection result
The self foaming agent concentration of optimization is 5-7%.
Embodiment 9
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:4 parts of caprylic/capric triglyceride, 5 parts of ethylhexyl palmitate, polyacrylate are handed over 2 parts of linked polymer -6, sodium lauroyl glutamate 3.4 (actives basis) part, 2.5 parts of Plantacare 818 (actives basis), dimerization silicon 6 parts of oxygen alkane, adds water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Lauroyl is dissolved with the water of residual share Sodium glutamate and Plantacare 818, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cool to 45 DEG C, be added to In the mixed phase of oil phase and thickener phase, stir;40 DEG C of two polysiloxanes of addition, stir and are combined as from foaming Thing.
Embodiment 10
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:4 parts of caprylic/capric triglyceride, 5 parts of ethylhexyl palmitate, polyacrylate are handed over 2 parts of linked polymer -6, sodium cocoyl glycinate 3.4 (actives basis) part, 2.5 parts of Plantacare 818 (actives basis), dimerization silicon 6 parts of oxygen alkane, adds water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Cocounut oil acyl is dissolved with the water of residual share Sodium Glycinate and Plantacare 818, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cool to 45 DEG C, be added to The mixed phase of oil phase and thickener phase, stirs;40 DEG C of two polysiloxanes of addition, stir as from composition, foam.
Embodiment 11
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:5 parts of caprylic/capric triglyceride, 7 parts of ethylhexyl palmitate, polyacrylate are handed over 2 parts of linked polymer -6,4 parts of sodium lauroyl glutamate (actives basis), 3 parts of Plantacare 818 (actives basis), lauroyl oat 1.5 parts of amino acid sodium (actives basis), 2.4 parts of sodium methyl cocoyl taurate (actives basis), 6 parts of two polysiloxanes, add Water is to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Lauroyl is dissolved with the water of residual share Sodium glutamate, Plantacare 818, lauroyl oat amino acid sodium and sodium methyl cocoyl taurate, agitating and heating, 80 DEG C- 85 DEG C of insulated and stirreds 15 minutes, cool to 45 DEG C, are added to the mixed phase of oil phase and thickener phase, stir;40℃ Two polysiloxanes are added, are stirred as from composition, foam.
Embodiment 12
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:5 parts of caprylic/capric triglyceride, 7 parts of ethylhexyl palmitate, polyacrylate are handed over 2 parts of linked polymer -6,4 parts of sodium cocoyl glycinate (actives basis), 3 parts of Plantacare 818 (actives basis), lauroyl oat 1.5 parts of amino acid sodium (actives basis), 2.4 parts of sodium methyl cocoyl taurate (actives basis), 6 parts of two polysiloxanes, add Water is to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Cocounut oil acyl is dissolved with the water of residual share Sodium Glycinate, Plantacare 818, lauroyl oat amino acid sodium and sodium methyl cocoyl taurate, agitating and heating, 80 DEG C- 85 DEG C of insulated and stirreds 15 minutes, cool to 45 DEG C, are added to the mixed phase of oil phase and thickener phase, stir;40℃ Two polysiloxanes are added, are stirred as from composition, foam.
