CN107353558A - A kind of conducting polymer composite - Google Patents

A kind of conducting polymer composite Download PDF

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Publication number
CN107353558A
CN107353558A CN201710387631.7A CN201710387631A CN107353558A CN 107353558 A CN107353558 A CN 107353558A CN 201710387631 A CN201710387631 A CN 201710387631A CN 107353558 A CN107353558 A CN 107353558A
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CN
China
Prior art keywords
parts
polymer composite
conducting polymer
esters
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710387631.7A
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Chinese (zh)
Inventor
潘征鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Chengshan Polymer Material Co Ltd
Original Assignee
Nantong Chengshan Polymer Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Chengshan Polymer Material Co Ltd filed Critical Nantong Chengshan Polymer Material Co Ltd
Priority to CN201710387631.7A priority Critical patent/CN107353558A/en
Publication of CN107353558A publication Critical patent/CN107353558A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of conducting polymer composite, including 20 30 parts of pyrrole monomers, 20 30 parts of acrylamides, 15 20 parts of benzene alkene, 26 parts of glass fibres, 5 10 parts of carbon fibers, 12 parts of carbon blacks, 12 parts of rare earths, 12 parts of alkyl aluminums, 20 40 parts of esters of acrylic acids.It the advantage is that：Big conducting polymer composite is made by adding glass fibre, carbon fiber, carbon black, rare earth, alkyl aluminum in pyrrole monomer, acrylamide, benzene alkene and esters of acrylic acid group mixture in the present invention, it is strong to provide conducting polymer composite heat endurance, and it is easy to process, suitable for industrial mass production.

Description

A kind of conducting polymer composite
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of conducting polymer composite.
Background technology
With the rapid development of modern industry, the utilization of high polymer material is more and more extensive, and major colleges and universities, research institute all set High polymer material research center is put.High polymer material is also referred to as polymeric material, is using high molecular polymer as matrix, is furnished with The material that other auxiliary agents are formed, high polymer material are divided into rubber, fiber, plastics, polymer binder, macromolecule by characteristic and applied Material and polymer-based composite etc..High polymer material is in electric and electronic industry, aerospace industry, construction industry, medicine equipment, medical treatment bag Suffer from being widely applied in the every profession and trades such as dress, transportation, home electric, agricultural.
Conducting polymer composite is with conducting function（Including semiconduction, metallic conductivity and superconductivity）, conductance Polymeric material of the rate in more than 10S/m.Macromolecule conducting material have small density, easy processing, it is corrosion-resistant, can large area into The features such as film and electrical conductivity can be adjusted in the range of the individual order of magnitude more than ten, can be used as various metals material and nothing The substitute of machine conductive material, and turn into the indispensable a kind of material of many advanced industrial departments and sophisticated technology field Material.The one kind of polyaniline as macromolecule conducting material, in addition to its electrical characteristics, also having can be simpler by cheap aniline Just synthesize and the excellent stability to oxygen etc. is shown in the state of showing electric conductivity the advantages of and characteristic.But it adds Caused by work is bad and stability is not high, the application of conductive polymer material industrially is seriously hindered.Especially in electrical equipment member Otherwise application in part, even if other performance is good again, can not be also applied, it is necessary to conductive material has good heat endurance.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide, a kind of heat endurance is strong, easy to process leads Electric high polymer material.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of conducting polymer composite, its innovative point It is：In parts by weight, including following component：
Pyrrole monomer 20-30 parts
Acrylamide 20-30 parts
Benzene alkene 15-20 parts
Glass fibre 2-6 parts
Carbon fiber 5-10 parts
Carbon black 1-2 parts
Rare earth 1-2 parts
Alkyl aluminum 1-2 parts
Esters of acrylic acid 20-40 parts
Further, the esters of acrylic acid is methyl acrylate, butyl acrylate, one kind in methyl methacrylate or two The mixture of kind.
Beneficial effects of the present invention are as follows：The present invention is mixed by pyrrole monomer, acrylamide, benzene alkene and esters of acrylic acid group Glass fibre, carbon fiber, carbon black, rare earth, alkyl aluminum are added in compound big conducting polymer composite is made, there is provided be conductive high Molecular material heat endurance is strong, and easy to process, suitable for industrial mass production.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of conducting polymer composite, in parts by weight, including following component：
20 parts of pyrrole monomer
20 parts of acrylamide
15 parts of benzene alkene
2 parts of glass fibre
5 parts of carbon fiber
1 part of carbon black
1 part of rare earth
1 part of alkyl aluminum
20 parts of methyl acrylate
Embodiment 2
A kind of conducting polymer composite, in parts by weight, including following component：
30 parts of pyrrole monomer
30 parts of acrylamide
20 parts of benzene alkene
6 parts of glass fibre
10 parts of carbon fiber
2 parts of carbon black
2 parts of rare earth
2 parts of alkyl aluminum
40 parts of butyl acrylate
Embodiment 3
A kind of conducting polymer composite, in parts by weight, including following component：
25 parts of pyrrole monomer
25 parts of acrylamide
17 parts of benzene alkene
4 parts of glass fibre
7 parts of carbon fiber
1.5 parts of carbon black
1.5 parts of rare earth
1.5 parts of alkyl aluminum
30 parts of methyl methacrylate
The present invention is by adding glass fibre, carbon fiber in pyrrole monomer, acrylamide, benzene alkene and esters of acrylic acid group mixture , carbon black, rare earth, alkyl aluminum big conducting polymer composite is made, there is provided conducting polymer composite heat endurance is strong, and is easy to Processing, suitable for industrial mass production.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention Rights protection scope in.

