CN107386540A - A kind of photovoltaic polymetal crust material - Google Patents

A kind of photovoltaic polymetal crust material Download PDF

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Publication number
CN107386540A
CN107386540A CN201710542015.4A CN201710542015A CN107386540A CN 107386540 A CN107386540 A CN 107386540A CN 201710542015 A CN201710542015 A CN 201710542015A CN 107386540 A CN107386540 A CN 107386540A
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photovoltaic
parts
photovoltaic film
metal
layer
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CN201710542015.4A
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Chinese (zh)
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林和国
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/10Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/036Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
    • H01L31/0392Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of photovoltaic polymetal crust material, include metal substrate layer, photovoltaic film superficial layer and fixed for metal substrate layer, the mutual gluing of photovoltaic film superficial layer and the hot melt adhesion oxidant layer of mutually insulated.It is an advantage of the invention that it is compound without later stage viscose glue, and suitable for being directly processed into specific frame shape by clod wash processing technology.

Description

A kind of photovoltaic polymetal crust material
Technical field
The invention belongs to photovoltaic and field of material technology, in particular to a kind of photovoltaic polymetal crust material.
Background technology
With the development of photovoltaic technology, the thin film solar photovoltaic products using copper iridium gallium selenium film as representative continuously emerge. These photovoltaic products are required for agreing to supporting body to carry out installation generating, are limited to supporting body geometry and installation load-bearing, Need to take substantial amounts of plane space resource.In addition, in the prior art, the supporting body of photovoltaic cell is all in advance according to installation position Put and manufactured in advance with purposes, be then again fixed thereon photovoltaic cell by support or fastener.
The metal framework such as still further aspect, door window frame or highway barrier, street lamp in current building occupies Substantial amounts of light-receiving area, and if these areas can be used to carry out photovoltaic generation, then drastically increase photovoltaic products The problem of taking extra mounting space.But problems of the prior art are:
(1)Lack a kind of adhesive of stabilization by photovoltaic film Material cladding on metal base;
(2)Photovoltaic film material is fixed on by follow-up viscose glue has been molded into the metal bases such as door window frame or highway barrier Upper Compound Machining is extremely difficult.
The content of the invention
The invention aims to overcome shortcoming and defect existing for prior art, and one kind is provided without later stage viscose glue It is compound, and suitable for being directly processed into the photovoltaic polymetal crust material of specific frame shape by clod wash processing technology.
To achieve the above object, the technical scheme is that include metal substrate layer, photovoltaic film superficial layer and Fixed for metal substrate layer, the mutual gluing of photovoltaic film superficial layer and the hot melt adhesion oxidant layer of mutually insulated.
It is that the photovoltaic polymetal crust material is coiled material further to set.
It is that metal substrate layer is aluminum alloy base material, aluminium base, heat zinc coating plate base material or stainless steel substrate further to set.
It is that described photovoltaic film superficial layer is flexible photovoltaic film further to set.Specially described photovoltaic film surface Layer is copper iridium gallium selenium photovoltaic film, female cadmium photovoltaic film or amorphous silicon photovoltaic film.
Further set is that the width of described metal substrate layer is more than the width of photovoltaic film superficial layer, described photovoltaic Film surface layer is centrally located in a side surface of metal substrate layer, and described metal substrate layer is relative to photovoltaic film superficial layer The region of upper and lower both sides forms clod wash processing district, and the photovoltaic film superficial layer includes length side of the multistage along metal substrate layer To spaced distribution photovoltaic film disjunction piece form, metal substrate layer relative to two sections of adjacent photovoltaic film disjunction pieces it Between region form coiled flexural deformation Ying Liang areas, it is that the width of clod wash processing district be at least 5cm further to set, and is bent in rolls The width for deforming Ying Liang areas is at least 2mm.By this setting, the convenient follow-up progress clod wash processing in clod wash processing district, and it is coiled curved When song deformation Ying Liang areas then facilitate photovoltaic polymetal crust material wound, there are enough deformation amounts of being full of, prevent metal substrate layer Between photovoltaic film superficial layer due to a lack of the deformation amount of being full of stress sidesway.