Embodiment 13
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:1 part of caprylic/capric triglyceride, -6 1.8 parts of polyacrylate cross-linked polymer, coconut palm 2 parts of oleoyl Sodium Glycinate (actives basis), 10 parts of two polysiloxanes, add water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride, 2800rpm homogeneous 5 minutes, 80 DEG C -85 DEG C continue insulated and stirred 15 minutes, cool to 45 DEG C;Sodium cocoyl glycinate is dissolved with the water of residual share, stirring adds Heat, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cools to 45 DEG C, is added to the mixed phase of oil phase and thickener phase, stirs Uniformly;40 DEG C of two polysiloxanes of addition, stir as from composition, foam
Embodiment 14
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:1 part of caprylic/capric triglyceride, -6 2 parts of polyacrylate cross-linked polymer, cocounut oil 5 parts of acyl Sodium Glycinate (actives basis), 5 parts of Plantacare 818 (actives basis), lauroyl oat amino acid sodium (actives basis) 2 Part, 3 parts of sodium methyl cocoyl taurate (actives basis), 2 parts of two polysiloxanes, add water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride, 2800rpm homogeneous 5 minutes, 80 DEG C -85 DEG C continue insulated and stirred 15 minutes, cool to 45 DEG C;With water dissolving sodium cocoyl glycinate, the decyl glucose of residual share Glycosides, lauroyl oat amino acid sodium and sodium methyl cocoyl taurate, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 are divided Clock, cool to 45 DEG C, be added to the mixed phase of oil phase and thickener phase, stir;40 DEG C of two polysiloxanes of addition, are stirred Mix is uniformly from composition, foam.
Embodiment 15
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:5 parts of caprylic/capric triglyceride, 10 parts of ethylhexyl palmitate, polyacrylate are handed over 3 parts of linked polymer -6,5 parts of sodium cocoyl glycinate (actives basis), 2 parts of two polysiloxanes, add water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Cocounut oil acyl is dissolved with the water of residual share Sodium Glycinate, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cool to 45 DEG C, be added to oil phase and thickener The mixed phase of phase, stirs;40 DEG C of two polysiloxanes of addition, stir as from composition, foam.
Embodiment 16
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:5 parts of caprylic/capric triglyceride, 10 parts of ethylhexyl palmitate, polyacrylate are handed over 0.3 part of linked polymer -6,5 parts of sodium cocoyl glycinate (actives basis), 5 parts of two polysiloxanes, add water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Cocounut oil acyl is dissolved with the water of residual share Sodium Glycinate, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cool to 45 DEG C, be added to oil phase and thickener The mixed phase of phase, stirs;40 DEG C of two polysiloxanes of addition, stir as from composition, foam.
Embodiment 17
The present invention is from a kind of embodiment of composition, foam, its preparation method and application, from foaming group described in the present embodiment Compound includes following components in parts by weight:5 parts of caprylic/capric triglyceride, 10 parts of ethylhexyl palmitate, polyacrylate are handed over 3 parts of linked polymer -6,5 parts of sodium cocoyl glycinate (actives basis), 7 parts of two polysiloxanes, add water to 100 parts.
It is from composition, foam preparation method described in the present embodiment:Polyacrylate cross-linked polymer -6 is added to 40 parts In water, stir, be heated with stirring to 80 DEG C, add caprylic/capric triglyceride and ethylhexyl palmitate, 2800rpm are equal Matter 5 minutes, 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, are cooled to 45 DEG C;Cocounut oil acyl is dissolved with the water of residual share Sodium Glycinate, agitating and heating, 80 DEG C -85 DEG C insulated and stirreds 15 minutes, cool to 45 DEG C, be added to oil phase and thickener The mixed phase of phase, stirs;40 DEG C of two polysiloxanes of addition, stir as from composition, foam.
The moisturizing effervescent cleansing facial mask of embodiment 18 and its preparation
A kind of embodiment of cosmetics of the present invention, cosmetics described in the present embodiment are moisturizing effervescent cleansing facial mask, and it contains From composition, foam described in embodiment 9.The formula of moisturizing effervescent cleansing facial mask is as shown in table 5 described in the present embodiment.
The moisturizing effervescent cleansing face pack prescription of table 5
The preparation technology of the moisturizing cleaning foam mask of the present embodiment is as follows:
1) No. 1 raw material being sprinkled into No. 2 raw materials in table 5 in stirring, stirs, and this is 1. phase;
2) No. 3-No. 7 raw materials are added to 1. phase, 80-85 DEG C of insulated and stirreds 15 minutes, then add No. 8 and No. 9 originals Material, 2800rpm homogeneous is after 5 minutes, and 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, then stirring cooling, be cooled to 45 DEG C this For 2. phase;
3) by No. 10-No. 12 agitating and heatings of raw material, 80 DEG C-85 DEG C insulated and stirreds 15 minutes, then cool to 45 DEG C this be 3. phase;
4) 2. phase is 3. added to, is stirred, obtains 4. phase;
5) No. 13 and No. 14 are added to 4. phase by 40 DEG C, are stirred, filtering and discharging, obtain 5. phase, and as moisturizing is cleaned Foam mask.
