CN107353877A - A kind of liquid anti-ice-snow material and its method is applied in combination with solid ice-melt snow material - Google Patents
A kind of liquid anti-ice-snow material and its method is applied in combination with solid ice-melt snow material Download PDFInfo
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- CN107353877A CN107353877A CN201710581138.9A CN201710581138A CN107353877A CN 107353877 A CN107353877 A CN 107353877A CN 201710581138 A CN201710581138 A CN 201710581138A CN 107353877 A CN107353877 A CN 107353877A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
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Abstract
Method is applied in combination the invention provides a kind of liquid anti-ice-snow material and its with " the consolidating after first liquid " of solid ice-melt snow material.This kind of application method be：Before snowfall is arrived or when just starting, to road surface spraying liquid anti-ice-snow material, the material has to be not easy to slide to curb when dispensing, it is not easy quickly to be lost in because ice and snow solution dilutes, can be produced on road surface separation layer to prevent stagnant ice snow be bonded on road surface, and will not road pavement cause corrosion the advantages of.After there is accumulated snow or icing phenomenon, then dispense solid ice-melt snow material.Two kinds of materials are used in combination, as soon as liquid anti-ice-snow material usage is solid ice-melt avenge material ten/, directly can avenge material for solid ice-melt and enough humidity is provided, and can produce to act synergistically and reach the effect of more preferable melting ice and snow.Wherein, liquid anti-ice-snow material by mass percentage consisting of：Freezing point depressing agent 20%~65%, carbohydrate 1%~10%, water 27%~79%.
Description
Technical field
The present invention relates to a kind of method that is applied in combination of snow melting material, this method is specifically related to a kind of liquid anti-ice-snow material
Exploitation and its method is applied in combination with solid ice-melt snow material.
Background technology
The winter accumulated snow on road surface freezes and has a strong impact on the safety of people, and usual snow removing method has three kinds:(1) resist
Snow and ice climbing, i.e., prevent snow and ice in road surface freezing by the method for chemistry；(2) snow removal with machine operation, that is, big machinery is utilized
Equipment removes accumulated snow from road surface；(3) melt snow and ice climbing, i.e., the accumulated snow being frozen on road surface is carried out by the method for chemistry clear
Remove.
Three of the above method respectively has advantage and disadvantage, and (1) anti-ice-snow material is usually using solid salt either salt at present
The aqueous solution, it is easy to use, but the simple aqueous solution using salt is as anti-ice-snow material, because it is playing a role
The ice and snow rapid dilution that can be melted simultaneously, in the case of a large amount of uses, when pavement temperature is higher than the freezing point of solution, it can make
Into the quick loss of anti-ice-snow material, when pavement temperature is less than the freezing point of solution, the solution after dilution is easy to freeze again
Cheng Bing, cause bigger road traffic hidden danger.(2) snow removal with machine due to efficiency it is low, it is icy on road after it is not easy to operate wait limitation, more
More is to need to coordinate snow melting material to be used together the adhesion that effectively could be reduced or eliminate between ice sheet and road surface.(3) it is single
Solid Snow Agent solely is used, is that Snow Agent particle spherical during shedding easily slides to curb first, causes the inequality dispensed
The waste of uniform Snow Agent, and the burden of increase environment.Secondly, solid Snow Agent needs to dissolve and could send out after environment moisture absorption
The effect of its deicing or snow melting is waved, it is longer to play efficacy window.Simultaneously as the spreading of solid Snow Agent is to snow or freezing
Carry out later, penetrate thicker ice sheet, melting the ice sheet combined with road surface needs the longer time.
In addition, use chief destructive to caused by environment of traditional freeze proof deicing product be it to metal, concrete and
The corrosion of bituminous paving, so add which kind of corrosion inhibiter has turned into whole world exploitation high-efficiency environment friendly to reduce the corrosivity of deicer
The main target of type product, the research work that there is correlation the country are carried out, but still suffer from corrosion mitigating effect and owe preferable, high expensive, and
Addition is small to cause product to be difficult the problems such as being well mixed.
