CN107364194A - A kind of infrared ray obstructs polycarbonate layered plate - Google Patents

A kind of infrared ray obstructs polycarbonate layered plate Download PDF

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Publication number
CN107364194A
CN107364194A CN201710583461.XA CN201710583461A CN107364194A CN 107364194 A CN107364194 A CN 107364194A CN 201710583461 A CN201710583461 A CN 201710583461A CN 107364194 A CN107364194 A CN 107364194A
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CN
China
Prior art keywords
infrared ray
plate
polycarbonate
infrared
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710583461.XA
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Chinese (zh)
Inventor
彭玉山
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Shanghai Fu Fu Chemical New Mstar Technology Ltd
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Shanghai Fu Fu Chemical New Mstar Technology Ltd
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Priority to CN201710583461.XA priority Critical patent/CN107364194A/en
Publication of CN107364194A publication Critical patent/CN107364194A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of infrared ray to obstruct polycarbonate layered plate, including:Multi-layer sheet body, its transparent acrylic for including two layers of polycarbonate plate and being folded in centre, two layers of polycarbonate plate presses close in the plate face of the transparent acrylic to offer several storage tanks for being used to house hollow glass bead respectively, and several described storage tanks are in lattice-distribution in the plate face of polycarbonate plate;Infrared-reflecting coated, it coats the outer surface of one layer of polycarbonate plate wherein, the infrared-reflecting coated reflection infrared ray;Infrared ray absorbing coating, it is laid on the outer surface of other one layer of polycarbonate plate, and the infrared ray absorbing coating is black transparent film;PC waterproof film layers, it is attached to the infrared-reflecting coated outer surface.Infrared ray disclosed by the invention, which obstructs polycarbonate layered plate, can effectively obstruct infrared ray, and the rejection rate of infrared ray has excellent ultraviolet isolating rate and visible light transmissivity close to 100%.