It is that described hot melt adhesion oxidant layer includes following components further to set:Include for being coated on metal base Layer side metal-to-metal adhesive and for the photovoltaic film glue coated on photovoltaic film superficial layer side, the metal-to-metal adhesive and photovoltaic film glue Mutually it is adjacent under hot melt state and bonds after the cooling period;
The metal-to-metal adhesive includes following components, in terms of mass fraction:
Nylon type copolyamide 45-50 parts
Ethylene-vinyl acetate copolymer 15-20 parts
Terpene resin 10-15 parts;
C9 Petropols 10-15 parts;
Microwax or paraffin 3-5 parts;
Ditridecyl phthalate fourth 1-2 parts
2,6 di tert butyl 4 methyl phenol 0.5-1.5 parts;
The ethylhexyl of tert-butyl hydroperoxide-2-carbonic ester 0.5-1 parts;
Aerosil 0-1 parts;
The photovoltaic film glue includes following components, in terms of mass fraction:
Ethylene-vinyl acetate copolymer 45-50 parts
Nylon type copolyamide 15-20 parts
Terpene resin 10-15 parts;
C9 Petropols 10-15 parts;
Microwax or paraffin 5-6 parts;
Ditridecyl phthalate fourth 1-2 parts
2,6 di tert butyl 4 methyl phenol 0.5-1.5 parts;
The ethylhexyl of tert-butyl hydroperoxide-2-carbonic ester 0.5-1 parts.
The present invention Innovation Mechanism and advantage be:
(1)Can clod wash:Ply-metal employs the new technology of hot melts agent, and the crucial technology of ply-metal is referred to Mark-can cold roll forming, toughness is high, bending is indeformable not broken, and two kinds of metals of 180 degree hardness bending are not shifted over peeling off, With can the special-performance such as punching press, stretching.By cold-bending molding technology the material can be processed into street lamp, door and window, guardrail, Mansion curtain wall etc., drastically increase the generating area of photovoltaic.Realize construction material or exterior wall with photovoltaic electric power function Ornament materials, construction is the steel-structure factory building or building with photovoltaic electric power, is all many photovoltaic stereo power stations.
(2)Using special hot melts agent, there is advantages below:
(2.1)The metal-to-metal adhesive and photovoltaic film glue configured using different component, is respectively used to be coated on metal base side and light Film side is lied prostrate, it is then mutually compound between metal-to-metal adhesive and photovoltaic film glue, it is this to be equipped with, it is contemplated that various metals member The metal base of element composition and the gluing characteristic on the photovoltaic film surface being made up of various metals and non-metallic substrate, respectively by not Metal-to-metal adhesive and photovoltaic film glue with component formula carry out matching bonding, then again by the metal-to-metal adhesive in similar compositions system and The progress of photovoltaic film glue is compound, and so as to drastically increase gluing stability, the peel strength of the hot melts agent is brought up to Splendid state(150N/CM), consequently facilitating the finished product holding surface flatness after keeping compound.
(2.2)The EVA components of different component are set in metal-to-metal adhesive and photovoltaic film glue, and the EVA components have outstanding electricity Insulation and rigidity, wearability, pliability, stress cracking resistance, impact and low temperature adhesion, pass through the EVA components so that this The hot melt adhesive of invention is inherently into insulating barrier and shock-resistant layer, so as to the production after photovoltaic film and metal composite Product(Photovoltaic polymetal crust material)When subsequently progress clod wash processing technology is molded, photovoltaic film and metal can be prevented Between hot melt adhesive layer be broken in bending part, cause failure of insulation, while be also convenient for the material making coiled material.
(2.3)The metal-to-metal adhesive side of the present invention sets 45-50 parts(Largely)The nylon type copolyamide of ratio so that this hair The bright hot melt adhesive layer formed between photovoltaic film and metal forms the sealant with watertightness in the side of the metal-to-metal adhesive, from And prevent that hydrone from mutually shifting between metal and photovoltaic film, anti-corrosive properties are drastically increased, and the photovoltaic of opposite side is thin The nylon type copolyamide that 15-20 parts are set in film glue is compound viscous between photovoltaic film glue in order to ensure between metal-to-metal adhesive Property intensity.