The content of the invention
The defects of present invention exists for prior art and application, there is provided a kind of liquid anti-ice-snow material, and propose one kind
The method of anti-ice snow removing is applied in combination in " solid after first liquid ".
Described liquid anti-ice-snow material, by mass percentage its specifically comprise：
Freezing point depressing agent 20%~65%
Carbohydrate 1%~10%
Water 27%~79%
Wherein：
Described freezing point depressing agent can be that sodium chloride, calcium chloride, magnesium chloride, potassium acetate, calcium acetate magnesium salt etc. are therein
It is one or more of.
Described carbohydrate can be monose, polysaccharide, cellulose and its derivates class, dietary fiber, xanthans, card
Draw the one or more therein such as glue.
Described " solid after first liquid " method of being applied in combination is：According to weather warning situation, open before snowfall is arrived or just
During the beginning, certain density liquid anti-ice-snow materials for later use first is prepared by quality composition, spraying operation, profit are carried out by watering device
With the amount of sprinkling sowing of linkage VFC liquid anti-ice-snow material, it is ensured that road surface is covered by liquid anti-ice-snow material, so on road surface
Upper generation is effectively isolated layer and is bonded in prevent stagnant ice snow on road surface.Appearance icing is further reduced when there is accumulated snow or temperature now
As rear, then the ice-melt of solid high-efficiency corrosion inhibition type is dispensed by truck spreader and avenges material, it is specific dispense dosage according to snowfall size (slight snow,
Middle school, heavy snow etc.) it is adjusted.
Material is avenged in described solid high-efficiency corrosion inhibition type ice-melt, and it is specifically comprised by mass percentage：
Freezing point depressing agent 95%~98%
Corrosion inhibiter 0.5%~4%
Water 1%~2%
Wherein：
Described freezing point depressing agent can be that sodium chloride, calcium chloride, magnesium chloride, potassium acetate, calcium acetate magnesium salt etc. are therein
It is one or more of.
Described corrosion inhibiter can be imidazoles, sodium gluconate, sodium dihydrogen phosphate, nine silicate hydrate disodiums, sodium molybdate
Etc. one or more therein.
Beneficial effect：
(1) fluid present invention anti-ice-snow material has good rust inhibition and adhesiveness, will not road pavement cause to corrode, delay
It is preferable to lose effect, is not easy during spreading to slide to curb, can be kept for the longer residence time, be not easy because ice and snow solution is dilute on road surface
Release and be quickly lost in, effectively ice and snow can be prevented to be bonded on road surface.The material has with solid ice-melt snow material and cooperateed with simultaneously
Effect, it just can be good at promoting the deicing or snow melting ability of solid ice-melt snow material in the case where dosage is seldom；
(2) liquid anti-ice-snow material is first sprayed, then broadcasts sowing solid ice-melt snow material again, the method being applied in combination can increase
The effect of strong anti-ice deicing, is greatly decreased the usage amount of solid Snow Agent, and reduces because the use of anti-snow and ice material is to gold
Corrosion and destruction etc. caused by category and road surface.
(3) the solid ice-melt snow material being used in combination, deicing or snow melting ability is strong, due to the liquid anti-ice-snow material first sprayed
Humidity can not only be provided for its dissolving, meanwhile, the ice sheet not being frozen in directly on road surface is easier to be worn by solid ice-melt snow material
Thoroughly, be advantageous to it and faster play deicing or snow melting effect.
Brief description of the drawings
Fig. 1 is deicing or snow melting schematic device.
Embodiment
The following examples can make those skilled in the art that the present invention be more fully understood, but these embodiments are not
Limiting the scope of the invention.