Embodiment 19 moistens foaming face cleaning makeup removing breast and its preparation
A kind of embodiment of cosmetics of the present invention, to moisten foaming face cleaning makeup removing breast, it contains cosmetics described in the present embodiment Have described in embodiment 12 from composition, foam.The composition that foaming face cleaning makeup removing breast is moistened described in the present embodiment is as shown in table 6.
Table 6 moistens foaming face cleaning makeup removing breast
The preparation technology of the moist foaming face cleaning makeup removing breast of the present embodiment is as follows:
1) in No. 1 raw material that No. 2 raw materials in table 7 are sprinkled into stirring, stir, this is 1. phase;
2) No. 3-No. 7 raw materials are added to 1. phase, 80-85 DEG C of insulated and stirreds 15 minutes, then add No. 8 and No. 9 originals Material, 2800rpm homogeneous is after 5 minutes, and 80 DEG C -85 DEG C are continued insulated and stirred 15 minutes, then stirring cooling, be cooled to 45 DEG C this For 2. phase;
3) by No. 10-No. 14 agitating and heatings of raw material, 80 DEG C-85 DEG C insulated and stirreds 15 minutes, then cool to 45 DEG C this be 3. phase;
4) 2. phase is 3. added to, is stirred, obtains 4. phase;
5) 40 DEG C by raw material No. 15 and No. 16 be added to 4. phase, stir, filtering and discharging, obtain 5. phase, as moisten Foam face cleaning makeup removing breast.
The compliance test result example of embodiment 20
(1) test case 1 is applied
Method:30 skin health female volunteers, age from 20 years old to 45 years old, average age 30 years old, use the present invention The moisturizing effervescent cleansing facial mask of embodiment 18, first washed away within 10 minutes with the wet face of water purification, then application.Then volunteer is asked Volume investigation, compares assessment item situation of change before and after use, discontented to mean 0 point, the satisfied arithmetic for being 1 point, calculating each project Average value.Statistical result is as shown in table 7.
The moisturizing effervescent cleansing facial mask application evaluation table of table 7
Moisturizing effervescent cleansing facial mask of the volunteer using the embodiment of the present invention 18 is can be seen that from the statistical result of table 5, respectively Individual assessment item all preferably approved, score is from 0.79-0.92, it is believed that after application moisturizing effervescent cleansing facial mask, skin is clean Only, it is moist, smooth, pale have it is glossy, comfortable not tight.
(2) test case 2 is applied
Method:The moisturizing effervescent cleansing facial mask of the embodiment of the present invention 18 is smeared in single the back of the hand of two female volunteers, point Do not taken pictures in t=0 minutes, t=4 minutes and t=8 minutes, record moisturizing effervescent cleansing facial mask foaming situation.As a result such as Fig. 1 Shown in Fig. 2.
More than 2 figures can be seen that the embodiment of the present invention 18 moisturizing effervescent cleansing facial mask can continue produce bubble, shape Into fine and close abundant foam.
(3) test case 3 is applied
Method:In single the back of the hand smearing lipstick of two female volunteers, the then moist foaming of application inventive embodiments 19 Face cleaning makeup removing breast, spreadable, gently massage is looped, and fully dissolves the lipstick residual at dermatoglyph, and shoot smearing respectively Lipstick and plus during makeup removing breast, massage when looping and water purification rinse after photo, record makeup removing situation.As a result as shown in Figure 3 and Figure 4.
The moist foaming face cleaning makeup removing breast preferably removal mouth of the embodiment of the present invention 19 is can be seen that from such as Fig. 3 and Fig. 4 It is red.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention And scope.

