CN107312311A - Automotive upholstery flame retardant plastics - Google Patents
Automotive upholstery flame retardant plastics Download PDFInfo
- Publication number
- CN107312311A CN107312311A CN201710731895.XA CN201710731895A CN107312311A CN 107312311 A CN107312311 A CN 107312311A CN 201710731895 A CN201710731895 A CN 201710731895A CN 107312311 A CN107312311 A CN 107312311A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- automotive upholstery
- compatilizer
- retardant plastics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of automotive upholstery flame retardant plastics, it is related to chemical material technical field, it is made up of the raw material of following masses part：45~55 parts of makrolon, 15~25 parts of siloxanes, 10~15 parts of APP, 6~8 parts of polycaprolactam, 5~7 parts of aluminium hydroxide, 3~4 parts of borax, compatilizer 1 ~ 3.The present invention solves the problem of automotive upholstery plastic flame performance is not good.
Description
Technical field
The present invention relates to chemical material technical field, especially a kind of automotive upholstery flame retardant plastics.
Background technology
Automotive upholstery generally refers to dividing plate, door trim panel, panel assembly, handrail, carpet of automobile bodies etc. zero
Part and material.The material of automotive upholstery typically has leather-like, Plastic, rubber-like, composite class, and these materials belong to
Inflammable or combustible material, if without certain anti-flammability, once vehicle fire, will result in than after more serious
Really, thus the fire resistance of automotive upholstery directly affects the security performance of vehicle.It is growing with plastics industry, with
And the features such as plastic processing good, light weight, long lifespan, easy cleaning, plastics is become the preferred material of automotive upholstery.It is existing
The plastics for being used to manufacture automotive upholstery having are mainly PU plastics or ABS engineering plastics, the elasticity of PU plastics, wearability and resistance to
Time property is good, and ABS engineering plastics have excellent combination property, there is fabulous impact strength, good stability of the dimension, wearability, into
Type is processed and machining is preferable, still, and the PU plastics of current automotive upholstery or the fire resistance of ABS engineering plastics are all
It is not good.
The content of the invention
It is an object of the invention to provide a kind of automotive upholstery flame retardant plastics, this automotive upholstery flame retardant plastics can
To solve the problem of automotive upholstery plastic flame performance is not good.
In order to solve the above problems, the technical solution adopted by the present invention is：This automotive upholstery flame retardant plastics is under
The raw material of row mass parts is made：45~55 parts of makrolon, 15~25 parts of siloxanes, 10~15 parts of APP, polycaprolactam
6~8 parts of amine, 5~7 parts of aluminium hydroxide, 3~4 parts of borax, compatilizer 1 ~ 3.
In the technical scheme of above-mentioned automotive upholstery flame retardant plastics, more specifically technical scheme can also be：Poly- carbonic acid
48 parts of ester, 18.5 parts of siloxanes, 12 parts of APP, 6.5 parts of polycaprolactam, 5.8 parts of aluminium hydroxide, 3.2 parts of borax is compatible
Agent 1.2.
Further, 52 parts of makrolon, 23 parts of siloxanes, 14 parts of APP, 7.4 parts of polycaprolactam, hydroxide
6.5 parts of aluminium, 3.6 parts of borax, compatilizer 2.5.
Further, compatilizer is maleic anhydride compatilizer.
By adopting the above-described technical solution, the present invention has the advantages that compared with prior art：
1st, siloxanes can improve the heat resistance, mechanical performance and processing characteristics of makrolon, its have anti-molten drop, suppression cigarette and
Ecological friendly advantage, with aluminium hydroxide synergetic flame retardant, oxidation resistance is strong；APP thermally decomposes generation gas in advance, with dilute
The concentration of oxygen release, polycaprolactam plays carbon forming agent, participates in pyrolysis and promotes partially carbonized；Borax has 10 points
The crystallization water of son, it is inhibited the temperature rising of material by discharging the crystallization water come draw heat because of its heat absorption,
So as to produce flame retardant effect；Flame retardant rating reaches V0, and flame retardant effect is excellent.
Embodiment
With reference to embodiment, the invention will be further described：
Embodiment 1
The automotive upholstery of the present embodiment is made up with flame retardant plastics of the raw material of following masses part：45 parts of makrolon, siloxanes
15 parts, 15 parts of APP, 6 parts of polycaprolactam, 5 parts of aluminium hydroxide, 3 parts of borax, compatilizer 1, wherein, compatilizer is Malaysia
Acid anhydrides compatilizer.
During making, batch mixer is preheated to 60 DEG C, makrolon, siloxanes, APP, polycaprolactam is proportionally added into
Amine, aluminium hydroxide, borax and compatilizer are well mixed, then heat to 135 DEG C, and 15min is stirred with 160rpm speed, in drop
Temperature naturally cools to room temperature to discharging after 45 DEG C；The mixed material of cooling is added in screw extruder, at 160~190 DEG C
Under the conditions of extruding pelletization.