Embodiment 1
The component proportion of the present embodiment is shown in Table 1 (by percentage to the quality)
Embodiment 2
The component proportion of the present embodiment is shown in Table 2 (by percentage to the quality)
Embodiment 3
The component proportion of the present embodiment is shown in Table 3 (by percentage to the quality)
Embodiment 4
The component proportion of the present embodiment is shown in Table 4 (by percentage to the quality)
Embodiment 5
The component proportion of the present embodiment is shown in Table 5 (by percentage to the quality)
Embodiment 6
The component proportion of the present embodiment is shown in Table 6 (by percentage to the quality)
Comparative example 1
The component proportion of the present embodiment is shown in Table 7 (by percentage to the quality)
Comparative example 2
The component proportion of the present embodiment is shown in Table 8 (by percentage to the quality)
The product of above-described embodiment and comparative example is tested by the following method：
First, deicing or snow melting effect
It is special for the deicing or snow melting effect under different occupation modes in more intuitively more each embodiment and comparative example
The gross mass for the freezing point depressing agent for arranging to use in each embodiment and comparative example is identical, is 10g.
Characterize liquid anti-ice-snow material by determining the volume of ice-melt solution in each embodiment and comparative example and consolidate
The deicing or snow melting ability of material is avenged in body ice-melt.Liquid anti-ice-snow is characterized by determining the concentration of freezing point depressing agent in ice-melt solution
The degree that material and solid ice-melt snow material are lost in solution.The concentration of freezing point depressing agent is higher, shows the easier stream of the material
Lose, cause deicing or snow melting less able, the increase of actual use amount.
1st, test material and device
1.1 test temperature
This experiment is carried out in -10 DEG C of Homothermal Proof Box.
1.2 liquid anti-ice-snow materials
Liquid anti-ice-snow material is after solid matter is weighed in mass ratio, is added sequentially to be placed in examination after dissolving in water
It is stand-by at a temperature of testing.
Material is avenged in 1.3 solid ice-melts
Solid ice-melt snow material is after solid matter is weighed in mass ratio, adds water, is made after well mixed through two pairs of rollers
Grain machine is granulated, and screening obtains finished product, and finished product is shaped as elliposoidal, and particle diameter is 6~8mm.
1.4 Marshall test blocks
Prepare the Marshall AC-13 test specimens of eight pieces of identical sizes, the length and width for the Marshall test block that this experiment uses are a height of
300mm×300mm×50mm.Test specimen is placed more than 1 hour in test temperature, and temperature reaches saturation state rear and can be used.
1.5 mould
Using 400mm × 400mm × 50mm square container, two pieces of cushion blocks are placed in lower section, collect and melt in convenient experiment
Liquid.The square container that this experiment uses is visual transparent acrylic material.
The preparation of 1.6 ice cubes
The length of side is used to freeze producing ice cakes for 30cm square mould.The accurate water for weighing 500g is placed in mould, it is rearmounted
It is standby after placement 12h in -10 DEG C of refrigerator, it is parallel to freeze eight parts of ice cubes of system.
1.7 syringe
Ice-melt solution is drawn, determines the volume of solution and the concentration of freezing point depressing agent afterwards.
The measure of freezing point depressing agent concentration in 1.8 liquid
The measure of freezing point depressing agent content is with reference to GB/T5462-2003
2nd, process is tested
2.1 test method
Specific deicing or snow melting device is as shown in schematic diagram 1：
Embodiment 1：A ice cube is placed after spraying one layer of anti-ice-snow material on test specimen, dispenses solid ice-melt snow material afterwards
Material.Wherein, the mass ratio of liquid anti-ice-snow material and solid ice-melt snow material is 1：10.Solid ice-melt snow material should be as far as possible
Uniformly dispense.
Embodiment 2：Anti-ice-snow material is sprayed on test specimen, places ice cube, sprays anti-ice-snow material repeatedly afterwards.
Embodiment 3-6：With the experimental procedure of embodiment 1.
Comparative example 1：Anti-ice-snow material is sprayed on test specimen, places ice cube, sprays anti-ice-snow material repeatedly afterwards.
Comparative example 2：Ice cube is directly placed on test specimen, dispenses solid ice-melt snow material afterwards.
2.2 ice-melt solution Collecting and dealings
After test specimen dispenses, syringe collecting ice-melt solution was utilized every 20 minutes, ice-melt solution is collected into and again can not
Untill drawing, preferably no more than 1.5 minutes.The solution being collected into carries out the measure of volume and freezing point depressing agent concentration.
