CN107325340A - A kind of graphene graphene oxide cable - Google Patents

A kind of graphene graphene oxide cable Download PDF

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Publication number
CN107325340A
CN107325340A CN201710674085.5A CN201710674085A CN107325340A CN 107325340 A CN107325340 A CN 107325340A CN 201710674085 A CN201710674085 A CN 201710674085A CN 107325340 A CN107325340 A CN 107325340A
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CN
China
Prior art keywords
accounts
graphene oxide
account
graphene
cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710674085.5A
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Chinese (zh)
Inventor
宋薇
何朝政
王斌
付喆
王金龙
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Xinxiang University
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Xinxiang University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinxiang University filed Critical Xinxiang University
Priority to CN201710674085.5A priority Critical patent/CN107325340A/en
Publication of CN107325340A publication Critical patent/CN107325340A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of graphene graphene oxide cable, including graphene oxide, natural rubber, titanium nitride, EVA resin, sepiolite powder, polyethyleneglycol diacrylate, modified montmorillonoid, kaolin, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, ATBC, citrate and triphenyl phosphate.Compared with prior art, the present invention is made of Multiple components and special technique, and the cable being made has high flexibility and the characteristic of high conductivity, has a wide range of application, and utilizes popularization and popularization.

Description

A kind of graphene graphene oxide cable
Technical field
The present invention relates to field of material technology, more particularly to a kind of graphene graphene oxide cable.
Background technology
Graphene oxide is the oxide of graphene, and its color is brown color, and common product has powdered, piece on the market Shape and solution shape.After oxidized, oxygen-containing functional group increases and makes property more active compared with graphene thereon, can be via each Plant the reaction with oxygen-containing functional group and improve nature.In the prior art, the species of cable is various, in order to adapt to different works Plant, it is necessary to which constantly innovation is, it is necessary to which more cables are born.
The content of the invention
The purpose of the present invention is that provides a kind of graphene graphene oxide cable to solve the above problems.
The present invention is achieved through the following technical solutions above-mentioned purpose:
The present invention includes graphene oxide, natural rubber, titanium nitride, EVA resin, sepiolite powder, the propylene of polyethylene glycol two Acid esters, modified montmorillonoid, kaolin, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, the fourth of citric acid three Ester, citrate and triphenyl phosphate.
Specifically, by weight, every part accounts for the 30%, natural rubber containing the graphene oxide and accounts for the 20%, nitrogen Change titanium account for the 5%, EVA resin account for the 5%, sepiolite powder account for the 5%, polyethyleneglycol diacrylate account for 5%, it is described Modified montmorillonoid, which accounts for the 5%, kaolin and accounts for the 2%, diisononyl phthalate and account for the 2%, methoxy ethylene, to be accounted for 2%th, the antioxidant account for the 2%, vaseline account for the 2%, ATBC account for the 5%, citrate account for 5%, The triphenyl phosphate accounts for 5%.
Preparation method of the present invention is as follows:
(1) graphene oxide is placed in container, adds natural rubber, be heated to 220-240 degree;Stir graphene oxide And natural rubber, titanium nitride, EVA resin, sepiolite powder and polyethyleneglycol diacrylate are added in whipping process;
(2) mixing speed is set as after 2500-2800rpm mixing speed stirring 4h, adds modified montmorillonoid, height Ridge soil, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, ATBC, citrate and phosphoric acid Triphenylmethyl methacrylate is stirred with 2000-2300rpm mixing speed;
(3) move in water-bath and cool, water-bath pot temperature is kept to 40 DEG C, then the mixture after cooling is inserted into extrusion Cable is made in machine.
The beneficial effects of the present invention are:
The present invention is a kind of graphene graphene oxide cable, compared with prior art, the present invention using Multiple components and Special technique is made, and the cable being made has high flexibility and the characteristic of high conductivity, has a wide range of application, using popularizing and push away Extensively.
Embodiment
The invention will be further described below:
The present invention includes graphene oxide, natural rubber, titanium nitride, EVA resin, sepiolite powder, the propylene of polyethylene glycol two Acid esters, modified montmorillonoid, kaolin, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, the fourth of citric acid three Ester, citrate and triphenyl phosphate.
Specifically, by weight, every part accounts for the 30%, natural rubber containing the graphene oxide and accounts for the 20%, nitrogen Change titanium account for the 5%, EVA resin account for the 5%, sepiolite powder account for the 5%, polyethyleneglycol diacrylate account for 5%, it is described Modified montmorillonoid, which accounts for the 5%, kaolin and accounts for the 2%, diisononyl phthalate and account for the 2%, methoxy ethylene, to be accounted for 2%th, the antioxidant account for the 2%, vaseline account for the 2%, ATBC account for the 5%, citrate account for 5%, The triphenyl phosphate accounts for 5%.
Preparation method of the present invention is as follows:
(1) graphene oxide is placed in container, adds natural rubber, be heated to 220-240 degree;Stir graphene oxide And natural rubber, titanium nitride, EVA resin, sepiolite powder and polyethyleneglycol diacrylate are added in whipping process;
(2) mixing speed is set as after 2500-2800rpm mixing speed stirring 4h, adds modified montmorillonoid, height Ridge soil, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, ATBC, citrate and phosphoric acid Triphenylmethyl methacrylate is stirred with 2000-2300rpm mixing speed;
(3) move in water-bath and cool, water-bath pot temperature is kept to 40 DEG C, then the mixture after cooling is inserted into extrusion Cable is made in machine.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