The performance data test of the automotive upholstery flame retardant plastics of the present embodiment is as follows：UL-94 flame retardant ratings are V0, oxygen
Index LOI is 30.2%, and smoke density is 958 ㎡/㎏.
Embodiment 2
The automotive upholstery of the present embodiment is made up with flame retardant plastics of the raw material of following masses part：48 parts of makrolon, siloxanes
18.5 parts, 12 parts of APP, 6.5 parts of polycaprolactam, 5.8 parts of aluminium hydroxide, 3.2 parts of borax, compatilizer 1.2, wherein, phase
Appearance agent is maleic anhydride compatilizer.
During making, batch mixer is preheated to 65 DEG C, makrolon, siloxanes, APP, polycaprolactam is proportionally added into
Amine, aluminium hydroxide, borax and compatilizer are well mixed, then heat to 140 DEG C, and 12min is stirred with 220rpm speed, in drop
Temperature naturally cools to room temperature to discharging after 40 DEG C；The mixed material of cooling is added in screw extruder, at 180~210 DEG C
Under the conditions of extruding pelletization.
The performance data test of the automotive upholstery flame retardant plastics of the present embodiment is as follows：UL-94 flame retardant ratings are V0, oxygen
Index LOI is 34.6%, and smoke density is 912 ㎡/㎏.
Embodiment 3
The automotive upholstery of the present embodiment is made up with flame retardant plastics of the raw material of following masses part：Makrolon makrolon 52
Part, 23 parts of siloxanes, 14 parts of APP, 7.4 parts of polycaprolactam, 6.5 parts of aluminium hydroxide, 3.6 parts of borax, compatilizer 2.5,
Wherein, compatilizer is maleic anhydride compatilizer.
During making, batch mixer is preheated to 68 DEG C, makrolon, siloxanes, APP, polycaprolactam is proportionally added into
Amine, aluminium hydroxide, borax and compatilizer are well mixed, then heat to 142 DEG C, and 10min is stirred with 230rpm speed, in drop
Temperature naturally cools to room temperature to discharging after 45 DEG C；The mixed material of cooling is added in screw extruder, at 170~200 DEG C
Under the conditions of extruding pelletization.
The performance data test of the automotive upholstery flame retardant plastics of the present embodiment is as follows：UL-94 flame retardant ratings are V0, oxygen
Index LOI is 33.8%, and smoke density is 921 ㎡/㎏.
Embodiment 4
The automotive upholstery of the present embodiment is made up with flame retardant plastics of the raw material of following masses part：55 parts of makrolon, siloxanes
25 parts, 10 parts of APP, 8 parts of polycaprolactam, 7 parts of aluminium hydroxide, 4 parts of borax, compatilizer 3, wherein, compatilizer is Malaysia
Acid anhydrides compatilizer.
During making, batch mixer is preheated to 62 DEG C, makrolon, siloxanes, APP, polycaprolactam is proportionally added into
Amine, aluminium hydroxide, borax and compatilizer are well mixed, then heat to 150 DEG C, and 15min is stirred with 160rpm speed, in drop
Temperature naturally cools to room temperature to discharging after 45 DEG C；The mixed material of cooling is added in screw extruder, at 190~220 DEG C
Under the conditions of extruding pelletization.
The performance data test of the automotive upholstery flame retardant plastics of the present embodiment is as follows：UL-94 flame retardant ratings are V0, oxygen
Index LOI is 31.1%, and smoke density is 943 ㎡/㎏.
Claims (4)
1. a kind of automotive upholstery flame retardant plastics, it is characterised in that be made up of the raw material of following masses part：Makrolon 45~
55 parts, 15~25 parts of siloxanes, 10~15 parts of APP, 6~8 parts of polycaprolactam, 5~7 parts of aluminium hydroxide, borax 3~4
Part, compatilizer 1 ~ 3.
2. automotive upholstery flame retardant plastics according to claim 1, it is characterised in that by the raw material system of following masses part
Into：48 parts of makrolon, 18.5 parts of siloxanes, 12 parts of APP, 6.5 parts of polycaprolactam, 5.8 parts of aluminium hydroxide, borax
3.2 parts, compatilizer 1.2.
3. automotive upholstery flame retardant plastics according to claim 1, it is characterised in that by the raw material system of following masses part
Into：52 parts of makrolon, 23 parts of siloxanes, 14 parts of APP, 7.4 parts of polycaprolactam, 6.5 parts of aluminium hydroxide, borax 3.6
Part, compatilizer 2.5.