(3)Material easy processing, its superior application property of photovoltaic multi-metal composite material, only need simple machine tool can be complete Into cutting, cut, plane side, bend camber, right angle various appearance, can matching design personnel, make various changes, install Simplicity, fast reduce construction cost.
(4)Fire prevention, thermal and insulating performance are remarkable:Be among photovoltaic multi-metal composite material hot melts agent be resistant to 180 degree, Subzero 50 degree of low temperature.Therefore, it is a kind of insulation fire safety material, meets fire resisting needs and the environmental protection and energy saving of building laws Requirement.There is the advantage of uniqueness in terms of photovoltaic multi-metal composite material weatherability simultaneously, it is no matter under the sunlight of sweltering heat or tight It can all be used throughout one's life without detriment to its beautiful outward appearance in cold wind and snow.
The present invention is described further with reference to specification drawings and specific embodiments.
Brief description of the drawings
Fig. 1 specific embodiment of the invention structural representations;
Fig. 2 specific embodiment of the invention composite construction enlarged diagrams;
Fig. 3 specific embodiment of the invention front schematic views;
Fig. 4 is the enlarged drawing of A in Fig. 3.
Embodiment
The present invention is specifically described below by embodiment, is served only for that the present invention is further described, no It is understood that for limiting the scope of the present invention, the technician in the field can be according to the content of foregoing invention to the present invention Make some nonessential modifications and adaptations.
Embodiment of the invention as Figure 1-4, photovoltaic multi-metal composite material, includes metal substrate layer 1st, photovoltaic film superficial layer 2 and fix for metal substrate layer 1,2 mutual gluing of photovoltaic film superficial layer and mutually insulated Hot melt adhesion oxidant layer 3.The present embodiment photovoltaic polymetal crust material is coiled material.Metal substrate layer 1 is aluminum alloy base material, aluminium base Material, heat zinc coating plate base material or stainless steel substrate.Described photovoltaic film superficial layer 2 is copper iridium gallium selenium photovoltaic film, female cadmium, non- The flexible photovoltaic film such as crystal silicon.
The width of metal substrate layer described in the present embodiment is more than the width of photovoltaic film superficial layer, described photovoltaic film Superficial layer is centrally located in a side surface of metal substrate layer, described metal substrate layer relative to photovoltaic film superficial layer above and below The region of both sides forms clod wash processing district a, and the photovoltaic film superficial layer includes length direction of the multistage along metal substrate layer The photovoltaic film disjunction piece 21 of spaced distribution forms, metal substrate layer relative to two sections of adjacent photovoltaic film disjunction pieces it Between region form coiled flexural deformation Ying Liang areas b, the width of the present embodiment clod wash processing district be at least 5cm, coiled bending change The width in Xing Yingliang areas is at least 2mm.By this setting, the convenient follow-up progress clod wash processing of clod wash processing district a, and bend in rolls When deforming Ying Liang area b and then facilitating photovoltaic polymetal crust material wound, there is enough deformation amounts of being full of, prevent metal substrate layer and Between photovoltaic film superficial layer due to a lack of the deformation amount of being full of stress sidesway.
The special hot melt adhesive of the present invention includes for the metal-to-metal adhesive coated on metal base side and for applying The photovoltaic film glue of photovoltaic film side is overlying on, the metal-to-metal adhesive and photovoltaic film glue are mutually adjacent to and cooled down under hot melt state After bond;
The metal-to-metal adhesive includes following components, in terms of mass fraction:
The photovoltaic film glue includes following components, in terms of mass fraction:
The quality of ethylene moiety accounts for whole ethylene-vinyl acetate copolymer in ethylene-vinyl acetate copolymer described in the present embodiment Mass ratio be 50-55wt%, preferably 50wt%.
The present embodiment nylon type copolyamide softening point 180(℃):± 5 resistance to low temperature (DEG C)≤- 20 elongation percentage (%) >=400 temperature in use(℃):200-230 characteristics:Cohesive is strong, tensile strength is big, low temperature flexibility is good, thermostabilization is good.
The metal-to-metal adhesive and photovoltaic film glue of the present invention is well mixed using by each component input high-speed mixer;Then will The material mixed is put into double screw extruder, is extruded after melting, produces the metal-to-metal adhesive and photovoltaic film glue, two kinds of hot melts Glue packing uses.

