CN107338671A - A kind of manufacture method of the pure matter paper of dab - Google Patents
A kind of manufacture method of the pure matter paper of dab Download PDFInfo
- Publication number
- CN107338671A CN107338671A CN201710596990.3A CN201710596990A CN107338671A CN 107338671 A CN107338671 A CN 107338671A CN 201710596990 A CN201710596990 A CN 201710596990A CN 107338671 A CN107338671 A CN 107338671A
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- paper
- apmp
- ctmp
- lbkp
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/10—Mixtures of chemical and mechanical pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of manufacture method of the pure matter paper of dab, as fibrous raw material match somebody with somebody with bleached sulphate softwood pulp NBKP, bleached sulphate hardwood chemical pulp LBKP, bleaching chemithermo mechanical pulp CTMP and alkaline hydrogen peroxide bleaching aspen mechanical slurry APMP and copy, product is sieved through underflow, condiment, punching slurry, desanding degasification, starching, fine screen, wet end dehydration forming, squeezing, preceding drying, surface are coated with, after drying, press polish, batch, packing forms, it is characterised in that:Its weight proportion is:NBKP20~30%;LBKP 20~30%;APMP 40‑60%;CTMP 5 10%, wherein, the 55SR of CTMP beating degrees 40 45SR, APMP beating degree 51;Bleached sulphate softwood pulp NBKP is using chitosan auxiliary mashing;LBKP and NBKP increases using chitosan auxiliary mashing.The pure matter paper of gained dab of the invention can be used as high-grade books, advertisement etc. to use paper, and paper exquisiteness is good, paper is clean, color and luster is soft, have excellent color rendition performance, while surface strength is high, can meet high speed printing.
Description
Technical field
The present invention relates to a kind of manufacture method of the pure matter paper of dab.
Background technology
As our people's living standard improves, more and more higher, especially some high-end print paper are required to paper quality,
It is required that sheet gloss is small, with uncoated conventional offset stationery seemingly, simultaneously, it is desirable to which good print gloss, paper are very thin
It is greasy, and printing effect especially color printing effect will be close to art paper, this paper feeding opens hair and proposes very hang-up.Sheet gloss is small then
It is required that paper smoothness can not be too high, and can not use traditional paper coating mode, this requires good exquisiteness with paper
And print gloss contradiction.Meanwhile such product in printing in use, typically no drying equipment, therefore to paper absorbency
It is required that it is very high, and traditional coating weight is poor in 16g/m2 products, absorbency, can not meet to print the fast requirement of rate of drying.Separately
Outside, the product requirement surface strength requires very high, and to meet low gloss, higher absorbency, often results in coating combination
Intensity declines, and can not meet rotation, eight color chromatography requirements at a high speed.Such high-end print often uses some external art papers, into
This height, seriously limit the development of the high-end Cultural Paper printing market in China.
The content of the invention
It is an object of the invention to provide a kind of manufacture method of the pure matter paper of dab, obtained product:Paper is fine and smooth, low paper
Face gloss and high print gloss, excellent color rendition performance, and paper are clean, color and luster is soft, and surface strength is high, can be full
Foot rotates at a high speed and lithographic printing, can be used as high-grade books, photograph album, brochure, advertisement etc. and uses paper.