2.3 testing result
The anti-ice of table 9 snow removing effect
Note：The volume for the solution that V- is collected into, mL；The concentration of the freezing point depressing agent for the solution that C- is collected into, gL-1
From table 9 cumulative volume of ice-melt solution can be seen that the present invention that method (embodiment 1) is applied in combination is more single
For liquid anti-ice-snow material (embodiment 2) or single use solid ice-melt snow material (comparative example 2), snow melt
Ice ability has significant raising；The sodium chloride concentration and volume for the solution being collected into from each period are found, in snow melt
40min before ice, compared to comparative example 1, embodiment 2 is added carbohydrate and can effectively reduced because of freezing point depressing agent quilt
The snow-broth of thawing dilutes and is lost in.
The liquid anti-ice-snow material (embodiment 2) of the present invention is compared to traditional liquid anti-ice-snow material (comparative example
1) there is the advantages of being not easy to be diluted by ice and snow, and grown in road surface retention time, being capable of significantly more efficient deicing or snow melting.
The anti-ice of table 10 snow removing effect
Note：The volume for the solution that V- is collected into, mL；The concentration of the freezing point depressing agent for the solution that C- is collected into, gL-1
For synthesis, the deicing or snow melting best results that method is applied in combination of the invention, under identical environmental condition, energy
The obvious usage amount for reducing Snow Agent.
2nd, corrosion mitigating effect
To determine the effect of corrosion inhibiter, the selection of component, test are carried out with reference to DB11/T 161-2012 rotary hanging plate method
Method and test condition are as follows：
Etchant solution is prepared first：
(1) liquid anti-ice-snow material can be directly used as etchant solution.
(2) solid ice-melt snow material is configured to the test solution that mass fraction is 18.0% in 2000mL beaker.
(3) it is applied in combination in method, liquid anti-ice-snow material and solid ice-melt snow material is pressed 1：10 matched after conduct
Etchant solution.
Sample is No. 20 carbon steel coupons (GB/T 699) of rectangle, and size is:5mm × 2.5mm × 0.2mm, surface area are
28mm2, sample wipes surface grease with filter paper before experiment, dried after acetone and soaked in absolute ethyl alcohol, finally by sample by
It is individual to be wrapped up with filter paper, it is placed in standby in drier.Experiment start after with being soaked in corresponding volume after assay balance correct amount sample
Number etchant solution in, liquor capacity and test piece area ratio are 24mL/cm2~26mL/cm2, experimental temperature is 40 DEG C, test piece
Linear velocity is 0.35m/s, during be not passed through air, after uninterrupted immersion 48 hours, wipe out surface iron rust again through pickling, alkali
Wash, pure water wash after with absolute ethyl alcohol remove excessive moisture, weighed after drying.Corrosion inhibition rate is determined according to corrosion weight loss.Rate of corrosion meter
It is as follows to calculate formula：
In formula：M is test piece mass loss, g；
m1For the mass loss average value of test piece pickling blank test, g；
S be test piece surface area, cm2；
ρ be test piece density, g/cm3；
T is test period, h；
8760 be the hourage suitable with 1 year, h/a；
10 be the millimeter suitable with 1cm, mm/cm.
The corrosion inhibition rate X being expressed as a percentage2：
In formula：X0For the rate of corrosion of test piece blank test, mm/a；
X1For the rate of corrosion of test piece, mm/a.
Each embodiment corrosion of carbon steel result is as shown in table 11：
The corrosion of carbon steel experimental result of table 11
Data, which can be seen that addition carbohydrate, from table 11 can significantly reduce liquid anti-ice-snow material to steel
Corrosion, the corrosion inhibition that method is applied in combination is good.
Claims (8)
- A kind of 1. liquid anti-ice-snow material, it is characterised in that：The liquid anti-ice-snow material by mass percentage consisting of：Ice Point inhibitor 20%~65%, carbohydrate 1%~10%, water 27%~79%.
- 2. liquid anti-ice-snow material according to claim 1, it is characterised in that：Described freezing point depressing agent be sodium chloride, One or more in calcium chloride, magnesium chloride, potassium acetate, calcium acetate magnesium salt.