Description

A kind of infrared ray obstructs polycarbonate layered plate
Technical field
The present invention relates to polycarbonate plate technical field, it is more particularly related to which a kind of barrier of infrared ray is poly- Carbonic ester multi-layer sheet.
Background technology
Polycarbonate plate is process with high performance engineering plastics polycarbonate resin, have transparency it is high, it is light, Shock resistance, sound insulation, it is heat-insulated, anti-aging the advantages that, can be widely used for the unusual decoration of gardens, casino or gaming and the corridor of recreating facility Booth;The curtain wall and door and window of modern city building;The transparent container of aviation, motorcycle front windshield, aircraft, train, steamer, automobile, Motorboat, submarine form;Telephone booth, road bill board, lamp box advertisement, the arrangement of exhibition display;High and low voltage switch cabinet panel, LED screen Plate and war industry;Agricultural greenhouse and cultivation greenhouse;Modern ecological dining room ceiling;Office building, department store, hotel, villa, School, hospital, stadiums, the lighting ceiling etc. of recreation center and public utility.But the translucency of polycarbonate plate in itself is strong, Effect of heat insulation is undesirable therefore needs polycarbonate plate to have infrared ray barriers function.
Patent No. CN104559119 A Chinese patent discloses a kind of poly- carbon that can obstruct ultraviolet and near infrared ray Acid esters sheet material and preparation method thereof, it is blue or green by adding caesium tungsten in the main constitutive material polycarbonate resin of polycarbonate plate Copper, tin-antiomony oxide, ultraviolet absorber, stabilizer, polycarbonate plate is prepared by the method for extrusion molding, shortcoming is Cost of material is high, increases use cost, reduces the performance of enterprises, while infrared ray rejection rate need to be improved.
The content of the invention
It is an object of the invention to solve at least the above, and provide the advantages of at least will be described later.
It is a still further object of the present invention to provide a kind of infrared ray to obstruct polycarbonate layered plate, its infrared ray rejection rate 100% can substantially be reached, while ultraviolet isolating rate can reach 99%, while light transmittance can also reach 85%, therefore can fit For any occasion, while there is preferable water resistance and compressive property.
It is a still further object of the present invention to provide a kind of infrared ray to obstruct polycarbonate layered plate, and it, which has to reduce, produces The advantages of cost and use cost.
To achieve these goals, the invention provides a kind of infrared ray to obstruct polycarbonate layered plate, including:
Multi-layer sheet body, its transparent acrylic for including two layers of polycarbonate plate and being folded in centre, two strata Carbonic ester plate presses close in the plate face of the transparent acrylic to offer several respectively and is used to house the accommodating of hollow glass bead Groove, several described storage tanks are in lattice-distribution, the transparent acrylic and two layers of institute in the plate face of polycarbonate plate State and structure is bonded as one by tack coat between polycarbonate plate;
Infrared-reflecting coated, it coats the outer surface of one layer of polycarbonate plate wherein, described infrared-reflecting coated Reflect infrared ray;
Infrared ray absorbing coating, it is laid on the outer surface of other one layer of polycarbonate plate, the infrared ray absorbing coating For black transparent film;
PC waterproof film layers, it is attached to the infrared-reflecting coated outer surface.
Preferably, wherein, it is described infrared-reflecting coated by nano ATO liquid coating one layer of polycarbonate plate wherein Outer surface formed, the infrared-reflecting coated coating thickness is 0.05-0.2mm.
Preferably, wherein, the thickness of two layers of polycarbonate plate is identical, and is 0.2-40mm.
Preferably, wherein, at least two hollow glass beads are fixed with each storage tank.
Preferably, wherein, the thickness of the multi-layer sheet body is 2-90mm.
Preferably, wherein, the infrared ray, which obstructs polycarbonate layered plate, also to be included:
Titanium dioxide layer, it is coated in the outer surface of the infrared ray absorbing coating;
Epoxy resin protective layer, it is coated in the outer surface of the titanium dioxide layer.
Preferably, wherein, the coating thickness of the titanium dioxide layer is 0.1-0.2mm.
Preferably, wherein, the thickness of the epoxy resin protective layer is 0.2-0.5mm.
The present invention comprises at least following beneficial effect:
1st, the infrared ray rejection rate of the polycarbonate layered plate of infrared ray barrier provided by the invention can substantially reach 100%, while ultraviolet isolating rate can reach 99%, while light transmittance can also reach 85%, therefore any occasion is can be suitably used for, There is preferable water resistance and compressive property simultaneously.
2nd, the polycarbonate layered board raw material cost of infrared ray barrier provided by the invention is low, use cost is low.
3rd, infrared ray provided by the invention, which obstructs polycarbonate layered plate, has light, resistance to compression and sound insulation value, and safety Coefficient is high.
4th, infrared ray provided by the invention obstructs polycarbonate layered plate good water-proof effect, and can improve as needed more The visual effect of laminate.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Brief description of the drawings
Fig. 1 is the profile that infrared ray of the present invention obstructs polycarbonate layered plate;
Fig. 2 is the profile that infrared ray of the present invention obstructs polycarbonate layered plate.
Embodiment
Below in conjunction with the accompanying drawings and embodiment the present invention is described in further detail, to make those skilled in the art join Book word can be implemented according to this as directed.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein are not precluded from one or more The presence or addition of individual other elements or its combination.
1~embodiment of embodiment 4
As shown in figure 1, the invention provides a kind of infrared ray to obstruct polycarbonate layered plate, including:
Multi-layer sheet body, its transparent acrylic for including two layers of polycarbonate plate 1 and being clipped among two layers of polycarbonate plate 1 Plate 2, press close in the plate face of transparent acrylic 2 to offer several respectively in two layers of polycarbonate plate 1 and be used to house hollow glass The storage tank 4 of glass pearl 3, and several storage tanks 4 are in lattice-distribution in the plate face of polycarbonate plate 1, each storage tank 4 Interior accommodating at least two hollow glass beads 3, for preferably fixation hollow bead 3, hollow glass bead 3 is bonded in storage tank In 4, while the tack coat formed between transparent acrylic 2 and two layers of polycarbonate plate 1 by high polymer binder is bonded as Integrative-structure, the particle diameter of hollow glass bead 3 is 500~600 mesh;