Claims (10)

1. one kind is continuously from composition, foam, it is characterised in that includes the component of following weight percentage:Grease 1-15%, increase Thick dose 0.3-3%, self foaming agent 2-10% and surfactant 2-15%.
2. as claimed in claim 1 continuously from composition, foam, it is characterised in that the thickener accounts for described continuous from foaming The percentage by weight of composition is 1.8-3%.
3. as claimed in claim 2 continuously from composition, foam, it is characterised in that the thickener accounts for described continuous from foaming The percentage by weight of composition is 2%.
It is 4. continuous from composition, foam as described in any one of claims 1 to 3, it is characterised in that the thickener includes third At least one of olefine acid ester polymer, natural polysaccharide, natural polysaccharide derivative, clay mineral, Modification of Clay Minerals product.
5. as claimed in claim 4 continuously from composition, foam, it is characterised in that the thickener is selected from acrylic ester polymerization In thing, cellulose gum, hydroxyethyl cellulose, modified starch, xanthans, carragheen, Magnesiumaluminumsilicate, lithium magnesium silicate, sodium magnesium silicate At least one.
6. as claimed in claim 1 continuously from composition, foam, it is characterised in that the self foaming agent accounts for described continuous spontaneous The percentage by weight of foaming composition is 5-7%.
It is 7. continuous from composition, foam as described in claim 1 or 6, it is characterised in that the self foaming agent is selected from perfluor fourth Base methyl ether, methylperfluoroisobutylether, ethyl perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor isohexane, Decafluoropentane, At least one of two polysiloxanes.
8. as claimed in claim 1 continuously from composition, foam, it is characterised in that the grease is selected from animal and plant fat, lattice At least one of your Bert alcohol, ester, ether, hydrocarbon and silicone oil;The surfactant is selected from anion surfactant, both sexes table At least one of face activating agent, nonionic surfactant.
9. as claimed in claim 8 continuously from composition, foam, it is characterised in that the anion surfactant is selected from alkane Base sulfuric acid, alkyl, polyether sulfate, isethionic acid ester sodium salt, alkyl sulfosuccinates salt, alkyl, polyether sulfosuccinic Acid esters salt, alkylamidoalkyl sulfosuccinamic acid ester salt, alkyl phosphate salt, alkyl carboxylate, alkyl, polyether carboxylate, acyl At least one of base amino-acid salt, acyl sarcosinates, acyl taurine salt;The amphoteric surfactant is selected from carboxylic acid sweet tea Dish alkali amphoteric surfactant, sulphonic acid betaine amphoteric surfactant, sulfuric ester beet alkali ampholytic surface active agent, alkyl acyl At least one of amine phosphate beet alkali ampholytic surface active agent, alkyl both sexes acetate, alkyl both sexes propionate;It is described non- Ionic surface active agent is selected from aliphatic alcohol polyether, alkyl phenol polyether, alkylolamides, cithrol, polyglycerol ester At least one of with alkyl glucoside.
10. it is a kind of containing as described in any one of claim 1~9 continuously from the medicine or cosmetics of composition, foam.
CN201710594975.5A 2017-07-19 2017-07-19 One kind is continuously from composition, foam and its application Pending CN107397686A (en)

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CN109276477A (en) * 2018-09-29 2019-01-29 广州市科能化妆品科研有限公司 A kind of bubble sense mousse composition and its application in cosmetics
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CN110585090A (en) * 2019-10-21 2019-12-20 广州艾蓓生物科技有限公司 Self-foaming red mud mask and preparation method thereof
CN110585090B (en) * 2019-10-21 2022-06-17 广州艾蓓生物科技有限公司 Self-foaming red mud mask and preparation method thereof
CN110693748A (en) * 2019-11-04 2020-01-17 木芷秋山(广州)化妆品研究开发有限公司 Amino acid bubble cleanser and preparation method thereof
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