4. the automotive upholstery flame retardant plastics according to claim 1 or 2 or 3, it is characterised in that：Compatilizer is maleic acid
Acid anhydride compatilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710731895.XA CN107312311A (en) | 2017-08-23 | 2017-08-23 | Automotive upholstery flame retardant plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710731895.XA CN107312311A (en) | 2017-08-23 | 2017-08-23 | Automotive upholstery flame retardant plastics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107312311A true CN107312311A (en) | 2017-11-03 |
Family
ID=60177010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710731895.XA Withdrawn CN107312311A (en) | 2017-08-23 | 2017-08-23 | Automotive upholstery flame retardant plastics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107312311A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102669A (en) * | 2013-01-25 | 2013-05-15 | 上海俊尔新材料有限公司 | Thermal-resistant light-smoke halogen-free flame-retardant PC/ABS alloy material and preparation method thereof |
| CN106009585A (en) * | 2016-05-28 | 2016-10-12 | 慈溪市法莱新塑料厂 | Halogen-free flame retardation polycarbonate material and preparation method thereof |
| CN107011644A (en) * | 2017-04-09 | 2017-08-04 | 福建华塑新材料有限公司 | A kind of polysiloxane polycarbonate copolymeric material and preparation method thereof |
-
2017
- 2017-08-23 CN CN201710731895.XA patent/CN107312311A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102669A (en) * | 2013-01-25 | 2013-05-15 | 上海俊尔新材料有限公司 | Thermal-resistant light-smoke halogen-free flame-retardant PC/ABS alloy material and preparation method thereof |
| CN106009585A (en) * | 2016-05-28 | 2016-10-12 | 慈溪市法莱新塑料厂 | Halogen-free flame retardation polycarbonate material and preparation method thereof |
| CN107011644A (en) * | 2017-04-09 | 2017-08-04 | 福建华塑新材料有限公司 | A kind of polysiloxane polycarbonate copolymeric material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103756135B (en) | A kind of Environment-friendlyflame flame retardant low-odor modified polypropene and its preparation method and application | |
| CN102153820B (en) | Preparation method of flame retarding styrene polymer composite material | |
| CN111205617A (en) | Polycarbonate composition and preparation method thereof | |
| CN105176028A (en) | Ultraviolet and aging resisting composite material for automotive upholstery and a preparing method composite material | |
| CN105176027A (en) | Low-VOC environmentally-friendly high-quality automobile interior trim part material and preparation method thereof | |
| CN110713657B (en) | Polypropylene composite flame-retardant material for vehicle interior trim and preparation method and application thereof | |
| CN103342880B (en) | A kind of high finish surface environment friendly halogen-free fireproof PBT composite and preparation method thereof | |
| CN105219043A (en) | A kind of novel poly(lactic acid) bastose composite environmental-friendly material for car interior trim parts and preparation method thereof | |
| CN105440615A (en) | Ageing-resistant polylactic acid fiber composite automotive upholstery material and preparation method thereof | |
| CN110016209A (en) | A kind of GWIT850 DEG C of enhancing flame-retardant PBT and its preparation method and application | |
| CN109206877A (en) | A kind of low smoke density, high oxygen index (OI), the automobile-used fire retardation PC/ABS composite material of low smell and preparation method thereof | |
| CN105440614A (en) | Basalt fiber-reinforced modified composite polylactic acid auto-interior decorative material and preparation method thereof | |
| CN103740038A (en) | High-glossiness halogen-free flame-retardant ABS material and preparation method thereof | |
| CN105219042A (en) | A kind of enhancement type composite automobile inner decoratire part material adding bamboo powder and preparation method thereof | |
| CN104945876A (en) | Low-smoke density PC/ABS polymer composite and preparation method thereof | |
| KR101772761B1 (en) | Flame retardant master batch of expanded polystyrene with enhanced cell uniformity and flame-resistance, and a method of the manufacturing | |
| CN112080074B (en) | Flame-retardant polypropylene composition and preparation method and application thereof | |
| CN107312311A (en) | Automotive upholstery flame retardant plastics | |
| CN102757617A (en) | High-toughness ABS (Acrylonitrile Butadiene Styrene) flame retardant material and preparation method thereof | |
| CN102061072A (en) | Environment-friendly halogen-free non-phosphorus flame-retardant polycarbonate resin composition | |
| CN103756276A (en) | Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof | |
| CN105482392A (en) | Polylactic acid fiber composite degradable material for automotive interior decoration and preparation method thereof | |
| CN105176026A (en) | Scratching-proof polylactic acid composite automotive upholstery material and preparing method thereof | |
| CN104558832A (en) | Flame-retardant polypropylene material containing char-forming agent and preparation method thereof | |
| CN104004269A (en) | Foaming enhancement halogen-free flame retardant polypropylene and preparation method of foaming enhancement halogen-free flame retardant polypropylene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171103 |