Infrared-reflecting coated 5, it coats the outer surface of one layer of polycarbonate plate 1 wherein, infrared-reflecting coated 5 by The outer surface that nano ATO liquid coats one layer of polycarbonate plate wherein is formed, for reflecting infrared ray;
Infrared ray absorbing coating 6, it is laid on the outer surface of other one layer of polycarbonate plate 1, for example, infrared ray absorbing applies Layer 6 is black transparent film;
PC waterproof film layers 7, it is attached to infrared-reflecting coated 5 outer surface.
Wherein, thickness, the thickness of transparent acrylic 2 of infrared-reflecting coated 5 thickness, two layers polycarbonate plate 1 And the infrared ray of each embodiment offer obstructs infrared ray rejection rate, ultraviolet isolating rate and the visible ray of polycarbonate layered plate Transmitance refers to table 1.
5~embodiment of embodiment 8
As shown in Fig. 2 the invention provides a kind of infrared ray to obstruct polycarbonate layered plate, including:
Multi-layer sheet body, its transparent acrylic for including two layers of polycarbonate plate 1 and being clipped among two layers of polycarbonate plate 1 Plate 2, press close in the plate face of transparent acrylic 2 to offer several respectively in two layers of polycarbonate plate 1 and be used to house hollow glass The storage tank 4 of glass pearl 3, and several storage tanks 4 are in lattice-distribution in the plate face of polycarbonate plate 1, each storage tank 4 Interior accommodating at least two hollow glass beads 3, for preferably fixation hollow bead 3, hollow glass bead 3 is bonded in storage tank In 4, while the tack coat formed between transparent acrylic 2 and two layers of polycarbonate plate 1 by high polymer binder is bonded as Integrative-structure;
Infrared-reflecting coated 5, it coats the outer surface of one layer of polycarbonate plate 1 wherein, infrared-reflecting coated 5 by The outer surface that nano ATO liquid coats one layer of polycarbonate plate wherein is formed, for reflecting infrared ray;
Infrared ray absorbing coating 6, it is laid on the outer surface of other one layer of polycarbonate plate 1, and the infrared ray absorbing applies Layer 6 is black transparent film;
Titanium dioxide layer 8, it is coated in the outer surface of infrared ray absorbing coating 6;
Epoxy resin protective layer 9, it is coated in the outer surface of titanium dioxide layer 8;
PC waterproof film layers 7, it is attached to infrared-reflecting coated 5 outer surface.
Wherein, infrared-reflecting coated 5 thickness, the thickness of two layers polycarbonate plate 1, transparent acrylic 2 thickness, The infrared ray barrier makrolon that the thickness of titanium dioxide layer 8 and the thickness of epoxy resin protective layer 9 and each embodiment provide Multiple-plate infrared ray rejection rate, ultraviolet isolating rate and visible light transmissivity refer to table 2.
The infrared ray that the 1~embodiment of embodiment 4 of table 1 provides obstructs the performance of polycarbonate layered plate
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
A wherein strata carbonic ester plate thickness (mm) 20 10 30 40
Other strata carbonic ester plate thickness (mm) 20 10 30 40
Transparent acrylic thickness (mm) 20 30 10 5
Infrared-reflecting coated thickness (mm) 0.2 0.1 0.05 0.25
Infrared ray absorbing coating layer thickness (mm) 0.05 0.08 0.2 0.1
Infrared ray rejection rate (%) 99.9 99.8 99.5 100
Ultraviolet isolating rate (%) 90 85 80 95
Visible light transmissivity (%) 80 78 70 75
The nano ATO liquid that the infrared ray that 1~embodiment of the embodiment of the present invention 4 provides is obstructed in polycarbonate layered plate rises To far infrared and barrier ultraviolet function, and the stable chemical performance of nano ATO is absorbed, infra-red radiation can be effectively prevented And ultraviolet radiation, the coating have fabulous compatibility with polycarbonate plate, adhesive force is strong, does not fall off persistently;Hollow glass bead As heat-reflecting material, can play a part of reflecting near infrared ray, and there is efficient ultraviolet isolating effect;Infrared ray is inhaled Receive coating and can absorb the infrared ray of any wavelength, and allow the visible light-transmissive of part, use 1~embodiment of embodiment 4 When the infrared ray barrier polycarbonate plate of offer, infrared ray absorbing coating can directly be contacted light source, can also be by PC Waterproof film layer directly contacts light source.
The infrared ray that the 5~embodiment of embodiment 8 of table 2 provides obstructs the performance of polycarbonate layered plate
Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
A wherein strata carbonic ester plate thickness (mm) 5 40 20 15
Other strata carbonic ester plate thickness (mm) 30 30 40 25
Transparent acrylic thickness (mm) 15 20 25 30
Infrared-reflecting coated thickness (mm) 0.07 0.16 0.12 0.18
Infrared ray absorbing coating layer thickness (mm) 0.03 0.06 0.12 0.09
Titanium dioxide layer thickness (mm) 0.1 0.2 0.15 0.18
Epoxy resin protective layer thickness (mm) 0.3 0.2 0.5 0.4
Infrared ray rejection rate (%) 99.5 99.8 99.7 100
Ultraviolet isolating rate (%) 98.5 98 99.5 100
Visible light transmissivity (%) 85 80 75 73
The nano ATO liquid that the infrared ray that 5~embodiment of the embodiment of the present invention 8 provides is obstructed in polycarbonate layered plate rises To far infrared and barrier ultraviolet function, and the stable chemical performance of nano ATO is absorbed, infra-red radiation can be effectively prevented And ultraviolet radiation, the coating have fabulous compatibility with polycarbonate plate, adhesive force is strong, does not fall off persistently;Hollow glass bead As heat-reflecting material, can play a part of reflecting near infrared ray, and there is efficient ultraviolet isolating effect;Infrared ray is inhaled Receive coating and can absorb the infrared ray of any wavelength, and allow the visible light-transmissive of part;Titanium dioxide layer can remove surrounding ring Peculiar smell in border, degradation of formaldehyde and other harmful substances, and can obstruct, decompose ultraviolet, improve barrier ultraviolet Function., can be by PC waterproofing membranes when the infrared ray provided using 5~embodiment of embodiment 8 obstructs polycarbonate plate Layer directly contacts light source, epoxy resin protective layer can also directly be contacted into light source.
As can be seen from Table 1 and Table 2, the polycarbonate layered plate of infrared ray barrier disclosed by the invention realizes excellent Infrared ray barrier property and ultraviolet isolating performance, and there is good light transmittance, cost of material is reduced, improves use Scope.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited In specific details and shown here as the legend with description.