To realize requirements above, the present invention uses following technical scheme, a kind of manufacture method of the pure matter paper of dab, with drift
White sulfate softwood pulp(NBKP), bleached sulphate hardwood chemical pulp(LBKP), bleaching chemithermo mechanical pulp
(CTMP)And alkaline hydrogen peroxide bleaching aspen mechanical slurry(APMP)Carried out as fibrous raw material with copying, product sieves through underflow, condiment,
Punching slurry, desanding degasification, starching, fine screen, wet end dehydration forming, squeezing, preceding drying, surface coating, rear drying, press polish, batch, beat
Bag forms, it is characterised in that:
(1)Slurry is bleached sulphate softwood pulp(NBKP), bleached sulphate hardwood chemical pulp(LBKP), bleaching it is pre-
Heat chemistry mechanical pulp(CTMP)And alkaline hydrogen peroxide bleaching aspen mechanical slurry(APMP).Slurry weight matches:NBKP20~
30%;LBKP 20~30%;APMP 40-60%;CTMP 5-10%.Wherein, CTMP beating degrees 40-45SR, APMP beating degree 51-
55SR;
(2)Using 2-3kg/t slurry chitosan assistant chemical slurry mashing, beating resultses are improved, improve paper sheet stiffness and surface strength,
LBKP and NBKP increases to be controlled in 30-35SR, 40-45SR respectively using chitosan auxiliary mashing mode, beating degree;
(3)Due to using large scale mechanical pulp, resin content is high, to ensure normal production, disconnected paper is reduced, using resin biology enzyme
Control resin, dosage 0.05-0.10kg/t paper;
(4)In formulation for coating material, using the hollow ball plastic pigments of 3-5 parts, print gloss is improved to reduce sheet gloss, together
When, improve absorbency;
(5)In formulation for coating material, using the big particle diameter coarse whiting of 70-90 parts, coarse whiting particle diameter rank is between 60 to 80 grades, to improve paper
Absorbency and reduction sheet gloss, while improve surface strength;
(6)In formulation for coating material, using a kind of sheet china clay of big particle diameter of 10-20 parts, it is less than the particle total amount of 2 micron grain sizes
Control is in 78-84%.To improve coating covering, further meet paper low gloss, high print gloss requirement;
(7)In formulation for coating material, in terms of adhesive, to improve absorbency, styrene-butadiene latex is substituted using polyvinyl acetate part.Its
In, polyvinyl acetate number is 4-8, and styrene-butadiene latex number is 4-8;In addition, relatively conventional coating paper, raising coating are formed sediment simultaneously
Powder dosage(6-10 parts), styrene-butadiene latex dosage is reduced, to improve absorbency;
(8)In formulation for coating material, to improve paper feel, using nonionic calcium stearate, number is controlled in 0.5-1.5 parts.
Product major parameter produced by the present invention is:Quantitative 60-100g/m2, paper absorbency K&N values:35-50%, move mill
Coefficient of friction is less than 0.4;Sheet gloss degree:2-10%, print gloss:35-50%;Surface strength >=1.0m/s;Smoothness >=
40s;Bulk >=1.2cm3/g;Fracture length >=5000m;Paper color is white, whiteness 84-86%ISO.
Present invention seek to address that problem above, meets that the country is high-end and is required with paper, mainly take following technology:(1), use
A kind of Novel coating formula of independent research, plastic pigments are introduced, and introduce a kind of big particle diameter coarse whiting, while introduce a kind of big grain
Footpath sheet china clay, adhesive aspect, to improve absorbency, styrene-butadiene latex is substituted using polyvinyl acetate part, reduced simultaneously
Dosage of latex, improve coating starch dosage;(2)In the case of higher coating weight, to reach good deflection using paper, using one
Kind deflection auxiliary agent, improves paper sheet stiffness;(3)To make paper surface fine and smooth, hardwood pulp is used as main body, a small amount of needlebush of adapted
Chemical pulp produces.
The pure matter paper technique of dab involved in the present invention, using domestic exclusive technology, product is as high-grade books, advertisement etc.
With paper, paper exquisiteness is good, paper is clean, color and luster is soft, has excellent color rendition performance, while surface strength is high, energy
Meet high speed printing.The product receives praises from customers after launch, develops this product for adjusting the product mix, opening up
Profit space is opened up, improves product specification, promotes the development of the high-end Cultural Paper printing market in China to be respectively provided with important meaning.
Main innovation point of the present invention is:(1)To realize the low sheet gloss of paper and high print gloss, higher suction
Function, a kind of unique coating of independent research such as Mo Xing, high surface strength, excellent handle and the reduction of excellent printing color are matched somebody with somebody
Side:Including:1)Using part hollow ball plastic pigments, print gloss is improved to reduce sheet gloss, meanwhile, improve blotting
Property.2)Using coarse whiting pigment of the particle diameter rank between 60 to 80 grades, to improve paper absorbency and reduce sheet gloss, simultaneously
Improve surface strength.3)Using a kind of sheet china clay of big particle diameter, to improve coating covering, further meet paper low gloss
And print high glaze requirement.4)Styrene-butadiene latex is substituted using polyvinyl acetate part, improves absorbency.5)To improve paper hand
Sense, using nonionic calcium stearate, Fractional domination is in 0.5-1.5%.(2)To realize the good deflection of paper, using 2-3kg/t
The chitosan assistant chemical slurry mashing of slurry, improves beating resultses.(3)Resin biology enzyme is employed, to control higher proportion mechanical
Pitch trouble problem caused by slurry.