- 3. liquid anti-ice-snow material according to claim 1, it is characterised in that：Described carbohydrate is monose, more Sugar, cellulose and its derivates class, the one or more in dietary fiber, xanthans, carragheen.
- 4. the application method of liquid anti-ice-snow material according to claim 1, it is characterised in that：The application method is will Liquid anti-ice-snow material uses with solid ice-melt snow combination of materials, before snowfall is arrived or when just starting, passes through watering device To road surface spraying liquid anti-ice-snow material, using VFC its amount of sprinkling sowing of linking, after there is accumulated snow or icing phenomenon, then Solid ice-melt is dispensed by truck spreader and avenges material.
- 5. the application method of liquid anti-ice-snow material according to claim 4, it is characterised in that：The liquid anti-ice-snow material Mass ratio when material and solid ice-melt snow combination of materials use is 1:10.
- 6. the application method of liquid anti-ice-snow material according to claim 4, it is characterised in that：Material is avenged in the solid ice-melt Material by mass percentage consisting of：Freezing point depressing agent 95%~98%, corrosion inhibiter 0.5%~4%, water 1%~2%.
- 7. the application method of liquid anti-ice-snow material according to claim 6, it is characterised in that：Described freezing point depressing agent For the one or more in sodium chloride, calcium chloride, magnesium chloride, potassium acetate, calcium acetate magnesium salt.
- 8. the application method of liquid anti-ice-snow material according to claim 6, it is characterised in that：Described corrosion inhibiter is miaow One or more in azole, sodium gluconate, sodium dihydrogen phosphate, nine silicate hydrate disodiums, sodium molybdate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581138.9A CN107353877B (en) | 2017-07-17 | 2017-07-17 | Liquid ice and snow resisting material and combined use method of liquid ice and snow resisting material and solid ice and snow melting material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710581138.9A CN107353877B (en) | 2017-07-17 | 2017-07-17 | Liquid ice and snow resisting material and combined use method of liquid ice and snow resisting material and solid ice and snow melting material |
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| CN107353877A true CN107353877A (en) | 2017-11-17 |
| CN107353877B CN107353877B (en) | 2020-10-02 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108485605A (en) * | 2018-05-03 | 2018-09-04 | 中盐金坛盐化有限责任公司 | A kind of dedicated snow melt deicer and preparation method thereof with antistrip performance of airfield runway |
| CN115851229A (en) * | 2021-09-24 | 2023-03-28 | 中国科学院宁波材料技术与工程研究所 | Multifunctional anti-icing double-ion material and preparation method and application thereof |
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| CN1332220A (en) * | 2001-06-08 | 2002-01-23 | 岳石 | Efficient low-corrosive ice and snow eliminating agent |
| CN1678709A (en) * | 2002-07-22 | 2005-10-05 | 托德·A·布卢默 | Anti-icing and deicing compositions and method of their application |
| CN105860931A (en) * | 2016-05-05 | 2016-08-17 | 中盐金坛盐化有限责任公司 | Efficient corrosion-inhibiting anti-freezing deicing agent and preparation method thereof |
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| CN1332220A (en) * | 2001-06-08 | 2002-01-23 | 岳石 | Efficient low-corrosive ice and snow eliminating agent |
| CN1678709A (en) * | 2002-07-22 | 2005-10-05 | 托德·A·布卢默 | Anti-icing and deicing compositions and method of their application |
| CN105860931A (en) * | 2016-05-05 | 2016-08-17 | 中盐金坛盐化有限责任公司 | Efficient corrosion-inhibiting anti-freezing deicing agent and preparation method thereof |
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Cited By (2)
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| CN108485605A (en) * | 2018-05-03 | 2018-09-04 | 中盐金坛盐化有限责任公司 | A kind of dedicated snow melt deicer and preparation method thereof with antistrip performance of airfield runway |
| CN115851229A (en) * | 2021-09-24 | 2023-03-28 | 中国科学院宁波材料技术与工程研究所 | Multifunctional anti-icing double-ion material and preparation method and application thereof |
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| CN107353877B (en) | 2020-10-02 |
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