Claims (8)

  1. A kind of 1. photovoltaic polymetal crust material, it is characterised in that:Include metal substrate layer, photovoltaic film superficial layer and Fixed for metal substrate layer, the mutual gluing of photovoltaic film superficial layer and the hot melt adhesion oxidant layer of mutually insulated.
  2. 2. the photovoltaic polymetal crust material according to right 1, it is characterised in that:The photovoltaic polymetal crust material is volume Material.
  3. 3. the photovoltaic polymetal crust material according to right 1, it is characterised in that:Metal substrate layer is aluminum alloy base material, aluminium Base material, heat zinc coating plate base material or stainless steel substrate.
  4. 4. the photovoltaic polymetal crust material according to right 1, it is characterised in that:Described photovoltaic film superficial layer is flexibility Photovoltaic film.
  5. 5. the photovoltaic polymetal crust material according to right 4, it is characterised in that:The photovoltaic film superficial layer is copper iridium gallium Selenium photovoltaic film, female cadmium photovoltaic film or amorphous silicon photovoltaic film.
  6. 6. the photovoltaic polymetal crust material according to right 2, it is characterised in that:The width of described metal substrate layer is more than The width of photovoltaic film superficial layer, described photovoltaic film superficial layer is centrally located in a side surface of metal substrate layer, described Metal substrate layer form clod wash processing district, and the photovoltaic film surface relative to the region of both sides above and below photovoltaic film superficial layer Layer includes the photovoltaic film disjunction piece composition of the spaced distribution of length direction of the multistage along metal substrate layer, metal substrate layer Coiled flexural deformation Ying Liang areas are formed relative to the region between two sections of adjacent photovoltaic film disjunction pieces.
  7. 7. the photovoltaic polymetal crust material according to right 6, it is characterised in that:The width of clod wash processing district is at least 5cm, The width in coiled flexural deformation Ying Liang areas is at least 2mm.
  8. 8. the photovoltaic polymetal crust material according to right 1, it is characterised in that:Described hot melt adhesion oxidant layer include with Lower component:Include for the metal-to-metal adhesive coated on metal substrate layer side and for coated on photovoltaic film superficial layer side Photovoltaic film glue, the metal-to-metal adhesive and photovoltaic film glue are mutually adjacent under hot melt state and bonded after the cooling period;
    The metal-to-metal adhesive includes following components, in terms of mass fraction:
    Nylon type copolyamide 45-50 parts
    Ethylene-vinyl acetate copolymer 15-20 parts
    Terpene resin 10-15 parts;
    C9 Petropols 10-15 parts;
    Microwax or paraffin 3-5 parts;
    Ditridecyl phthalate fourth 1-2 parts
    2,6 di tert butyl 4 methyl phenol 0.5-1.5 parts;
    The ethylhexyl of tert-butyl hydroperoxide-2-carbonic ester 0.5-1 parts;
    Aerosil 0-1 parts;
    The photovoltaic film glue includes following components, in terms of mass fraction:
    Ethylene-vinyl acetate copolymer 45-50 parts
    Nylon type copolyamide 15-20 parts
    Terpene resin 10-15 parts;
    C9 Petropols 10-15 parts;
    Microwax or paraffin 5-6 parts;
    Ditridecyl phthalate fourth 1-2 parts
    2,6 di tert butyl 4 methyl phenol 0.5-1.5 parts;
    The ethylhexyl of tert-butyl hydroperoxide-2-carbonic ester 0.5-1 parts.
CN201710542015.4A 2017-07-05 2017-07-05 A kind of photovoltaic polymetal crust material Pending CN107386540A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710542015.4A CN107386540A (en) 2017-07-05 2017-07-05 A kind of photovoltaic polymetal crust material

Applications Claiming Priority (1)

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CN201710542015.4A CN107386540A (en) 2017-07-05 2017-07-05 A kind of photovoltaic polymetal crust material

Publications (1)

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CN107386540A true CN107386540A (en) 2017-11-24