Embodiment
Below by embodiment, the present invention is described in detail:
Embodiment 1
Poplar raw material is by stock, using PRC-APMP(P represents the pretreatment before defibrination, represents the chemistry that mill promotes slurry
Effect, APMP represent APMP)Whiteness 75%ISO, beating degree 54 is made in pulping process0SR poplar machine plasmas,
Outsourcing chemi-thermo-mechanical pulp CTMP beating degree 42SR, outsourcing bleached sulphate softwood pulp mashing to 430SR, bleach sulfuric acid
Salt hardwood pulp is beaten to 330SR, wherein, the shells of 2.5kg/t slurries is added in NBKP and LBKP pulping process, during pulping respectively
Glycan.Above-mentioned four kinds of slurries are by 45% poplar machine plasma, 25% bleached sulphate softwood pulp, 25% BRATSK, 5%
The ratio of chemi-thermo-mechanical pulp carry out with slurry, mixing disposed slurry is deployed into the mixing slurry of concentration 3.5%, in mixing slurry, addition
0.06 kg/t paper resin Pitch Control with Enzyme.Mixing slurry is sieved through underflow, adds starch enhancer during condiment, then rush slurry, desanding
Degasification, starching, fine screen, the dehydration of upper net forming(Control online concentration 0.92%, pH value 8.1 of surfing the Net), squeezing, preceding drying, surface apply
Drying, press polish after cloth, batch, packing forms the pure matter paper of dab.
In terms of coating, formulation for coating material is 3 parts of hollow ball pigment, 85 parts of coarse whiting pigment, 12 parts of china clay pigment, with paint
Total 100 parts, on the basis of pigment total amount, other coating chemicals are pressed:5 parts of polyvinyl acetate, 8 parts of styrene-butadiene latex, coating
8 parts of starch, 1 part of nonionic calcium stearate, CMC(Sodium carboxymethylcellulose)0.1 part, 0.5 part of water repellent agent, 0.3 part of defoamer,
Other chemicals are appropriate.Coating configuration concentration 68%, controlled using solid content by coating weight 16g/m2.
Through measuring:Quantitative 80g/m2, paper absorbency K&N values:38.5%, move mill coefficient of friction and be less than 0.28;Sheet gloss
Degree 3%, print gloss 36%;Surface strength 1.32m/s;Smoothness 50s;Bulk 1.26cm3/g;Fracture length 5260m;Paper
Color is white, whiteness 85.1%ISO.
Embodiment 2
Poplar raw material is by stock, using PRC-APMP(P represents the pretreatment before defibrination, represents the chemistry that mill promotes slurry
Effect, APMP represent APMP)Whiteness 75%ISO, beating degree 53 is made in pulping process0SR poplar machine plasmas,
Outsourcing chemi-thermo-mechanical pulp CTMP beating degree 42SR, outsourcing bleached sulphate softwood pulp mashing to 420SR, bleach sulfuric acid
Salt hardwood pulp is beaten to 340SR, wherein, the shells of 2.8kg/t slurries is added in NBKP and LBKP pulping process, during pulping respectively
Glycan.Above-mentioned four kinds of slurries are by 48% poplar machine plasma, 22% bleached sulphate softwood pulp, 22% BRATSK, 8%
The ratio of chemi-thermo-mechanical pulp carry out with slurry, mixing disposed slurry is deployed into the mixing slurry of concentration 3.6%, in mixing slurry, adds
Add 0.08 kg/t paper resin Pitch Control with Enzyme.Mixing slurry is sieved through underflow, adds starch enhancer during condiment, then rush slurry, remove
Sand degasification, starching, fine screen, the dehydration of upper net forming(Control online concentration 0.93%, pH value 8.3 of surfing the Net), squeezing, preceding drying, surface
Drying, press polish after coating, batch, packing forms the pure matter paper of dab.
In terms of coating, formulation for coating material is 5 parts of hollow ball pigment, 82 parts of coarse whiting pigment, 13 parts of china clay pigment, with paint
Total 100 parts, on the basis of pigment total amount, other coating chemicals are pressed:8 parts of polyvinyl acetate, 6 parts of styrene-butadiene latex, coating
6 parts of starch, 1.3 parts of nonionic calcium stearate, CMC(Sodium carboxymethylcellulose)0.2 part, 0.4 part of water repellent agent, defoamer 0.5
Part.Coating configuration concentration 67%, controlled using solid content by coating weight 17.5g/m2.