1. a kind of graphene graphene oxide cable, it is characterised in that:Including graphene oxide, natural rubber, titanium nitride, EVA Resin, sepiolite powder, polyethyleneglycol diacrylate, modified montmorillonoid, kaolin, diisononyl phthalate, vinyl Methyl ether, antioxidant, vaseline, ATBC, citrate and triphenyl phosphate.
2. graphene graphene oxide cable according to claim 1, it is characterised in that:By weight, every part contains described Graphene oxide, which accounts for the 30%, natural rubber and accounts for the 20%, titanium nitride and account for the 5%, EVA resin, accounts for the 5%, Hai Pao Stone flour, which accounts for the 5%, polyethyleneglycol diacrylate and accounts for the 5%, modified montmorillonoid and account for the 5%, kaolin, accounts for 2%, institute State diisononyl phthalate and account for the 2%, methoxy ethylene and account for the 2%, antioxidant and account for the 2%, vaseline and account for 2%th, the ATBC, which accounts for the 5%, citrate and accounts for the 5%, triphenyl phosphate, accounts for 5%.
3. graphene graphene oxide cable according to claim 1, it is characterised in that preparation method is as follows:
(1) graphene oxide is placed in container, adds natural rubber, be heated to 220-240 degree;Stir graphene oxide and day Right rubber, adds titanium nitride, EVA resin, sepiolite powder and polyethyleneglycol diacrylate in whipping process;
(2) mixing speed is set as after 2500-2800rpm mixing speed stirring 4h, adds modified montmorillonoid, kaolinite Soil, diisononyl phthalate, methoxy ethylene, antioxidant, vaseline, ATBC, citrate and tricresyl phosphate Phenyl ester is stirred with 2000-2300rpm mixing speed;
(3) move in water-bath and cool, water-bath pot temperature is kept to 40 DEG C, then the mixture after cooling is inserted in extruder Cable is made.
CN201710674085.5A 2017-08-09 2017-08-09 A kind of graphene graphene oxide cable Pending CN107325340A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710674085.5A CN107325340A (en) 2017-08-09 2017-08-09 A kind of graphene graphene oxide cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710674085.5A CN107325340A (en) 2017-08-09 2017-08-09 A kind of graphene graphene oxide cable

Publications (1)

Publication Number Publication Date
CN107325340A true CN107325340A (en) 2017-11-07

Family

ID=60198947

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710674085.5A Pending CN107325340A (en) 2017-08-09 2017-08-09 A kind of graphene graphene oxide cable

Country Status (1)

Country Link
CN (1) CN107325340A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980599A (en) * 2014-05-30 2014-08-13 江苏德威新材料股份有限公司 Semiconductive shielding material for high-voltage direct-current cables and preparation method thereof
CN103992577A (en) * 2014-04-25 2014-08-20 安徽华鸿电气股份有限公司 Cable material containing graphene
CN104211999A (en) * 2014-09-22 2014-12-17 安徽电气集团股份有限公司 Modified graphene cable material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103992577A (en) * 2014-04-25 2014-08-20 安徽华鸿电气股份有限公司 Cable material containing graphene
CN103980599A (en) * 2014-05-30 2014-08-13 江苏德威新材料股份有限公司 Semiconductive shielding material for high-voltage direct-current cables and preparation method thereof
CN104211999A (en) * 2014-09-22 2014-12-17 安徽电气集团股份有限公司 Modified graphene cable material

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Application publication date: 20171107