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6215060B1 (en) * 1997-04-21 2001-04-10 Canon Kabushiki Kaisha Method for manufacturing a solar cell module
WO2001067523A1 (en) * 2000-03-09 2001-09-13 ISOVOLTA Österreichische Isolierstoffwerke Aktiengesellschaft Method for producing a photovoltaic thin film module
CN102270667A (en) * 2011-07-27 2011-12-07 保定天威英利新能源有限公司 Component for increasing power generation efficiency of N-type monocrystalline silicon photovoltaic cell and manufacturing method thereof
CN102656243A (en) * 2010-03-16 2012-09-05 乐金华奥斯有限公司 Adhesive film and touch panel
CN102760782A (en) * 2012-06-05 2012-10-31 丁锋 Sectional material for photovoltaic module frame
CN102816536A (en) * 2011-06-08 2012-12-12 苏州达同新材料有限公司 Adhesive tape used for solar cell assembly and preparation method thereof
CN102963090A (en) * 2012-11-21 2013-03-13 江苏创景科技有限公司 Insulation back plate for solar photovoltaic assembly and preparation method of back plate
CN204029829U (en) * 2014-08-28 2014-12-17 陈晓征 A kind of photovoltaic module shady face packaging plastic
CN104576796A (en) * 2015-01-28 2015-04-29 明冠新材料股份有限公司 Photovoltaic component back protecting film and manufacturing method thereof
CN105329885A (en) * 2015-11-26 2016-02-17 北京大学 Method and device for transferring CVD graphene to plastic substrate in reel-to-reel way
CN205680690U (en) * 2016-03-25 2016-11-09 阿特斯(中国)投资有限公司 Photovoltaic module and the backboard of photovoltaic module
CN205810835U (en) * 2016-05-25 2016-12-14 湖北卓宝建筑节能科技有限公司 A kind of novel photovoltaic module structure
CN106753059A (en) * 2016-12-28 2017-05-31 杭州福斯特光伏材料股份有限公司 A kind of pair of glass photovoltaic module hot melt butyl sealant and preparation method
CN207122058U (en) * 2017-07-05 2018-03-20 林和国 A kind of more metal coiled materials of photovoltaic

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6215060B1 (en) * 1997-04-21 2001-04-10 Canon Kabushiki Kaisha Method for manufacturing a solar cell module
WO2001067523A1 (en) * 2000-03-09 2001-09-13 ISOVOLTA Österreichische Isolierstoffwerke Aktiengesellschaft Method for producing a photovoltaic thin film module
CN102656243A (en) * 2010-03-16 2012-09-05 乐金华奥斯有限公司 Adhesive film and touch panel
CN102816536A (en) * 2011-06-08 2012-12-12 苏州达同新材料有限公司 Adhesive tape used for solar cell assembly and preparation method thereof
CN102270667A (en) * 2011-07-27 2011-12-07 保定天威英利新能源有限公司 Component for increasing power generation efficiency of N-type monocrystalline silicon photovoltaic cell and manufacturing method thereof
CN102760782A (en) * 2012-06-05 2012-10-31 丁锋 Sectional material for photovoltaic module frame
CN102963090A (en) * 2012-11-21 2013-03-13 江苏创景科技有限公司 Insulation back plate for solar photovoltaic assembly and preparation method of back plate
CN204029829U (en) * 2014-08-28 2014-12-17 陈晓征 A kind of photovoltaic module shady face packaging plastic
CN104576796A (en) * 2015-01-28 2015-04-29 明冠新材料股份有限公司 Photovoltaic component back protecting film and manufacturing method thereof
CN105329885A (en) * 2015-11-26 2016-02-17 北京大学 Method and device for transferring CVD graphene to plastic substrate in reel-to-reel way
CN205680690U (en) * 2016-03-25 2016-11-09 阿特斯(中国)投资有限公司 Photovoltaic module and the backboard of photovoltaic module
CN205810835U (en) * 2016-05-25 2016-12-14 湖北卓宝建筑节能科技有限公司 A kind of novel photovoltaic module structure
CN106753059A (en) * 2016-12-28 2017-05-31 杭州福斯特光伏材料股份有限公司 A kind of pair of glass photovoltaic module hot melt butyl sealant and preparation method
CN207122058U (en) * 2017-07-05 2018-03-20 林和国 A kind of more metal coiled materials of photovoltaic

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