Through measuring:Quantitative 98g/m2, paper absorbency K&N values:40.5%, move mill coefficient of friction and be less than 0.32;Sheet gloss
Degree 5%, print gloss 37%;Surface strength 1.25m/s;Smoothness 48s;Bulk 1.23cm3/g;Fracture length 5360m;Paper
Color is white, whiteness 84.8%ISO.
Embodiment 3
Poplar raw material is by stock, using PRC-APMP(P represents the pretreatment before defibrination, represents the chemistry that mill promotes slurry
Effect, APMP represent APMP)Whiteness 75%ISO, beating degree 53 is made in pulping process0SR poplar machine plasmas,
Outsourcing chemi-thermo-mechanical pulp CTMP beating degree 41SR, outsourcing bleached sulphate softwood pulp mashing to 410SR, bleach sulfuric acid
Salt hardwood pulp is beaten to 310SR, wherein, the shells of 2.1kg/t slurries is added in NBKP and LBKP pulping process, during pulping respectively
Glycan.It is above-mentioned four kinds slurry by 50% poplar machine plasma, 20% bleached sulphate softwood pulp, 20% BRATSK,
The ratio of 10% chemi-thermo-mechanical pulp carries out with slurry, and mixing disposed slurry is deployed into the mixing slurry of concentration 3.5%, in mixing slurry,
Add 0.10kg/t paper resin Pitch Control with Enzyme.Mixing slurry is sieved through underflow, adds starch enhancer during condiment, then rush slurry,
Desanding degasification, starching, fine screen, the dehydration of upper net forming(Control online concentration 0.91%, pH value 8.1 of surfing the Net), squeezing, preceding drying, table
Face coating after drying, press polish, batch, packing forms the pure matter paper of dab.
In terms of coating, formulation for coating material is 4 parts of hollow ball pigment, 76 parts of coarse whiting pigment, 20 parts of china clay pigment, with paint
Total 100 parts, on the basis of pigment total amount, other coating chemicals are pressed:6 parts of polyvinyl acetate, 7 parts of styrene-butadiene latex, coating
10 parts of starch, 1.5 parts of nonionic calcium stearate, CMC(Sodium carboxymethylcellulose)0.15 part, 0.45 part of water repellent agent, defoamer
0.4 part.Coating configuration concentration 67.5%, controlled using solid content by coating weight 18g/m2.
Through measuring:Quantitative 70g/m2, paper absorbency K&N values:45.5%, move mill coefficient of friction 0.36;Sheet gloss degree
4%, print gloss 40%;Surface strength 1.28m/s;Smoothness 55s;Bulk 1.21cm3/g;Fracture length 5150m;Paper face
Color is white, whiteness 85.1%ISO.
Claims (2)
- A kind of 1. manufacture method of the pure matter paper of dab, with bleached sulphate softwood pulp NBKP, bleached sulphate leaf wood Chemical pulp LBKP, bleaching chemithermo mechanical pulp CTMP and alkaline hydrogen peroxide bleaching aspen mechanical slurry APMP enter as fibrous raw material Row with copying, product sieves through underflow, condiment, punching slurry, desanding degasification, starching, fine screen, wet end dehydration forming, squeezing, preceding drying, table Face coating, rear drying, press polish, batch, packing forms, it is characterised in that:(1)The bleached sulphate softwood pulp NBKP, bleached sulphate hardwood chemical pulp LBKP, bleaching chemithermo Mechanical pulp CTMP and alkaline hydrogen peroxide bleaching aspen mechanical slurry APMP weight proportion be:NBKP20~30%;LBKP 20~ 30%;APMP 40-60%;CTMP 5-10%, wherein, CTMP beating degrees 40-45SR, APMP beating degree 51-55SR;(2)Bleached sulphate softwood pulp NBKP is starched using chitosan auxiliary mashing, addition for 2-3kg/t;LBKP and NBKP increases to be controlled in 30-35SR, 40-45SR respectively using chitosan auxiliary mashing, beating degree;(3)Using resin Pitch Control with Enzyme, dosage 0.05-0.10kg/t paper, addition point is with stock tank;(4)In formulation for coating material, using the hollow ball plastic pigments of 3-5 parts;(5)In formulation for coating material, using the big particle diameter coarse whiting of 70-90 parts, coarse whiting particle diameter rank is 60-80 levels;(6)In formulation for coating material, using the sheet china clay of the big particle diameter of 10-20 parts, it is less than the particle overall control of 2 micron grain sizes In 78-84%;(7)In formulation for coating material, adhesive uses polyvinyl acetate and styrene-butadiene latex, wherein, polyvinyl acetate number is 4- 8, styrene-butadiene latex number is 4-8;In addition, relatively conventional coating paper simultaneously, improves coating starch dosage(6-10 parts);(8)In formulation for coating material, using nonionic calcium stearate, number is controlled in 0.5-1.5 parts.