Claims (2)

  1. A kind of 1. conducting polymer composite, it is characterised in that：In parts by weight, including following component：
    Pyrrole monomer 20-30 parts
    Acrylamide 20-30 parts
    Benzene alkene 15-20 parts
    Glass fibre 2-6 parts
    Carbon fiber 5-10 parts
    Carbon black 1-2 parts
    Rare earth 1-2 parts
    Alkyl aluminum 1-2 parts
    Esters of acrylic acid 20-40 parts.
  2. A kind of 2. conducting polymer composite according to claim 1, it is characterised in that：The esters of acrylic acid is acrylic acid The mixture of one or both of methyl esters, butyl acrylate, methyl methacrylate.
CN201710387631.7A 2017-05-27 2017-05-27 A kind of conducting polymer composite Pending CN107353558A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710387631.7A CN107353558A (en) 2017-05-27 2017-05-27 A kind of conducting polymer composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710387631.7A CN107353558A (en) 2017-05-27 2017-05-27 A kind of conducting polymer composite

Publications (1)

Publication Number Publication Date
CN107353558A true CN107353558A (en) 2017-11-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710387631.7A Pending CN107353558A (en) 2017-05-27 2017-05-27 A kind of conducting polymer composite

Country Status (1)

Country Link
CN (1) CN107353558A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101023138A (en) * 2004-09-22 2007-08-22 信越聚合物株式会社 Conductive composition and process for production thereof, antistatic coating material, antistatic membrane, antistatic film, optical filter, optical information recording media, and condenser and pro
CN101418107A (en) * 2007-10-22 2009-04-29 东丽纤维研究所（中国）有限公司 Nano graphite high conductivity composite material and preparation method
CN103224694A (en) * 2013-04-18 2013-07-31 苏州旭光聚合物有限公司 Conductive PBT composite material
CN106589939A (en) * 2015-10-15 2017-04-26 徐文智 Conductive high polymer material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101023138A (en) * 2004-09-22 2007-08-22 信越聚合物株式会社 Conductive composition and process for production thereof, antistatic coating material, antistatic membrane, antistatic film, optical filter, optical information recording media, and condenser and pro
CN101418107A (en) * 2007-10-22 2009-04-29 东丽纤维研究所（中国）有限公司 Nano graphite high conductivity composite material and preparation method
CN103224694A (en) * 2013-04-18 2013-07-31 苏州旭光聚合物有限公司 Conductive PBT composite material
CN106589939A (en) * 2015-10-15 2017-04-26 徐文智 Conductive high polymer material

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Application publication date: 20171117