CN107354714A - 用氯化锌/甲酸溶液制备磁性蚕丝织物 - Google Patents
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title claims abstract description 36
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 title claims abstract description 34
- 239000004744 fabric Substances 0.000 title claims abstract description 33
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 235000019253 formic acid Nutrition 0.000 title claims abstract description 18
- 235000005074 zinc chloride Nutrition 0.000 title claims abstract description 17
- 239000011592 zinc chloride Substances 0.000 title claims abstract description 17
- 239000000243 solution Substances 0.000 claims abstract description 19
- 239000006166 lysate Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000002122 magnetic nanoparticle Substances 0.000 claims abstract description 14
- 239000011259 mixed solution Substances 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000013019 agitation Methods 0.000 claims abstract description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 229910000859 α-Fe Inorganic materials 0.000 claims description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 4
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000006249 magnetic particle Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 18
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 241000255789 Bombyx mori Species 0.000 description 2
- 108010022355 Fibroins Proteins 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
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- 238000007906 compression Methods 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000863 Ferronickel Inorganic materials 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Abstract
本发明提供了一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法,该方法包括如下步骤:(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度5%‑20%的混合溶液,然后在混合溶液中加入磁性纳米粒子,机械搅拌制备得到分散有磁性纳米粒子的溶解液;(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧;(3)将浸轧后的蚕丝织物在微波下辐照;(4)将辐照后的蚕丝织物浸渍于乙醇水溶液中凝固,然后水洗、烘干。本制备技术简单易行,成本低廉,对蚕丝织物的强力损伤小,不改变蚕丝纤维表面性能,磁性纳米粒子在蚕丝织物上具有良好的牢度;本制备过程中未使用任何粘合剂,无毒无害。
Description
技术领域
本发明涉及一种功能织物的制备方法,尤其是一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法。
背景技术
将纳米粒子引入纺织纤维中,可以制备得到功能性纤维材料。目前将纳米粒子引入蚕丝纤维的制备方法很多,如:吸附法,溶胶凝胶法,层层组装法,涂层法,喂食法等。然而,吸附法通过主要通过分子间范德华力和离子键力使纳米粒子吸附到蚕丝纤维表面,水洗牢度较低;溶胶凝胶法和层层组装法的工艺过程较长,且较难控制;涂层法是利用粘合剂将纳米粒子粘合到蚕丝纤维表面,降低了蚕丝纤维对人体的亲肤性;喂食法是将纳米粒子混入家蚕食物中,使蚕丝纤维混入纳米粒子,缺点是效率很低。
氯化锌/甲酸溶液可以用于蚕丝与羊毛或其他动物毛纤维的混合物的定量测试,即氯化锌/甲酸溶液可以在较低温度下完全溶解蚕丝纤维。因此,本发明采用氯化锌/甲酸溶液在低温下部分溶解蚕丝表面丝素大分子,使纳米粒子能嵌入到蚕丝纤维表面,达到功能化蚕丝纤维,且不损伤蚕丝纤维机械性能的目的。
发明内容
本发明所要解决的技术问题是,针对以上现有技术存在的缺点,提出一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法。该制备技术简单易行,成本低廉,对蚕丝织物的强力损伤小,不改变蚕丝纤维表面性能,磁性纳米粒子在蚕丝织物上具有良好的牢度;该制备过程中未使用任何粘合剂,无毒无害。
为了实现上述目的,本发明采取的解决方案为:一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法,其特征在于包括以下步骤:
(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度5%-20%的混合溶液,然后在混合溶液中加入磁性纳米粒子,机械搅拌制备得到分散有磁性纳米粒子的溶解液;
(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧;
(3)将浸轧后的蚕丝织物在100-200W微波下辐照3-10min;
(4)将辐照后的蚕丝织物浸渍于乙醇水溶液中凝固,然后水洗、烘干。
本发明的有益效果在于,(1)采用浸轧法使有限的氯化锌/甲酸溶液主要分布于蚕丝纤维的表面,短时间的微波辐照只能对蚕丝纤维表面进行部分溶解,而不会损伤蚕丝纤维内部,减小对蚕丝纤维及织物物理机械性能的损伤;(2)在蚕丝纤维表面部分溶解的蚕丝蛋白形成蛋白质浓溶液,对纳米粒子具有粘附作用;(3)蚕丝纤维表面形成的蛋白质浓溶液在乙醇水溶液中重新凝固,起到对纳米粒子的粘合、包裹作用;(4)制备过程中未使用任何粘合剂,无毒无害。
具体实施方式
下文将结合具体实施例详细描述本发明。应当注意的是,下述实施例中描述的技术特征或者技术特征的组合不应当被认为是孤立的,它们可以被相互组合从而达到更好的技术效果。
实施例1
(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度5%的混合溶液,然后在混合溶液中加入0.4%(w/w)磁性纳米粒子钴铁氧体,机械搅拌制备得到分散有磁性纳米粒子钴铁氧体的溶解液;
(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧,轧余率为95%;
(3)将浸轧后的蚕丝织物在180W微波下辐照5min;
(4)将辐照后的蚕丝织物浸渍于乙醇溶液中凝固10min,然后水洗、烘干。
实施例2
(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度15%的混合溶液,然后在混合溶液中加入0.2%(w/w)磁性纳米粒子镍铁氧体,机械搅拌制备得到分散有磁性纳米粒子镍铁氧体的溶解液;
(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧,轧余率为115%;
(3)将浸轧后的蚕丝织物在150W微波下辐照8min;
(4)将辐照后的蚕丝织物浸渍于乙醇溶液中凝固10min,然后水洗、烘干。
实施例3
(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度12%的混合溶液,然后在混合溶液中加入0.7%(w/w)磁性纳米粒子四氧化三铁,机械搅拌制备得到分散有磁性纳米粒子四氧化三铁的溶解液;
(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧,轧余率为75%;
(3)将浸轧后的蚕丝织物在100W微波下辐照10min;
(4)将辐照后的蚕丝织物浸渍于乙醇溶液中凝固10min,然后水洗、烘干。
本文虽然已经给出了本发明的一些实施例,但是本领域的技术人员应当理解,在不脱离本发明精神的情况下,可以对本文的实施例进行改变。上述实施例只是示例性的,不应以本文的实施例作为本发明权利范围的限定。
Claims (2)
1.一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法,其特征在于,包括如下步骤:
(1)溶解液的制备:将氯化锌加入到甲酸中,形成浓度5%-20%的混合溶液,然后在混合溶液中加入磁性纳米粒子,机械搅拌制备得到分散有磁性纳米粒子的溶解液;
(2)将蚕丝织物在步骤(1)所得的溶解液中多次浸轧;
(3)将浸轧后的蚕丝织物在100-200W微波下辐照3-10min;
(4)将辐照后的蚕丝织物浸渍于乙醇水溶液中凝固,然后水洗、烘干。
2.根据权利要求1所述的一种使用氯化锌/甲酸溶液制备磁性蚕丝织物的方法,其特征在于:磁性粒子包括钴铁氧体、镁铁氧体、镍铁氧体、四氧化三铁等纳米粒子。
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