- 2. the manufacture method of the pure matter paper of dab according to claim 1, it is characterised in that:Be made product major parameter be: Quantitative 60-100g/m2, paper absorbency K&N values:35-50%, move mill coefficient of friction and be less than 0.4;Sheet gloss degree:2-10%, print Brush glossiness:35-50%;Surface strength >=1.0m/s;Smoothness >=40s;Bulk >=1.2cm3/g;Fracture length >=5000m; Paper color is white, whiteness 84-86%ISO.
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CN201710596990.3A CN107338671A (en) | 2017-07-20 | 2017-07-20 | A kind of manufacture method of the pure matter paper of dab |
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CN201710596990.3A CN107338671A (en) | 2017-07-20 | 2017-07-20 | A kind of manufacture method of the pure matter paper of dab |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109457534A (en) * | 2018-11-13 | 2019-03-12 | 岳阳林纸股份有限公司 | A kind of this production method for using paper of book |
CN109680536A (en) * | 2019-03-05 | 2019-04-26 | 山东天阳纸业有限公司 | A kind of production method of light weight papers |
CN110244028A (en) * | 2019-05-23 | 2019-09-17 | 岳阳林纸股份有限公司 | A kind of method of quick detection beating degree |
CN112176753A (en) * | 2020-09-30 | 2021-01-05 | 江苏理文造纸有限公司 | Mild pulping process |
CN114108375A (en) * | 2021-10-11 | 2022-03-01 | 金东纸业(江苏)股份有限公司 | Light printing paper and preparation method thereof |
CN114507999A (en) * | 2022-01-28 | 2022-05-17 | 湛江晨鸣浆纸有限公司 | Coated white cardboard made of multiple fiber raw materials and production process thereof |
CN114541170A (en) * | 2022-02-24 | 2022-05-27 | 岳阳林纸股份有限公司 | Coating composition for papermaking, gravure light coated paper and manufacturing method thereof |
CN115613387A (en) * | 2022-11-11 | 2023-01-17 | 岳阳林纸股份有限公司 | Mark paper and manufacturing method thereof |
CN116876258A (en) * | 2023-08-18 | 2023-10-13 | 岳阳林纸股份有限公司 | DM single paper manufacturing method |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109457534A (en) * | 2018-11-13 | 2019-03-12 | 岳阳林纸股份有限公司 | A kind of this production method for using paper of book |
CN109680536A (en) * | 2019-03-05 | 2019-04-26 | 山东天阳纸业有限公司 | A kind of production method of light weight papers |
CN110244028A (en) * | 2019-05-23 | 2019-09-17 | 岳阳林纸股份有限公司 | A kind of method of quick detection beating degree |
CN112176753A (en) * | 2020-09-30 | 2021-01-05 | 江苏理文造纸有限公司 | Mild pulping process |
CN114108375A (en) * | 2021-10-11 | 2022-03-01 | 金东纸业(江苏)股份有限公司 | Light printing paper and preparation method thereof |
CN114507999A (en) * | 2022-01-28 | 2022-05-17 | 湛江晨鸣浆纸有限公司 | Coated white cardboard made of multiple fiber raw materials and production process thereof |
CN114507999B (en) * | 2022-01-28 | 2023-11-10 | 湛江晨鸣浆纸有限公司 | Coated white cardboard of various fiber raw materials and production process thereof |
CN114541170A (en) * | 2022-02-24 | 2022-05-27 | 岳阳林纸股份有限公司 | Coating composition for papermaking, gravure light coated paper and manufacturing method thereof |
CN115613387A (en) * | 2022-11-11 | 2023-01-17 | 岳阳林纸股份有限公司 | Mark paper and manufacturing method thereof |
CN115613387B (en) * | 2022-11-11 | 2023-11-28 | 岳阳林纸股份有限公司 | Mark paper and manufacturing method thereof |
CN116876258A (en) * | 2023-08-18 | 2023-10-13 | 岳阳林纸股份有限公司 | DM single paper manufacturing method |
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Application publication date: 20171110 |