Claims (8)

1. a kind of infrared ray obstructs polycarbonate layered plate, it is characterised in that including:
Multi-layer sheet body, its transparent acrylic for including two layers of polycarbonate plate and being folded in centre, the two stratas carbonic acid Ester plate presses close in the plate face of the transparent acrylic to offer several storage tanks for being used to house hollow glass bead, institute respectively It is in lattice-distribution, the transparent acrylic and two layers of the poly- carbon in the plate face of polycarbonate plate to state several storage tanks Structure is bonded as one by tack coat between acid esters plate;
Infrared-reflecting coated, it coats the outer surface of one layer of polycarbonate plate wherein, the infrared-reflecting coated reflection Infrared ray;
Infrared ray absorbing coating, it is laid on the outer surface of other one layer of polycarbonate plate, and the infrared ray absorbing coating is black Color light-transmissive film;
PC waterproof film layers, it is attached to the infrared-reflecting coated outer surface.
2. a kind of infrared ray according to claim 1 obstructs polycarbonate layered plate, it is characterised in that the infrared ray is anti- Coating is penetrated to be formed by the outer surface of nano ATO liquid coating one layer of polycarbonate plate wherein, it is described infrared-reflecting coated Coating thickness is 0.05-0.2mm.
3. a kind of infrared ray according to claim 1 obstructs polycarbonate layered plate, it is characterised in that two layers of the poly- carbon The thickness of acid esters plate is identical, and is 0.2-40mm.
4. a kind of infrared ray according to claim 1 obstructs polycarbonate layered plate, it is characterised in that in each storage tank It is fixed with least two hollow glass beads.
5. a kind of infrared ray according to claim 1 obstructs polycarbonate layered plate, it is characterised in that the multi-layer sheet sheet The thickness of body is 2-90mm.
6. a kind of infrared ray according to claim 1 obstructs polycarbonate layered plate, it is characterised in that also includes:
Titanium dioxide layer, it is coated in the outer surface of the infrared ray absorbing coating;
Epoxy resin protective layer, it is coated in the outer surface of the titanium dioxide layer.
7. a kind of infrared ray according to claim 6 obstructs polycarbonate layered plate, it is characterised in that the titanium dioxide The coating thickness of layer is 0.1-0.2mm.
8. a kind of infrared ray according to claim 6 obstructs polycarbonate layered plate, it is characterised in that the epoxy resin The thickness of protective layer is 0.2-0.5mm.
CN201710583461.XA 2017-07-18 2017-07-18 A kind of infrared ray obstructs polycarbonate layered plate Withdrawn CN107364194A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710583461.XA CN107364194A (en) 2017-07-18 2017-07-18 A kind of infrared ray obstructs polycarbonate layered plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710583461.XA CN107364194A (en) 2017-07-18 2017-07-18 A kind of infrared ray obstructs polycarbonate layered plate

Publications (1)

Publication Number Publication Date
CN107364194A true CN107364194A (en) 2017-11-21

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN107364194A (en)

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Application publication date: 20171121